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1.
Geologic and geochemical variations across a 4200 km2 area of south-central Wisconsin (USA) were used to examine their relationship to phosphorus concentrations in groundwater from more than four hundred private water supply wells. Surficial geology in the study area ranged from Cambrian sandstones to Ordovician dolomites. Groundwater phosphorus concentrations were higher in aquifers of older Cambrian age compared to the concentrations in aquifers of younger Cambrian and Ordovician age. Because iron concentrations were relatively low in these waters and agricultural land use was similar in all geologic regions, we propose that the differences in bedrock phosphorus and anthropogenic geochemical impacts explain the differences in phosphorus concentrations between aquifers. Within the older Cambrian aquifers, groundwater phosphorus concentrations were elevated in groundwater with higher nitrate-nitrogen concentrations. This finding is consistent with the presence of phosphorus within sediment in these strata and geologic conditions that weakly buffered pH reduction from anthropogenic acidification. In contrast, groundwater phosphorus concentrations in younger Cambrian and Ordovician aquifers were not elevated in samples with higher nitrate. Anthropogenic acidification in these carbonate-rich aquifers was neutralized through increased carbonate weathering, which led to higher groundwater calcium and alkalinity and would limit the dissolution of phosphate-rich minerals, such as apatite, where present. Low iron concentrations observed in most samples suggest that the phosphorus release in the Cambrian strata occurs beyond the zone of secondary mineral retention in the soil. These results have important implications for the eutrophication of inland surface waters in areas with bedrock phosphorus and anthropogenic acidity that is not neutralized before it contacts phosphatic rock.  相似文献   

2.
The dependency of people on groundwater has increased in the past few decades due to tremendous increase in crop production, population and industrialization. Groundwater is the main source of irrigation in Shiwaliks of Punjab. In the present study the samples were collected from predetermined location as was located on satellite image on basis of spectral reflectance. Global positioning system was used to collect samples from specific locations. Principal components analysis (PCA) together with other factor analysis procedures consolidate a large number of observed variables into a smaller number of factors that can be more readily interpreted. In the present study, concentrations of different constituents were correlated based on underlying physical and chemical processes such as dissociation, ion exchange, weathering or carbonate equilibrium reactions. The PCA produced six significant components that explained 78% of the cumulative variance. The concentration of the few trace metals was found to be much higher indicating recharge due to precipitation as main transport mechanism of transport of heavy metals in groundwater which is also confirmed by PCA. Piper and other graphical methods were used to identify geochemical facies of groundwater samples and geochemical processes occurring in study area. The water in the study area has temporary hardness and is mainly of Ca–Mg–HCO3 type.  相似文献   

3.
银川平原深层地下水14C年龄校正   总被引：7，自引：1，他引：6  
地下水14C年龄的校正精度取决于对地下水溶解无机碳演化过程中影响地下水14C活度主要因素的准确识别及其影响程度的定量评价。以银川平原为例,在进行银川平原承压水反向地球化学反应路径模拟的基础上,识别出影响区内深层地下水碳酸演化的主要作用并进行深层地下水14C年龄的校正。研究认为,控制银川平原深层地下水化学演化的主要反应路径为碳酸盐矿物的沉淀和长石、角闪石、石膏等矿物的溶解以及Ca-Na离子交换。地下水流路径上所发生的水文地球化学反应对路径上14C的浓度变化影响较小。地下水14C年龄校正结果表明,除补给区和承压水水位漏斗区外,银川平原承压水年龄均在2 000 a以上,属“古水”,天然条件下径流缓慢、地下水更新速度小。在承压水水位漏斗区外,沿地下水流方向,地下水年龄逐渐增大;而在承压水集中开采区,承压水的年龄明显小于路径上游地下水,潜水与承压水之间的垂向水力联系比较密切。  相似文献   

