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1.
An ultra-high-pressure (UHP) metamorphic slab at Yangkou Beach near Qingdao in the Sulu region of China consists of blocks of eclogite facies metagabbro, metagranitoid, ultramafic rock and mylonitic orthogneisses enclosed in granitic gneiss. A gradational sequence from incipiently metamorphosed gabbro to completely recrystallized coesite eclogite formed at ultra-high-pressures was identified in a single 30 m block; metagabbro is preserved in the core whereas coesite eclogite occurs along the block margins. The metagabbro contains an igneous assemblage of Pl+Aug+Opx+Qtz+Bt+Ilm/Ti-Mag; it shows relict magmatic textures and reaction coronas. Fine-grained garnet developed along boundaries between plagioclase and other phases; primary plagioclase broke down to Ab+Ky+Ms+Zo±Grt±Amp. Augite is rimmed by sodic augite or omphacite, whereas orthopyroxene is rimmed by a corona of Cum±Act and Omp+Qtz layers or only Omp+Qtz. In transitional rocks, augite and orthopyroxene are totally replaced by omphacite, and the lower-pressure assemblage Ab+Ky+Phn+Zo+Grt coexists with domains of Omp (Jd70–73)+Ky±Phn in pseudomorphs after plagioclase. Both massive and weakly deformed coesite-bearing eclogites contain Omp+Ky+Grt+Phn+Coe/Qtz+Rt, and preserve a faint gabbroic texture. Coesite inclusions in garnet and omphacite exhibit limited conversion to palisade quartz; some intergranular coesite and quartz pseudomorphs after coesite also occur. Assemblages of the coronal stage, transitional and UHP peak occurred at about 540±50 °C at c. 13 kbar, 600–800 °C at ≥15–25 kbar and 800–850 °C at >30 kbar, respectively. Garnet from the coronal- through the transitional- to the eclogite-stage rocks show a decrease in almandine and an increase in grossular±pyrope components; garnet in low-grade rocks contains higher MnO and lower pyrope components. The growth textures of garnet within pseudomorphs after plagioclase or along grain boundaries between plagioclase and other phases are complex; the application of garnet zoning to estimate P–T should be carried out with caution. Some garnet enclosing quartz aggregates as inclusions shows radial growth boundaries; these quartz aggregates, as well as other primary and low-P phases, persisted metastably at UHP conditions due to sluggish reactions resulting from the lack of fluid during prograde and retrograde P–T evolution.  相似文献   

2.
Eclogites in the Tromsø area, northern Norway, are intimately associated with meta-supracrustals within the Uppermost Allochthon of the Scandinavian Caledonides (the Tromsø Nappe Complex). The whole sequence, which includes pelitic to semipelitic schists and gneisses, marbles and calc-silicate rocks, quartzofeldspathic gneisses, metabasites and ultramafites, has undergone three main deformational/metamorphic events (D1/M1, D2/M2 and D3/M3). Detailed structural, microtextural and mineral chemical studies have made it possible to construct separate P–T paths for these three events. Chemically zoned late syn- to post-D1 garnets with inclusions of Bt, Pl and Qtz in Ky-bearing metapelites indicate a prograde evolution from 636°C, 12.48 kbar to c. 720°C, 14–15 kbar. This latter result is in agreement with Grt–Cpx geothermometry and Grt–Cpx–Pl–Qtz geobarometry on eclogites and trondhjemitic to dioritic gneisses. Maximum pressures at c. 675°C probably reached 17–18 kbar based on Cpx–Pl–Qtz inclusions in eclogitic garnets, and Grt–Ky–Pl–Qtz and Jd–Ab–Qtz in trondhjemitic gneisses. Post-D1/pre-D2 decompressional breakdown of the high-P assemblages indicates a substantial drop in pressure at this stage. Inclusions and chemical zoning in syn- to post-D2 garnets from metapelites record a second episode of prograde metamorphism, from 552°C, 7.95 kbar, passing through a maximum pressure of 10.64 kbar at 644°C, with final equilibration at c. 665°C, 9–10 kbar. The corresponding apparently co-facial paragenesis Grt + Cpx + Pl + Qtz in metabasites yields c. 635°C, 8–10 kbar. In the metapelites post-D3, Grt in apparent equilibrium with Bt, Phe and Pl yield c. 630°C, 9 kbar. The D1/M1 and D2/M2 episodes are exclusively recorded in the Tromsø Nappe Complex and must thus pre-date the emplacement of this allochthonous unit on top of the underlying Lyngen Nappe, while the D3/M3 episode is common for the two units. A previously published Sm–Nd mineral isochron (Grt–Cpx–Am) on a partly retrograded and recrystallized ecologite of 598 ± 107 Ma represents either the timing of formation of the eclogites or the post-eclogite/pre-D2 decompression stage, while a Rb–Sr whole rock isochron of an apparently post-D1/pre-D2 granite of 433 ± 11 Ma is consistent with a K–Ar age of post-D1/pre-D2 amphiboles from a retrograded eclogite of 437 ± 16 Ma which most likely record cooling below the 475–500°C isotherm after the M3 metamorphism.  相似文献   

