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1.
Marine sediments were dissolved by HNO3-HF-HCIO4 in a sealed container at low pressure; I-IF was evaporated in an open container and salts were dissolved in HCl by heating, then transferred to 2% HNO3 solution. A total of 45 elements, including Li, Be, So, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Mo, Cd, In, Sb, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, TI, Pb, Bi, Th and U, were measured by inductively coupled plasma mass spectrometry (ICP-MS). Condi-tions and sample experiments showed that this procedure defines a good experimental method which has the advantages of clear interference, easy operation and reliable results. The concentrations of the 45 elements could be used for resource exploration, envi-ronmental assessment and academic research. 相似文献
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何良彪 《中国海洋湖沼学报》1995,13(2):183-190
Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene. 相似文献
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利用土壤元素资料2069448个数据,大肠癌死亡调查资料42480例,研究了大肠癌死亡率与土壤环境中砷、镉、钴、铬、铜、氟、汞、锰、镍、铅、硒、钒、锌、锂、钠、钾、铷、铯、银、铍、镁、钙、锶、钡、硼、铝、镓、铟、铊、钪、钇、镧、铈、镨、钕、钐、铕、钆、铽、镝、钬、铒、铥、镱、镥、钍、铀、锗、锡、钛、锆、铪、锑、铋、钽、碲、钼、钨、溴、碘、铁等61个元素的相关性.结果表明.砷、钒、铯、铊、铀、锑元素与大肠癌死亡率有相关性.等级相关分数分别为-0.5123(p＜0.005),-0.3179(p＜0.05),-0.3190(p＜0.05),-0.4552(p＜0.01),-0.4857(p＜0.005),-0.3232(p＜0.05) 相似文献
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为了探讨大巴山早寒武世黑色岩层的稀土元素特征及古沉积环境,采用电感耦合等离子体质谱法(ICP-MS)对大巴山城巴断块内的水井沱组黑色岩层的稀土元素及V、Ni、Cr、U、Th、Zn、Co等微量元素质量分数进行了测定,并与前人研究的鲁家坪组黑色岩层进行了对比分析。研究结果表明,城巴断块内的黑色岩层轻稀土元素相对重稀土元素富集,Ce异常值δCeN为0.47~0.94(平均值0.69),δCeS为0.46~0.91(平均值0.67)呈负异常,Eu异常值δEuN=0.27~1.03(平均值0.57),δEuS=0.42~1.57(绝大多数小于0.87),δEu基本呈现负异常;U/Th比值为2.52~67.51,Sr/Cu比值为5.83~27.96,V/(V+Ni)比值为0.65~0.98,V/Cr比值为1.35~17.79及δU值为1.77~1.99,结合REE的北美页岩标准化曲线、La-Ce图解、Zn-Ni-Co三角图解及La/Yb-REE判别图解的分析表明,大巴山城巴断块内的早寒武世黑色岩层沉积时所处的古气候为干热型气候,黑色岩层形成于被动大陆边缘的缺氧浅海陆棚-斜坡过渡带的沉积环境,且明显受到热液作用的影响。 相似文献
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LINXiaotong LIWeiran DUShujie 《中国海洋大学学报(英文版)》2005,4(2):131-136
The multivariate statistical techniques, principal component analysis, Q-mode factor analysis, correspondence analysis and fuzzy C-means clustering were applied to analyzing the datasets of minor element concentrations in sediment samples of a core collected from the outer shelf of the East China Sea. According to the analysis results, the sediment core Q43 can be divided into three strata with different features in minor elements. The first stratum (unit Ⅰ) is characterized by higher concentrations of V, Cr, Cd and Sc, which are active and inactive elements. The second stratum (unit Ⅱ) is controlled by ultrastable elements V, Ti, Cr, Th, Sc, Pb, etc. The third stratum (unit Ⅲ) is dominated by Ni, Co, Ba, Rb and Mn, which are authigenic and volcanogenic elements. The geochemical features of the core Q43 show environmental changes in the depositional process from the Late Pleistocene to Holocene. 相似文献
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According to the lithological assemblages and elemental geochemistry of the measured Profile,the authors studied the sedimentary and tectonic environment of the Late Carboniferous Tangjiatun Formation ... 相似文献
