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1.
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2.
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3.
Seismic coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) characteristics in the Garhwal region, northwestern Himalaya is studied using 113 short-period, vertical component seismic observations from local events with hypocentral distance less than 250?km and magnitude range between 1.0 to 4.0. They are located mainly in the vicinity of the Main Boundary Thrust (MBT) and the Main Central Thrust (MCT), which are well-defined tectonic discontinuities in the Himalayas. Coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) is estimated using the single isotropic scattering method at central frequencies 1.5, 3, 5, 7, 9, 12, 16, 20, 24 and 28?Hz using several starting lapse times and coda window lengths for the analysis. Results show that the ( $ Q_{\text{c}}^{ - 1} $ ) values are frequency dependent in the considered frequency range, and they fit the frequency power law ( $ Q_{\text{c}}^{ - 1} \left( f \right) = Q_{0}^{ - 1} f^{ - n} $ ). The Q 0 (Q c at 1?Hz) estimates vary from about 50 for a 10?s lapse time and 10?s window length, to about 350 for a 60?s lapse time and 60?s window length combination. The exponent of the frequency dependence law, n ranges from 1.2 to 0.7; however, it is greater than 0.8, in general, which correlates well with the values obtained in other seismically and tectonically active and highly heterogeneous regions. The attenuation in the Garhwal region is found to be lower than the Q c ?1 values obtained for other seismically active regions of the world; however, it is comparable to other regions of India. The spatial variation of coda attenuation indicates that the level of heterogeneity decreases with increasing depth. The variation of coda attenuation has been estimated for different lapse time and window length combinations to observe the effect with depth and it indicates that the upper lithosphere is more active seismically as compared to the lower lithosphere and the heterogeneity decreases with increasing depth.  相似文献   

4.
The TKE dissipation rate in the northern South China Sea   总被引：1，自引：0，他引：1  
The microstructure measurements taken during the summer seasons of 2009 and 2010 in the northern South China Sea (between 18°N and 22.5°N, and from the Luzon Strait to the eastern shelf of China) were used to estimate the averaged dissipation rate in the upper pycnocline 〈ε p〉 of the deep basin and on the shelf. Linear correlation between 〈ε p〉 and the estimates of available potential energy of internal waves, which was found for this data set, indicates an impact of energetic internal waves on spatial structure and temporal variability of 〈ε p〉. On the shelf stations, the bottom boundary layer depth-integrated dissipation $ {\widehat{\varepsilon}}_{\mathrm{BBL}} $ reaches 17–19 mW/m2, dominating the dissipation in the water column below the surface layer. In the pycnocline, the integrated dissipation $ {\widehat{\varepsilon}}_{\mathrm{p}} $ was mostly ～10–30 % of $ {\widehat{\varepsilon}}_{\mathrm{BBL}} $ . A weak dependence of bin-averaged dissipation $ \overline{\varepsilon} $ on the Richardson number was noted, according to $ \overline{\varepsilon}={\varepsilon}_0+\frac{\varepsilon_{\mathrm{m}}}{{\left(1+ Ri/R{i}_{\mathrm{cr}}\right)}^{1/2}} $ , where ε 0 + ε m is the background value of $ \overline{\varepsilon} $ for weak stratification and Ri cr?=?0.25, pointing to the combined effects of shear instability of small-scale motions and the influence of larger-scale low frequency internal waves. The latter broadly agrees with the MacKinnon–Gregg scaling for internal-wave-induced turbulence dissipation.  相似文献   

5.
A new methodology is developed to estimate an aquatic community toxicity threshold concentration based on the limited toxicity data that are available for thiosalts. To analyze the indirect effect of thiosalts on decreasing pH, an exposure model is developed that estimates the residual concentration of thiosalts and pH in the water body. The results from this model are incorporated in thiosalts risk assessment and a case study is used to illustrate the applicability of the proposed model. In this study, the exposure model predicts that, trithionate and tetrathionate degraded to $ {{\text{SO}}_{4}}^{2 - } $ ions, $ {{\text{HSO}}_{3}}^{ - } $ ions, $ {{\text{SO}}_{3}}^{2 - } $ ions and elemental sulfur. The concentration of thiosulfate, trithionate and tetrathionate, initially at 25, 40 and 6 mg/L, respectively are expected to decrease. Over the duration of 77 h, thiosulfate degrades completely, while the estimated residual trithionate and tetrathionate concentrations are 13 and 5.77 mg/L, respectively. pH of the undiluted effluent is estimated to decrease from 9.2 to 5.6 within an hour of the effluent discharge and decreases further to 4 over a period of next 3 days. A framework and methodology developed in this paper can be utilized to estimate the potential direct and indirect risk of thiosalts exposure to ecological entities.  相似文献   

