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1.
A. D. Koussis E. Georgopoulou A. Kotronarou D. P. Lalas P. Restrepo G. Destouni 《水文科学杂志》2013,58(7):1217-1233
Abstract Semi-arid coastal zones often suffer water-stress, as water demand is high and markedly seasonal, due to agriculture and tourism. Driven by scarcity of surface water, the communities in semi-arid coastal regions turn to aquifers as prime water source; but intensive exploitation of coastal aquifers causes seawater intrusion, which degrades the quality of groundwater. The cost-efficient and sustainable development of coastal aquifers can be achieved through a holistic management scheme which combines two non-traditional water sources: (a) saltwater, to be treated to the desired quality, and (b) wastewater, to be re-claimed to augment aquifer recharge for control of seawater intrusion, and also to meet certain demands. This management scheme is based on the idea that it is cost-advantageous to: (i) desalt brackish groundwater, instead of seawater, as the former requires far less energy, and (ii) to re‐use wastewater at only the differential cost to any treatment already practiced. In this paper, we present the general framework of the proposed management scheme, and a decision aid tool (DAT) which has been developed to assist decision makers to explore the scheme's decision space. The DAT uses cost as optimization criterion to screen various management scenarios, via modelling of the dynamic natural-engineered system behaviour, and identifies those cost-efficient ones that meet the water demand and achieve aquifer protection. Citation Koussis, A. D., Georgopoulou, E., Kotronarou, A., Lalas, D. P., Restrepo, P., Destouni, G., Prieto, C., Rodriguez, J. J., Rodriguez-Mirasol, J., Cordero, T. & Gomez-Gotor, A. (2010) Cost-efficient management of coastal aquifers via recharge with treated wastewater and desalination of brackish groundwater: general framework. Hydrol. Sci. J. 55(7),1217–1233. 相似文献
2.
Abstract This paper describes a research project based in Cyprus to investigate a number of different methods for determining quantitative recharge to aquifers in semiarid areas. Large lysimeters and geochemical profile techniques have been used in the southeastern Mesaoria area of Cyprus where there has already been a quantitative water resources investigation and where a groundwater model is in preparation. Further joint geochemical and lysimeter studies are also being undertaken in the Akrotiri peninsula (average annual rainfall 430 mm). Excavation and piling techniques have been used to install the lysimeters which are up to 100 m2 in area by 4 m deep. The lysimeters have been made as large as possible to minimize edge effects whilst maintaining the soil and aquifer material within them in an ‘undisturbed’ state. A dry drilling method has been developed to obtain sand samples from the unsaturated zone together with a method for processing the core material to obtain data on moisture and solutes. Chloride profiles have been interpreted to provide estimates of the direct recharge component using a steady state, mass balance approach and initial results compare favourably with tritium estimates. The preliminary results for recharge obtained by the different techniques are compared with each other and with estimates obtained from conventional methods. Initial results from the lysimeters indicate a current annual recharge of 5 mm in southeastern Mesaoria (1978), whilst a mean annual recharge of 50 mm at Akrotiri has been obtained by the chloride profile method. 相似文献
3.
Jamal Asfahani 《水文科学杂志》2013,58(2):468-482
Abstract Traditional and polar vertical electrical sounding (VES) techniques were used for computing and characterizing the transmissivity of the Quaternary and Palaeogene aquifers in the Khanasser Valley, northern Syria. The VES technique with its different applied approaches is inexpensive, easy and gives rapid results with high spatial resolution. The Dar-Zarrouk parameters were determined to estimate the groundwater potential of the aquifers. The results show the mean transmissivity of the Quaternary aquifer to be 49 m2/d (minimum: 10 m2/d; maximum: 131 m2/d; standard deviation: 32 m2/d), and that of the Palaeogene aquifer is 0.94 m2/d (minimum: 0.31 m2/d; maximum: 1.54 m2/d; standard deviation: 0.33 m2/d). Editor D. Koutsoyiannis Citation Asfahani, J., 2013. Groundwater potential estimation using vertical electrical sounding measurements in the semi-arid Khanasser Valley region, Syria. Hydrological Sciences Journal, 58 (2), 468--482. 相似文献
4.