4.
The systematic sampling of the chemical composition of the groundwater from five karst springs (including an overflow spring) and one outflowing borehole have permitted to determine distinctive chemical changes in the waters that reflect the geochemical processes occurring in a carbonate aquifer system from southern Spain. The analysis of the dissolution parameters revealed that geochemical evolution of the karst waters basically depends on the availability of the minerals forming aquifer rocks and the residence time within the aquifers. In the three proposed scenarios in the aquifers, which include the preferential flow routines, the more important geochemical processes taking place during the groundwater flow from the recharge to the discharge zones are: CO2 dissolution and exsolution (outgassing), calcite net dissolution, calcite and dolomite sequential dissolution, gypsum/anhydrite and halite dissolution, de-dolomitization and calcite precipitation. A detailed analysis of the hydrochemical data set, saturation indices of the minerals and partial pressure of CO2 in the waters joined to the application of geochemical modelling methods allowed the elaboration of a hydrogeochemical model of the studied aquifers. The developed approach contributes to a better understanding of the karstification processes and the hydrogeological functioning of carbonate aquifers, the latter being a crucial aspect for the suitable management of the water resources.  相似文献   

5.
The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.  相似文献   

6.
Shallow groundwater is one of the main water resources in the arid and semi-arid regions. However, it is threatened by not only the reduced rainfall and recharge capacity, but also the water table drawdown and seawater intrusion. Such factors could cause a deterioration of the water quality and consequently the loss of a valuable hydraulic resource. This study aimed to improve our knowledge on the groundwater chemical quality evolution of the Sfax shallow aquifer, one of the most vulnerable areas in Tunisia, by developing a geochemical study using statistical and numerical methods. Salinization was identified by factorial analysis, PCA, and hierarchical clustering analysis in addition to the numerical MODPATH model. These findings confirmed that the groundwater quality has deteriorated due to natural and anthropogenic processes with a different influence of mineralization factors. They also revealed the location of seawater intrusion by focusing on the most vulnerable areas which are Chaffar and Djbeniana. Methodologically, the use of MODPATH model for seawater intrusion determination might be considered as the backbone for future studies in Tunisian coastal aquifers. The numerical model supports the results obtained by the geochemical analysis. Both methods are valuable tools as they contribute to trend determinations, management, and recovery plans.  相似文献   

7.
The study of brine aquifers in southern Taiwan is highly complicated by hybrid geochemical reactions, which obscure important geochemical information. Using multivariate analysis on major and minor ion compositions normalized by Cl− content, chemical constituents were combined into two principal components representing brine mixing and mineral precipitation. Comparing to multivariate analysis on the original data, this procedure reveals more geochemical information. It demonstrates that the brine groundwater of the region is primarily composed of highly evaporated seawater. The evaporation ratio is >70%; a point at which calcite, dolomite and gypsum precipitate. Oxygen and hydrogen isotopic compositions confirm this inference; and further, geochemical modeling quantitatively determined the evaporation ratio to be about 85%. Natural boron contamination is a consequence of brine groundwater. Two evolutionary trends in the plotting of the Cl/B ratio versus Cl− can be identified: (1) Cl/B ratio decreases with boron being released from clay minerals when brine aquifers are flushed with freshwater; and (2) Cl/B ratio increases when seawater of a high Cl/B ratio infiltrates coastal aquifers.  相似文献   

8.
Detailed geochemical analysis of groundwater beneath 1223 km2 area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: ‘excellent’, ‘good’ and ‘poor’ and seven hydrochemical facies are assigned to three broad types: ‘fresh’, ‘mixed’ and ‘brackish’ waters. The ‘fresh’ water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich ‘brackish’ groundwater represents freshening of modified connate water. The ‘mixed’ type groundwater has possibly evolved due to hydraulic mixing of ‘fresh’ and ‘brackish’ waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.  相似文献   

9.
A study was conducted to bring out the relationship and behavior of different Saturation Index (SI) of carbonate minerals in layered coastal aquifers. Carbonates present in groundwater aids in different nature of the water like hardness, partial pressure of carbon-di-oxide (pCO2), pH and saturation index of different carbonate minerals at various temperatures. The SI of the carbonates helps us to define the thermodynamic stability of water and to find out the geochemical behavior of water. 98 groundwater samples were collected from specific aquifers (alluvium, upper Cuddalore, lower Cuddalore and Cretaceous) during Pre-Monsoon (May 2007) and Post-Monsoon (January 2008) seasons. The physicochemical parameters such as pH, EC, Ca, Mg, Na, K, Cl, HCO3, SO4 and PO4 were analyzed. Geochemical model, WATEQ4F was used to calculate the SI of different minerals. The SI was studied in relation to mHCO3 concentration, pCO2 and correlation between SI of different minerals.  相似文献   