6.
Photochemistry of Ions at D-region Altitudes of the Ionosphere: A Review   总被引：2，自引：2，他引：0  
The current state of knowledge of the D-region ion photochemistry is reviewed. Equations determining production rates of electrons and positive ions by photoionization of atmospheric neutral species are presented and briefly discussed. Considerable attention is given to the progress in the chemistry of O+(4S), O+(2D), O+(2P), N+, N2 +, O2 +, NO+, N4 +, O4 +, NO+(N2), NO+(CO2), NO+(CO2)2, NO+(H2O) n for n = 1–3, NO+(H2O)(N2), NO+(H2O)2(N2), NO+(H2O)(CO2), NO+(H2O)2(CO2), O2 +(H2O), H3O+(OH), H+(H2O) n for n = 1–8, O?, O2 ?, O3 ?, O4 ?, OH?, CO3 ?, CO4 ?, NO2 ?, NO3 ?, ONOO?, Cl?, Cl?(H2O), Cl?(CO2), HCO3 ?, CO3 ?(H2O), CO3 ?(H2O)2, NO3 ?(H2O), NO3 ?(H2O)2, OH?(H2O), and OH?(H2O)2 ions. The analysis of the D-region rocket ion mass spectrometer measurements shows that, among these ions, O2 +, NO+, NO+(H2O), and H+(H2O) n for n = 1–7 can make the main contribution to the total positive ion number density, and O?, O2 ?, Cl?, OH?(H2O), CO3 ?, HCO3 ?, NO3 ?, ONOO?, CO4 ?, NO3 ?(H2O), NO3 ?(H2O)2, and 35Cl?(CO2) ions can be responsible for the main contribution to the total negative ion number density. Photodetachment of electrons from O?, Cl?, O2 ?, O3 ?, OH?, NO2 ?, and NO3 ?, dissociative electron photodetachment of O4 ? and OH?(H2O), and photodissociation of O3 ?, O4 ?, CO3 ?, CO4 ?, ONOO?, HCO3 ?, CO3 ?(H2O), NO3 ?(H2O), O2 +(H2O), O4 +, N4 +, NO+(H2O), NO+(H2O)2, H+(H2O) n for n = 2–4, NO+(N2), and NO+(CO2) are studied, and the photodetachment and photodissociation rate coefficients are calculated using the current state of knowledge on the cross sections of these processes and fluxes of solar radiation.  相似文献   