Abstract The Quaternary and Tertiary deposits on the south coast of Portugal are distinguished by their excellent aquifer characteristics. The transmissivity of the Pleistocene-Pliocene formations reaches a maximum of 1 550 m2 d?1. In comparison the Miocene deposits are fairly good aquifers with a transmissivity of about 270 m2 d?1. Among the Holocene deposits the barrier dunes show reasonably good water-bearing qualities. The good hydraulic conductivities (19–22 m d?l) result in a flat shape of the groundwater table and fresh water flows towards the ocean. Excessive groundwater withdrawal has caused sea-water intrusion. The locations of the sea-water intrusions correspond with those centres where a spectacular growth of the tourist industry has taken place since 1968, and also with those areas where new developments in the irrigation techniques for the citrus industry have been applied. On the ocean front where sea water intrusion occurs, the thickness of the freshwater-lens has been reduced to 27–32 m. 相似文献
5.
Assimilation of historical head data to estimate spatial distributions of stream bed and aquifer hydraulic conductivity fields 
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下载免费PDF全文 Management of water resources in alluvial aquifers relies mainly on understanding interactions between hydraulically connected streams and aquifers. Numerical models that simulate this interaction often are used as decision support tools for water resource management. However, the accuracy of numerical predictions relies heavily on unknown system parameters (e.g., streambed conductivity and aquifer hydraulic conductivity), which are spatially heterogeneous and difficult to measure directly. This paper employs an ensemble smoother to invert groundwater level measurements to jointly estimate spatially varying streambed and alluvial aquifer hydraulic conductivity along a 35.6‐km segment of the South Platte River in Northeastern Colorado. The accuracy of the inversion procedure is evaluated using a synthetic experiment and historical groundwater level measurements, with the latter constituting the novelty of this study in the inversion and validation of high‐resolution fields of streambed and aquifer conductivities. Results show that the estimated streambed conductivity field and aquifer conductivity field produce an acceptable agreement between observed and simulated groundwater levels and stream flow rates. The estimated parameter fields are also used to simulate the spatially varying flow exchange between the alluvial aquifer and the stream, which exhibits high spatial variability along the river reach with a maximum average monthly aquifer gain of about 2.3 m3/day and a maximum average monthly aquifer loss of 2.8 m3/day, per unit area of streambed (m2). These results demonstrate that data assimilation inversion provides a reliable and computationally affordable tool to estimate the spatial variability of streambed and aquifer conductivities at high resolution in real‐world systems. 相似文献
6.
AbstractA comprehensive hydro-ecological investigation was conducted to determine the ecological response of increased groundwater withdrawals from the Kirkwood-Cohansey aquifer system, an important source of water supply in southern New Jersey, USA. Collocated observations were made of aquatic-macroinvertebrate assemblages and stream hydrologic attributes to develop flow–ecology response relations. A sub-regional transient groundwater flow model (MODFLOW) was used to simulate three plausible high-stress groundwater-withdrawal scenarios which resulted in stream baseflow reductions of approximately 0.12, 0.20, and 0.26 m3 s-1. These reduction scenarios were used to construct flow-alteration ecological response models to evaluate aquatic-macroinvertebrate response to streamflow reduction. For example, flow-alteration ecological response models indicate that if groundwater withdrawals diminish mean annual streamflow from 1.1 to 0.6 m3 s-1, the abundance of intolerant taxa could be reduced by as much as 20%. These flow-alteration ecological response modelling results could be used by resource professionals to evaluate alternative water management strategies to determine maximum basin withdrawal rates that meet ongoing human water demand while protecting biological integrity.
Editor D. Koutsoyiannis; Guest editor M. AcremanCitation Kennen, J.G., Riskin, M.L., and Charles, E.G., 2014. Effects of streamflow reductions on aquatic macroinvertebrates: linking groundwater withdrawals and assemblage response in southern New Jersey streams, USA. Hydrological Sciences Journal, 59 (3–4), 545–561. 相似文献
7.
