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1.
It is established that the formation and evolution of the anaerobic zone of the Black Sea are associated with the beginning and development of the most recent salinization of the sea and the formation of pycnocline at intermediate depths; a deterioration of deep-water aeration and the formation of anaerobic conditions in deeper layers; the rate of sulfate-reduction first in the near-bed layer and later, as oxygen is depleted, in the water mass. Formalization of these processes based on refined present-day data on water balance enabled the reproduction of profiles of water salinity and vertical-exchange coefficient for different formation stages of salinity regime in the Black Sea. The vertical distribution of oxygen and hydrogen sulfide is reconstructed, and the rates of oxygen consumption in water column and sulfate reduction in the near-bed layer and at the upper boundary of the anaerobic zone are evaluated in numerical experiments. The obtained data show the transformation of the vertical distribution of oxygen and hydrogen sulfide in the Black Sea from the beginning of its most recent salinization to the present-day state. It is shown that the anaerobic zone rises from 2000 to 200 m within 500–600 years (in the period 3.9–4.5 Ka from the beginning of water exchange through the Bosphorus), and next the upper boundary of the anaerobic zone slowly ascends up to its present-day position (130–180 m). Mathematical modeling was used to evaluate the fluxes of oxygen and hydrogen sulfide at different formation stages of the anaerobic zone in the sea.__________Translated from Vodnye Resursy, Vol. 32, No. 3, 2005, pp. 307–321.Original Russian Text Copyright © 2005 by Leonov, Shaporenko.  相似文献   

2.
Results of the sampling for temperature, salinity, and isotopic composition of water masses that was performed in the Caspian Sea at deepwater stations along a meridional profile during the international expeditions of 1994–1996 are presented. The water-exchange processes in this basin are analyzed on the basis of the distributions of salinity and isotopes in space and time.  相似文献   

3.
The Ross Sea is an important area for the ventilation of the deep layers of the Southern Ocean (e.g. [Jacobs, S.S., Fairbanks, R.G., Horibe, Y., 1985. Origin and evolution of water masses near the Antarctic continental margin: evidence from H218O/H216O ratios in seawater. In: Jacobs, S.S. (Ed.), Oceanology of the Antarctic Continental Shelf. Antarctic Research Series, vol. 43. pp. 59–85; Orsi, A.H., Johnson, G.C., Bullister, J.L., 1999. Circulation, mixing, and the production of Antarctic bottom water. Progress in Oceanography 109, 43–55]). These processes are driven by the atmospheric forcing which, at high latitude, plays a key role in the formation and thickness of sea ice. In order to investigate the effect of the atmospheric forcing variability at different time scales, we analysed the surface heat budget over the Ross Sea continental shelf and in Terra Nova Bay (TNB) polynya, using analyses for the period 1990–2006 provided by European Centre for Medium-range Weather Forecast (ECMWF). This study was also performed using thermohaline data collected within the activities of Climatic Long-term Interaction for the mass-balance in Antarctica project of the Italian National Programme for Antarctic Research for the summer periods from 1994 until 2001.The annual average of the heat budget over the continental shelf of the Ross Sea estimated in the period 1990–2006 shows an interannual variability ranging between −97 and −123 W m−2. Assuming that the heat loss must be compensated by the sensible heat carried by the Circumpolar Deep Water we estimated its transport (3.1 Sv) and its variability (0.2 Sv). Similarly in the TNB polynya the heat loss reaches its maximum in 2003 (−313 W m−2) and its minimum (−58 W m−2) in 1996. The related production of sea ice and the High Salinity Shelf Water (HSSW) were also estimated. The HSSW production switched from the lowest values during the first 10 years of the investigated period (1990–2000) to the highest values for the remaining period (2001–2006).The thermohaline characteristics of the water column in TNB show a general decrease in salinity with a superimposed variability. Comparison between the estimated HSSW production and the salinity observed within the TNB water column show similar tendency in the last years after 2002, while during the period 1995–1998 the behaviour is different. Our hypothesis concern a possible role of the CDW inflow in the TNB area and our results could be explained by a different contribution of CDW transport and HSSW production to the salt content within the water column.  相似文献   