7.
Applications of the entrainment process to layers at the boundary, which meet the self similarity requirements of the logarithmic profile, have been studied. By accepting that turbulence has dominating scales related in scale length to the height above the surface, a layer structure is postulated wherein exchange is rapid enough to keep the layers internally uniform. The diffusion rate is then controlled by entrainment between layers. It has been shown that theoretical relationships derived on the basis of using a single layer of this type give quantitatively correct factors relating the turbulence, wind and shear stress for very rough surface conditions. For less rough surfaces, the surface boundary layer can be divided into several layers interacting by entrainment across each interface. This analysis leads to the following quantitatively correct formula compared to published measurements. 1 $$\begin{gathered} \frac{{\sigma _w }}{{u^* }} = \left( {\frac{2}{{9Aa}}} \right)^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} \left( {1 - 3^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \frac{a}{k}\frac{{d_n }}{z}\frac{{\sigma _w }}{{u^* }}\frac{z}{L}} \right)^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} \hfill \\ = 1.28(1 - 0.945({{\sigma _w } \mathord{\left/ {\vphantom {{\sigma _w } {u^* }}} \right. \kern-\nulldelimiterspace} {u^* }})({z \mathord{\left/ {\vphantom {z L}} \right. \kern-\nulldelimiterspace} L})^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} \hfill \\ \end{gathered} $$ where \(u^* = \left( {{\tau \mathord{\left/ {\vphantom {\tau \rho }} \right. \kern-0em} \rho }} \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-0em} 2}} \) , σ w is the standard deviation of the vertical velocity,z is the height andL is the Obukhov scale lenght. The constantsa, A, k andd n are the entrainment constant, the turbulence decay constant, Von Karman's constant, and the layer depth derived from the theory. Of these,a andA, are universal constants and not empirically determined for the boundary layer. Thus the turbulence needed for the plume model of convection, which resides above these layers and reaches to the inversion, is determined by the shear stress and the heat flux in the surface layers. This model applies to convection in cool air over a warm sea. The whole field is now determined except for the temperature of the air relative to the water, and the wind, which need a further parameter describing sea surface roughness. As a first stop to describing a surface where roughness elements of widely varying sizes are combined this paper shows how the surface roughness parameter,z 0, can be calculated for an ideal case of a random distribution of vertical cylinders of the same height. To treat a water surface, with various sized waves, such an approach modified to treat the surface by the superposition of various sized roughness elements, is likely to be helpful. Such a theory is particularly desirable when such a surface is changing, as the ocean does when the wind varies. The formula, 2 $$\frac{{0.118}}{{a_s C_D }}< z_0< \frac{{0.463}}{{a_s C_D (u^* )}}$$ is the result derived here. It applies to cylinders of radius,r, and number,m, per unit boundary area, wherea s =2rm, is the area of the roughness elements, per unit area perpendicular to the wind, per unit distance downwind. The drag coefficient of the cylinders isC D . The smaller value ofz o is for large Reynolds numbers where the larger scale turbulence at the surface dominates, and the drag coefficient is about constant. Here the flow between the cylinders is intermittent. When the Reynolds number is small enough then the intermittent nature of the turbulence is reduced and this results in the average velocity at each level determining the drag. In this second case the larger limit forz 0 is more appropriate.  相似文献   

8.
The following Poisson’s equation with the Stokes’ boundary condition is dealt with $$\left\{ \begin{gathered} \nabla ^2 T = - 4\pi Gp outside S, \hfill \\ \left. {\frac{{\partial T}}{{\partial h}} = \frac{1}{\gamma }\frac{{\partial y}}{{\partial h}}T} \right|_s = - \Delta g, \hfill \\ T = O\left( {r^{ - 3} } \right) at infinity, \hfill \\ \end{gathered} \right.$$ whereS is reference ellipsord. Under spherical approximation transformation, the ellipsoidal correction terms about the boundary condition, the equation and the density in the above BVP are respectively given. Therefore, the disturbing potentialT can he obtained if the magnitudes aboveO(ε4) are neglected.  相似文献   

9.
Millstone Hill ionospheric storm time measurements of the electron density and temperature during the ionospheric storms (15-16 June 1965; 29–30 September 1969 and 17–18 August 1970) are compared with model results. The model of the Earth’s ionosphere and plasmasphere includes interhemispheric coupling, the H+, O+(4S), O+(2D), O+(2P), NO+, O+2 and N+2 ions, electrons, photoelectrons, the electron and ion temperature, vibrationally excited N2 and the components of thermospheric wind.In order to model the electron temperature at the time of the 16 June 1965 negative storm, the heating rate of the electron gas by photoelectrons in the energy balance equation was multiplied by the factors 5–30 at he altitude above 700 km for the period 4.50-12.00 LT, 16 June 1965. The [O]/[N2] MSIS-86 decrease and vibrationally excited N2 effects are enough to account for the electron density depressions at Millstone Hill during the three storms. The factor of 2 (for 27–30 September 1969 magnetic storm) and the & actor 2.7 (for 16–18 August 1970 magnetic storm) reduction in the daytime peak density due to enhanced vibrationally excited N2 is brought about by the increase in the O++N2 rate factor.  相似文献   