Abstract The Complex Terminal (CT) and Plio-Quaternary (P-Q) aquifers in the Chott Gharsa plain in southwestern Tunisia have been investigated with the aid of chemical and isotopic tools. It has been demonstrated that groundwater from the CT is mainly of palaeo-origin, especially in the western and central parts of the plain where the most negative values of δ18O and δ2H were observed (between??8.1 and??7.6‰ for δ18O, and??60 to??57‰ for δ2H), combined with low concentrations of radiocarbon (6.8–7.5 pmc) and absence of tritium. Modern recharge of the aquifer occurs only in the eastern part of the system where younger waters were observed, as indicated by their stable isotope composition, relatively high radiocarbon content and presence of tritium. Groundwater from the P-Q multi-layer aquifer represents mixtures of ascending deep CT waters and modern water recharging the P-Q aquifer system. Isotope mass balance was used to quantify mixing proportions. The calculations showed that the contribution of deep CT groundwater to the P-Q aquifer system reaches about 75% in the western and central parts of the plain where the CT aquifer remains strongly artesian. This contribution decreases to about 15% towards the eastern part of the plain, as a consequence of significant reduction of artesian pressure in this area of the CT aquifer. Chemical data suggest that mineralization of the studied groundwater systems is controlled mainly by dissolution of evaporative minerals (halite, anhydrite and gypsum) and cation exchange reactions with the matrix, possibly enhanced by recent anthropogenic disturbance of the system caused by lowering of the water table due to heavy exploitation and return flow of saline irrigation water into the P-Q aquifer. Editor D. Koutsoyiannis; Associate editor E. Custodio Citation Yangui, H., Abidi, I., Zouari, K., and Rozanski, K., 2012. Deciphering groundwater flow between the Complex Terminal and Plio-Quaternary aquifers in Chott Gharsa plain (southwestern Tunisia) using isotopic and chemical tools. Hydrological Sciences Journal, 57 (5), 967–984. 相似文献
8.
ABSTRACTIntegrated two-dimensional electrical resistivity imaging (ERI) and hydrochemical surveys were used to investigate the groundwater alluvial aquifer in Kuala Langat, Malaysia. The study in the Langat basin considered the thickness of the aquifer, the depth of the bedrock, the regions influenced by seawater intrusion, and the monitoring of water levels. The resistivity imaging results show that the upper layer consists of clay, while the second layer is an aquifer whose thickness varies mostly in the range of 10–30 m, and in some cases extends to 40 m. The bedrock depth varies from 30 to 65 m. The chemical analyses were carried out on groundwater samples from nine boreholes collected between 2008 and 2012. The analyses indicate that the total dissolved solids (TDS) exceed 1000 mg L-1 near the coastal area and are often less than 500 mg L-1 further inland. The ERI and hydrochemical analyses reveal that groundwater in the study area, especially towards the coast, is a mixture of brackish and fresh waters.
EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR M.D. Fidelibus 相似文献
9.
A Geochemical Approach to Determine Sources and Movement of Saline Groundwater in a Coastal Aquifer 总被引：1，自引：0，他引：1
Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major‐ions, the chemical composition is classified as Na‐Ca‐Cl‐SO4, Na‐Cl, or Na‐Ca‐Cl type water. δ2H and δ18O values range from ?47.7‰ to ?12.8‰ and from ?7.0‰ to ?1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. 87Sr/86Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. 3H and 14C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher‐elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest‐to‐southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers. 相似文献
10.
This paper studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion. The investigation concerns the Mamora coastal aquifer, northwest of Morocco. A large‐scale groundwater model was established to model (a) the amount of freshwater discharge towards the ocean and the sea water volumes flowing inland as a consequence of the inverse hydraulic gradient, (b) the impact of drought and pumping discharge on the water table level and, as a consequence, on marine water intrusion. In fact, the simulated submarine groundwater discharge (SGWD) would decrease from 864 m3/d/km in 1987 to 425 m3/d/km in 2000. The simulated volumes of sea water intruding the aquifer as a result of inverse hydraulic gradient would increase from 0·25 Mm3/y in 1987 to 0·3 Mm3/y in 2000. As a consequence of a negative rainfall gradient of −5 mm/y, the simulated SGWD would decline to 9 m3/d/km and the sea water intrusion (SWI) would increase to 0·35 Mm3/y since the year 2010. Due to insufficient data on the trend of pumping discharge, a hypothetical increase of this latter from 38·3 Mm3/y to 53·2 Mm3/y is simulated to induce an increase of marine water intrusion from 0·25 Mm3/y to 0·9 Mm3/y. Consequently, to optimally exploit this seemingly fragile coastal aquifer, a plan of future actions to implement is proposed. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
11.