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Sediment cores with length of 25 - 45cm at 12 stations in Zhujiang(Pearl) River Estuary were sampled in summer of 1999. Chemical components (Al2O3 , Fe2O3, CaO, TiO2, Cu, Pb, Cr, Zn, Co, Ni, V, Ba, Sr and Y) and grain sizes were analyzed. Sediments in Zhujiang River Estuary are characterized by relatively coarse grain size. The grain sizes of the sediments in the area outside the estuary are relatively finer than those in the north part of the estuary but coarser than those in the middle of Lingdingyang and have a trend similar to the spatial distribution trend of some chemical components such as Fe2O3, Al2O3, TiO2, V, Cu, Ni, Zn and Y. This showed that grain size is an important factor that controls the spatial distribution and depth profile of chemical elements in the Zhujiang River Estuary. Frequent re-suspension, re-transportation and redistribution of settled sediment on estuary floor could be deduced from the spatial distributions and depth profiles of chemical components. Except for CaO and Sr, the chemical components always enrich at the west side of, in the middle of, and at the north side of, the estuary. Fe2O3, Al2O3, Ti, V, Cr, Ni, Zn, Cu and Y in Zhujiang River Estuary sediments mainly result from rock and soil weathering except that parts of Cr, Ni, Zn Cu and Y are anthropogenic. CaO and Sr in sediments originate from marine source. Although Co as well as Pb derives from anthropogenic sources, human activities related to Co might differ from the activities related to Pb. 相似文献
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西天山温泉地区广泛发育泥盆—石炭纪火山—沉积地层,布拉格达瓦一带出露的托斯库尔他乌组发育一套由滨海间夹陆相—滨浅海相—浅海相过渡的碎屑岩夹火山碎屑岩的沉积建造,沉积物源主要为中酸性火山岩,碎屑颗粒沉积速度较快,属于近源沉积,蚀源区构造环境具活动性质,形成于未切割的活动岛弧。火山岩呈夹层、透镜体状分布于托斯库尔他乌组地层中,火山作用具周期性间歇喷发的特征,岩相表现为爆发—喷溢—沉积—爆发—沉积—爆发的周期性特点。火山岩属钙碱性岩石系列,火山岩浆对应的俯冲深度为上地幔。火山岩微量元素Nb,Sr,P,Ti,Ba为亏损型,Th,Zr元素富集,与岛弧环境密切相关;Nb/Ta为11.96~15.19,略低于原始地幔值,Zr/Hf为30.17~38.20,与原始地幔值相近。稀土总量∑REE为(186.57~208.58)×10-6,轻重稀土比值为5.38~6.13;(Ce/Yb)N为3.90~4.48,(La/Yb)N为4.67~6.70,δEu为0.28~0.49,属于轻稀土富集型,显示为负铕异常。根据沉积物源区分析及主、微量元素特征,结合区域构造背景,认为晚泥盆世托斯库尔他乌组沉积建造所反映的构造环境为消减带俯冲碰撞的岛弧环境。 相似文献
10.
阎百兴 《中国地理科学(英文版)》1998,8(4):352-361
Ｉ．ＩＮＴＲＯＤＵＣＴＩＯＮＭｏｓｔｖｏｌｃａｎｏｅｓａｒｅｄｉｓｔｒｉｂｕｔｅｄｉｎｎｏｒｔｈｅａｓｔｏｆＣｈｉｎａ．Ｔｈｅｖｏｌｃａｎｉｃｅｒｕｐｔｉｏｎｓｃａｎｃｈａｎｇｅｔｈｅｇｅｎｅｒａｌｍｏｒｐｈｏｌｏｇｉｃｃｏｎｆｉｇｕｒａｔｉｏｎｏｆ... 相似文献
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激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)技术在矿物微量元素分析方面具有原位、高分辨率和高灵敏度等优势，近年来磁铁矿LA-ICP-MS原位微量元素研究进展迅速，并在地质领域得到了广泛应用。利用长安大学成矿作用及其动力学实验室Agilent 7700X四极杆等离子体质谱和Photo Machines Analyte Excite 193 nm激光，建立了LA-ICP-MS测定磁铁矿原位微量元素组成的分析方法。以美国地质调查局(USGS)玻璃标样BIR-1G、BHVO-2G、BCR-2G和GSE-1G为校正标准，采用无内标-多外标法对磁铁矿中微量元素进行了定量计算，并测定了NIST612和自然岩浆磁铁矿BC28的微量元素组成，以评估本实验室建立方法的可靠性。结果表明，NIST612所有微量元素的相对标准偏差(RSD, N=30)变化于1.31%~6.33%之间，多数元素的测定结果与推荐值及前人LA-ICP-MS方法测定值的相对误差小于10%；BC28大部分微量元素的相对标准偏差(RSD, N=30)小于10%，其中11个重要微量元素与前人LA-ICP-MS测定值的相对误差基本小于10%。以上结果表明本实验室建立的方法可以实现对磁铁矿原位微区微量元素的分析测定，分析数据结果准确可靠，具有良好的应用前景。 相似文献
12.