10.
In the last two decades, south-central Europe and the Eastern Alps have been widely explored by many seismic refraction experiments (e.g., CELEBRATION 2000, ALP 2002, SUDETES 2003). Although quite detailed images are available along linear profiles, a comprehensive, three-dimensional crustal model of the region is still missing. This limitation makes this region a weak spot in continental-wide comprehensive representations of crustal structure. To improve on this situation, we select and collect 37 published active-source seismic lines in this region. After geo-referencing each line, we sample them along vertical profiles—every 50?km or less along the line—and derive P-wave velocities in a stack of homogeneous layers (separated by discontinuities: depth of crystalline basement, top of lower crust, and Moho). We finally merge the information using geostatistical methods, and infer S-wave velocity and density using empirical scaling relations. We present here the resulting crustal model for a region encompassing the Eastern Alps, Dinarides, Pannonian basin, Western Carpathians and Bohemian Massif, covering the region within $45^{\circ}\text{--}51^{\circ}\hbox{N}$ and $11^{\circ} \text{--} 22^{\circ}\hbox{E}$ with a resolution of $0.2^{\circ} \times 0.2^{\circ}.$ We are also able to extend and update the map of Moho depth in a wider region within $35^{\circ}\text{--}51^{\circ}\hbox{N}$ and $12^{\circ}\text{--}45^{\circ}\hbox{E},$ gathering Moho values from the collected seismic lines, other published dataset and using the European plate reference EPcrust as a background. All the digitized profiles and the resulting model are available online.  相似文献   

11.
Vulnerability maps are designed to show areas of greatest potential for groundwater contamination on the basis of hydrogeological conditions and human impacts. The objective of this research is (1) to assess the groundwater vulnerability using DRASTIC method and (2) to improve the DRASTIC method for evaluation of groundwater contamination risk using AI methods, such as ANN, SFL, MFL, NF and SCMAI approaches. This optimization method is illustrated using a case study. For this purpose, DRASTIC model is developed using seven parameters. For validating the contamination risk assessment, a total of 243 groundwater samples were collected from different aquifer types of the study area to analyze \( {\text{NO}}_{ 3}^{ - } \) concentration. To develop AI and CMAI models, 243 data points are divided in two sets; training and validation based on cross validation approach. The calculated vulnerability indices from the DRASTIC method are corrected by the \( {\text{NO}}_{3}^{ - } \) data used in the training step. The input data of the AI models include seven parameters of DRASTIC method. However, the output is the corrected vulnerability index using \( {\text{NO}}_{3}^{ - } \) concentration data from the study area, which is called groundwater contamination risk. In other words, there is some target value (known output) which is estimated by some formula from DRASTIC vulnerability and \( {\text{NO}}_{3}^{ - } \) concentration values. After model training, the AI models are verified by the second \( {\text{NO}}_{3}^{ - } \) concentration dataset. The results revealed that NF and SFL produced acceptable performance while ANN and MFL had poor prediction. A supervised committee machine artificial intelligent (SCMAI), which combines the results of individual AI models using a supervised artificial neural network, was developed for better prediction of vulnerability. The performance of SCMAI was also compared to those of the simple averaging and weighted averaging committee machine intelligent (CMI) methods. As a result, the SCMAI model produced reliable estimates of groundwater contamination risk.  相似文献   

12.
The influence of atmospheric solar radiation absorption on the photodetachment, dissociative photodetachment, and photodissociation rate coefficients (photodestruction rate coefficients) of O?, Cl?, O2 ?, O3 ?, OH?, NO2 ?, NO3 ?, O4 ?, OH?(H2O), CO3 ?, CO4 ?, ONOO?, HCO3 ?, CO3 ?(H2O), NO3 ?(H2O), O2 +(H2O), O4 +, N4 +, NO+(H2O), NO+(H2O)2, H+(H2O) n for n = 2–4, NO+(N2), and NO+(CO2) at D-region altitudes of the ionosphere is studied. A numerical one-dimensional time-dependent neutral atmospheric composition model has been developed to estimate this influence. The model simulations are carried out for the geomagnetically quiet time period of 15 October 1998 at moderate solar activity over the Boulder ozonesonde. If the solar zenith angle is not more than 90° then the strongest influence of atmospheric solar radiation absorption on photodestruction of ions is found for photodissociation of CO4 ? ions when CO3 ? ions are formed. It follows from the calculations that decreases in the photodestruction rate coefficients of ions under consideration caused by this influence are less than 2 % at 70 km altitude and above this altitude if the solar zenith angle does not exceed 90°.  相似文献   