AbstractThe multi-layered Jeffara de Gabes aquifer system is greatly influenced by tectonics. This system is limited at the base and laterally by evaporite layers and has lateral contacts with the sebkhas (salt flats). The groundwater in this aquifer is characterized by high salinity (3–10 g L-1). Multivariate statistical analysis and a geochemical approach were applied to determine the influence of the evaporite layers and sebkhas on the hydrochemical quality of the Jeffara de Gabes aquifer, and to understand the processes governing its salinity. According to these methods, and based in part on the Sr2+/Ca2+ ratio, it is demonstrated that the strong salinity of the groundwater is due to interactions between water and the evaporite layers that act as a substratum of this aquifer, as well as saltwater intrusion from the sebkhas. Moreover, the medium- to poor-quality groundwaters are characterized by geochemical interactions: cationic exchange and the precipitation/dissolution process of minerals in the aquifer formations.Editeur Z.W. KundzewiczCitation Ben Alaya, M., Zemni, T., Mamou, A. et Zargouni, F., 2014. Acquisition de salinité et qualité des eaux d’une nappe profonde, Tunisie: approche statistique et géochimique. Hydrological Sciences Journal, 59 (2), 395–419. 相似文献
12.
Abstract Knowledge of the processes that control nitrate migration and its geochemical evolution in the subsurface are fundamental for the regional management of polluted aquifers. In this paper, the spatial distribution and transient variations of nitrate concentrations, associated with manure fertilization, are used to depict hydrogeological dynamics within the sedimentary aquifer system of la Plana de Vic in the Osona region of Spain. Flow systems are identified from geological, hydraulic head, hydrochemical and isotopic data, and by considering nitrate itself as a tracer that indicates how flow paths are modified by human pressures. In this area, nitrates move through fractured aquitards in flows induced by groundwater pumping. Moreover, the lack of casing in the boreholes permits a mixing of groundwater from distinct layers inside the wells, which negates any benefits from the low-nitrate groundwater found in the deepest aquifer layers. Therefore, impacts on groundwater quality are related to intensive manure fertilization as well as to inadequate well construction and exploitation strategies. Citation Menció, A., Mas-Pla, J., Otero, N. & Soler, A. (2011) Nitrate as a tracer of groundwater flow in a fractured multilayered aquifer. Hydrol. Sci. J. 56(1), 108–122. 相似文献
13.
Abstract This paper develops a new analytical solution for the aquifer system, which comprises an unconfined aquifer on the top, a semi-confined aquifer at the bottom and an aquitard between them. This new solution is derived from the Boussinesq equation for the unconfined aquifer and one-dimensional leaky confined flow equation for the lower aquifer using the perturbation method, considering the water table over-height at the remote boundary. The head fluctuation predicted from this solution is generally greater than the one solved from the linearized Boussinesq equation when the ratio of the tidal amplitude to the thickness of unconfined aquifer is large. It is found that both submarine groundwater discharges from upper and lower aquifers increase with tidal amplitude–aquifer thickness ratio and may be underestimated if the discharge is calculated based on the average head fluctuation. The effects of the aquifer parameters and linearization of the Boussinesq equation on the normalized head fluctuation are also investigated. Editor D. Koutsoyiannis; Associate editor J. Simunek Citation Chuang, M.-H., Mahdi, A.-A. and Yeh, H.-D., 2012. A perturbation solution for head fluctuations in a coastal leaky aquifer system considering water table over-height. Hydrological Sciences Journal, 57 (1), 162–172. 相似文献
14.
