Drought impacts on water quality and potential implications for agricultural production in the Maipo River Basin,Central Chile     

M. D. Peña-Guerrero  A. Nauditt  C. Muñoz-Robles  L. Ribbe  F. Meza 《水文科学杂志》2020,65(6):1005-1021

ABSTRACT

Droughts can have serious negative impacts on the water quality needed for irrigated agriculture. The Metropolitan region of Chile is a relevant producer of high-value crops and is prone to droughts. Standardized Drought Indices were used to characterize meteorological and hydrological droughts for the period from 1985 to 2015. To understand the relationship between droughts and water quality, we evaluated the correlations between daily discharge and surface water quality observations. The threshold level method was used to compare physicochemical parameters during hydrological drought periods with the Chilean water quality thresholds for agricultural uses. A significant (p < 0.05) negative relationship between discharge and electrical conductivity and major ions was found in most of the basin. Hydrological stations located in irrigation districts exceeded the official thresholds for these parameters during hydrological drought periods seriously threatening irrigated agriculture of the region.  相似文献   

Groundwater problems in the karstic aquifers of the Dobrich region,northeastern Bulgaria     

A. PULIDO-BOSCH  M. LÓPEZ-CHICANO  J. M. CALAFORRA  M. L. CAL VACHE  M. MACHKOVA  D. DIMITROV 《水文科学杂志》2013,58(6):913-927

Abstract

In the Dobrich region, with an area of a little over 4000 km², two important aquifer systems can be differentiated, which we have named the Upper and Deep Aquifers. The hydrodynamic and hydrogeochemical characteristics of these two aquifers are different. Agricultural activities, livestock units, and urban waste waters and solid wastes constitute the principal sources of contamination of the Upper Aquifer. Furthermore, signs of marine intrusion in some coastal zones have been detected. The Deep Aquifer is found to be affected by hydrogeochemical processes related to hydrocarbons that generate elevated concentrations of H₂S and NO₂ (which may exceed 10 mg 1^?1). This aquifer has numerous deep overflowing boreholes that lack appropriate capping, with the consequent loss of resource, draining in the order of 4 m³ s^?1 of thermal and sulphurous waters.  相似文献   

Nitrogen compounds in the surface and subsurface waters of Karelia     

P. A. Lozovik  G. S. Borodulina 《Water Resources》2009,36(6):672-682

Materials of long-term studies of the concentration and distribution of N forms (NH₄⁺, NO₃⁻, NO₂⁻, N_org) in precipitation, surface water and groundwater are generalized. Precipitation was found to be the main source of N compounds input into these waters. The effect of anthropogenic factors is local and does not influence the concentration and distribution of N forms in most water bodies that serve as wastewater recipients. The N forms dominating in precipitation are NO₃⁻ and N H₄⁺; N_org dominates in most surface water bodies, and NO₃⁻ dominates in groundwater. The median concentrations of N_tot in clear surface and subsurface waters are similar. The obtained characteristics of the concentrations and distribution of N forms in natural waters of Karelia can be used for other water bodies in the humid zone.  相似文献   

An index to assess hydromorphological quality of Estonian surface waters based on macroinvertebrate taxonomic composition     