3.
The Mollendo–Camana Block (MCB) is a 50 × 150 km Precambrian inlier of the Andean belt that outcrops along the Pacific coast of southern Peru. It consists of stromatic migmatites of Paleoproterozoic heritage intensely metamorphosed during the Grenville event (c. 1 Ga; U‐Pb and U‐Th‐Pb ages on zircon and monazite). In the migmatites, aluminous mesosomes (FMAS) and quartzofeldspathic leucosomes (KFMASH), contain various amounts of K‐feldspar (Kfs), orthopyroxene (XMg Opx = 0.86), plagioclase (Pl), sillimanite (Sil; exceptionally kyanite, Ky) ilmenite (Ilm), magnetite (Mag), quartz (Qtz), and minor amounts of garnet (XMg Grt = 0.60), sapphirine (XMg Spr = 0.87), cordierite (XMg Crd = 0.92) and biotite (XMg Bt = 0.83). The ubiquitous peak mineral assemblage is Opx‐Sil‐Kfs‐Qtz‐(± Grt) in most of the MCB, which, together with the high Al content of orthopyroxene (10% Al2O3) and the local coexistence of sapphirine‐quartz, attest to regional UHT metamorphism (> 900 °C) at pressures in excess of 1.0 GPa. Fluid‐absent melting of biotite is responsible for the massive production of orthopyroxene that proceeded until exhaustion of biotite (and most of the garnet) in the southern part of the MCB (Mollendo‐Cocachacra areas). In this area, a first stage of decompression from 1.1–1.2 to 0.8–0.9 GPa at temperatures in excess of 950 °C, is marked by the breakdown of Sil‐Opx to Spr‐Opx‐Crd assemblages according to several bivariant FMAS reactions. High‐T decompression is also shown by Mg‐rich garnet being replaced by Crd‐Spr‐ and Crd‐Opx‐bearing symplectites, and reacting with quartz to produce low‐Al‐Opx‐Sil symplectites in quartz‐rich migmatites. Neither osumilite nor spinel‐quartz assemblages being formed, isobaric cooling at about 0.9 GPa probably followed the initial decompression and proceeded with massive precipitation of melts towards the (Os) invariant point, as demonstrated by Bt‐Qtz‐(± pl) symplectites in quartz‐rich migmatites (melt + Opx + Sil = Bt + Grt + Kfs + Qtz). Finally, Opx rims around secondary biotite attest to late fluid‐absent melting, compatible with a second stage of decompression below 900 °C. The two stages of decompression are interpreted as due to rapid tectonic denudation whereas the regional extent of UHT metamorphism in the area, probably results from large‐scale penetration of hot asthenospheric mantle at the base of an over‐thickened crust.  相似文献   

4.
Low‐pressure crystal‐liquid equilibria in pelitic compositions are important in the formation of low‐pressure, high‐temperature migmatites and in the crystallization of peraluminous leucogranites and S‐type granites and their volcanic equivalents. This paper provides data from vapour‐present melting of cordierite‐bearing pelitic assemblages and augments published data from vapour‐present and vapour‐absent melting of peraluminous compositions, much of which is at higher pressures. Starting material for the experiments was a pelitic rock from Morton Pass, Wyoming, with the major assemblage quartz‐K feldspar‐biotite‐cordierite, approximately in the system KFMASH. A greater range in starting materials was obtained by addition of quartz and sillimanite to aliquots of this rock. Sixty‐one experiments were carried out in cold‐seal apparatus at pressures of 1–3.5 kbar (particularly 2 kbar) and temperatures from 700 to 840 °C, with and without the addition of water. In the vapour‐present liquidus relations at 2 kbar near the beginning of melting, the sequence of reactions with increasing temperature is: Qtz + Kfs + Crd + Sil + Spl + V = L; Qtz + Kfs + Crd + Spl + Ilm + V = Bt + L; and Qtz + Bt + V = Crd + Opx + Ilm + L. Vapour‐absent melting starts at about 800 °C with a reaction of the form Qtz + Bt = Kfs + Crd + Opx + Ilm + L. Between approximately 1–3 kbar the congruent melting reaction is biotite‐absent, and biotite is produced by incongruent melting, in contrast to higher‐pressure equilibria. Low pressure melts from pelitic compositions are dominated by Qtz‐Kfs‐Crd. Glasses at 820–840 °C have calculated modes of approximately Qtz42Kfs46Crd12. Granites or granitic leucosomes with more than 10–15% cordierite should be suspected of containing residual cordierite. The low‐pressure glasses are quite similar to the higher‐pressure glasses from the literature. However, XMg increases from about 0.1–0.3 with increasing pressure from 1 to 10 kbar, and the low‐temperature low‐pressure glasses are the most Fe‐rich of all the experimental glasses from pelitic compositions.  相似文献   