赵风清 《地球科学与环境学报》1994,(2)
冷口变质火山岩为较典型的双峰式火山岩，以变质基性火山岩为主，夹变质英安质岩石。依据元素地球化学和同位素地球化学分析，它应形成于大陆或大陆边缘裂谷环境。基性岩浆来源于亏损地幔，岩浆在侵位过程中受到强烈的地壳成分混杂作用改造，而英安质岩石可能是由大陆地壳部分熔融作用形成的。 相似文献
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Instrumental neutron activation analysis (INAA) was applied to analyze the bulk, high-volume aerosol samples, collected at Zhongshan Station in the Eastern Antarctica, during 1998-2001, to study the chemical species. .A graphical technique was applied to the INAA data. Results showed that Na, Cl, Mg, Ca, Sr, Br, I, Sr and Rb were marine elements while Al, Sc, Fe and Mn were crustal elements. Compared to marine and crustal elements, five elements (Se、Co、Sb、Zn、Cr) were highly abundant in the aerosols collected at Zhongshan station, which indicated that they might come from the petroleum burning, heating and equipment operation. The presence of pollutant elements suggested that human activities have affected the local environments in Antarctica. 相似文献
14.
小平坝接触交代矽卡岩型白钨矿床位于滇东南薄竹山岩体东缘,矿体主要产于第一期中粒黑云母二长花岗岩与寒武系碳酸盐岩接触部位,对区内花岗岩的主量、微量、稀土元素分析结果显示:其w(SiO2)变化于67.69%~76.98%之间,平均为70.96%,w(K2O+Na2O)较高,平均为8.06%,K2O/Na2O、A/CNK、里特曼指数σ平均值分别为2.04,1.03,2.36,具铝过饱和、高钾钙碱性特征;富集Rb、Pb、Th、U、La、Zr等大离子亲石元素,而亏损Nb、Ta、Sr、Ba、Ti等高场强元素和不相容元素;稀土元素总量较高,平均为288.01×10-6,轻重稀土元素分馏明显,LREE富集,δEu为0.36~0.69,平均为0.57,具中等负异常;CaO/Na2O-Al2O3/TiO2图解、Rb/Ba-Rb/Sr图解暗示其源岩为砂泥质沉积岩;综合分析认为其为地壳重熔S型花岗岩,且经历了高度分异演化,形成于同碰撞构造环境。 相似文献
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Using neutron activation analysis method we determined contents of rare-earth and radioactive elements (La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Cs, Rb, Sb, Sc, Sr, Ba, U, Th) in source water system of the Changjiang (Yangtze) River, which is mainly composed of the Tuotuo River, the Chumaer River, and the Buqu River. The contents of these elements in the unflltered water have a great variation and a close correlation with the water turbidity. The contents of these elements in filtered water only have a little variation and are lower than those in the unflltered water. The variations in contents of these elements in sediments are also very little. These elements in the unifiltered water are in geometric distribution, except Sc. Most of the elements in sediments are in arithmetic distribution, but Cs, Sb, Th, are in deviation distribution. The contents of most of these elements in the river source area correspond to the contents of fresh water of the earth. Most of these elements have a little variation in their c 相似文献
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The geochemical features of the monzonitic granite in Qimantage Hutouya deposit area,Qinghai,in respect to the mineralization,suggest that this granite belongs to weak peraluminous and high-k calc alkaline rock series. The REE of the samples show right slope with obvious LREE/HREE differentiation and negative Eu abnormity. The trace elements show enrichment of LILE( Rb,Th,U,La,Nd),and deleption of Ba,Sr,Nd,P,Ti. The Sr-Nb isotopic data indicate that the magma source is mainly aluminosilicate lower crust with a small amount of new crustal materials. The weighted mean zircon U-Pbage of the Hutouya monzonitic granite is 221±1.7 Ma,belonging to Late Triassic. The Hutouya monzonitic granite was formed in the tectonic setting of transition from compression to extension during Middle-Late Triassic. 相似文献
18.