Henn Timm  Kairi Käiro  Tõnu Möls  Taavi Virro 《Limnologica》2011,41(4):398-410

We developed an index (MESH – Macroinvertebrates in Estonia: Score of Hydromorphology) to assess hydromorphological quality of Estonian surface waters based on macroinvertebrate taxonomic composition. The MESH is an average score based on the affinities of selected indicator taxa to flow velocity and bottom type. As both parameters were highly correlated (r = 0.65) indicator response to both parameters were combined. The list of MESH indicators includes 394 freshwater macroinvertebrate taxa derived from 3282 samples collected from rivers and lakes during 1985–2009. The indicators were selected out of 690 taxa, by applying the information-theoretical Kullback–Leibler divergence. The individual scores of macroinvertebrates range from 0 to 3, the higher scores indicating faster flow and/or solid bottom substrate. For standing waters, flow velocity was always considered zero. Among the reference waterbodies, mean MESH was the highest for small streams followed by middle streams, large streams, and lakes. In lakes with medium water hardness (the prevailing type in Estonia), the MESH decreased gradually from stony to muddy bottom. The highest MESH values for standing waters were observed in the stony surf zone of very large lakes (area > 100 km²). The lowest values occurred for small lakes with exceptional hydrochemical characteristics (soft- and darkwater, and calcareous types). Similarly, MESH indicated stream degradation by damming. Mean MESH in reservoirs with a muddy bottom was significantly lower than in reservoirs with a hard bottom, or in unregulated stream sections.  相似文献   

Impacts anthropiques sur les termes du bilan hydrologique d’un aquifère alluvial dans le Nordeste semi-aride,Brésil / Human impacts on components of hydrological balance in an alluvial aquifer in the semiarid Northeast,Brazil     

《水文科学杂志》2013,58(1)

Abstract

Abstract The exploitation of an alluvial aquifer (2 × 10⁶ m³) has been developed since 1998 in the Valley of Forquilha (Quixeramobim, State of Ceará). For this purpose, 165 wells were drilled along the 23 km of the valley that supplies 500 families and their farms. Monthly monitoring of piezometric and electrical conductivity (2000–2003) show seasonal variations in the water volume (35%) and in the mean value of the conductivity (800–1200 µS cm^-1). A conceptual hydrogeological model was developed. Analysis of the data and simulations highlight that the recharge of the aquifer is mainly due to infiltration from the river in the rainy season, which is of the order of 1% of the rain over the catchment area (195 km²). The abstractions increase the recharge between 30 and 60%. The model makes it possible to propose scenarios of sustainable exploitation of the water resource in the catchment. For the period between 1970 and 1988, other simulations show that it would have been possible to maintain irrigated cultures on 75 ha for 80% of the time. During the remaining 20%, the water level is too low, and farmers would have to reduce the irrigated area.  相似文献   

Dissolved oxygen levels in estuarine and coastal waters around Ireland     

Shane O&#x;Boyle  Georgina McDermott  Robert Wilkes 《Marine pollution bulletin》2009,58(11):1657-1663

This paper presents the status of summer oxygen conditions in estuarine and coastal waters around Ireland between 2003 and 2007. Of the 95 water bodies surveyed, 85 had oxygen levels sufficient to support aquatic life. This corresponds to a surface area of 3125 km² or 99.4% of the total area assessed. Ten water bodies, representing a surface area of 20.2 km², were deficient in oxygen but still capable of supporting most aquatic life. No evidence of hypoxia (<2.0 mg/l O₂) or anoxia (<0.2 mg/l O₂) was found. Dissolved oxygen conditions in a number of estuaries continue to improve, probably due to improved municipal waste water treatment. The implementation of measures contained in both the Nitrates and Urban Waste Water Treatment Directives, together with those of the Water Framework Directive, should ensure areas of oxygen deficiency are eliminated from Irish waters.  相似文献   

Geochemical weathering at the bed of Haut Glacier d'Arolla,Switzerland—a new model     