5.
In mafic granulites, garnet can form by reactions such as Opx + Pl = Cpx + Grt + Qtz; Opx + Pl = Grt + Qtz. As a result of isothermal decompression (ITD), garnet can then break down to a characteristic orthopyroxene-plagioclase symplectite. Mafic, iron-rich garnet-pyroxene granulite from the Guaxupé Massif has symplectite that formed by near-isothermal decompression, as a consequence of uplift of the granulite facies terrane. This symplectite was found to consist of vermicular clinopyroxene-orthopyroxene-plagioclase, with clinopyroxene clearly growing from the garnet that is breaking down, modal amounts of clinopyroxene being less than orthopyroxene. Electron probe analyses show clear differences between core (Cpx1), rim, and symplectite clinopyroxene (Cpx2). Considering also the presence of magnetite in the symplectite texture, garnet breakdown is thought to be better represented by a reaction such as Cpx1 + Grt + O2 = Cpx2 + Opx + Pl +Mt + Qtz.  相似文献   

6.
Highly anhydrous granulites from Río Santa Rosa in the eastern Sierras Pampeanas of Argentina occur as a thick lens surrounded by melt-depleted migmatites. Grt–Crd granulite composed of Qtz+Pl+Grt+Crd+Ilm±Spl±Ath±Phl is the dominant rock, whereas Opx–Grt granulite appears as discontinuous lenses in the center of the granulite body. Grt–Crd granulite includes blocks of metabasite that are relics of refractory lithologic beds interlayered in the supracrustal sequence. A distinct assemblage composed of Qtz, Pl, Grt, Crd, Opx, Spl, Crn, Sil, Bt, Phl, Ath, and Fe–Ti oxides in different combinations was generated in a reaction zone between Grt–Crd granulites and metabasites at peak metamorphism (850–900 °C and 7.6±0.5 kbar). The PT trajectory of Grt–Crd granulites suggests an early prograde garnet-forming stage followed by nearly isothermal decompression that caused garnet breakdown. Melting and melt draining accompanying garnet growth was active during heating (to 900 °C) at intermediate pressures (∼7.6 kbar). Peak PT estimates for Opx–Grt granulites are similar to those obtained with Grt–Crd granulites, which indicates that both granulites passed through the highest thermal stage. These results constrain the late evolution of Opx–Grt granulite to a garnet-consuming stage. Furthermore, they imply that garnet formation in Opx–Grt granulite happened at an early prograde PT trajectory. Garnet growth in Opx–Grt granulite cannot result from heating at high pressure, which would lead to an apparent contradiction in the prograde PT paths of the two granulites. This discrepancy may be solved by demonstrating that Opx–Grt granulite is the product of synmetamorphic mafic magmatism that was contaminated while cooling. The Río Santa Rosa granulites are inferred to have formed in a thickened crust in which mafic magmatic activity providing a local heat input.  相似文献   