10.
The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.  相似文献   

11.
Fluoride (F?) is essential for normal bone growth, but higher concentration in the drinking water causes health problems which are reported in many states of India. Andhra Pradesh is one of the states which suffer from excess fluoride in groundwater particularly in the hard rock terrain. In this context, a study was conducted in Andhra Pradesh based on chemical analysis of water samples from hydrograph net work stations (dug wells) and exploratory bore wells. The concentration of fluoride in groundwaters ranges from traces to 9.75 mg/l. The occurrence of fluoride is mostly sporadic, uneven and varies with depth. The highly affected districts include Nalgonda and Warangal in Telangana region, Prakasam in coastal region, Anantapur and Kurnool in Rayalaseema region. In certain areas of Nalgonda district, 85% of wells have fluoride more than permissible limit (> 1.5 mg/l) for drinking water. High F? is present in all the geological formations, predominantly in granitic aquifers, compared to the other formations. The average value of fluoride is high in the deeper zone (1.10 mg/L), compared to the shallow zone (0.69 mg/L). The fluoride-rich minerals present are the main sources for fluoride concentrations in groundwater. Residence time, evapotranspiration and weathering processes are some of the other supplementary factors for high fluoride concentrations in groundwater. Long-term data of hydrograph net work stations (dug wells) reveal that fluoride concentrations do not show any marked change of trend with respect to time. The concentration of fluoride is found to increase with increase of Na+and HCO 3 ? , and decrease with increase of Ca2+. Sodium bicarbonate waters are more effective in releasing fluoride from minerals into groundwater. High fluoride waters are of Na+ type. The paper presents a brief account of the study and its results.  相似文献   

12.
Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO4 water type with little contribution of Ca–Mg–HCO3, Na–K–Cl–SO4 and Na–K–HCO3. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO4, HCO3, pCO2, Ca, Mg, Na, K, Cl and NO3). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).  相似文献   

13.
In the current research to determine the mineralization pattern and discuss the mineralization components, the information of position - scale domain of geochemical data has been analyzed. A new method is proposed based on coupling discrete wavelet transforms (DWT) and principal component analysis (PCA) for mineralization elements forecasting applications. The results of this study indicate the potential of DWT–PCA method for geochemical data processing. Wavelet transform (WT), as a multi-spectral analysis method, can decompose the spatial and temporal signals into different frequencies. The features of mineralization can be identified using the position - scale domain of geochemical data that may not be achievable in spatial domain. The geochemical data from the Dalli region have been processed in the spatial domain using PCA. The surface geochemical data of 30 elements have been transformed to position–scale domain using two-dimensional discrete wavelet transform (2DDWT). Wavelet functions (WFs) of Haar, Coiflet2, Biorthogonal3.3 and Symlet7 have been applied separately to decompose the geochemical data to high and low frequencies in one level. To obtain more accurate and complete information of mineralization, a new index has been presented based on wavelet coefficients. Based on this new index, significant results have been obtained by using PCA of the index. The coefficients distribution map (CDM) as a new exploratory criterion has been generated based on 2DDWT to show the geochemical distribution map (GDM). Finally, the results of WT have been compared with the results of spatial domain and the best method of wavelet for interpretation of geochemical data has been introduced. The results of geochemical data analysis by DWT–PCA approach have been confirmed by the exploratory drillings in the study area.  相似文献   