M. Tranter  M. J. Sharp  H. R. Lamb  G. H. Brown  B. P. Hubbard  I. C. Willis 《水文研究》2002,16(5):959-993

Waters were sampled from 17 boreholes at Haut Glacier d'Arolla during the 1993 and 1994 ablation seasons. Three types of concentrated subglacial water were identified, based on the relative proportions of Ca²⁺, HCO₃^? and SO₄^2? to Si. Type A waters are the most solute rich and have the lowest relative proportion of Si. They are believed to form in hydrologically inefficient areas of a distributed drainage system. Most solute is obtained from coupled sulphide oxidation and carbonate dissolution (SO–CD). It is possible that there is a subglacial source of O₂, perhaps from gas bubbles released during regelation, because the high SO₄^2? levels found (up to 1200 µeq/L) are greater than could be achieved if sulphides are oxidized by oxygen in saturated water at 0 °C (c.414 µeq/L). A more likely alternative is that sulphide is oxidized by Fe³⁺ in anoxic environments. If this is the case, exchange reactions involving Fe^III and Fe^II from silicates are possible. These have the potential to generate relatively high concentrations of HCO₃^? with respect to SO₄^2?. Formation of secondary weathering products, such as clays, may explain the low Si concentrations of Type A waters. Type B waters were the most frequently sampled subglacial water. They are believed to be representative of waters flowing in more efficient parts of a distributed drainage system. Residence time and reaction kinetics help determine the solute composition of these waters. The initial water–rock reactions are carbonate and silicate hydrolysis, and there is exchange of divalent cations from solution for monovalent cations held on surface exchange sites. Hydrolysis is followed by SO–CD. The SO₄^2? concentrations usually are <414 µeq/L, although some range up to 580 µeq/L, which suggests that elements of the distributed drainage system may become anoxic. Type C waters were the most dilute, yet they were very turbid. Their chemical composition is characterized by low SO₄^2? : HCO₃^? ratios and high pH. Type C waters were usually artefacts of the borehole chemical weathering environment. True Type C waters are believed to flow through sulphide‐poor basal debris, particularly in the channel marginal zone. The composition of bulk runoff was most similar to diluted Type B waters at high discharge, and was similar to a mixture of Type B and C waters at lower discharge. These observations suggest that some supraglacial meltwaters input to the bed are stored temporarily in the channel marginal zone during rising discharge and are released during declining flow. Little of the subglacial chemical weathering we infer is associated with the sequestration of atmospheric CO₂. The progression of reactions is from carbonate and silicate hydrolysis, through sulphide oxidation by first oxygen and then Fe^III, which drives further carbonate and silicate weathering. A crude estimate of the ratio of carbonate to silicate weathering following hydrolysis is 4 : 1. We speculate that microbial oxidation of organic carbon also may occur. Both sulphide oxidation and microbial oxidation of organic carbon are likely to drive the bed towards suboxic conditions. Hence, we believe that subglacial chemical weathering does not sequester significant quantities of atmospheric CO₂ and that one of the key controls on the rate and magnitude of solute acquisition is microbial activity, which catalyses the reduction of Fe^III and the oxidation of FeS₂. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

A natural tracer investigation of the hydrological regime of Spring Creek Springs, the largest submarine spring system in Florida     

Natasha T. Dimova  William C. BurnettKevin Speer 《Continental Shelf Research》2011,31(6):731-738

This work presents results from a nearly two-year monitoring of the hydrologic dynamics of the largest submarine spring system in Florida, Spring Creek Springs. During the summer of 2007 this spring system was observed to have significantly reduced flow due to persistent drought conditions. Our examination of the springs revealed that the salinity of the springs' waters had increased significantly, from 4 in 2004 to 33 in July 2007 with anomalous high radon (²²²Rn, t_1/2=3.8 days) in surface water concentrations indicating substantial saltwater intrusion into the local aquifer. During our investigation from August 2007 to May 2009 we deployed on an almost monthly basis a continuous radon-in-water measurement system and monitored the salinity fluctuations in the discharge area. To evaluate the springs' freshwater flux we developed three different models: two of them are based on water velocity measurements and either salinity or ²²²Rn in the associated surface waters as groundwater tracers. The third approach used only salinity changes within the spring area. The three models showed good agreement and the results confirmed that the hydrologic regime of the system is strongly correlated to local precipitation and water table fluctuations with higher discharges after major rain events and very low, even reverse flow during prolong droughts. High flow spring conditions were observed twice during our study, in the early spring and mid-late summer of 2008. However the freshwater spring flux during our observation period never reached that reported from a 1970s value of 4.9×10⁶ m³/day. The maximum spring flow was estimated at about 3.0×10⁶ m³/day after heavy precipitation in February-March 2008. As a result of this storm (total of 173 mm) the salinity in the spring area dropped from about 27 to 2 in only two days. The radon-in-water concentrations dramatically increased in parallel, from about 330 Bq/m³ to about 6600 Bq/m³. Such a rapid response suggests a direct connection between the deep and the surficial aquifers.  相似文献   