7.
Sapphirine granulites from a new locality in the Palni Hill Ranges, southern India, occur in a small enclave of migmatitic, highly magnesian metapelites (mg=85–72) within massive enderbitic orthogneiss. They show a variety of multiphase reaction textures that partially overprint a coarse-grained high-pressure assemblage of Bt+Opx+Ky+Grt+Pl+Qtz. The sequence of reactions as deduced from the corona and symplectite assemblages, together with petrogenetic grid considerations, records a clockwise P–T evolution with four distinct stages. (1) Equilibration of the initial high-P assemblage in deep overthickened crust (12 kbar/800–900 °C) was followed by a stage of near-isobaric heating, presumably as a consequence of input of extra heat provided by the voluminous enderbitic intrusives. During heating, kyanite was converted to sillimanite, and biotite was involved in a series of vapour-phase-absent melting reactions, which resulted in the ultra-high-temperature assemblage Opx+Crd+Kfs+Spr±Sil, Grt, Qtz, Bt, coexisting with melt (equilibration at c. 950–1000° C/11–10 kbar). (2) Subsequently, as a result of decompression of the order of 4 kbar at ultra-high temperature, a sequence of symplectite assemblages (Opx+Sil+Spr/Spr+Crd→Opx+Spr+Crd→Opx+Crd→Opx+Crd+Spl/Crd+Spl) developed at the expense of garnet, orthopyroxene and sillimanite. This stage of near-isothermal decompression implies rapid ascent of the granulites into mid-crustal levels, possibly due to extensional collapse and erosion of the overthickened crust. (3) Development of late biotite through back-reaction of melt with residual garnet indicates a stage of near-isobaric cooling to c. 875 °C at 7–8 kbar, i.e. relaxation of the rapidly ascended crust to the stable geotherm. (4) A second period of near-isothermal exhumation up to c. 6–5 kbar/850 °C is indicated by the partial breakdown of late biotite through volatile phase-absent melting reactions. Available isotope data suggest that the early part of the evolutionary history (stages 1–3) is presumably coeval with the early Proterozoic metamorphism in the extended granulite terrane of the Nilgiri, Biligirirangan and Shevaroy Hills to the north, while the exhumation of the granulites from mid-crustal levels (stage 4) occurred only during the Pan-African thermotectonic event, which led to the accretion of the Kerala Khondalite Belt to the south.  相似文献   

8.
Abstract Dehydration-melting reactions, in which water from a hydrous phase enters the melt, leaving an anhydrous solid assemblage, are the dominant mechanism of partial melting of high-grade rocks in the absence of externally derived vapour. Equilibria involving melt and solid phases are effective buffers of aH2,o. The element-partitioning observed in natural rocks suggests that dehydration melting occurs over a temperature interval during which, for most cases, aH2o is driven to lower values. The mass balance of dehydration melting in typical biotite gneiss and metapelite shows that the proportion of melt in the product assemblage at T± 850°C is relatively small (10–20%), and probably insufficient to mobilize a partially melted rock body. Granulite facies metapelite, biotite gneiss and metabasic gneiss in Namaqualand contain coarse-grained, discordant, unfoliated, anhydrous segregations, surrounded by a finer grained, foliated matrix that commonly includes hydrous minerals. The segregations have modes consistent with the hypothesis that they are the solid and liquid products of the dehydration-melting reactions: Bt + Sil + Qtz + PI = Grt ° Crd + Kfs + L (metapelite), Bt + Qtz + Pl = Opx + Kfs + L (biotite gneiss), and Hbl + Qtz = Opx + Cpx + Pl + L (metabasic gneiss). The size, shape, distribution and modes of segregations suggest only limited migration and extraction of melt. Growth of anhydrous poikiloblasts in matrix regions, development of anhydrous haloes around segregations and formation of dehydrated margins on metabasic layers enclosed in migmatitic metapelites all imply local gradients in water activity. Also, they suggest that individual segregations and bodies of partially melted rock acted as sinks for soluble volatiles. The preservation of anhydrous assemblages and the restricted distribution of late hydrous minerals suggest that retrograde reaction between hydrous melt and solids did not occur and that H2O in the melt was released as vapour on crystallization. This model, combined with the natural observations, suggests that it is possible to form granulite facies assemblages without participation of external fluid and without major extraction of silicate melt.  相似文献   