《水文科学杂志》2013,58(6):1241-1252
Abstract Major ion geochemistry, and water molecule isotopes (18O, 2H) and radiogenic carbon (14C) of dissolved inorganic carbon (DIC) were used to investigate the hydrodynamic functioning of the multilayer aquifer system in the Moulares-Redayef basin, southern Tunisia. The groundwater of different aquifer levels is characterized by sulphate to calcium sulphate water type. The major geochemical processes in the aquifer system are evaporite mineral dissolution and mixing. The isotopic study allows two groundwater types to be identified: an old palaeoclimatic groundwater, marked by low 14C activity and relatively depleted stable isotope (18O and 2H) content characterizes the shallowest aquifers of the Plio-Quaternary and Miocene formations; however, a recent groundwater, distinguished by relatively high 14C activity and slightly enriched 18O and 2H content, characterizes the deep Upper Cretaceous artesian aquifer. In addition to these two water groups, other groundwaters are identified, indicating a mixing effect. 相似文献
15.
《水文科学杂志》2013,58(3):543-555
Abstract The contact between freshwater and seawater in coastal aquifers is studied using a relatively simple model for homogeneous aquifers. However, for real aquifers it is not so simple. The desalination plant built to supply water to the city of Almería is situated over the aquifer in the southern part of the River Andarax Delta. Its design capacity is 1100 L s?1, and it is supplied from boreholes pumping water from beneath the freshwater—seawater contact in this aquifer. Well logs kept over a period of two years have allowed us to accurately define the interface geometry of the freshwater—seawater contact. Lithological data collected from 31 boreholes have also indicated the existence of strata with low hydraulic conductivity, within others of high conductivity. During a simultaneous pumping test of six wells with 690 L s?1 total discharge, electrical conductivity measurements showed the influx of seawater 6–10 m below sea level and a drawdown of the interface in the piezometers closest to the pumping wells. 相似文献
16.
《水文科学杂志》2013,58(4):844-856
Abstract The feasibility of aquifer storage and recovery (ASR) was tested in a deep aquifer near Koksijde, Belgium. To achieve this, oxic drinking water was injected into a deep aquifer (the Tienen Formation) that contains anoxic brackish water. The hydraulic properties of the aquifer were determined using a step-drawdown test. Chemical processes caused by the injection of the water were studied by two push—pull tests. The step-drawdown test was interpreted by means of an inverse numerical model, resulting in a transmissivity of 3.38 m2/d and a well loss coefficient of 0.00038 d2/m5. The push—pull tests identified mixing between the injection and pristine waters, and cation exchange, as the major processes determining the quality of the recovered water. Mobilization of DOC, aerobic respiration, denitrification and mobilization of phosphate were also observed. 相似文献
17.
Abstract Despite the Sahelian drought of the 1970s–1990s, the unconfined aquifer in southwest Niger exhibits a multidecadal increase in groundwater reserves. Recent changes in land surface conditions have enhanced runoff and thus indirect groundwater recharge below endorheic ponds. This paper presents a model-based investigation of surface runoff and groundwater recharge at mesoscale (～5000 km2). A new lumped-conceptual runoff model applicable to the large number of ungauged endorheic catchments is specially developed, derived from an existing fine-scale, physically-based hydrologic model. Runoff simulated for sites identified as groundwater recharge sources are used to derive recharge forcing for a Modflow-based model of the aquifer. The rising water table trend and its spatial distribution over the period 1992–2003 are generally well simulated, albeit smoothed year-to-year dynamics. Comparison with alternative methods of recharge estimation suggests, however, that there may presently exist more recharging sites and/or contributing surfaces than those considered so far. Citation Massuel, S., Cappelaere, B., Favreau, G., Leduc, C., Lebel, T. & Vischel, T. (2011) Integrated surface water–groundwater modelling in the context of increasing water reserves of a regional Sahelian aquifer. Hydrol. Sci. J. 56(7), 1242–1264. 相似文献
18.