4.
The surface water of the Japan Sea contained226Ra of70 ± 4dpm m−3 which was nearly equal to that of the surface water in the North Pacific. The concentration of226Ra in the Japan Sea deep water below 500 m was151 ± 8dpm m−3, showing a vertically and regionally small variation. This concentration of226Ra in the deep water is unexpectedly high, because the Japan Sea deep water has a higher Δ14 C value by about 50‰ than the Atlantic deep water containing the same226Ra. One of the causes to be considered is larger contribution of226Ra from biogenic particles dissolving in the Japan Sea deep water, but the Japan Sea is not so fertile in comparison to the Bering Sea. The other more plausible cause is the internal ventilation of the Japan Sea water, which means that the residence time of the Japan Sea Proper water is considerably long although the water is vertically mixed fairly well especially in winter. The ventilation may supply some amounts of radiocarbon and oxygen but does not change the inventory of226Ra. The residence times of the Japan Sea deep water and of water within the Japan Sea are calculated by solving simultaneous equations for226Ra and14C with a three-box model to be 300–400 years and 700–1000 years, respectively.  相似文献   

5.
Morpho-physiological and biochemical parameters were determined in Scorpion fish Scorpaena porcus L. from two bays in the area of Sevastopol, which experience a high anthropogenic load. The effect of natural and anthropogenic factors on the size, weight, and age composition, as well as on the sex ratio of the fish from both populations, was studied. The relationships between the concentrations of chlororganic substances in the water of the bays, their accumulation in the liver and gonads of the fish, the activity of antioxidant enzymes in the blood, and the fractional composition of serum proteins were determined. A possibility for the use of the Scorpion fish as a indicator species for the biomonitoring and assessment of the environmental conditions in the coastal waters of the Black Sea was considered.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 238–246.Original Russian Text Copyright © 2005 by Rudneva, Shevchenko, Zalevskaya, Zherko.  相似文献   

6.
Results of field observations and numerical modeling of hydrogen sulfide pollution of the Sea of Azov in 2001 are presented.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 171–183.Original Russian Text Copyright © 2005 by Debolskaya, Yakushev, Sukhinov.  相似文献   

7.
An inverse model is applied for the analysis of hydrographic and current meter data collected on the repeat WOCE section SR4 in the Weddell Sea in 1989–1992. The section crosses the Weddell Sea cyclonic gyre from Kapp Norvegia to the northern end of the Antarctic Peninsula. The concepts of geostrophy, conservation of planetary vorticity and hydrostatics are combined with advective balances of active and passive properties to provide a dynamically consistent circulation pattern. Our variational assimilation scheme allows the calculation of three-dimensional velocities in the section plane. Current speeds are small except along the coasts where they reach up to 12 cm/s. We diagnose a gyre transport of 34 Sverdrup which is associated with a poleward heat transport of 28 × 1012 W corresponding to an average heat flux of 15 Wm–2 in the Weddell Sea south of the transect. This exceeds the estimated local flux on the transect of 2 Wm–2. As the transect is located mostly in the open ocean, we conclude that the shelf areas contribute significantly to the ocean-atmosphere exchange and are consequently key areas for the contribution of the Weddell Sea to global ocean ventilation. Conversion of water masses occuring south of the section transform 6.6 ± 1.1 Sv of the inflowing warm deep water into approximately equal amounts of Weddell Sea deep water and Weddell Sea bottom water. The volume transport of surface water equals in the in-and outflow. This means that almost all newly formed surface water is involved in the deep and bottom water formation. Comparison with the results obtained by pure velocity interpolation combined with a hydrographic data subset indicates major differences in the derived salt transports and the water mass conversion of the surface water. The differences can be explained by deviations in the structure of the upper ocean currents to which shelf areas contribute significantly. Additionally a rigorous variance analysis is performed. When only hydrographic data are used for the inversion both the gyre transport and the poleward heat transport are substantially lower. They amount to less than 40% of our best estimate while the standard deviations of both quantities are 6.5 Sv and 37 × 1012 W, respectively. With the help of long-term current meter measurements these errors can be reduced to 2 Sv and 8 × 1012 W. Our result underlines the importance of velocity data or equivalent information that helps to estimate the absolute velocities.  相似文献   