14.
Insufficient knowledge of the hydrogeochemistry of aquifers in the Central Region of Ghana has necessitated a preliminary water quality assessment in some parts of the region. Major and minor ions, and trace metal compositions of groundwater have been studied with the aim of evaluating hydrogeochemical processes that are likely to impair the quality of water in the study area. The results show that groundwater in the area is weakly acidic with mean acidity being 5.83 pH units. The dominant cation in the area is Na, followed by K, Ca, and Mg, and the dominant anion is Cl?, followed by HCO3 ? and SO4 2?. Two major hydrochemical facies have been identified as Na–Cl and Na–HCO3, water types. Multivariate statistical techniques such as cluster analysis (CA) and factor analysis/principal component analysis (PCA), in R mode, were employed to examine the chemical compositions of groundwater and to identify factors that influenced each. Q-mode CA analysis resulted in two distinct water types as established by the hydrochemical facies. Cluster 1 waters contain predominantly Na–Cl. Cluster 2 waters contain Na–HCO3 and Na–Cl. Cluster 2 waters are fresher and of good quality than cluster 1. Factor analysis yielded five significant factors, explaining 86.56% of the total variance. PC1 explains 41.95% of the variance and is contributed by temperature, electrical conductivity, TDS, turbidity, SO4 2?, Cl?, Na, K, Ca, Mg, and Mn and influenced by geochemical processes such as weathering, mineral dissolution, cation exchange, and oxidation–reduction reactions. PC2 explains 16.43% of the total variance and is characterized by high positive loadings of pH and HCO3 ?. This results from biogenic activities taking place to generate gaseous carbon dioxide that reacts with infiltrating water to generate HCO3 ?, which intend affect the pH. PC3 explains 11.17% of the total variance and is negatively loaded on PO4 3? and NO3 ? indicating anthropogenic influence. The R-mode PCA, supported by R-mode CA, have revealed hydrogeochemical processes as the major sources of ions in the groundwater. Factor score plot revealed a possible flow direction from the northern sections of the study area, marked by higher topography, to the south. Compositional relations confirmed the predominant geochemical process responsible for the various ions in the groundwater as mineral dissolution and thus agree with the multivariate analysis.  相似文献   

15.
The groundwaters from Zhongxiang City, Hubei Province of central China, have high fluoride concentration up to 3.67 mg/L, and cases of dental fluorosis have been found in this region. To delineate the nature and extent of high fluoride groundwaters and to assess the major geochemical factors controlling the fluoride enrichment in groundwater, 14 groundwater samples and 5 Quaternary sediment samples were collected and their chemistry were determined in this study. Some water samples from fissured hard rock aquifers and Quaternary aquifers have high fluoride concentrations, whereas all karst water samples contain fluoride less than 1.5 mg/L due to their high Ca/Na ratios. For the high fluoride groundwaters in the fissured hard rocks, high HCO3 − concentration and alkaline condition favor dissolution of fluorite and anion exchange between OH− in groundwater and exchangeable F− in some fluoride-bearing minerals. For fluoride enrichment in groundwaters of Quaternary aquifers, high contents of fluoride in the aquifer sediments and evapotranspiration are important controls.  相似文献   

16.
The present study aims to evaluate the possible source of major and some minor elements and heavy metals in the groundwater of Qareh-Ziaeddin plain, NW Iran with respect to chemical elements, saturation index, and multivariate statistics including correlation coefficient, cluster analysis, and factor analysis. Groundwater samples were collected in Jun 2016 and measured with respect to EC, pH, major and some minor elements and heavy metals including Fe, Mn, Zn, Cr, Pb, Cd, Al, and As. Among all the measured parameters, some of the samples exceed the World Health Organization (WHO) guideline value for EC, Na, Mg, HCO3, SO4, Cl, NO3, F, As, Zn, and Pb. The results of correlation analysis show that weathering and dissolution of minerals especially evaporites and silicates, water-rock interaction, and cation exchange are dominant occurred processes in the groundwater of the study area. Also, denitrification process is occurred in the groundwater system. Cluster analysis categorizes the samples into three distinct groups which are different based on their EC and dependent variables, e.g., Na, Ca, Cl, SO4 and pH, Pb, Cd, and As. It can be found that volcanic, evaporite, and clay formations have the least impact on the chemistry of the cluster 1 samples while clay and evaporite formations have the highest impact on the cluster 3 and also calcareous formations on cluster 2. Factor analysis shows that five factors, with total variance of 83%, are effective in the release of heavy metals and groundwater chemistry which are mostly geogenic.  相似文献   