C.L. Djebebe-Ndjiguim A. Denis E. Foto G. Moloto-a-Kenguemba H. Celle-Jeanton 《水文科学杂志》2013,58(8):1760-1778
AbstractThis paper presents the results of a survey carried out in 2010 aimed at evaluating the type and quality of the groundwater resources of the Bangui region of the Central African Republic. This work is the first step towards the development of groundwater resources in the Central African Republic in order to find alternatives to direct pumping from the Ubangi River and provide the population of the suburbs with a safer drinking water supply from deep boreholes. By combining both geological and hydrogeochemical approaches, it appears that the geology of Bangui is favourable to the development of a secure and sustainable water supply from groundwater provided that the conditions of exploitation would be constrained by the local authorities. The deep Precambrian carbonate aquifers, known as the Bimbo and Fatima formations, are identified as target resources in view of the relatively good quality of their water from the chemical point of view, and the semi-confined structure of the aquifers that prevents the mixing with shallow aquifers that are already strongly affected by domestic and industrial pollution. The main difficulty in terms of exploitation is to appreciate the depth of the resource and the more or less fractured/palaeo-karstified type of the porosity.Editor Z.W. KundzewiczCitation Djebebe-Ndjiguim, C.L., Huneau, F., Denis, A., Foto, E., Moloto-a-Kenguemba, G., Celle-Jeanton, H., Garel, E., Jaunat, J., Mabingui, J., and Le Coustumer, P., 2013. Characterization of the aquifers of the Bangui urban area, Central African Republic, as an alternative drinking water supply resource. Hydrological Sciences Journal, 58 (8), 1760–1778. 相似文献
19.
AbstractNew and previously published data sets including stable and radiogenic isotope measurements (18O, 2H, 3H, 13C and 14C) were used to investigate, conceptualize and compare groundwater hydrodynamics within three major multilayer aquifer systems located in central and southern Tunisia. It has been demonstrated that the investigated aquifer systems contain modern and palaeoclimatic waters. Modern groundwaters, which refer to contemporaneous and post-nuclear recharge waters, are characterized by enriched stable isotope contents, high carbon-14 activities and high to moderate tritium concentration. While palaeoclimatic groundwaters, which refer to Late Pleistocene and Early Holocene recharge waters, are distinguished by their depleted stable isotope contents, low carbon-14 activities and insignificant tritium concentrations. Established conceptual models have elucidated the groundwater hydrodynamics within the studied aquifer systems. They show that groundwater mixing occurs between end-members from the shallow and deep aquifers that migrate by downward and upward leakage towards the intermediate aquifer.Editor D. Koutsoyiannis; Associate editor S. FayeCitation Dassi, L. and Tarki, M., 2014. Isotopic tracing for conceptual models of groundwater hydrodynamics in multilayer aquifer systems of central and southern Tunisia. Hydrological Sciences Journal, 59 (6), 1240–1258. http://dx.doi.org/10.1080/02626667.2014.892206 相似文献
20.
The Kaluvelly watershed is a coastal area (Tamil Nadu, India) where water abstraction has resulted in a dramatic fall in the level of the water table and a piezometric depression in the most exploited aquifer, the Vanur aquifer. In addition, intensification/mechanization of agriculture may have affected the quality of recharge water. An initial hydrodynamic study showed that the Vanur aquifer is highly vulnerable to salinization due to potential seawater intrusion, and our aim was to determine the source of salinity recorded in the groundwater of this multilayered aquifer. Our approach involved the use of existing boreholes and of a moderate number of samples, with the aim of developing appropriate water resource management techniques. Major element, 18O/16O, 2H/1H and 87Sr/86Sr, ratios were measured in rainwater, surface water and groundwater collected during five sampling campaigns over a 2‐year period. Geochemical data indicate that the Vanur aquifer is recharged and that small mixings between aquifers fluctuate according to monsoon intensity. There was no evidence of seawater intrusion. The range of recorded salinity originated mainly from water–rock interaction but a disconnection of some deeper parts of the aquifer was apparent. Strontium isotopic ratios in the recharge area suggest an anthropogenic influence, possibly related to fertilizer use. A high SO4/Cl ratio was observed in the aquifer; in the deeper parts, the influence of a formation containing lignite is hypothesized, whereas near the surface, sulphate may partly originate from fertilizer use and fossil fuel combustion. Water isotopic data suggest that the origin of precipitation in this region has been unchanged for several hundreds or thousands of years. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献