8.
Hazardous sinkholes started to appear in alluvial fans and unconsolidated sediments along the western Dead Sea coast in 1990. Since then hundreds of sinkholes have appeared from north to south along the shoreline. The Electrical Resistivity Tomography (ERT) method was used to achieve a better understanding of the subsurface geoelectric structure at the sinkhole development sites, taking into account that electric parameters (such as resistivity or conductivity) are very sensitive to formation properties and their variations in time. Fifteen image lines were surveyed at the Ein Gedi area during a period of active sinkhole development (in 2001–2002) over an area of 300 × 550 m2. Resistivity cross-sections and maps were constructed from 2-D linear surveys. The process of sinkhole formation in the surveyed area is located in a strip 50–70 m wide and 300–500 m long, extending approximately in a north–south direction. The sinkholes are arranged along a tortuous line within this strip. On resistivity maps and sections this U-shaped zone appears as an alternation of high resistivity anomalies of 350–1000 Ωm (at sinkhole group locations) with narrow background resistivity zones of 50–100 Ωm. The large size of resistivity anomalies (250 × 300 m2), which are considerably greater than those of the sinkholes, form one of the features of the sinkhole sites in the Ein Gedi area. The anomalies continue down to the water table or even deeper (maximum of 25–35 m depth). A low resistivity layer of 1–8 Ωm underlies them. The combined analysis of the image results and other geophysical data shows that high resistivity anomalies are associated with the decompaction of the soil mass at the sinkhole development sites and surrounding areas. Recent studies have shown that sinkholes in the Ein Gedi area are developing along the salt western edge located at a depth of 50 m. The subsurface high resistivity anomaly conforms to the sinkhole line (and salt boundary). They are presumably located above the great dissolution caverns at the salt edge. The heterogeneity of the resistivity structure within the high resistivity anomaly (seen in both lateral and vertical planes) confirms that a disintegration of internal formation structure takes place. Away from the sinkhole sites the subsurface resistivity distribution is homogeneous.  相似文献   

9.
The available published data were used to reveal the principal conditions and factors that control the formation and evolution of the Black Sea water salinity. Formalization of the major processes that contribute to the formation of sea salinity structure enabled, based on the present-day data on water balance, the reproduction of profiles of water salinity and the coefficient of vertical water exchange K Z after 2, 4, 6, 8, and 10 ka since the beginning of water exchange with the Sea of Marmara through the Bosphorus. The time during which the present-day profile of the Black Sea water salinity had formed was evaluated. The results of simulation for different formation stages of the Black Sea salinity structure were used to determine the major ways of salt input into the sea (with river runoff and waters of the Lower Bosphorus Current) and its removal from the sea (the Upper Bosphorus Current). It was established that the Black Sea water salinity regime has virtually attained a stationary state.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 154–164.Original Russian Text Copyright © 2005 by Leonov.  相似文献   

10.
Microcrystals of biochemogenic calcite were found for the first time in the water of the slightly mineralized and eutrophic Mozhaisk Reservoir in Moscow region. Photographs of eight samples of such particles of autochthonous mineral suspension, magnified several tens of thousand times are presented, and the conditions of their crystallization in the trophogenic layer of the reservoir are described in detail. Analysis of data collected during seven-year hydroenvironmental observations of diurnal variations in the characteristics of the state of aquatic ecosystem was used to demonstrate the role of various physical, chemical, and biological processes, biochemic calcite, and mineral phosphorus in the minor cycle of matter. This cycle in the upper part of the stratified water mass serves as a natural mechanism regulating the intensity of blooming in eutrophic lakes and reservoirs.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 477–488.Original Russian Text Copyright © 2005 by Edel’shtein, Ershova, Zaslavskaya.  相似文献   

11.
Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO4–Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce “immature” solutions. The strong D and 18O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and 18O content. The large ΔSO4–S0 (23.8–26.4‰) measured in the lake suggest that dissolved SO4 forms during disproportionation of magmatic SO2 in the hydrothermal conduit at temperatures of 250280°C. The lake δ18OSO4 and δ18OH2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lake's bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO2-rich gas input to the lake system.Thermal springs at Kawah Ijen consist of acidic SO4–Cl waters on the lakeshore and neutral pH HCO3–SO4–Cl–Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO4/Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO4–Cl water and ground water.The lakeshore fumarole discharges (T=170245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is 260°C. The proportions of the oxidized, SO2-dominated magmatic vapor and of the reduced, H2S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO2-bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H2S/SO2 ratio deduced for the gas producing the SO4–Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid–vapor zone at about 350°C.Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H2S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H2S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ34S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.  相似文献   

