首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
We experimentally examined the effects of increased temperature on growth and demography of two Mediterranean seagrasses Posidonia oceanica and Cymodocea nodosa. Shoots of C. nodosa and seedlings and shoots of P. oceanica were kept in mesocosms for 3?months and exposed to temperatures between 25 and 32?°C encompassing the range of maximum summer seawater temperatures projected for the Mediterranean Sea during the twenty-first century. The response of P. oceanica seedlings to warming was evident with reduced growth rates, leaf formation rates and leaf biomass per shoot. Younger life stages of P. oceanica may therefore be particularly vulnerable to climate change and warming. Leaf formation rates in the shoots of P. oceanica declined with increasing temperature and the lowest population growth (?0.005?day?1) was found at 32?°C. Temperature effects on C. nodosa were variable. Rhizome growth increased with warming (0.07?C0.09?cm?day?1?°C of warming), whereas other indicators of plant performance (aboveground/belowground biomass, leaf biomass and population growth) appeared to be stimulated by increased temperature to a threshold temperature of around 29?C30?°C beyond which they declined. P. oceanica and C. nodosa are likely to be negatively impacted by the effects of global warming over the next century and climate change poses a significant challenge to seagrasses and may stress these key habitat-forming species that are already suffering losses from anthropogenic impacts.  相似文献   

2.
Seasonal temperature patterns may have changed through time in response to current global warming. However, the temporal resolution of available proxy records is not sufficient to quantify paleotemperature seasonality prior to anthropogenic forcing of the climate. In the present study, we reconstructed seasonal and inter-annual temperature patterns of the North Sea during the last 140 years, the Allerød Interglacial and the Late Medieval Climate Optimum using sclerochronological and δ18Oaragonite data from bivalve shells, Arctica islandica. On average, the climate during 1278–1353 AD was ca. 1.1°C colder and seasonality was ca. 60% less than today. During the Allerød, long-term temperatures remained about 3.2°C below present values, and absolute summer and winter anomalies were ca. ?4 and ?2.7°C, respectively. However, seasonality was statistically indistinguishable from today. Long-term average temperatures compare well with existing data for the Late Medieval and Allerød, but detailed information on seasonality during the studied time intervals has never been presented before. Our data also demonstrated that annual instrumental and δ18Oaragonite-derived temperatures did not always match. This difference is explained by (1) NAO-driven salinity changes, which influence the temperature estimation from δ18Oaragonite and (2) food-driven changes in growth rates; portions of the shell that formed more rapidly are overrepresented in carbonate samples. Our study indicated that individual bivalve shells can open discrete, near-century long, ultra-high-resolution windows into the climate past. Such information can be vital for testing and verifying numerical climate models.  相似文献   

3.
Hypoxia is emerging as a major threat to marine coastal biota. Predicting its occurrence and elucidating the driving factors are essential to set successful management targets to avoid its occurrence. This study aims to elucidate the effects of warming on the likelihood of hypoxia. High-frequency dissolved oxygen measurements have been used to estimate gross primary production (GPP), net ecosystem production (NEP) and community respiration (CR) in a shallow macroalgae (Caulerpa prolifera) ecosystem in a highly human-influenced closed Mediterranean bay. Daily averaged GPP and CR ranged from 0 to 1,240.9 and 51.4 to 1,297.3?mmol?O2?m?2?day?1, respectively. The higher GPP and CR were calculated for the same day, when daily averaged water temperature was 28.3?°C, and resulted in a negative NEP of ?56.4?mmol?O2?m?2?day?1. The ecosystem was net heterotrophic during the studied period, probably subsidized by allochthonous organic inputs from ground waters and from the surrounding town and boating activity. Oxygen dynamics and metabolic rates strongly depend on water temperature, with lower oxygen content at higher temperatures. The probability of hypoxic conditions increased at a rate of 0.39?% °C?1 (±0.14?% °C?1). Global warming will increase the likelihood of hypoxia in the bay studied, as well as in other semi-enclosed bays.  相似文献   

