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1.
Abstract

Major ions and stable isotopes in groundwaters of the Plio-Quaternary shallow aquifer of the Djerid oases, southern Tunisia, were investigated to elucidate the origin of groundwater recharge and the mineralization processes. It has been demonstrated that the groundwater composition is mainly controlled by the water–rock interaction, the encroachment of brines from the Chotts and the return flow of irrigation waters. The isotopically depleted groundwater samples suggest that the recharge waters derive from an old palaeoclimatic origin. However, the enriched groundwater samples reflect the presence of evaporated recharge water. Furthermore, the large negative deuterium-excess values indicate the effect of secondary evaporation processes, probably related to the return flow of irrigation waters pumped from the underlying aquifer.

Editor D. Koutsoyiannis; Associate editor E. Custodio

Citation Tarki, M., Dassi, L. and Jedoui, Y., 2012. Groundwater composition and recharge origin in the shallow aquifer of the Djerid oases, southern Tunisia: implications of return flow. Hydrological Sciences Journal, 57 (4), 790–804.  相似文献   

2.
Multivariate statistical techniques, cluster and factor analyses were applied on the Amman/Wadi Sir groundwater chemistry, Yarmouk River basin, north Jordan. The main objective was to investigate the main processes affecting the groundwater chemical quality and its evolution. The k‐means cluster analysis yields three groups with distinct ionic concentrations. Cluster 1 comprises the vast majority of the sampled wells, and the water that belongs to this cluster can be classified as freshwater. Cluster 2 comprises only 2% of the sampled wells; it has the highest ionic concentration. The water of this cluster can be classified as brackish water. Cluster 3 involves 23% of the sampled wells, and it has total ionic concentration intermediate to that of clusters 1 and 2. Factor analysis yields a three‐factor model, which explains 76.77% of the groundwater quality variation. Factor 1 ‘salinity factor’ involves EC, Na+, Cl, SO4‐2, K+ and Mg+2 and reflects groundwater salinization because of overpumping. Factor 2 ‘hardness factor’ includes Ca+2, HCO3 and the pH value and signifies soil–water/rock interaction. Factor 3 ‘nitrate factor’ involves only NO3 and points to groundwater contamination because of human activities, mainly untreated wastewater, and crops and animal cultivation in the unconfined portion of the aquifer. Factors 1 and 3 can be described as human‐induced factors, whereas factor 2 can be described as geogenic factor. Factors' scores were mapped to deduce the controlling processes on the groundwater chemistry. Stable isotope composition of 18O and 2H has revealed that the groundwater is a mixture of two water types. The radioactive isotopes tritium and 14 C were used to evaluate present day recharge to the aquifer and to estimate the groundwater age, respectively. Present day recharge to the groundwater is taking place in the unconfined portion of the aquifer as it is indicated by the measurable tritium content and low groundwater age. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

3.
Abstract

A case study is presented for the application of statistical and geostatistical methods to the problem of estimating groundwater quality variables. This methodology has been applied to the investigation of the detrital aquifer of the Bajo Andarax (Almería, Spain). The use of principal components analysis is proposed, as a first step, for identifying relevant types of groundwater and the processes that bring about a change in their quality. As a result of this application, three factors were obtained, which were used as three new variables (VI: sulphate influence; V2: thermal influence; and V3: marine influence). Analysis of their spatial distribution was performed through the calculation of experimental and theoretical variograms, which served as input for geostatistical modelling using ordinary block kriging. This analysis has allowed a probabilistic representation of the data to be obtained by mapping the three variables throughout the aquifer for each sampling point. In this way, one can evaluate the spatial and temporal variation of the principal physico-chemical processes associated with the three variables VI, V2 and V3 implicated in the groundwater quality of the detrital aquifer.  相似文献   

