首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 237 毫秒
1.
13C of 367 C3 herbaceous plants was measured in loess area in northern China. Their δ13C values vary between −21.7%. and −30.0%., with a mean of −26.7%.. In the center of Loess Plateau (semimoist area) with annual precipitation of 400–600 mm, the δ13 C values of C3 herbaceous plants range from −24.4%. to −28.5%., with a mean of −27.5%.. In the west of Loess Plateau (semiarid and arid area) with annual precipitation less than 400 mm, they range between −21.7%. and −30.0%., with a mean of −26.2%.. Annual precipitation is the main factor that makes δ13C values of C3 herbaceous plants in the west greater than those in the central Loess Plateau. The composition of δ13C in C3 plants increases with deceasing annual precipitation, and the mean change is −49%./100 mm.  相似文献   

2.
Source rock extracts and crude oils from the Songliao Basin were analyzed by high-temperature gas chromatography (HTGC), gas chromatography-mass spectrometry (HTGC-MS) and gas chromatography-isotope ratio-mass spectrometry (GC-IRMS), for high molecular-weight alkanes. The distributions of n-alkanes in the Nenjiang Formation extracts are in the C14―C63 range; a bimodal distribution occurs in the C-21 and C21―40 regions. The C30―C37 n-alkanes are accompanied by C29―C35 hopanes, whereas the high molecular-weight C45―C47 n-alkanes co-occur with abundant isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The high δ 13C values of the n-alkanes and the microscopic maceral compositions indicate a highly diversified organic source input for the Nenjiang Formation source rocks, ranging from aquatic plants, blue alge-bacteria, to land plant material. In contrast, n-alkanes in the rock extracts of the Qingshankou Formation are characterized by a single modal distribution, with relatively low abundances of C29―C35 hopanes, but high molecular-weight isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The relatively low δ 13C values of C22―C44 n-alkanes and organic material compositions indicate that the source rocks in the Qingshankou Formation contain dominantly type I algal organic matter. The relative abundance of C 40 compounds in source rocks changes little at low maturity stage, but decreases drastically at higher maturity levels, with a concurrent reduction in the odd/even carbon predominance. In crude oils, in contrast, the relative abundance of C 40 compounds appears to relate closely with the oil source and oil viscosity.  相似文献   

3.
Carbon isotope ratios (δ 13C) of 89 C4 plant samples were determined from the loess area in North China. δ 13C values vary between −10.5‰ and −14.6‰ with a mean of −12.6‰. Along a precipitation gradient from the semi-moist area to the semiarid area, then to the arid area, the δ 13C values of C4 plants show a slight decreasing trend. The δ 13C values of C4 plants in the dry season are found lower than those in the wet season. These trends are opposite to those observed for C3 species.  相似文献   

4.
We describe analytical details and uncertainty evaluation of a simple technique for the measurement of the carbon isotopic composition of CO2 in volcanic plumes. Data collected at Solfatara and Vulcano, where plumes are fed by fumaroles which are accessible for direct sampling, were first used to validate the technique. For both volcanoes, the plume-derived carbon isotopic compositions are in good agreement with the fumarolic compositions, thus providing confidence on the method, and allowing its application at volcanoes where the volcanic component is inaccessible to direct sampling. As a notable example, we applied the same method to Mount Etna where we derived a δ13C of volcanic CO2 between −0.9 ± 0.27‰ and −1.41 ± 0.27‰ (Bocca Nuova and Voragine craters). The comparison of our measurements to data reported in previous work highlights a temporal trend of systematic increase of δ13C values of Etna CO2 from ~ −4‰, in the 1970’s and the 1980’s, to ~ −1‰ at the present time (2009). This shift toward more positive δ13C values matches a concurrent change in magma composition and an increase in the eruption frequency and energy. We discuss such variations in terms of two possible processes: magma carbonate assimilation and carbon isotopic fractionation due to magma degassing along the Etna plumbing system. Finally, our results highlight potential of systematic measurements of the carbon isotopic composition of the CO2 emitted by volcanic plumes for a better understanding of volcanic processes and for improved surveillance of volcanic activity.  相似文献   

5.
The carbon isotopic compositions of individual lip-ids can provide the genetic information about sedi-mentary lipids so that it has extensively applied pros-pects in geochemically studied field[1―8]. However, this applied research relies heavily on the accumula-tion of studied data in the genetic relationships between carbon isotopic compositions of individual lipids and their biological precursors in different sedi-mentary environments. Recently, the useful δ 13C data of individual lipids f…  相似文献   