4.
The objective of the present study was to reconstruct a short-term (12–14 years) trend of surface temperature and precipitation patterns using their surrogates as provided by satellite images for selected locations along the Red Sea mountains in Saudi Arabia. Time series land surface temperature (LST) and normalized difference vegetation index (NDVI) data acquired from the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite were temporally plotted to delineate the trend and the decadal rates of change of both parameters. Results showed that real climate change is reported in the study area during the study period. There is a net increasing in the surface temperatures by 0.45 to 1.2 °C/decade and a net decrease in annual rainfall between 2001 and 2014. Findings of the present study show that the region is under a warming of the climate and a declining of wetness, which coincide with the air temperature and rainfall trends obtained from meteorological stations.  相似文献   

5.
Holocene cooling events have been reconstructed for the southern Adriatic Sea (central Mediterranean) by means of analyses of organic walled dinoflagellate cysts, planktonic foraminifera, oxygen isotopes, calcareous nanoplankton, alkenones and pollen from a sediment core. Two cooling events have been detected, during which sea‐surface temperatures (SSTs) were ca. 2°C lower. Unravelling the SST signal into dominant seasonal components suggests maximum winter cooling of 2°C at around 6.0 ka, whereas the cooling at ca. 3.0 ka might be the result of a spring temperature cooling of 2–3°C. The events, lasting several hundred years, are apparently synchronous with those in the Aegean Sea, where they have been related to known cooling events from the Greenland ice‐core record. A distinct interruption in Adriatic Sea sapropel S1 is not clearly accompanied by a local drop in winter temperatures, but seems to be forced by ventilation, which probably occurred earlier in the Aegean Sea and was subsequently transmitted to the Adriatic Sea. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

6.
Future variability of droughts in three Mediterranean catchments   总被引：3，自引：3，他引：0  
Lopez-Bustins  Joan A.  Pascual  Diana  Pla  Eduard  Retana  Javier 《Natural Hazards》2013,66(3):1405-1429
This study investigates the intensity change in typhoons and storm surges surrounding the Korean Peninsula under global warming conditions as obtained from the MPI_ECHAM5 climate model using the A1B series. The authors use the Cyclostationary Empirical Orthogonal Function to estimate future background fields for typhoon simulations from twenty-first-century prediction results. A series of numerical experiments applies WRF (Weather Research and Forecasting) and POM (Prinston Ocean Model) models to simulate two historical typhoons, Maemi (2003) and Rusa (2002), and associated storm surges under real historical and future warming conditions. Applying numerical experiments to two typhoons, this study found that their central pressure dropped about 19 and 17 hPa, respectively, when considering the future sea surface temperature (a warming of 3.9 °C for 100 years) over the East China Sea (Exp. 1). The associated enhancement of storm surge height ranged from 16 to 67 cm along the southern coast of the Korean Peninsula. However, when the study considered global warming conditions for other atmospheric variables such as sea-level pressure, air temperature, relative humidity, geopotential height, and wind in the typhoon simulations (Exp. 2), the intensities of the two typhoons and their associated surge heights scarcely increased compared to the results of Exp. 1. Analyzing projected atmospheric variables, the authors found that air temperatures at the top of the storm around 200 hPa increased more than those at the surface in tropical and mid-latitudes. The reduced vertical temperature difference provided an unfavorable condition in the typhoon’s development even under conditions of global warming. This suggests that global warming may not always correlate with a large increase in the number of intense cyclones and/or an increase in associated storm surges.  相似文献   

7.
The comparison between the first results of comprehensive micropaleontological analysis (pollen, spores, foraminifera, and ostracods) and those of radiocarbon dating (AMS14C) for the sediments of the eastern inner shelf of the Laptev Sea (the core collected from depth of 37 m) indicates that considerable changes in natural conditions in the sea and on land coincide in time and refer to the time period of 1500–1700 years B.P. This period is characterized by changes in microfossils: appearance of thermophilic pollen and planktonic foraminifera and increase in total number of benthic foraminifera and ostracods. Intense warming and humidification of the climate reconstructed for this 200-year period promoted the expansion of large-shrub tundra. Summer air temperatures were lower than that in the peak mid-Holocene climatic optimum by 2°–3°C, but 1°C higher than the present-day temperature. An estuary freshwater basin developed: it was strongly affected by river discharge, but North Atlantic waters also intensely penetrated here in short-term intervals. In general, the studied microfossil complex reflects the relatively stable environmental conditions and decrease in seawater salinity in the eastern part of the Laptev Sea shelf during the last 2300 years.  相似文献   