4.
ABSTRACT

Groundwater is used by 3?million inhabitants in the coastal urban city of Douala, Cameroon, but comprehensive data are too sparse for it to be managed in a sustainable manner. Hence this study aimed to (1) assess the potability of the groundwater; (2) evaluate the spatial variation of groundwater composition; and (3) assess the interaction and recharge mechanisms of different water bodies. Hydrogeochemical tools and methods revealed the following results in the Wouri and Nkappa formations of the Douala basin, which is beneath Douala city: 30% of water samples from hand-dug wells in the shallow Pleistocene alluvium aquifer were saline and highly mineralized. However, water from boreholes in the deeper (49–92 m depth) Palaeocene aquifer was saline-free, less mineralized and potable. Water in the shallow aquifer (0.5–22 m depth) was of Na+-K+-Cl?-NO3? type and not potable due to point source pollution, whereas Ca+-HCO3? unpolluted water dominates in the deeper aquifer. Water in the deep and shallow aquifers indicates the results of preferential flow pass and evaporative recharge, respectively. Possible hydrogeochemical processes include point source pollution, reverse ion exchange, remote recharge areas and mixing of waters with different chemical signatures.
EDITOR D. Koutsoyiannis ASSOCIATE EDITOR M.D. Fidelibus  相似文献   

5.
Abstract

The multi-layered Jeffara de Gabes aquifer system is greatly influenced by tectonics. This system is limited at the base and laterally by evaporite layers and has lateral contacts with the sebkhas (salt flats). The groundwater in this aquifer is characterized by high salinity (3–10 g L-1). Multivariate statistical analysis and a geochemical approach were applied to determine the influence of the evaporite layers and sebkhas on the hydrochemical quality of the Jeffara de Gabes aquifer, and to understand the processes governing its salinity. According to these methods, and based in part on the Sr2+/Ca2+ ratio, it is demonstrated that the strong salinity of the groundwater is due to interactions between water and the evaporite layers that act as a substratum of this aquifer, as well as saltwater intrusion from the sebkhas. Moreover, the medium- to poor-quality groundwaters are characterized by geochemical interactions: cationic exchange and the precipitation/dissolution process of minerals in the aquifer formations.

Editeur Z.W. Kundzewicz

Citation Ben Alaya, M., Zemni, T., Mamou, A. et Zargouni, F., 2014. Acquisition de salinité et qualité des eaux d’une nappe profonde, Tunisie: approche statistique et géochimique. Hydrological Sciences Journal, 59 (2), 395–419.  相似文献   

6.
Abstract

The assessment of groundwater vulnerability to pollution has proved to be an effective tool for water resource management, especially in arid and semi-arid regions like Mahdia and Ksour Essaf. The main objective of this study is to assess the aquifer vulnerability by applying the DRASTIC method as well as using sensitivity analysis to evaluate the effect of each DRASTIC parameter on the final vulnerability map. An additional objective is to demonstrate the role of the GIS techniques in the vulnerability assessment. The DRASTIC method assigns a high vulnerability to the coast of the Mahdia-Ksour Essaf. The lowest values are observed in the southern part of the study area. A sensitivity analysis applied in this study suggests that net recharge, aquifer media and depth of groundwater are the key factors determining vulnerability. The model is validated with groundwater quality data and the results have shown strong relationships between modified DRASTIC Vulnerability Index and nitrate and chloride concentrations.

Citation Saidi, S., Bouri, S. & Ben Dhia, H. (2011) Sensitivity analysis in groundwater vulnerability assessment based on GIS in the Mahdia-Ksour Essaf aquifer, Tunisia: a validation study. Hydrol. Sci. J. 56(2), 288–304.  相似文献   