9.
胶北莱西古元古代的高压基性麻粒岩和钙硅酸盐岩的基本矿物组合分别为以铁铝榴石为主的石榴石-普通辉石-铁紫苏辉石和钙铝榴石-黝帘石-葡萄石-钠长石.矿物岩石学研究表明钙硅酸盐岩是由含石榴石高压基性麻粒岩经退变质和钙质交代作用形成.南山口高压基性麻粒岩记录了麻粒岩相变质作用前、麻粒岩相变质作用、退变质和钙硅酸盐岩化共同作用以及完全钙硅酸盐岩化的四个阶段的地质作用,其矿物组合分别为Cpx+ Pl+ Qtz(M1),Grt+ Cpx+ Rt+ Qtz(M2),Cpx+Pl+ Opx+ Ilm+ Mgt+ Ep(M3)和Grs+ Zo+ Prh+ Ab+ Cal(M4).微量元素研究表明,高压基性麻粒岩中大离子亲石元素Ba、Rb、K、Rb、Th富集,而高场强元素Nb、Zr、Ti、Y亏损,具有轻稀土富集的右倾型稀土配分曲线.稀土元素和微量元素配分图解显示了岛孤拉斑玄武岩的特征.主元素、微量元素的构造判别图解进一步分析表明高压基性麻粒岩及其钙硅酸盐岩的原岩形成于大陆边缘的岛弧环境.综合高压基性麻粒岩岩石学、元素地球化学特征认为,莱西高压基性麻粒岩的原岩是拉斑玄武岩质岩石,可能是形成于孤后扩张背景下基性的侵入岩或喷出岩.岩石形成以后,在胶-辽-吉带碰撞闭合过程中,经历了麻粒岩相变质作用,又在后来的抬升过程中经历退变质和钙硅酸盐岩化作用.  相似文献   

10.
We discuss upper-amphibolite to granulite facies, early Palaeozoic metamorphism and partial melting of aluminous greywackes from the Sierra de Comechingones, SE Sierras Pampeanas of Central Argentina. Consistent P–T estimates, obtained from equilibria involving Al and Ti exchange components in biotite and from more traditional thermobarometric equilibria, suggest that peak metamorphism of the exposed section took place at an essentially constant pressure of 7–8 kbar, and at temperatures ranging from 650 to 950 °C. Mineral compositions record an initial decompression, after peak metamorphism, of c. 1.5 kbar, which was accompanied by a cooling of c. 100 °C. Upper-amphibolite facies gneisses consist of the assemblage Qtz+Pl+Bt+Grt+Rt/Ilm. The transition to the granulite facies is marked by the simultaneous appearance of the assemblage Kfs+Sil and of migmatitic structures, suggesting that the amphibolite to granulite transition in the Sierra de Comechingones corresponds to the beginning of melting. Rocks with structural and/or chemical manifestations of partial melting range from metatexites, to diatexites, to melt-depleted granulites, consisting of the assemblage Grt+Crd+Pl+Qtz+Ilm±Ath. The melting stage overlapped at least partially with decompression, as suggested by the occurrence of cordierite, in both the migmatites and the residual granulites, of two distinct textural types: idiomorphic porphyroblasts (probably representing peritectic cordierite) and garnet-rimming coronas. Metapelitic rocks are unknown in the Sierra de Comechingones. Therefore, it appears most likely that the Al-rich residual assemblages found in the migmatites and residual granulites were formed by partial melting of muscovite- and sillimanite-undersaturated metagreywackes. We propose a mechanism for this that relies on the sub-solidus stabilization of garnet and the ensuing changes in the octahedral Al content of biotite with pressure and temperature.  相似文献   

11.
The Xolapa Complex (XC) is the largest plutonic and metamorphic mid‐crustal basement unit in Mexico and represents an ancient continental magmatic‐arc. A complete range from metatexite to diatexite migmatitic structures has been produced during a single high‐grade metamorphic event. However, structural relics reveal the existence of early Cpx + Pl + Qtz ± Opx and Grt + Opx + Pl + Qtz ± Cpx pre‐migmatitic metamorphic assemblages. Field relationships and microstructural observations allow us to constrain five pre‐, syn‐ and post‐migmatitic deformational phases. It is argued that migmatitic structures and minor anatectic granites were developed during ductile recumbent folding and shear structures related to the D2–D3 phases. Late post‐migmatitic ductile‐brittle deformation is evidenced by the development of NNE trending transpressional thrusting (D4), and E–W left‐lateral mylonitic shear zones (D5). Biotite‐breakdown melting in felsic rocks and amphibole‐breakdown melting in mafic rocks, as well as geothermobarometric results, indicate that metamorphism took place at temperatures from 830 to 900 °C and pressures ranging from ≥6.3 to 9.5 kbar. Late migmatitic assemblages equilibrated in the highest temperature range along a clockwise P–T path. The relationships between the large diversity of migmatitic structures and the progressive production of melt suggest that feedback relations prevailed as a time‐marker during a contractional regime. Deformation, metamorphism, and plutonism of the XC show that this terrane evolved as a north‐east‐verging thrust system with synkinematic metamorphism and partial melting, during the Late Cretaceous – Palaeogene. The tectonothermal history of XC is analogous to a Cordilleran metamorphic magmatic‐arc formed in an accretionary tectonic framework. This new model provides constraints on the exhumation mechanism and thermal evolution of southern Mexico.  相似文献   