8.
The mean sea surface temperature anomalies (SSTA) of the Mediterranean Sea during the past 150 years (1856–2000) are analysed. The first empirical orthogonal function (EOF) of the covariance matrix of the SSTA explains more than 45% of the variance, suggesting that the temporal variation of the Mediterranean Sea is largely in phase over the whole basin. The mean variability of Mediterranean SSTA from 1856 to 2000 superposes a main irregular oscillation (period of 60–70 years and mean amplitude of 0.4–0.5 °C) and a weak long-term positive trend (equivalent to an increase of +0.1 °C per century). The last warm phase, which is strongest in the western basin, is not warmer than the decade 1935–1945 or the ending part of the 1960s. The mean temporal evolution of the North Hemisphere is close to the variation of the Mediterranean Sea, except that the long-term increase is more intense in the North Hemisphere. To cite this article: V. Moron, C. R. Geoscience 335 (2003).  相似文献   

9.
Methane is one of the potential greenhouse gases contributing to global climate change, with a global warming potential of about 25 times than that of carbon dioxide. Aerobic methane oxidation (methanotrophy) is the key process that counteracts emission of methane to atmosphere. In this study, methane oxidation capacity of different methane-oxidizing bacteria (methanotrophs) isolated from six different ecosystems was investigated. Methanotrophic consortium isolated from dumpsite proved to be most effective in oxidizing methane. Initially, methane oxidation rate was found to be 0.72 ± 0.036 mM/day; in course of the study consortium M5 showed an increase in methane oxidation rate up to 1.7 ± 0.016 mM/day. A maximum of 0.78 mol of CO2 production was found during methane oxidation in methanotrophs from dumpsite (M5). While varying temperatures, methane oxidation rate was in the range of 1.3–1.7 mM/day which has been found in the temperature range of 30–40 °C. Even at higher temperature (50 °C), 0.076 ± 0.14 mM of the methane was utilized per day. Methane oxidation was assessed by Michaelis–Menten kinetics. By varying the methane concentration, methane oxidation was studied and kinetic parameters such as V max and K m were derived using Lineweaver–Burk plot and found to be 1.497 mM/day and 2.23 mM, respectively. In methane mitigation approach, Methane soil sink is very essential because a balance between methane production by methanogens and consumption by methanotrophs plays an important role in methane emission reduction. Enhancing the methane soil sink will be a cost-effective method to cut down methane emission.  相似文献   

10.
Surface air temperature is one of the main factors that can be used to denote climate change. Its variation in the westerly and monsoon-influenced part of China (i.e., North-West and East China) were analyzed by using monthly data during 1961–2006 from 139 and 375 meteorological stations over these two regions, respectively. The method of trend coefficient and variability was utilized to study the consistency and discrepancy of temperature change over North-West and East China. The results suggest that whether for the annual or the seasonal mean variations of temperature, there were consistent striking warming trends based on the background of global warming over North-West and East China. The most obvious warming trends all appeared in winter over the two regions. Except for the period in spring, the annual and seasonal mean warming trends in North-West China are more obvious than those in East China. The annual mean temperature warming rates are 0.34°C per decade and 0.22°C per decade over North-West and East China, respectively. The average seasonal increasing rates in spring, summer, autumn, and winter are 0.22°C per decade, 0.24°C per decade, 0.35°C per decade, and 0.55°C per decade in North-West China, respectively. At the same time, they are 0.25°C per decade, 0.11°C per decade, 0.22°C per decade, and 0.39°C per decade in East China, respectively. The temperature discrepancies of two adjacent decades are positive over the westerlies and monsoonal region, and they are bigger in the westerlies region than those in the monsoonal region. The most significant warming rate is from the North-East Xinjiang Uygur Autonomous Region of China to West Qinghai Province of China in all seasons and annually over the westerlies region. The North and North-East China are the main prominent warming areas over the monsoonal region. The warming rate increases with latitude in the monsoonal region, but this is not the case in the westerlies region.  相似文献   