7.
The primary objective of this study was to evaluate use of the hydraulic profiling tool‐groundwater sampler (HPT‐GWS) log data as an indicator of water quality (level of dissolved ionic species) in an alluvial aquifer. The HPT‐GWS probe is designed for direct push advancement into unconsolidated formations. The system provides both injection pressure logs and electrical conductivity (EC) logs, and groundwater may be sampled at multiple depths as the probe is advanced (profiling). The combination of these three capabilities in one probe has not previously been available. During field work it was observed that when HPT corrected pressure (Pc) indicates a consistent aquifer unit then bulk formation EC can be used as an indicator of water quality. A high correlation coefficient (R 2 = 0.93) was observed between groundwater specific conductance and bulk formation EC in the sands and gravels of the alluvial aquifer studied. These results indicate that groundwater specific conductance is exerting a controlling influence on the bulk formation EC of the coarse‐grained unit at this site, and probably many similar sites, consistent with Archie's Law. This simple relationship enables the use of the EC and Pc logs, with targeted water samples and a minimum of core samples, to rapidly assess groundwater quality over extended areas at high vertical resolution. This method was used to identify both a brine impacted zone at the base of the aquifer investigated and a groundwater recharge lens developing below storm water holding ponds in the upper portion of the same aquifer. Sample results for trace level, naturally occurring elements (As, Ba, U) further demonstrate the use of this system to sample for low level groundwater contamination.  相似文献   

8.
《水文科学杂志》2013,58(6):1241-1252
Abstract

Major ion geochemistry, and water molecule isotopes (18O, 2H) and radiogenic carbon (14C) of dissolved inorganic carbon (DIC) were used to investigate the hydrodynamic functioning of the multilayer aquifer system in the Moulares-Redayef basin, southern Tunisia. The groundwater of different aquifer levels is characterized by sulphate to calcium sulphate water type. The major geochemical processes in the aquifer system are evaporite mineral dissolution and mixing. The isotopic study allows two groundwater types to be identified: an old palaeoclimatic groundwater, marked by low 14C activity and relatively depleted stable isotope (18O and 2H) content characterizes the shallowest aquifers of the Plio-Quaternary and Miocene formations; however, a recent groundwater, distinguished by relatively high 14C activity and slightly enriched 18O and 2H content, characterizes the deep Upper Cretaceous artesian aquifer. In addition to these two water groups, other groundwaters are identified, indicating a mixing effect.  相似文献   

9.
Abstract

Knowledge of the processes that control nitrate migration and its geochemical evolution in the subsurface are fundamental for the regional management of polluted aquifers. In this paper, the spatial distribution and transient variations of nitrate concentrations, associated with manure fertilization, are used to depict hydrogeological dynamics within the sedimentary aquifer system of la Plana de Vic in the Osona region of Spain. Flow systems are identified from geological, hydraulic head, hydrochemical and isotopic data, and by considering nitrate itself as a tracer that indicates how flow paths are modified by human pressures. In this area, nitrates move through fractured aquitards in flows induced by groundwater pumping. Moreover, the lack of casing in the boreholes permits a mixing of groundwater from distinct layers inside the wells, which negates any benefits from the low-nitrate groundwater found in the deepest aquifer layers. Therefore, impacts on groundwater quality are related to intensive manure fertilization as well as to inadequate well construction and exploitation strategies.

Citation Menció, A., Mas-Pla, J., Otero, N. & Soler, A. (2011) Nitrate as a tracer of groundwater flow in a fractured multilayered aquifer. Hydrol. Sci. J. 56(1), 108–122.  相似文献   

10.
Abstract

Groundwater, possibly of fossil origin, is used for water supply in some arid regions where the replenishment of groundwater by precipitation is low. Numerical modelling is a helpful tool in the assessment of groundwater resources and analysis of future exploitation scenarios. To quantify the groundwater resources of the East Owienat area in the southwest of the Western Desert, Egypt, the present study assesses the groundwater resources management of the Nubian aquifer. Groundwater withdrawals have increased in this area, resulting in a disturbance of the aquifer’s natural equilibrium, and the large-scale and ongoing depletion of this critical water reserve. Negative impacts, such as a decline in water levels and increase in salinity, have been experienced. The methodology includes application of numerical groundwater modelling in steady and transient states under different measured and abstraction scenarios. The numerical simulation model developed was applied to assess the responses of the Nubian aquifer water level under different pumping scenarios during the next 30 years. Groundwater management scenarios are evaluated to find an optimal management solution to satisfy future needs. Based on analysis of three different development schemes that were formulated to predict the future response of the aquifer under long-term water stress, a gradual increase in groundwater pumping to 150% of present levels should be adopted for protection and better management of the aquifer. Similar techniques could be used to improve groundwater management in other parts of the country, as well as other similar arid regions.
Editor D. Koutsoyiannis; Associate editor X. Chen  相似文献   