13.
Lozovatsky  Iossif  Liu  Zhiyu  Fernando  Harindra Joseph S.  Hu  Jianyu  Wei  Hao 《Ocean Dynamics》2013,63(11):1189-1201

The microstructure measurements taken during the summer seasons of 2009 and 2010 in the northern South China Sea (between 18°N and 22.5°N, and from the Luzon Strait to the eastern shelf of China) were used to estimate the averaged dissipation rate in the upper pycnocline 〈ε p〉 of the deep basin and on the shelf. Linear correlation between 〈ε p〉 and the estimates of available potential energy of internal waves, which was found for this data set, indicates an impact of energetic internal waves on spatial structure and temporal variability of 〈ε p〉. On the shelf stations, the bottom boundary layer depth-integrated dissipation \( {\widehat{\varepsilon}}_{\mathrm{BBL}} \) reaches 17–19 mW/m2, dominating the dissipation in the water column below the surface layer. In the pycnocline, the integrated dissipation \( {\widehat{\varepsilon}}_{\mathrm{p}} \) was mostly ∼10–30 % of \( {\widehat{\varepsilon}}_{\mathrm{BBL}} \). A weak dependence of bin-averaged dissipation \( \overline{\varepsilon} \) on the Richardson number was noted, according to \( \overline{\varepsilon}={\varepsilon}_0+\frac{\varepsilon_{\mathrm{m}}}{{\left(1+ Ri/R{i}_{\mathrm{cr}}\right)}^{1/2}} \), where ε 0 + ε m is the background value of \( \overline{\varepsilon} \) for weak stratification and Ri cr = 0.25, pointing to the combined effects of shear instability of small-scale motions and the influence of larger-scale low frequency internal waves. The latter broadly agrees with the MacKinnon–Gregg scaling for internal-wave-induced turbulence dissipation.

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14.
Strombolian-type volcanic activity is characterized by a series of gas bubbles bursting at the top of a magma column and leading to the ejection of lava clots and gas emission at the surface. The quantitative analysis of physical parameters (e.g., velocity, size, and mass fluxes) controlling the emission dynamics of these volcanic products is very important for the understanding of eruption source mechanisms but remains difficult to obtain in a systematic fashion. Ground-based Doppler radar is found to be a very effective tool for measuring ejecta velocities at a high acquisition rate and close to the emission source. We present here a series of measurements carried out at Mt. Etna’s Southeast crater, using an L-band volcanological Doppler radar, during the 4 July 2001 Strombolian eruptions. Doppler radar data are supplemented by the analysis of video snapshots recorded simultaneously. We provide here a set of physical parameters systematically retrieved from 247 Strombolian explosions spanning 15 min and occurring during the paroxysm of the eruption from 21:30 to 21:45 UT. The time-average values give a maximum particle velocity of Vmaxp = 94.7±24 \textm/s V_{{\max }}^p = {94}.{7}\pm {24} {\text{m/s}} , a bulk lava jet velocity of V\textPW - rad = 37.6±1.9 \textm/s {V_{{{\text{PW - rad}}}}} = {37}.{6}\pm {1}.{9} {\text{m/s}} , and an initial gas velocity at the source vent of V0g = 118.4±36 \textm/s V_0^g = {118}.{4}\pm {36} {\text{m/s}} . The time-averaged particle diameter is found to be about D\textPW - rad = 4.2±2.1 \textcm {D_{{{\text{PW - rad}}}}} = {4}.{2}\pm {2}.{1} {\text{cm}} . The volume and mass gas fluxes are estimated from time-averaged source gas velocities over the sequence duration at Qvg = 3 - 11 ×103\textm3\text/s Q_v^g = {3} - {11} \times {1}{0^{{3}}}{{\text{m}}^{{3}}}{\text{/s}} and Qmg = 0.5 - 2 ×103\textkg/s Q_m^g = 0.{5} - {2} \times {1}{0^{{3}}}{\text{kg/s}} , respectively.  相似文献   