11.
Perennial ice covers on many Antarctic lakes have resulted in high lake inorganic carbon contents. The objective of this paper was to evaluate and compare the brine and CO2 chemistries of Lake Vida (Victoria Valley) and West Lake Bonney (Taylor Valley), two lakes of the McMurdo Dry Valleys (East Antarctica), and their potential consequences during global warming. An existing geochemical model (FREZCHEM-15) was used to convert measured molarity into molality needed for the FREZCHEM model, and this model added a new algorithm that converts measured DIC into carbonate alkalinity needed for the FREZCHEM model. While quite extensive geochemical information exists for ice-covered Taylor Valley lakes, such as West Lake Bonney, only limited information exists for the recently sampled brine of >25 m ice-thick Lake Vida. Lake Vida brine had a model-calculated pCO2 = 0.60 bars at the field pH (6.20); West Lake Bonney had a model-calculated pCO2 = 5.23 bars at the field pH (5.46). Despite the high degree of atmospheric CO2 supersaturation in West Lake Bonney, it remains significantly undersaturated with the gas hydrate, CO2·6H2O, unless these gas hydrates are deep in the sediment layer or are metastable having formed under colder temperatures or greater pressures. Because of lower temperatures, Lake Vida could start forming CO2·6H2O at lower pCO2 values than West Lake Bonney; but both lakes are significantly undersaturated with the gas hydrate, CO2·6H2O. For both lakes, simulation of global warming from current subzero temperatures (?13.4 °C in Lake Vida and ?4.7 °C in West Lake Bonney) to 10 °C has shown that a major loss of solution-phase carbon as CO2 gases and carbonate minerals occurred when the temperatures rose above 0 °C and perennial ice covers would disappear. How important these Antarctic CO2 sources will be for future global warming remains to be seen. But a recent paper has shown that methane increased in atmospheric concentration due to deglaciation about 10,000 years ago. So, CO2 release from ice lakes might contribute to atmospheric gases in the future.  相似文献   

12.
A vertical two-dimensional, laterally averaged hydrodynamic and water quality model CE-QUAL-W2 was used to simulate water temperature, dissolved oxygen, electrical conductivity, chlorophyll a, total suspended solids, alkalinity, ammonium, phosphate, and total iron in the Sejnane Dam (North Tunisia) in response to external forcings that characterize main features of climate in the southern side of the Mediterranean Sea. The hydrodynamic modelling results show that the model is able to reproduce accurately the measured water surface elevation, spatio-temporal patterns of temperature, dissolved oxygen and other state of variables and to capture most of the seasonal changes in the reservoir. Three scenarios involving the impacts of severe drought season, summer rainfall and total suspended solids load on hydrodynamics and water quality are analyzed. Severe drought reduces the thickness of hypoxic waters from 10 to 2–4 m and shifts the temperature of the entire water column up to 5 °C during summer and about 1.2 °C in winter. The thermocline takes place 1 month before that of the reference and sinks to the bottom faster by 1–2 m per month. Summer rainfall dilutes the first waves of the autumn rains and disrupts the thermal gradient in the water column, which may show complex thermal structures. TSS load has the most negative effects on water quality in that it shifts the phosphorus concentration by 1–3 mg/l and promotes an early warming of surface water in spring and an early cooling since late summer by up to 1 °C. During summer stratification, it contributes to the cooling of the metalimnion by 2 °C on average, which may alter its structure and dynamics as an aquatic biotope.  相似文献   