Changing Land Use a Threat to Surface Water Quality: a Vulnerability Assessment Approach in Zanjanroud Watershed,Central Iran     

Mahsa Mirhosseini  Parvin Farshchi  Ali Akbar Noroozi  Mahmood Shariat  Ali Asghar Aalesheikh 《Water Resources》2018,45(2):268-279

Maintaining the quality of surface water resources as one of the most vital water supplies has always been at the center of global concerns. A set of manifest and latent factors have yet been identified by researchers worldwide that are subject to affect the quality of surface water. Among which, the effect of land use change, due to a spatial and temporal complexity, is often not easily verifiable. The present study attempts to offer an index-based model to quantify vulnerability of surface water resources in a semi arid basin in central Iran against land use changes. For this, water quality data including Na, K, Mg, Ca, Sodium Adsorption Ratio (SAR), total anions (Sum. A), SO₄, Cl, HCO₃, EC, TDS, and pH were collected from hydrometric stations over a period of 26 years (1987?2013). In order to detect land use changes, the land use maps of the years 1987, 1998, 2002, 2009, and 2013 were prepared from TM satellite images using supervised classification method. At next step, changing patterns of different land uses were traced by Shanon’s Diversity Index (SHDI) as a metric of patch diversity indicating diversity and heterogeneity of a landscape over time. Relationship between the SHDI values and water quality indicators revealed the impact of land use changes on quality of surface water resources. Statistical analysis confirmed a significant relationship between nine water quality factors and water discharge in the basin during the study period. From 1998 to 2009, the greatest changes were visible in the total anions, Ca, SO₄, and HCO₃. These parameters along with salinity were increasing in almost all sub-basins. According to the results, conversion of poor rangelands to rain fed agriculture fields is the most apparent land use change occurred in the study area over the study period. In 1987, SHDI as an indicator of the diversity and changes in the basin, showed a significant relationship with good rangelands (R² =–0.835). This indicates that fragmentation of the entire watershed area was initiated in 1987, which reached its peak in 2013. Generally speaking, urbanization, poor rangeland, and irrigated agriculture were recognized as three influential land uses adversely affect the water quality in the study area.  相似文献   

Radium isotopes in sub-Arctic waters     

Willard S. Moore  Herbert W. Feely  Yuan-Hui Li 《Earth and Planetary Science Letters》1980,49(2):329-340

Measurements of the²²⁸Ra/²²⁶Ra activity ratio in the waters of the Greenland, Norwegian and Labrador Seas and Baffin Bay reveal strong horizontal gradients in the surface waters. The coastal waters are dominated by²²⁸Ra injection from nearshore sediments. There is an inverse correlation between the²²⁸Ra/²²⁶Ra activity ratio and salinity in the 30–36‰ salinity range. Vertical profiles indicate that the²²⁸Ra/²²⁶Ra activity ratio is also strongly coupled toσ_θ except for some regions where²²⁸Ra is being injected into higher density water as these isopycnals intersect coastal areas. We use these measurements in the area of formation of North Atlantic Deep Water to estimate that this water mass forms with a²²⁸Ra/²²⁶Ra activity ratio of 0.10.  相似文献   

Hydrogen and oxygen isotope ratios in the waters of the Ngawha hydrothermal area,North Auckland     