12.
Methods of systems analysis and mathematical modeling are used to generalize hydrological, hydrochemical, and hydrobiological observational data with the aim to study the biohydrochemical conditions of organic and biogenic substance transformations in eight water areas in the White Sea. A hydroecological model describing transformations of N, P, and Si compounds and dissolved organic C, as well as the regime of O2 was used as a means of the study. Water exchange between water areas was evaluated using a hydrodynamic model. Averaged data on annual variations in water temperature, illumination, and transparency, as well as run-off characteristics (water flow in river mouths and organic and biogenic matter concentrations in the river water entering the sea) were used to calculate the dynamics of organic and mineral compounds of nutrients in different areas of the sea. The principal attention is paid to the verification of the model against field observational data, assessment of the biomass development conditions of aquatic animals, analysis of model results regarding the turnover time of organic and mineral components, and the evaluation of balances of organic dissolved and particulate N and P forms.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 435–451.Original Russian Text Copyright © 2005 by Leonov, Filatov, Chicherina.  相似文献   

13.
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14.
The distributions of dimethylsulfide (DMS) and its precursor, dimethylsulfoniopropionate (DMSP), were examined in the surface microlayer and corresponding subsurface water of the Yellow Sea, China, in April 2006. The average concentrations of DMS and DMSP of dissolved (DMSPd) and particulate (DMSPp) forms were 5.42 (1.78–12.75), 9.22 (2.85–19.73) and 17.50 (4.33–36.09) nmol L−1 in the subsurface water, and those in the surface microlayer were 4.92 (1.69–10.66), 17.08 (3.13–38.82) and 22.54 (4.85–47.24) nmol L−1, respectively. The enrichment factor (EF) of DMS in the microlayer ranged from 0.47 to 2.24 with a mean of 0.98. In contrast, DMSPd and DMSPp appeared to be enriched in the microlayer with average EFs of 1.98 and 1.39, respectively. A close correlation of integrated DMS, DMSPp and chlorophyll a concentrations for compiled data from all stations in the microlayer and the subsurface water indicated that phytoplankton biomass might play an important role in controlling the distributions of biogenic sulfurs in the study area. Moreover, a statistically significant relationship was found between the microlayer concentrations of DMS, DMSP and chlorophyll a and their subsurface water concentrations, suggesting a close linkage between these two water compartments. Interestingly, we observed higher biological production rates and consumption rates of DMS in the microlayer relative to the subsurface water. Furthermore, the DMS production rates were closely correlated both with DMSPd and chlorophyll a concentrations. Our study showed that the major sink of DMS in microlayer was escape into the atmosphere, which greatly exceeded its bacterial consumption. A preliminary estimate for average flux of DMS from the Yellow Sea to the atmosphere was 6.41 μmol m−2 d−1 during spring.  相似文献   

15.
A system of efficient on-line monitoring of the state of water in surface water bodies is developed. The expediency of using new general-purpose bioassays for the integral express evaluation of the natural-water toxic impact on living organisms is substantiated. Fundamentally new methods of bioassaying with gasteropoda from special laboratory cultures (“PRM-TESTS”) used as test organisms are presented. The results of complex hydrochemical and biological (toxicological) investigations with PRM-TESTS as applied to water bodies in St. Petersburg are discussed.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 425–434.Original Russian Text Copyright © 2005 by Kurilenko, Zaitseva.  相似文献   

16.
Two main groups of methods used for comprehensive evaluation of continental surface water quality are analyzed. A new method of comprehensive evaluation of the degree of continental surface water contamination, developed by the authors of this paper based on a combination of the differentiated and comprehensive approaches, is described in detail.Translated from Vodnye Resursy, Vol. 32, No. 1, 2005, pp. 61–69.Original Russian Text Copyright © 2005 by Nikanorov, Yemelyanova.  相似文献   

17.
Factors responsible for the formation of water salinity in the Yumaguzinskoe Reservoir, which is under construction in the upper reaches of the Belaya River, are analyzed. Based on the prediction experience and a sufficient amount of initial data on water quality of the Belaya River, the universally accepted algorithm of prediction for years of different water supply levels using the calculation method of running-out has been modified. As revealed, the minimum water salinity at the reservoir spillway is observed in May–August, the maximum water salinity being in January–March. The regularities of a general nature have been found.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 214–222.Original Russian Text Copyright © 2005 by Popov, Oboldina.  相似文献   