15.
The relative rate constants of O2(b1Σ g + , v= 1–4) production at an inelastic interaction between electronically excited N(2D) atoms and O2(X3Σ g ? , v = 0) oxygen molecules have been calculated. It was shown that an increase in equilibrium distances between oxygen atoms in NO2 quasi-molecule, produced during the interaction, substantially increases the calculated relative production rates of O2(b1Σ g + , v > 1). The obtained coefficients are used to calculate the O2(b1Σ g + , v= 1–4) relative populations at 110 km (T = 250 K) and 150 km (T = 500 K) altitudes of the polar ionosphere. The calculated populations have been compared with the results of the published measurements of the Atmospheric system band luminosity intensities, and satisfactory agreement has been obtained for low altitudes.  相似文献   

16.
The viscosity of a series of six synthetic dacitic liquids, containing up to 5.04 wt% dissolved water, was measured above the glass transition range by parallel-plate viscometry. The temperature of the 1011 Pa s isokom decreases from 1065 K for the anhydrous liquid, to 864 K and 680 K for water contents of 0.97 and 5.04 wt% H2O. Including additional measurements at high temperatures by concentric-cylinder and falling-sphere viscometry, the viscosity (η) can be expressed as a function of temperature and water content w according to: where η is in Pa s, T is temperature in K, and w is in weight percent. Within the conditions of measurement, this parameterization reproduces the 76 viscosity data with a root-mean square deviation (RMSD) of 0.16 log units in viscosity, or 7.8 K in temperature. The measurements show that water decreases the viscosity of the dacitic liquids more than for andesitic liquids, but less than for rhyolites. At low temperatures and high water contents, andesitic liquids are more viscous than the dacitic liquids, which are in turn more viscous than rhyolitic liquids, reversing the trend seen for high temperatures and low water contents. This suggests that the relative viscosity of different melts depends on temperature and water content as much as on bulk melt composition and structure. At magmatic temperatures, rhyolites are orders of magnitude more viscous than dacites, which are slightly more viscous than andesites. During degassing, all three liquids undergo a rapid viscosity increase at low water contents, and both dacitic and andesitic liquids will degas more efficiently than rhyolitic liquids. During cooling and differentiation, changing melt chemistry, decreasing temperature and increasing crystal content all lead to increases in the viscosity of magma (melt plus crystals). Under closed system conditions, where melt water content can increase during crystallization, viscosity increases may be small. Conversely, viscosity increases are very abrupt during ascent and degassing-induced crystallization.  相似文献   

17.
A new approach to the theory of electromagnetic induction is developed that is applicable to moving as well as stationary sources. The source field is considered to be a standing wave generated by two waves travelling in opposite directions along the surface of the earth. For a stationary source the incident waves have velocities of the same magnitude, however for a moving source the velocities of the two incident waves are respectively increased and decreased by the velocity of the source. Electromagnetic induction in the earth is then considered as refraction of these waves and gives, for both stationary and moving sources, the magnetotelluric relation: $$\frac{{ - E_y }}{{H_x }} = \left( {\frac{{i\omega \mu }}{\sigma }} \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \left( {1 - i\frac{{v^2 }}{{\omega \mu \sigma }}} \right)^{ - {1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} $$ where ν is the wavenumber of the source, μ is the permeability (4π·10?7) and σ is the conductivity of the earth. ω is the angular frequency of the variation observed on the earth. For a stationary source the observed frequency is the same as the source frequency, however the effect of moving a time-varying source is to make the observed frequency different from the frequency of the source. Failure to recognise this in previous studies led to some erroneous conclusions. This study shows that a moving source isnot “electromagnetically broader” than a stationary source as had been suggested.  相似文献   