D. C. McDonald 《Bulletin of Volcanology》1966,29(1):691-707

The ratios of D/H and O¹⁸/O¹⁶ in natural waters from streams, boreholes, soda springs, hot pools, ponds and larger bodies of water in the Ngawha hydrothermal area were determined. The results are considered in relation to the isotopic changes known to occur in water subjected to evaporation. Where applicable chemical and other work was also considered. It is assumed that stream water isotope composition is the mean value for the isotopic composition of meteoric waters. Measurements on waters taken from boreholes drilled to 65 feet and 350 feet and from the other water sources mentioned, indicate that they were of meteoric origin as judged by stream isotope composition. The waters from the soda springs appeared to be isotopically the same as the stream water, a finding consistent with the absence of evaporative surface. These borehole waters were similar but slightly different in O¹⁸ due probably to exchange between rock and water. Heavy isotope enrichment of the ponds and larger bodies of water appeared to be due to non-equilibrium evaporation at ambient temperature. The hot pools in the Ngawha springs area proper were enriched in the heavier isotopes probably due to non-equilibrium evaporation at the usual hot pool temperature of about 40°C and also to exchange of O¹⁸ between water and rock. The water from a further borehole drilled to approximately 2,000 feet appeared also to be of meteoric origin but was changed in O¹⁸ content to an extent consistent with the assumption that oxygen isotope exchange with rock had taken place at approximately 230°C. The results are used to illustrate possibilities for the use of oxygen and hydrogen isotope measurements in hydrothermal investigations.  相似文献   

The distribution of ²¹⁰Pb and ²¹⁰Po in the surface waters of the Pacific Ocean     

Y. Nozaki  J. Thomson  K.K. Turekian 《Earth and Planetary Science Letters》1976,32(2):304-312

By modelling the observed distribution of²¹⁰Pb and²¹⁰Po in surface waters of the Pacific, residence times relative to particulate removal are determined. For the center of the North Pacific gyre these are τ_Po = 0.6years andτ_Pb = 1.7years. The surface ocean τ_Pb is determined by particulate transport rather than plankton settling. The fact that it is about two orders of magnitude smaller than τ_Pb for the deep ocean implies a sharp change in the adsorptive quality of particles during descent through the water column.  相似文献   

Estimating the influence of increased nitrate loads from wastewater on phosphorus mobility in river sediments     

Oliver Gabriel  Dagmar Balla  Thomas Kalettka  Christian Schilling  Matthias Zessner 《洁净——土壤、空气、水》2006,34(4):333-345

Research on the sediment‐surface water transition zone in three study site regions, different in hydrological conditions, was conducted to estimate to which extent nitrate in surface water can contribute to riverbed sediment oxidation and thus prevent release of sediment phosphorus to surface water. Consequently, the Du tch Flow Model (DUFLOW) based water quality model “Spreewald” and results from the emission model “ Mo delling N utrient E missions in Ri ver S ystems” (MONERIS) were used to estimate to which extent wastewater treatment plants (WWTPs) could contribute to the NO₃^– concentration in surface waters if they were operated without denitrification. It is demonstrated that an effective phosphorus retention in sediments by means of surface water NO₃^– is possible only under specific conditions, i. e. (i) a sufficient supply of surface water to the sediment by advective fluxes, (ii) a sufficient amount of sediment iron to provide phosphorus binding sites in the case of sediment oxidation, (iii) a redox system not leading to a rapid NO₃^– and FeOOH depletion and to phosphorus release from organic pools by high microbial activities. Model results show that in‐stream denitrification processes counteract a significant increase of NO₃^– surface water concentrations from WWTPs operated without denitrification during summer, when eutrophication risk through phosphorus is highest. The increase of NO₃^– surface water concentrations in winter due to decreased denitrification in the surface water is of minor relevance for phosphorus release from sediments.  相似文献   

Evaluation of historical nitrate sources in groundwater and impact of current irrigation practices on groundwater quality     