18.
The consequences of a coastal upwelling event on physical and chemical patterns were studied in the central Gulf of Finland. Weekly mapping of hydrographical and -chemical fields were carried out across the Gulf between Tallinn and Helsinki in July–August 2006. In each survey, vertical profiles of temperature and salinity were recorded at 27 stations and water samples for chemical analyses (PO43−, NO2−+NO3−) were collected at 14 stations along the transect. An ordinary distribution of hydrophysical and -chemical variables with the seasonal thermocline at the depths of 10–20 m was observed in the beginning of the measurements in July. Nutrient concentrations in the upper mixed layer were below the detection limit and nutriclines were located just below or in the lower part of the thermocline. In the first half of August, a very intense upwelling event occurred near the southern coast of the Gulf when waters with low temperature and high salinity from the intermediate layer surfaced. High nutrient concentrations were measured in the upwelled water – 0.4 μmol l−1 of phosphates and 0.6 μmol l−1 of nitrates+nitrites. We estimated the amount of nutrients transported into the surface layer as 238–290 tons of phosphorus (P)-PO43− and 175–255 tons of N-NOx for a 12 m thick, 20 km wide and 100 km long coastal stretch. Taking into account a characteristic along-shore extension of the upwelling of 200 km, the phosphate-phosphorus amount is approximately equal to the average total monthly riverine load of phosphorus to the Gulf of Finland. It is shown that TS-characteristics of water masses and vertical distribution of nutrients along the study transect experienced drastic changes caused by the upwelling event in the entire studied water column. TS-analysis of profiles obtained before and during the upwelling event suggests that while welled up, the cold intermediate layer water was mixed with the water from the upper mixed layer with a share of 85% and 15%. We suggest that the coastal upwelling events contribute remarkably to the vertical mixing of waters in the Gulf of Finland. Intrusions of nutrient-rich waters along the inclined isopycnal surfaces in the vicinity of upwelling front were revealed. The upwelling event widened the separation of phosphocline and nitracline which in turn prevented surfacing of nitrate+nitrite-nitrogen during the next upwelling event observed a week after the upwelling relaxation. A suggestion is made that such widening of nutricline separation caused by similar upwelling events in early summer could create favourable conditions for late summer cyanobacterial blooms.  相似文献   

19.
On Some Issues of Maintaining Water Quality and Self-Purification   总被引：7，自引：0，他引：7  
Generalizations presented in this paper represent, in systematized form, the basic elements of the qualitative theory of water self-purification in freshwater and marine ecosystems. Recommendations are given for maintaining water quality and sustainable development of water resources. Results of experimental studies of the effect exerted by Triton X-100 and OMO synthetic detergent on mollusks Unio tumidus.__________Translated from Vodnye Resursy, Vol. 32, No. 3, 2005, pp. 337–346.Original Russian Text Copyright © 2005 by Ostroumov.  相似文献   

20.
Oceanographic studies have been carried out in coastal and riverine waters of the area around Timika, West Papua in November 1999, March–April, July and November 2000. The temperature of the seawater along the coast is around 28 °C in winter (November 99), rising to 30.0 °C (November 00). In the open sea, 30 miles off the coast at 40 m water depth, the temperature is >30 °C with no stratification. Water temperature near the coast is consistently lower than in the open sea. This is thought to be due the cooling effect of the land, being densely covered by mangrove forest. In the upper parts of the Kamora, West Tipuka, East Tipuka, Ajkwa, Minajerwi, Mawati and Otakwa Rivers, at salinity zero psu, water temperature varies between 24.6 and 26.2 °C, which is as cold as the temperature in the upwelling Banda Sea to the NW. Some of these rivers are fed by glacial melt water from the high mountains to the east. At mid estuary, warm seawater is found under the cooler river water.Salinity near this coast varied between 24 and 30, and offshore salinity was 31–33 with no stratification. Inshore surface waters were turbid (11–14 ntu), and near bottom waters were generally much more turbid from river sediment supply and tidal resuspension. The Ajkwa River estuary has the highest turbidity (750 ntu) at zero salinity. Offshore waters were very clear (5.0–6.0 ntu), and there was no increase in turbidity near the bottom.  相似文献   

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