11.
Abstract

Estimating groundwater recharge is essential to ensure the sustainable use of groundwater resources, particularly in arid and semi-arid regions. Soil water balances have been frequently advocated as valuable tools to estimate groundwater recharge. This article compares the performance of three soil water balance models (Hydrobal, Visual Balan v2.0 and Thornthwaite) in the Ventós-Castellar aquifer, Spain. The models were used to simulate wet and dry years. Recharge estimates were transformed into water table fluctuations by means of a lumped groundwater model. These, in turn, were calibrated against piezometric data. Overall, the Hydrobal model shows the best fit between observed and calculated levels (r2 = 0.84), highlighting the role of soil moisture and vegetation in recharge processes.

Editor D. Koutsoyiannis; Associate editor X. Chen

Citation Touhami, I., et al., 2014. Comparative performance of soil water balance models in computing semi-arid aquifer recharge. Hydrological Sciences Journal, 59 (1), 193–203.  相似文献   

12.
Abstract

The Complex Terminal (CT) and Plio-Quaternary (P-Q) aquifers in the Chott Gharsa plain in southwestern Tunisia have been investigated with the aid of chemical and isotopic tools. It has been demonstrated that groundwater from the CT is mainly of palaeo-origin, especially in the western and central parts of the plain where the most negative values of δ18O and δ2H were observed (between??8.1 and??7.6‰ for δ18O, and??60 to??57‰ for δ2H), combined with low concentrations of radiocarbon (6.8–7.5 pmc) and absence of tritium. Modern recharge of the aquifer occurs only in the eastern part of the system where younger waters were observed, as indicated by their stable isotope composition, relatively high radiocarbon content and presence of tritium. Groundwater from the P-Q multi-layer aquifer represents mixtures of ascending deep CT waters and modern water recharging the P-Q aquifer system. Isotope mass balance was used to quantify mixing proportions. The calculations showed that the contribution of deep CT groundwater to the P-Q aquifer system reaches about 75% in the western and central parts of the plain where the CT aquifer remains strongly artesian. This contribution decreases to about 15% towards the eastern part of the plain, as a consequence of significant reduction of artesian pressure in this area of the CT aquifer. Chemical data suggest that mineralization of the studied groundwater systems is controlled mainly by dissolution of evaporative minerals (halite, anhydrite and gypsum) and cation exchange reactions with the matrix, possibly enhanced by recent anthropogenic disturbance of the system caused by lowering of the water table due to heavy exploitation and return flow of saline irrigation water into the P-Q aquifer.

Editor D. Koutsoyiannis; Associate editor E. Custodio

Citation Yangui, H., Abidi, I., Zouari, K., and Rozanski, K., 2012. Deciphering groundwater flow between the Complex Terminal and Plio-Quaternary aquifers in Chott Gharsa plain (southwestern Tunisia) using isotopic and chemical tools. Hydrological Sciences Journal, 57 (5), 967–984.  相似文献   