12.
The Southern Brittany Migmatite Belt (SBMB), which evolved through the metamorphic peak between c. 400 Ma and c. . 370 Ma ago, consists of a heterogeneous suite of high-grade gneisses and anatectic migmatites, both metatexites and diatexites. Rare garnet-cordierite gneiss layers record evidence of an early prograde P-T path. In these rocks, growth-zoned garnet cores and a sequence of included mineral assemblages in garnet, from core to rim, of Qtz + Ilm + Ky, Pl + Ky + St + Rt + Bt and Pl + Sil + St + Rt + Bt constrain a prograde evolution during which the reactions Ilm + Ky + Qtz→ Aim + Rt, Ms + Chl→ St + Bt + Qtz + V and St + Qtz→ Grt + Sil + V were crossed. Parts of this prograde evolution are preserved as inclusion assemblages in garnet in all other rock types. In all rock types, garnet has reverse zoned rims, and garnet replacement by cordierite and/or biotite and plagioclase suggests the following reactions have occurred: Grt + Sil + Qtz→ Crd → Hc ± Ilm, Bt + Sil + Qtz → Crd ± Hc → Ilm → Kfs + V and (Na + Ca + K + Ti) + Grt → Bt + Pl + Qtz. Microstructural analysis of reaction textures in conjunction with a petrogenetic grid has enabled the construction of a tightly constrained 'clockwise' P–T path for the SBMB. The high-temperature part of the path has a steep dT/dP slope characteristic of near isothermal decompression. It is proposed that the P-T path followed by the SBMB is the result of the inversion, by overthrusting, of a back-arc basin and that such a tectonic setting may be applicable to other high-temperature migmatite terranes. The near isothermal decompression is at least partly driven by the upward (diapiric) movement of the diatexite/anatectic granite core of the SBMB.  相似文献   

13.
We report a new occurrence of incipient charnockite from Mavadi in the Trivandrum Granulite Block (TGB), southern India, and discuss the petrogenesis of granulite formation in an arrested stage on the basis of petrography, geothermobarometry, and mineral equilibrium modeling. In Mavadi, patches and lenses of charnockite (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Opx?+?Ilm?+?Mag) of about 30 to 220 cm in length occur within Opx-free Grt-Bt gneiss (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Ilm). The application of mineral equilibrium modeling on the charnockite assemblage in the NCKFMASHTO system to constrain the conditions of charnockitization defines a PT range of 800 °C at 4.5 kbar to 850 °C at 8.5 kbar, which is broadly consistent with the results from the conventional geothermobarometry (810–880 °C at 7.7–8.0 kbar) on these rocks. The PT conditions are lower than the peak metamorphic conditions reported for the ultrahigh-temperature granulites from this area (T?>?900 °C). The heterogeneity in peak PT conditions within the same crustal block might be related to local buffering of metamorphic temperatures by the Opx-Bt-Kfs-Qtz assemblage. The result of T versus mole H2O (M(H2O)) modeling demonstrated that the Opx-free assemblage in the Grt-Bt gneiss is stable at M(H2O)?=?0.3 to 1.5 mol%, and orthopyroxene occurs as a stable mineral at M(H2O) <0.3 mol%, which is consistent with the petrogenetic model of incipient charnockite related to the lowering of the water activity and stabilization of orthopyroxene through the breakdown of biotite by dehydration caused by the infiltration of CO2-rich fluid from external sources. We also propose a possible alternative mechanism to form charnockite from Grt-Bt gneiss through slight variations in bulk-rock chemistry (particularly for the K- and Fe-rich portion of Grt-Bt gneiss) that can enhance the stability of orthopyroxene rather than that of biotite, with K-metasomatism playing a possible role.  相似文献   