6.
A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS 230Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ 18O and δ 13C, mostly in the 2.3–26 cm part. The δ 18O and δ 13C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ 18O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ 18O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ 18O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ 18O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ 18O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)  相似文献   

7.
A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.34 was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3) between carbonate and B(OH)3 in seawater range 0.937 and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and collaborators show that the αcarb-3 values between carbonate and B(OH)3 in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ11B4-pH curves and neither do they exactly parallel any theoretical δ11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3 with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4 − in carbonate. Hence, in the reconstruction of the paleo-pH of seawater from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic fractionation factor (α4−3) between B(OH)4 − and B(OH)3 is not suitable. Instead, an empirical equation should be established. Supported by National Natural Science Foundation of China (Nos. 40573013 and 40776071), State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences (Grant No SKLLQG0502) and State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences  相似文献   

8.
Discrimination of abiogenic and biogenic alkane gases   总被引：5，自引：0，他引：5  
We have combined the analytical data of the carbon isotope distribution pattern, R/Ra and CH4/3He values of abiogenic and biogenic (referring to the thermogenic and bacterial or microbial) alkane gases in China with those of alkane gases from USA, Russia, Germany, Australia and other countries. Four discrimination criteria are derived from this comparative study: 1) Carbon isotopic composition is generally greater than -30‰ for abiogenic methane and less than -30‰ for biogenic methane; 2) Abiogenic alkane gases have a carbon isotopic reversal trend (δ 13C1> δ 13C2> δ 13C3> δ 13C4) with δ 13C1>-30‰ in general; 3) Gases with R/Ra >0.5 and δ 13C11 δ 13C2>0 are of abiogenic origin; 4) Gases (meth- ane) with CH4/3He≤106 are of abiogenic origin, whereas gases with CH4/3He≥1011 are of biogenic origin.  相似文献   

9.
Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ 18O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ 18O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ 18O and temperature suggests that δ 18O can be used as an indicator of temperature in this region. The δ 18O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.  相似文献   

10.
In the reconstruction of past climate using stable carbon isotope composition (δ13C) in tree ring, the responses of the stable carbon composition (δ13C) of multiple tree species to environmental factors must be known detailedly. This study presented two δ13C series in annual tree rings for Chinese hemlock (Tsuga chinensis Pritz) and alpine pine (Pinus densata Mast), and investigated the relationships between climatic parameters and stable carbon discrimination (Δ13C) series, and evaluated the potential of climatic reconstruction using Δ13C in both species, in a temperate-moist region of Chuanxi Plateau, China. The raw δ13C series of the two species was inconsistent, which may be a result of different responses caused by tree's inherent physiological differences. After removing the low-frequency effects of CO2 concentration, the high-frequency (year-to-year) inter-series correlation of Δ13C was strong, indicating that Δ13C of the two tree species were controlled by common environmental conditions. The Δ13C series of the species were most significantly correlated with temperature and moisture stress, but in different periods and intensity between the species. During the physiological year, the impacts of temperature and moisture stress on Δ13C occur earlier for Chinese hemlock (previous December to February for moisture stress and February to April for temperature, respectively) than for alpine pine (March to May for moisture stress and April to July for temperature, respectively). In addition, in temperatemoist regions, the control on Δ13C of single climatic parameter was not strongly dominant and the optimal multiple regressions functions just explained the 38.5% variance of the total. Therefore, there is limited potential for using δ13C alone to identify clear, reliable climatic signals from two species.  相似文献   

11.
This study presents baseline data for future geochemical monitoring of the active Tacaná volcano–hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO3–SO4 waters are thought to have formed by the absorption of a H2S/SO2–CO2-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO3-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ18O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at ~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ18O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO2-dominated. The δ13CCO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in 3He/4He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric 3He/4He ratio (R A)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (4He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO2/3He ratio of gases: bubbling springs with lower gas/water ratios show higher 3He/4He ratios and consequently lower CO2/3He ratios (e.g. Zarco spring). Typical Central American CO2/3He and 3He/4He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 1010 and 6.0 ± 0.9 R A, respectively). The L/S (5.9 ± 0.5) and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc, Tacaná.  相似文献   