13.
Climate dynamics during the past ca. 700 years in southern Finland were reconstructed using fossil midge (Diptera:Nematocera) assemblages aiming to estimate quantitatively the temperature change that has occurred from the Little Ice Age to the present. Midge stratigraphies of two sediment cores from eastern and southern Finland were chosen to be examined for temperature inferences utilizing the modern analogue technique. The new midge-based temperature inference model had a coefficient of determination of 0.901 and a prediction error of 0.498 °C, showing improvement over the previous Finnish models. The combined curve of the inferred temperatures derived from both of the cores showed a decrease towards ca. 1700 AD, when temperatures were approximately 1 °C cooler than the past 700 years average and almost 2 °C colder than present. The temperatures began to increase in southern Finland from 1800 AD and in eastern Finland from 1900 AD onwards. The highest temperatures were reached at the top of the core, representing the present climate warming. Although there was slight overestimation in the recent inferred values, the reconstructed trends were in close correspondence with the previous proxy-based, historical, and measured data that suggests that the reconstruction was realistic and reliable.  相似文献   

14.
This study was conducted to reveal the trends of the air temperature and soil temperature for 51 years (1960–2010) and their relationship in four of Korea’s largest metropolitan cities (Seoul, Incheon, Busan and Daejeon). Also, the trends of the air and soil temperatures between the studied metropolitan cities and a rural area (Chupungryong) were compared to examine the effect of urban heat. Among the metropolitan cities, the long-term mean soil temperatures (depth 0.0, 0.5, 1.0, 1.5, 3.0, 5.0 m) were lowest (13.34–14.80 °C) in Seoul and highest (16.24–16.54 °C) in Busan, which is mainly the effect of the latitude. The soil temperature exponentially increased with depth in the three cities except for Busan and was closely related to the air temperature. The soil temperatures responded well to the air temperature change (maximum correlation coefficients 0.88–0.98) but this response was slightly delayed with depth. The air and soil temperatures increased at the rates of 0.24–0.40 and 0.11–0.73 °C/decade, respectively, for the period. The increasing rate of the soil temperature was the largest in Daejeon as 0.39–0.73 °C/decade, which was almost 2–4 times greater than those of the other cities (0.11–0.40 °C/decade), and it rose with depth. The increase of the soil temperature was coincident with the increase of the air temperature, which indicates that the soil temperature was largely affected by the increasing of the air temperature. In contrast, the increase in air temperature in Chupungryong (0.06 °C/decade) was significantly lower than in the metropolitan cities. In addition, the increase of the soil temperature in the rural area (0.13 °C/decade) was also much lower than that in the inland cities (0.20–0.27 °C/decade) while it showed no substantial difference from that in the coastal cities (0.11–0.15 °C/decade). Therefore, it is inferred that the soil temperature of the metropolitan cities increased with the increase of the air temperature due to global warming as well as the anthropogenic urban heat.  相似文献   

15.
The history of life on Earth is critically dependent on the carbon, sulfur and oxygen cycles of the lithosphere – hydrosphere – atmosphere – biosphere system. An Archean oxygen-poor greenhouse atmosphere developed through: (i) accumulation of CO2 and CH4 from episodic injections of CO2 from volcanic activity, volatilised crust impacted by asteroids and comets, metamorphic devolatilisation processes and release of methane from sediments; and (ii) little CO2 weathering-capture due to both high temperatures of the hydrosphere (low CO2 solubility) and a low ratio of exposed continents to oceans. In the wake of the Sturtian glaciation, enrichment in oxygen and appearance of multicellular eukaryotes heralded the onset of the Phanerozoic where greenhouse conditions were interrupted by periods of strong CO2-sequestration through intensified capture of CO2 by marine plants, onset of land plants and burial of carbonaceous shale and coal (Late Ordovician; Carboniferous – Permian; Late Jurassic; Late Tertiary – Quaternary). The progression from Late Mesozoic and Early Tertiary greenhouse conditions to Late Tertiary – Quaternary ice ages was related to the sequestration of CO2 by rapid weathering of the emerging Alpine and Himalayan mountain chains. A number of peak warming and sea-level-rise events include the Late Oligocene, mid-Miocene, mid-Pliocene and Pleistocene glacial terminations. The Late Tertiary – Quaternary ice ages were dominated by cyclic orbital-forcing-triggered terminations which involved CO2-feedback effects from warming seas and the biosphere and albedo flips due to ice-sheet melting. Since ca AD 1750 human emissions were ～305 Gt of carbon, as compared with ～750 Gt C in the atmosphere. The emissions constitute ～12% of the terrestrial biosphere and ～10% of the known global fossil fuel reserve of ～4000 Gt C, whose combustion would compare to the ～ 4600 Gt C released to the atmosphere during the K – T impact event 65 million years ago, with associated ～65% mass extinction of species. The current growth rate of atmospheric greenhouse gases and global mean temperatures exceed those of Pleistocene glacial terminations by one to two orders of magnitude. The relationship between temperatures and sea-levels for the last few million years project future sea-level rises toward time-averaged values of at least 5 m per 1°C. The instability of ice sheets suggested by the Dansgaard – Oeschinger glacial cycles during 50 – 20 ka, observed ice melt lag effects of glacial terminations, spring ice collapse dynamics and the doubling per-decade of Greenland and west Antarctic ice melt suggest that the Intergovernmental Panel on Climate Change's projected sea-level rises (<59 cm) for the 21st century may be exceeded. The biological and philosophical rationale underlying climate change and mass extinction perpetrated by an intelligent carbon-emitting mammal species may never be known.  相似文献   