14.
Abstract The widespread khondalite series of south-east Inner Mongolia consists largely of biotite–sillimanite–garnet gneiss and quartzo-feldspathic gneiss with some marble and mafic granulite layers. It has experienced two metamorphic events at c. 2500 and 1900–2000 Ma.
A pre-peak stage of the first metamorphism at T = 600–700°C and P > 6–7 kbar is recognized by the relict amphibolite facies assemblage Ky–Grt–Bt–Pl–Qtz and 'protected'inclusions of biotite, hornblende, sodic plagioclase and quartz in garnet or orthopyroxene. The peak stage, with T = c. 800 ± 50°C and P 8–10 kbar, is characterized by the widespread granulite facies assemblages Sil–Grt–Bt–Kfs–Pl–Qtz in gneiss and Opx–Cpx–Pl ± Hbl ± Grt in granulite. The P–T–t path suggests that the supracrustal sequence was buried in the lower crust by tectonic thickening during D1–D2.
The beginning of the second metamorphism is characterized by further temperature rise to 700°C or more at lower pressure. This stage is manifested by the appearance of cordierite after garnet, fibrolite (Sil2) after biotite in gneiss and transformation of Hbl1 into Opx2 and Cpx2 in granulite. Coronas of symplectitic Opx2 + Pl2 surrounding Grt1 and Cpx1 in mafic granulite are interpreted as products of near-isothermal decompression. The P–T–t path may be related tectonically to waning extension of the crust by the end of the early Proterozoic.  相似文献   

15.
《International Geology Review》2012,54(11):1229-1240
Intrusion-bordering migmatites comprise a substantial, high-grade metamorphic part of the Alvand aureole near Hamadan, western Iran. Abundant Al-rich metasedimentary rocks and various granites occur in this region. Migmatites consist of Bt?+?Sill?+?Grt?+?Crd?+?Sp ± Opx melanosomes and Grt?+?Pl?+?Kfs?+?Qtz leucosomes. These assemblages reflect upper pyroxene hornfels to lower sanidinite facies physical conditions. The appearance of orthopyroxene in these rocks marks the pressure–temperature transition from the pyroxene hornfels to the sanidinite facies. Field relations, mineral parageneses, and pressure–temperature estimates suggest that intrusion of granitic magma and concomitant partial melting of metasedimentary wallrock units were the main processes involved in the migmatization. Peak metamorphism took place at 650–750°C and ~2–4 kbar; such high-temperature/low-pressure metamorphism was caused mainly by advective heat derived from the emplacement of plutons. Regional metamorphism, granitic magmatism, and contact metamorphism reflected arc construction and collision during subduction of a Neotethyan seaway and subsequent Late Cretaceous–early Tertiary oblique collision of Afro-Arabia (Gondwana) with the Iranian microcontinent.  相似文献   

16.
Metapelites, migmatites and granites from the c. 2 Ga Mahalapye Complex have been studied for determining the PT–fluid influence on mineral assemblages and local equilibrium compositions in the rocks from the extreme southwestern part of the Central Zone of the Limpopo high‐grade terrane in Botswana. It was found that fluid infiltration played a leading role in the formation of the rocks. This conclusion is based on both well‐developed textures inferred to record metasomatic reactions, such as Bt ? And + Qtz + (K2O) and Bt ± Qtz ? Sil + Kfs + Ms ± Pl, and zonation of Ms | Bt + Qtz | And + Qtz and Grt | Crd | Pl | Kfs + Qtz reflecting a perfect mobility (Korzhinskii terminology) of some chemical components. The conclusion is also supported by the results of a fluid inclusion study. CO2 and H2O ( = 0.6) are the major components of the fluid. The fluid has been trapped synchronously along the retrograde PT path. The PT path was derived using mineral thermobarometry and a combination of mineral thermometry and fluid inclusion density data. The Mahalapye Complex experienced low‐pressure granulite facies metamorphism with a retrograde evolution from 770 °C and 5.5 kbar to 560 °C and 2 kbar, presumably at c. 2 Ga.  相似文献   

17.
Mafic garnet-bearing granulites from Sostrene Island, 150 km southwest of Davis Station on the coast of Prydz Bay, East Antarctica, exhibit two-stage symplectic coronas on garnet, formed after peak metamorphic conditions (M1). An outer corona of Opx (Mg66) + Pl (An94–97) + minor Hbl mantles a finer-grained inner corona of Opx (Mg67) + Pl (An95–96) + Spl (Mg36). Both symplectites contain minor ilmenite–magnetite intergrowths. The finer-grained symplectite also occurs along a fracture cleavage in the garnet. The outer corona originated during a second metamorphic event (M2) via the reaction Grt + Cpx (Hbl) + SiO2= Opx + Pl (1), whereas the inner corona formed later in response to decompression and minor deformation, resulting in the fracture cleavage in the garnet, according to the reaction Grt = Opx + Pl + Spl (2). The grossular content of the garent (XGrs= 0.168) is almost exactly that which is required for the stoichiometric breakdown by reaction (2) (calculated XGrs= 0.167). The mafic rocks are silica undersaturated, and the SiO2 for reaction (1) was most probably derived externally from the surrounding felsic gneisses. Preferred P–T estimates for M1 based on garnet core (Prp40Alm42Grs17Sps1)–matrix Opx–Cpx–Hbl pairs are c. 10 kbar at 980°C. The fine-grained symplectite formed post-peak M2 at c. 7 kbar and 850°C. The enclosing felsic gneisses yield pressure estimates of between 5 and 7 kbar, which compare with conditions of c. 6 kbar and 775°C in the nearby Bolingen Islands. These lower P–T estimates are considered to be representative of the widespread 1100-Ma metamorphic event recognized in outcrops along the Prydz Bay coast. The high-P, high-T estimates derived from the garnet relics provide evidence for an earlier, possibly Archaean, high-grade metamorphic event.  相似文献   