12.
Abiogenic hydrocarbons in commercial gases from the Songliao Basin, China   总被引：3，自引：0，他引：3  
This paper discusses the kinetic fractionation, composition and distribution characteristics of carbon and hydrogen isotopes for various alkane gases formed in different environments, by different mecha- nisms and from different sources in nature. It is demonstrated that the biodegradation or thermode- gradation of complex high-molecule sedimentary organic material can form microbial gas or thermogenic gas. The δ 13C1 value ranges from -110‰ to -50‰ for microbial gases but from -50‰ to -35‰ (even heavier) f...  相似文献   

13.
The distribution of two formation pathways of biogenic methane, acetate fermentation and reduction of CO2, has been extensively studied. In general, CO2 reduction is the dominate pathway in marine envi- ronment where acetate is relatively depleted because of SRB consuming. While in terrestrial freshwater or brackish environment, acetate fermentation is initially significant, but decreases with increasing buried depth. In this paper, character of biogenic gases is profiled in the XS3-4 well of the Sebei 1 gas field in the Sanhu depression, Qaidam Basin. It indicates that those two pathways do not change strictly with increasing buried depth. CO2 reduction is important near the surface (between 50 m and 160 m), and at the mesozone (between 400 and 1650 m). While acetate fermentation is the primary pathway at two zones, from 160 to 400 m and from 1650 to 1700 m. δ 13C of methane generated in those two acetate fermentation zones varies greatly, owing to different sediment circumstances. At the sec- ond zone (160-400 m), δ 13C1 ranges from ?65‰ to ?30‰ (PDB), because the main deposit is mudstone and makes the circumstance confined. At the fourth zone of the well bottom (1650-1700 m), δ 13C1 is lighter than ?65‰ (PDB). Because the deposit is mainly composed of siltstone, it well connects with outer fertile groundwater and abundant nutrition has supplied into this open system. The high con- centration of acetate is a forceful proof. δ 13C of methane would not turn heavier during fermentation, owing to enough nutrition supply. In spite of multi-occurrence of acetate fermentation, the commercial gas accumulation is dominated by methane of CO2-reduction pathway. A certain content of alkene gases in the biogenic gases suggests that methanogensis is still active at present.  相似文献   

14.
Despite great achievements in the origins of domestic pigs made by the methods of zooarchaeology and molecular biology, how to scientifically distinguish the domesticated pigs from wild boars during the early stage of pig domestication is still poorly understood. Compared to wild boar’s diets which come from the natural environment, the diets of domestic pigs are more easily influenced by human feeding activities. Therefore, in principle, exploration of the dietary differences among pigs and under-standing the impact on pig diets fed by humans can have great potential to differentiate between wild boars and domesticated pigs. To reveal dietary differences among pigs and distinguish the domesticated pigs from wild boars based on comparison with the diets of humans and other animals, we analyzed the carbon and nitrogen stable isotopes of human bones from Xiaojingshan Site and animal bones from Yuezhuang Site, both of which belong to Houli Culture in Shandong Province and date to about 8500-7500 years ago. The mean δ13C value ((−17.8 ± 0.3)‰) and δ15N value ((9.0±0.6)‰) in human collagen indicate that although millet agriculture began it was not the main subsistence strategy as millets are typical of C4 plants and that humans made a living mainly by gathering, hunting or raising some domesticated animals. The δ13C value (−16.1‰) and δ15N value (6.9‰) in the bovine suggest that C3 plants were dominant in its diet with some C4 plants complemented. The fish has lower δ13C value (−24.9‰) and higher δ15N value (8.8‰) than the bovine, which is the characteristic of the isotopic values from Eurasian freshwater fish. Based on the differences in carbon and nitrogen isotope values, the pigs can be divided into three groups. A group, composed of two pigs, has low δ13C values (−18.1‰, −20.0‰) and low δ15N values (4.7‰, 6.0‰). B group, only one pig, has the highest δ13C value (−10.6‰) and mediate δ15N value (6.4‰). As for the C group, also only one pig, low δ13C value (−19.0‰) and the highest δ15N value (9.1‰) are observed. Previous studies on the stable isotopes from modern or ancient wild boars’ bones have suggested that C3 plants are predominated in their diets and that their δ15N values are close to those in herbivores and far from those in carnivores. Based on the comparison with the isotope values from humans, the wild boars and the domestic pigs from Xipo Site in Henan 6000-5500 years ago and Kangjia Site in Shaanxi 4500-4000 years ago, we conclude that A pig group belongs to wild boars while B and C groups can be attributed to domesticated pigs. Supported by Max-Planck Society and Chinese Academy of Sciences, Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KJCX3.SYW.N12), National Natural Science Foundation of China (Grant No. 40702003) and President Funding of Graduate University of Chinese Academy of Sciences  相似文献   