16.
The geothermal potential of the basal clastics of Saskatchewan,Canada   总被引：1，自引：0，他引：1  
The Winnipeg and Deadwood formations form deep clastic reservoirs in Saskatchewan, Canada, with temperatures exceeding 40 °C over most of southern Saskatchewan and reaching 100 °C in southwestern Saskatchewan. At these temperatures, the formations have geothermal potential for development of direct use and electricity generation systems. Numerous disposal wells operating at rates of 30 L/s or more are currently installed in these formations, suggesting that electricity could be generated at rates exceeding 2 megawatts of electrical output (MWe) from individual wells. These basal clastic units, thus, could provide significant energy supply over a broad region of Saskatchewan.  相似文献   

17.
A palaeotemperature reconstruction based on periglacial phenomena in Europe north of approximately 51 °N, is compared with high‐resolution regional climate model simulations of the marine oxygen isotope Stage 3 (Stage 3) palaeoclimate. The experiments represent Stage 3 warm (interstadial), Stage 3 cold (stadial) and Last Glacial Maximum climatic conditions. The palaeotemperature reconstruction deviates considerably for the Stage 3 cold climate experiments, with mismatches up to 11 °C for the mean annual air temperature and up to 15 °C for the winter temperature. However, in this reconstruction various factors linking climate and permafrost have not been taken into account. In particular a relatively thin snow cover and high climatic variability of the glacial climate could have influenced temperature limits for ice‐wedge growth. Based on modelling the 0 °C mean annual ground temperature proves to be an appropriate upper temperature limit. Using this limit, mismatches with the Stage 3 cold climate experiments have been reduced but still remain. We therefore assume that the Stage 3 ice wedges were generated during short (decadal time‐scale) intervals of extreme cold climate, below the mean temperatures indicated by the Stage 3 cold climate model simulations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

18.
The present analysis adjusts previous estimates of global ocean CaCO3 production rates substantially upward, to 133 × 1012 mol yr?1 plankton production and 42 × 1012 mol yr?1 shelf benthos production. The plankton adjustment is consistent with recent satellite-based estimates; the benthos adjustment includes primarily an upward adjustment of CaCO3 production on so-called carbonate-poor sedimentary shelves and secondarily pays greater attention to high CaCO3 mass (calcimass) and turnover of shelf communities on temperate and polar shelves. Estimated CaCO3 sediment accumulation rates remain about the same as they have been for some years: ~20 × 1012 mol yr?1 on shelves and 11 × 1012 mol yr?1 in the deep ocean. The differences between production and accumulation of calcareous materials call for dissolution of ~22 × 1012 mol yr?1 (~50 %) of shelf benthonic carbonate production and 122 × 1012 mol yr?1 (>90 %) of planktonic production. Most CaCO3 production, whether planktonic or benthonic, is assumed to take place in water depths of <100 m, while most dissolution is assumed to occur below this depth. The molar ratio of CO2 release to CaCO3 precipitation (CO2↑/CaCO3↓) is <1.0 and varies with depth. This ratio, Ψ, is presently about 0.66 in surface seawater and 0.85 in ocean waters deeper than about 1000 m. The net flux of CO2 associated with CaCO3 reactions in the global ocean in late preindustrial time is estimated to be an apparent influx from the atmosphere to the ocean, of +7 × 1012 mol C yr?1, at a time scale of 102–103 years. The CaCO3-mediated influx of CO2 is approximately offset by CO2 release from organic C oxidation in the water column. Continuing ocean acidification will have effects on CaCO3 and organic C metabolic responses to the oceanic inorganic C cycle, although those responses remain poorly quantified.  相似文献   