13.
This study explores linkages between the microbial composition and hydrochemical variables of pristine groundwater to identify active redox conditions and processes. Two confined aquifers underlying the city of Qianjiang in the Jianghan Plain in China were selected for this study, having different recharge sources and strong hydrochemical gradients. Typical methods for establishing redox processes according to threshold concentration criteria for geochemical parameters suggest iron or sulphate reduction processes. High‐throughput 16S rRNA sequencing was used to obtain diversity and taxonomic information on microbial communities. Instead of revealing iron‐ and sulphate‐reducing bacteria, salt‐ and alkali‐tolerant bacteria, such as the phylum Firmicutes and the class Gammaproteobacteria, and in particular, the family Bacillaceae, were dominant in the downstream groundwater of the first aquifer that had high ion concentrations caused by the dissolution of calcite and dolomite; meanwhile, the heterotrophic microaerophilic families Comamonadaceae and Rhodocyclaceae prevailed in the upstream groundwater of the first aquifer. Sulphate‐reducing bacteria were extremely abundant in the upstream groundwater of the second aquifer, as the SO42? concentration was especially high. Methanogens and methanotrophs were predominant in the downstream groundwater of the second aquifer even though the concentration of SO42? was much higher than 0.5 mg L?1. The microbial communities, together with the geochemical parameters, indicated that the upstream region of the first aquifer was suboxic, that Fe(III) and Mn(IV) reductions were not the main redox processes in the downstream groundwater of the first aquifer with high Fe and Mn concentrations, and that the redox processes in the upstream and downstream regions of the second confined aquifer were SO42? reduction and methanogenesis, respectively. This study expands understanding of the linkages between microbial communities and hydrogeochemistry in pristine groundwaters and provides more evidence for identifying active redox conditions and processes.  相似文献   

14.
Abstract

The increasing water demand is a concern affecting many regions in the Mediterranean Basin. To overcome this situation rim countries resorted during the last decades to a massive mobilization of their water resources, often resulting in excessive water exploitation. In such a context, understanding the effects of present recharge and aquifer salinization is crucial for correct water management. Understanding the present hydrogeological situation of coastal plains requires the knowledge of both their past morphologic conditions and their recent geological evolution. Within this framework, this paper presents a review of water related problems in the Mediterranean Basin. It suggests a conceptual model for groundwater resources in Mediterranean coastal plains, deriving from the present and past recharge processes. Special attention is paid to providing a better understanding of climate change impacts on water quantity and quality, and conservation of ecological diversity.

Citation Re, V. & Zuppi, G. M. (2011) Influence of precipitation and deep saline groundwater on the hydrological systems of Mediterranean coastal plains: a general overview. Hydrol. Sci. J. 56(6), 966–980.  相似文献   

15.
Abstract

The Wadi Al Ayn plain is a coastal system on the eastern coast of Cap Bon in northeastern Tunisia. The area is known for its intensive agriculture, which is based mainly on groundwater exploitation. The aim of this study is to identify the sources of groundwater salinization in the Wadi Al Ayn aquifer system and deduce the processes that drive the mineralization. Surface water and groundwater samples were taken and analysed for major ions and stable isotopes. The geochemical data were used to characterize and classify the water samples based on a variety of ion plots and diagrams. Stable isotopes are useful tools to help us understand recharge processes and to differentiate between salinity origins. The oilfield brines infiltrated from the sandy bed of Wadi Al Ayn comprise the main source of groundwater salinization in the central part of the plain, while seawater intrusion is mainly responsible for the increased salinity in the groundwater of the coastal part of the plain (at Daroufa).

Citation Chekirbane, A., Tsujimura, M., Kawachi, A., Isoda, H., Tarhouni, J., and Benalaya, A., 2013. Hydrogeochemistry and groundwater salinization in an ephemeral coastal flood plain: Cap Bon, Tunisia. Hydrological Sciences Journal, 58 (5), 1097–1110.  相似文献   