15.
(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determination of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, pace group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some metallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525-0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893-0.2169 nm. The coordination number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonalprismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.  相似文献   

16.
Stable carbon and oxygen isotopes have been observed in dinosaur eggshell samples,identified as Macroolithus yaotunensis,collected in two sections of the Nanxiong Basin,Guangdong Province,South China.Multiple positiveδ18O perturbations that occurred during the K/T transition of about 150 ka suggest that there may have been at least three periods of the extreme dry climate with a mean annual air temperature over 27℃.δ13C ranges from -8.37‰ to -11.60‰ of the dinosaur eggshells,added to the metabolic enrichment of 16‰,may indicate that the dinosaurs represented by this type of eggshells probably consumed the plant species of C3 type with the δ13C values of -24.3‰- -27.6‰.Moreover,the trend toward more negative δ13C values of the eggshells during the K/T transition could be an indirect consequence of a lasting increase in atmospheric CO2 concentration.  相似文献   

17.
We present an uncertainty analysis of ecological process parameters and CO2 flux components (R eco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance measurements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different models and optimization methods in influencing estimation of key parameters and CO2 flux components. The results show that: (1) Random flux error more closely follows a double-exponential (Laplace), rather than a normal (Gaussian) distribution. (2) Different optimization methods result in different estimates of model parameters. Uncertainties of parameters estimated by the maximum likelihood estimation (MLE) are lower than those derived from ordinary least square method (OLS). (3) The differences between simulated Reco, NEE and GEE derived from MLE and those derived from OLS are 12.18% (176 g C·m−2·a−1), 34.33% (79 g C·m−2·a−1) and 5.4% (92 g C·m−2·a−1). However, for a given parameter optimization method, a temperature-dependent model (T_model) and the models derived from a temperature and water-dependent model (TW_model) are 1.31% (17.8 g C·m−2·a−1), 2.1% (5.7 g C·m−2·a−1), and 0.26% (4.3 g C·m−2·a−1), respectively, which suggested that the optimization methods are more important than the ecological models in influencing uncertainty in estimated carbon fluxes. (4) The relative uncertainty of CO2 flux derived from OLS is higher than that from MLE, and the uncertainty is related to timescale, that is, the larger the timescale, the smaller the uncertainty. The relative uncertainties of Reco, NEE and GEE are 4%−8%, 7%−22% and 2%−4% respectively at annual timescale. Supported by the National Natural Science Foundation of China (Grant No. 30570347), Innovative Research International Partnership Project of the Chinese Academy of Sciences (Grant No. CXTD-Z2005-1) and National Basic Research Program of China (Grant No. 2002CB412502)  相似文献   

18.
High-resolution sampling, measurements of organic carbon contents and 14C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of 14C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO2 flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×104 kg C hm−2 to 30.75×104 kg C hm−2 in the alpine meadow ecosystems, with an average of 26.86×104 kg C hm−2. Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO2 flux ranges from 103.24 g C m−2 a−1 to 254.93 gC m−2 a−1, with an average of 191.23 g C m−2 a−1. The CO2 efflux produced from microbial decomposition of organic matter varies from 73.3 g C m−2 a−1 to 181 g C m−2 a−1. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO2 emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)  相似文献   

19.
The Luliang and Baoshan basins are two small ba- sins in Yunnan Province. In the recent ten years or so, there have been found a number of natural gas pools of commercial importance in the two basins. Although the gas pools are small in size, the natural …  相似文献   

20.
Two types of Hepialus larvae with different diets were distinguished in the Sejila Mountain, Tibetan Plateau based on the stable carbon isotope data of the host Hepialus larva of Cordyceps sinensis and its closely adjacent tender plant roots and humus fractions. Type I is the larva chiefly fed by soil humus, and characterized by the δ 13C values of −22.6‰ to −23.4‰, and more than −23.4‰ in its heads. Type II is the larva chiefly fed by tender plant roots, and characterized by the δ 13C values of −24.6‰ to −27.6‰, and less than −24.6‰ in its heads. Our result has exceeded the traditional understanding that their food sources only come from the tender plant roots, and may provide evidence for choosing cheap and high-quality foods and further establishing artificial habitats in their large-scale reproduction. Supported by the National Key Technology R & D Program (Grant No. 2007BAI32B05)  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号