19.
Orthopyroxene reaction rims were synthesized between polished plates of natural olivine or synthetic forsterite and quartz at 1.9 GPa and temperatures of 750–950°C. The experiments were performed in a piston-cylinder apparatus after drying the samples at 600°C. Each experiment comprised 4 or 7 quartz-olivine contacts that were positioned along a temperature gradient. As a monitor for water content in the samples, the water concentration in the two olivines was determined by FTIR before and after the experiments. The orthopyroxene layers show two different structural variants. Type one (normal layers) has very constant thickness at each contact and formed with equal growth rates at both interfaces. Type two (bulging layers) comprises more irregular areas with 3–5 times thicker rims where porosity provides evidence for the local presence of a fluid. In the bulging layers the growth rate at the olivine-orthopyroxene interface exceeds that at the quartz-orthopyroxene interface. The relative growth rates at the interfaces are in accordance with SiO2-immobile growth of the normal layers and SiO2-mobile growth of the bulging layers. The natural olivine contains about 60 wt-ppm intracrystalline water before and after experiment and took up about 20 wt-ppm water molecular adsorbed to micro- and nanocracks and -pores during the runs. The synthetic forsterite contains about 7 wt-ppm internally adsorbed molecular water before and after experiment, and during the runs took up hydrogen equivalent to 3 wt-ppm adsorbed water. The IR spectra indicate that large parts of the point defects (possibly tetrahedral) were frozen-in at the conditions of the experiments. In both olivines a new band appeared at 3,355 or 3,357 cm?1, respectively, equivalent to about 3 wt-ppm water that at the high pressure of the experiments and opx-buffered aSiO2 of the experiments might already mean water saturation of the olivines. Despite the effective drying before experiment and the absence of porosity, the bulk diffusivity derived from the rim growth rates is perfectly in line with data from water-bearing piston-cylinder experiments at higher temperatures. The bulk diffusivity during rim growth is 4 to 7 orders of magnitude higher than an extrapolation of really dry experiments to the temperature range of this study.  相似文献   

20.
The transition between rutile and α-PbO2 structured TiO2 (TiO2II) has been investigated at 700–1,200 °C and 4.2–9.6 GPa. Hydrothermal phase equilibrium experiments were performed in the multi-anvil apparatus to bracket the phase boundary at 700, 1,000, and 1,200 °C. The equilibrium phase boundary is described by the equation: P (GPa)=1.29+0.0065 T ( °C). In addition, growth of TiO2II was observed in experiments at 500 and 600 °C, although growth of rutile was too slow to bracket unambiguously the equilibrium boundary at these temperatures. Water was not detected in either rutile or TiO2II, and dry synthesis experiments at 1,200 °C were consistent with the phase boundary determined in the fluid-bearing experiments, suggesting that the equilibrium is unaffected by the presence of water. Our bracket of the phase boundary at 700 °C is consistent with the reversed, dry experiments of Akaogi et al. (1992) and the reversals of Olsen et al. (1999). The new data suggest that the phase boundary is linear, in agreement with Akaogi et al. (1992), but in striking contrast to the phase diagram inferred by Olsen et al. (1999). The natural occurrence of TiO2II requires formation pressures considerably higher than the graphite–diamond phase boundary.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号