哈图岩体侵位于西准噶尔南部早-中泥盆世海相火山-沉积地层中,主要岩性为二长花岗岩、正长花岗岩及少量碱长花岗岩,是研究西准噶尔晚石炭世构造环境的理想对象。哈图岩体花岗岩中SiO2含量(质量分数,下同)为72.06%~76.53%,全碱(Na2O+K2O)为7.80%~8.57%,CaO为0.20%~1.58%,MgO为0.07%~0.42%,明显具有高Si、富碱、贫Ca、低Mg的特征;这些花岗岩的Al2O3含量为12.55%~14.06%,A/CNK值为1.06~1.15,A/NK值为1.15~1.36,显示其为弱过铝质-强过铝质花岗岩。此外,哈图岩体具有较低的稀土元素总含量((88.14~139.53)×10-6)和高的轻、重稀土元素比值((La/Yb)N值为3.04~6.50),在球粒陨石标准化稀土元素配分模式中显示为典型的右倾"V"字形且具有强烈的负Eu异常,表明源区可能有斜长石残留或出现斜长石的分离结晶作用;在原始地幔标准化微量元素蛛网图中,这些花岗岩明显富集Rb、Th、U、K、Pb等大离子亲石元素,相对富集Zr、Hf,强烈亏损Sr、Ti、P,相对亏损Ba、Nb。以上特征及主量、微量元素特征和图解表明,哈图岩体为典型的弱过铝质-强过铝质A2型花岗岩,其形成于造山后伸展阶段,是由洋壳和岛弧组成的新生地壳受上涌的幔源物质加热,在浅部低压条件下发生部分熔融,再经分离结晶作用的产物。 相似文献
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Heavy metal content in coral reef sediments from Red Sea of Yemen and its significance on marine environment 
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下载免费PDF全文 In order to determine and assess the concentrations of trace elements in coral reefs sediments from Red Sea of Yemen, sediment samples were collected, treated and analyzed for cadmium, chromium, cobalt, copper, manganese, nickel, iead, iron, zinc and vanadium by the atomic absorption spectrometric analysis. The result is that cadmium, cobalt and lead concentrations were high and other elements are low or the same as natural background. It is concluded that the high cadmium, cobalt and lead levels in coral reefs sediments will have negative effects on marine life of the sites, so further researches are needed to characterize the sources fate, biogeochemical processes and impacts of these trace elements on coral reefs and marine of the region. 相似文献
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《中国海洋湖沼学报》2017,(1)
Coral bleaching has generally been recognized as the main reason for tropical coral reef degradation, but there are few long-term records of coral bleaching events. In this study, trace metals including chromium(Cr), copper(Cu), molybdenum(Mo), manganese(Mn), lead(Pb), tin(Sn), titanium(Ti), vanadium(V), and yttrium(Y), were analyzed in two Porites corals collected from Meiji Reef in the tropical South China Sea(SCS) to assess differences in trace metal concentrations in bleached compared with unbleached coral growth bands. Ti, V, Cr, and Mo generally showed irregular fluctuations in both corals. Bleached layers contained high concentrations of Mn, Cu, Sn, and Pb. Unbleached layers showed moderately high concentrations of Mn and Cu only. The different distribution of trace metals in Porites may be attributable to different selectivity on the basis of vital utility or toxicity. Ti, V, Cr, and Mo are discriminated against by both coral polyps and zooxanthellae, but Mn, Cu, Sn, and Pb are accumulated by zooxanthellae and only Mn and Cu are accumulated by polyps as essential elements. The marked increase in Cu, Mn, Pb, and Sn are associated with bleaching processes, including mucus secretion, tissue retraction, and zooxanthellae expulsion and occlusion. Variation in these trace elements within the coral skeleton can be used as potential tracers of short-lived bleaching events. 相似文献