Xiuhua Liu  Shijun Sun  Peng Ji  Jirka Šimůnek 《水文科学杂志》2013,58(1):198-212

Abstract

Large-scale agricultural activities cause deterioration of groundwater resources throughout the world. This study focuses on the irrigated agricultural district of Jinghuiqu in Shaanxi, China. The objectives are to identify the main sources and processes that control nitrate transport, and to assess the impact of long-term irrigation practices on nitrate leaching. The hydrogeochemistry of major solute constituents and stable isotope ratios of NO₃ ^? in groundwater were used to identify historical sources of contamination and transformation processes occurring in the shallow groundwater of the Jinghuiqu irrigation district. The N-NO₃ ^? concentrations in groundwater ranged from 0.0 to more than 100 mg L^?1 in April 1990, and from 0.47 to 42.0 mg L^?1 in December 2009. Our measurements of N-NO₃ ^? show that the main reasons for this dramatic decline in N-NO₃ ^? concentrations from 1990 to 2009 are denitrification, which controls nitrogen types, together with the sharp decline of the groundwater table. The isotope ratios in collected samples showed that the source of nitrate was mainly manure, a result that corresponds with historical data showing that manure was the main nitrate source before the 1980s, and that fertilizers became dominant thereafter. A numerical model was then used to evaluate future impacts of current irrigation practices on groundwater sources. The HYDRUS-1D model was employed first to evaluate the water movement and the N-NO₃ ^? solute transport for a single irrigation pulse experiment carried out under field conditions, and then in evaluating the long-term impact of irrigation on N-NO₃ ^? leaching. Simulations showed that, after introducing irrigation, the downward drainage fluxes of N-NO₃ ^?, and the N-NO₃ ^? and N-tot concentrations increased at all depths within the 2-m soil profile. This indicates that N concentrations below 1-m depth and in the groundwater could become even more elevated with increased future irrigation.

Editor D. Koutsoyiannis

Citation Liu, X.-H., Sun, S.-J., Ji, P., and ?im?nek, J., 2013. Evaluation of historical nitrate sources in groundwater and impact of current irrigation practices on groundwater quality. Hydrological Sciences Journal, 58 (1), 1–15.  相似文献   

Ammonium Ion, Humic Materials, and Trihalomethane Potential in Northeastern Kansas Ground Waters   总被引：1，自引：0，他引：1  

Jane E. Denne  Lawrence R. Hathaway  S. Patrick McCool 《Ground water》1984,22(6):755-763

Glacial buried-valley aquifers serve as primary sources of potable ground water in northeastern Kansas. A long known problem, however, is that a large percentage of well waters in this region exceed the U.S. Environmental Protection Agency (EPA) limits for nitrate (NO⁻₃). A detailed study of the hydrogeology and water quality of the buried valleys has confirmed the nitrate problem and led to a recognition that some well waters with low ( 5 mg/l) NO⁻₃ concentrations have anomalous ( 0.5 mg/l) ammonium ion (NH⁺₄) levels, with an NH⁺₄ range from <0.1 to 4.8 mg/l. The extractable NH⁺₄ concentrations in related glacial sediments range up to approximately 75 mg/kg, and the amounts generally increase from an average of 2 mg/kg in the topsoil downward to bedrock. Migration of brines from subjacent Permian or Pennsylvanian bedrock into the unconsolidated sediments locally may cause desorption of NH⁺₄ and an increase in its levels in the associated ground waters. Numerous test holes drilled in the study area showed a black scum on the fluid and cuttings, which may be from buried humic materials. Recently measured total organic carbon (TOC) contents of the ground waters confirm a significant level in some areas, with a range from 0.1 to 2.4 mg/l as C. Chlorination of water with dissolved organics may lead to production of halogenated compounds. Two public-water-supply well waters contained total trihalomethane (TTHM) levels close to the maximum contaminant level (MCL) of 100 /μg/l in chlorinated samples quenched after one week. The presence of NH⁺₄ inhibits the formation of THMs, but it also can give rise to odor and taste problems in the finished water. The inhibition of THM formation by NH⁺₄ is achieved by reactions which compete with the organics for combination with chlorine. These reactions make maintaining appropriate chlorine residuals difficult and also may lead to production of undesirable side products. Present efforts to evaluate the regional water-quality problems are focused in Nemaha County, Kansas.  相似文献