16.
A variety of multivariate statistical procedures were applied to three separate sets of quantitative analytical data from a coastal aquifer located in Malia, Crete (Greece), in order to identify the major hydrochemical processes affecting the groundwater quality and to investigate the evolution of groundwater composition in three different sampling periods. Two of them were carried out on October 2001 and September 2002 at the end of the dry season and the third on April 2002 at the end of the wet period. Two factors were found that explained major hydrochemical processes in the aquifer. These factors reveal the existence of an intensive intrusion of seawater and mechanisms of nitrate contamination of groundwater. Bivariate plots of the scores of the two main factors showed that the seawater intrusion and nitrate pollution processes are maintained through three surveys and that the process of nitrate pollution increases from the first to the second dry survey. Q‐mode factor analysis and discriminant analysis of the three sampling periods clearly showed a seasonal variation of the whole chemistry of groundwater samples. This seasonal variation can be attributed to the freshwater recharge and seawater intrusion that affect the groundwater quality of the Malia aquifer. The results of trend surface analysis are in agreement with those of factor analysis. Moreover, the fourth‐order trend surfaces of EC, Cl? and NO3? showed that the salinization process is more intensive during the first dry period and the spatial variation of NO3? maxima plumes are strongly affected by the flow regime of the Malia aquifer. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
Coastal aquifers are at threat of salinization in most parts of the world. This work investigated the seasonal hydrochemical evolution of coastal groundwater resources in Urmia plain, NW Iran. Two recently proposed methods have been used to comparison, recognize and understand the temporal and spatial evolution of saltwater intrusion in a coastal alluvial aquifer. The study takes into account that saltwater intrusion is a dynamic process, and that seasonal variations in the balance of the aquifer cause changes in groundwater chemistry. Pattern diagrams, which constitute the outcome of several hydrochemical processes, have traditionally been used to characterize vulnerability to sea/saltwater intrusion. However, the formats of such diagrams do not facilitate the geospatial analysis of groundwater quality, thus limiting the ability of spatio-temporal mapping and monitoring. This deficiency calls for methodologies which can translate information from some diagrams such Piper diagram into a format that can be mapped spatially. Distribution of groundwater chemistry types in Urmia plain based on modified Piper diagram using GQIPiper(mix) and GQIPiper(dom) indices that Mixed Ca–Mg–Cl and Ca-HCO3 are the dominant water types in the wet and dry seasons, respectively. In this study, a groundwater quality index specific to seawater intrusion (GQISWI) was used to check its efficiency for the groundwater samples affected by Urmia hypersaline Lake, Iran. Analysis of the main processes, by means of the Hydrochemical Facies Evolution Diagram (HFE-Diagram), provides essential knowledge about the main hydrochemical processes. Subsequently, analysis of the spatial distribution of hydrochemical facies using heatmaps helps to identify the general state of the aquifer with respect to saltwater intrusion during different sampling periods. The HFE-D results appear to be very successful for differentiating variations through time in the salinization processes caused by saltwater intrusion into the aquifer, distinguishing the phase of saltwater intrusion from the phase of recovery, and their respective evolutions. Both GQI and HFE-D methods show that hydrochemical variations can be read in terms of the pattern of saltwater intrusion and groundwater quality status. But generally, in this case (i.e. saltwater and not seawater intrusion) the HFE-D method was presented better efficiency than GQI method (including GQIPiper and GQISWI).  相似文献   

18.
《水文科学杂志》2013,58(4):844-856
Abstract

The feasibility of aquifer storage and recovery (ASR) was tested in a deep aquifer near Koksijde, Belgium. To achieve this, oxic drinking water was injected into a deep aquifer (the Tienen Formation) that contains anoxic brackish water. The hydraulic properties of the aquifer were determined using a step-drawdown test. Chemical processes caused by the injection of the water were studied by two push—pull tests. The step-drawdown test was interpreted by means of an inverse numerical model, resulting in a transmissivity of 3.38 m2/d and a well loss coefficient of 0.00038 d2/m5. The push—pull tests identified mixing between the injection and pristine waters, and cation exchange, as the major processes determining the quality of the recovered water. Mobilization of DOC, aerobic respiration, denitrification and mobilization of phosphate were also observed.  相似文献   

19.
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals.  相似文献   

20.
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals.  相似文献   

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