17.
The lower Liaohe River Plain (LRP) is an economically and ecologically important area situated on an alluvial plain, where anthropogenic activities are very intensive. Field investigations were conducted in the LRP and 15 water quality parameters surveyed at 216 wells during September and October of 2009 and 2010. These showed significant variation in the hydrochemistry of groundwater throughout the plain. A Piper plot was used to identify the major geochemical processes occurring in the entire plain. Principal components analysis (PCA) was used to identify various underlying natural and anthropogenic processes that created these distinct water types. The Stuyfzand classification was used to subdivide and interpret the complex groundwater hydrochemistry of the Liaohe River delta. Five principal components (PCs) were extracted in terms of PCA, which can be invoked to explain 82% of the total variance in water quality parameters. The PCA results can be categorized by five major factors: (1) Holocene transgression and mixing; (2) surface water infiltration; (3) multi-factor processes; (4) rainfall and agricultural fertilizer contamination; and (5) Geogenic F enrichment. This study demonstrates that the great variation of groundwater hydrochemistry in the LRP should be attributed to both natural and anthropogenic processes.  相似文献   

18.
In Scopia basin, central Greece, a hydrochemical investigation was completed. Groundwater samples from 41 sites were used to assess the natural and anthropogenic impacts in groundwater, utilizing the principal component analysis (PCA) involved with the inverse distance weighted (IDW) interpolation modeling and hierarchical cluster analysis (HCA). Best fit model to explain the spatial distribution of both hydrochemical parameters and PCA was chosen by optimizing the IDW interpolator’s parameters. Precision of the model was picked based on less root-mean-squared prediction error (RMSPE) amongst predicted and actual values measured at the same locations. Groundwater exhibit Ca–Mg–HCO3 as the dominant hydrochemical type and their greater part are mixed waters with non-dominant ion. Interpolation models demonstrate high estimations of nitrates in zones with agricultural activities and high estimations of nickel and chromium in regions with the strong presence of ultrabasic rocks. Dominant part of the groundwater samples surpasses in many cases the European Community (EC) drinking water permissible limits. Thus, they are unsuitable for human consumption. PCA illustrated four factors, which clarified 80.62% of the aggregate variance of data and HCA classified two statistically significant clusters of sampling sites. Results show natural procedures ascribed to the weathering of the minerals contained in the ultrabasic rocks and anthropogenic influences related to the use of fertilizers and wastewater leak. In light of FAO standards and Richards’s classification, the groundwaters are reasonable for irrigation purposes, featuring waters with low sodium hazard and moderate salinity hazard.  相似文献   

19.
水文地球化学方法在研究矿区水文地质条件中的应用   总被引：8，自引：0，他引：8  
应用水文地球化学方法,研究了肥城西部矿区不同含水层的水化学特征,分析了它们相互间水力联系方式与联系程度,推断了奥灰水越流补给煤系灰岩水的补给地段,大致估计了其补给量,为防治水方案的制定提供了依据。   相似文献   

20.
Rapid population growth, industrialization, and agricultural expansion in the Khoy area (northwestern Iran) have led to its dependence on groundwater and degradation of groundwater quality. This study attempts to decipher the major processes and factors that degrade the groundwater quality of the Khoy plain. For this purpose, 54 groundwater samples from unconfined and confined aquifers of the plain were collected in July 2017 and analyzed for major cations and anions (Na, K, Ca, Mg, HCO3, SO4, and Cl), minor ions (NO3 and F), and Al. Magnesium and bicarbonate were identified as the dominant cation and anion, respectively. Several ionic ratios and geochemical modeling using PHREEQC indicated that the most important hydrogeochemical processes to affect groundwater quality in the plain were weathering and dissolution of evaporitic and silicate minerals, mixing, and ion exchange. There were smaller effects from evaporation and anthropogenic factors (e.g., industries). Results showed that the high salinity of the groundwater in the northeast area of the plain was due to the high solubility of the evaporitic minerals, e.g., halite and gypsum. Reverse ion exchange and the contribution of mineral dissolution were more significant than ion exchange in the northeastern part of the plain. Elevated salinity of the groundwater in the southeast was attributed mostly to reverse ion exchange and somewhat to evaporation.  相似文献   

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