18.
哀牢山构造带泥质高压麻粒岩主要由石榴石、夕线石、钾长石和斜长石变斑晶及尖晶石、铁假蓝宝石、蓝晶石、石英、金红石和钛铁矿包裹体组成,为确定印支地块和华南地块的边界提供了关键性标志。石榴石-黑云母-斜长石-石英地质温压计(GBPQ)计算结果及标志性高温矿物组合(Spl+Qz)表明泥质高压麻粒岩的形成和演化经历了高压/高温进变质到中温/低压退变质的顺时针P-T演化过程。其中:1)高压/高温进变质阶段的矿物组合为Ky+Sil+Grt1+Kf1+Pl1+Spr+Ter(Kf+Pl)+Bt1+Spl+Qtz+Ilm1+Rut1,形成于850~919℃,≥10.4kbar;2)中温/低压退变质阶段的矿物组合为Grt2+Bt2+Pl2+Ms+Qtz+Ilm2+Rut2,早期和晚期的温压条件分别为664~754℃,4.9~6.5kbar和572~576℃,3.5~3.9kbar。反映陆壳物质在碰撞过程中俯冲到地下深处(≥30km)经高压高温变质后快速折返到中上地壳的动力学演变轨迹。  相似文献   

19.
The basement of the North China craton (NCC) can be divided into eastern and western blocks separating the Trans-North China orogen on the basis of petrologic associations, structures, metamorphic processes, and isotopic ages. Aluminous gneiss khondalites occur in the western block, and record a clockwise metamorphic P–T history characterized by nearly isothermal decompression following peak metamorphism at ca. 1.3 GPa and 825°C. Four metamorphic stages are recognized based on mineral assemblages. The early prograde metamorphic assemblage contains Ky+Bt+Ms+Grt+Pl+Qtz. The peak metamorphic mineral assemblage is characterized by Grt+Sil+Bt+Kfs+Pl+Qtz and the formation of cordierite after garnet, leading to a retrograde assemblage of Grt+Sil+Crd+Pl+Kfs+Qtz. Garnet retrogrades to biotite and the formation of pervasive matrix muscovite define a final metamorphic stage, inferred at ca. < 0.6 GPa and 700°C. Quantified metamorphic stages and a related clockwise P–T path derived from pseudosection analysis in the KMASH system suggest collision of the north Yinshan block with the South Ordos block at 1.92 Ga, before final suturing of the entire NCC basement.  相似文献   

20.
The early Precambrian khondalite series is widely distributed in the Jining-Zhuozi-Fengzhen-Liangcheng area, southeastern Inner Mongolia. The khondalite series mainly consists of sillimanite garnet potash feldspar (or two-feldspar) gneiss and garnet biotite plagioclase gneiss. These gneissic rocks have commonly experienced granulite-facies metamorphism. In zircons separated from sillimanite garnet potash feldspar gneisses, many mineral inclusions, including Sil, Grt, Ky, Kfs, Qtz and Ap, have been identified by the Laser Raman spectroscopy. Generally, prograde metamorphic mineral inclusion assemblages such as Ky + Kfs + Qtz + Ap and Ky + Grt + Kfs + Qtz are preserved in the core of zircon, while peak granulite-facies metamorphic minerals including Sil + Grt + Kfs + Qtz and Sil + Grt + Kfs + Qtz + Ap are identified in the mantle and rim of the same zircon. However, in some zircons are only preserved the peak metamorphic minerals such as Sil + Grt + Kfs + Qtz and Sil + Grt + Kfs + Qtz + Ap from core to ri  相似文献   

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