18.
Low cost adsorbents were prepared from dried plants for the removal of heavy metals, nitrate, and phosphate ions from industrial wastewaters. The efficiency of these adsorbents was investigated using batch adsorption technique at room temperature. The dried plant particles were characterized by N2 at 77 K adsorption, scanning electron microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, and phytochemical screening. The adsorption experiments showed that the microparticles of the dried plants presented a good adsorption of heavy metals, phosphate, and nitrate ions from real wastewaters. This adsorption increased with increasing contact time. The equilibrium time was found to be 30 min for heavy metals and nitrate ions and 240 min for phosphate ions. After the adsorption process, the Pb(II) concentrations, as well as those of Cd(II), Cu(II), and Zn(II) were below the European drinking water norms concentrations. The percentage removal of heavy metals, nitrates, and phosphates from industrial wastewaters by dried plants was ～94% for Cd2+, ～92% for Cu2+, ～99% for Pb2+, ～97% for Zn2+, ～100% for ${\rm NO}_{{\rm 3}}^{{-} } $ and ～77% for ${\rm PO}_{{\rm 4}}^{3{-} } $ ions. It is proved that dried plants can be one alternative source for low cost absorbents to remove heavy metals, nitrate, and phosphate ions from municipal and industrial wastewaters.  相似文献   

19.
Dew samples were collected between October 2007 and February 2008 from a suburban site in Agra. pH, conductivity, major inorganic ions (F?, Cl?, NO 3 ? , SO 4 2? , Na+, K+, Ca2+, Mg2+, and NH 4 + ), and some trace metals (Cr, Sn, Zn, Pb, Cd, Ni, Mn, Fe, Si, Al, V, and Cu) were determined to study the chemistry of dew water. The mean pH was 7.3, and the samples exhibited high ionic concentrations. Dew chemistry suggested both natural and anthropogenic influences, with acidity being neutralized by atmospheric ammonia and soil constituents. Ion deposition flux varied from 0.25 to 3.0?neq?m?2?s?1, with maximum values for Ca2+ followed by NH 4 + , Mg2+, SO 4 2? , Cl?, NO 3 ? , Na+, K+, and F?. Concentrations of trace metals varied from 0.13 to 48?μg?l?1 with maximum concentrations of Si and minimum concentration of Cd. Correlation analysis suggested their contributions from both crustal and anthropogenic sources.  相似文献   

20.
This study compares the OV1-10 satellite measurements of the integral airglow intensities at 630 nm in the SAR arc regions observed in the northern and southern hemisphere as a conjugate phenomenon, with the model results obtained using the time-dependent one-dimensional mathematical model of the Earth ionosphere and plasmasphere (the IZMIRAN model) during the geomagnetic storm of the period 15–17 February 1967. The major enhancements to the IZMIRAN model developed in this study are the inclusion of He+ ions (three major ions: O+ H+ and He+ and three ion temperatures), the updated photochemistry and energy balance equations for ions and electrons, the diffusion of NO+ and O+2 ions and O(1D) and the revised electron cooling rates arising from their collisions with unexcited N2, O2 molecules and N2 molecules at the first vibrational level. The updated model includes the option to use the models of the Boltzmann or non-Boltzmann distributions of vibrationally excited molecular nitrogen. Deviations from the Boltzmann distribution for the first five vibrational levels of N2 were calculated. The calculated distribution is highly non-Boltzmann at vibrational levels v > 2 and leads to a decrease in the calculated electron density and integral intensity at 630 nm in the northern and southern hemispheres in comparison with the electron density and integral intensity calculated using the Boltzmann vibrational distribution of N2. It is found that the intensity at 630 nm is very sensitive to the oxygen number densities. Good agreement between the modeled and measured intensities is obtained provided that at all altitudes of the southern hemisphere a reduction of about factor 1.35 in MSIS-86 atomic oxygen densities is included in the IZMIRAN model with the non-Boltzm-ann vibrational distribution of N2. The effect of using of the O(1D) diffusion results in the decrease of 4–6% in the calculated integral intensity of the northern hemisphere and 7–13% in the calculated integral intensity of the southern hemisphere. It is found that the modeled intensities of the southern hemisphere are more sensitive to the assumed values of the rate coefficients of O+(4S) ions with vibrationally excited nitrogen molecules and quenching of O+(2D) by atomic oxygen than the modeled intensities of the northern hemisphere.  相似文献   

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