Factors controlling the chemical evolution of travertine‐depositing rivers of the Barkly karst,northern Australia     

Russell N. Drysdale  Mark P. Taylor  Christian Ihlenfeld 《水文研究》2002,16(15):2941-2962

Groundwaters feeding travertine‐depositing rivers of the northeastern segment of the Barkly karst (NW Queensland, Australia) are of comparable chemical composition, allowing a detailed investigation of how the rate of downstream chemical evolution varies from river to river. The discharge, pH, temperature, conductivity and major‐ion concentrations of five rivers were determined by standard field and laboratory techniques. The results show that each river experiences similar patterns of downstream chemical evolution, with CO₂ outgassing driving the waters to high levels of calcite supersaturation, which in turn leads to widespread calcium carbonate deposition. However, the rate at which the waters evolve, measured as the loss of CaCO₃ per kilometre, varies from river to river, and depends primarily upon discharge at the time of sampling and stream gradient. For example, Louie Creek (Q = 0·11 m³ s^?1) and Carl Creek (Q = 0·50 m³ s^?1) have identical stream gradients, but the loss of CaCO₃ per kilometre for Louie Creek is twice that of Carl Creek. The Gregory River (Q = 3·07 m³ s^?1), O'Shanassy River (Q = 0·57 m³ s^?1) and Lawn Hill Creek (Q = 0·72 m³ s^?1) have very similar gradients, but the rate of hydrochemical evolution of the Gregory River is significantly less than either of the other two systems. The results have major implications for travertine deposition: the stream reach required for waters to evolve to critical levels of calcite supersaturation will, all others things being equal, increase with increasing discharge, and the length of reach over which travertine is deposited will also increase with increasing discharge. This implies that fossil travertine deposits preserved well downstream of modern deposition limits are likely to have been formed under higher discharge regimes. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Impact of urbanization on the ecology of Mukuvisi River,Harare, Zimbabwe     

《Physics and Chemistry of the Earth》2016

The main objective in this study was to compare the physico-chemical characteristics and biota of a river (Mukuvisi) passing through an urban area to that of a non-urbanised river (Gwebi). Five sites in the Mukuvisi River and five sites in the Gwebi River were sampled for water physico-chemical parameters (pH, conductivity, DO, BOD, TDS, ammonia, Cl, SO₄²⁻, PO₄²⁻, NO₃³⁻, F⁻, Pb, Cu, Fe, Mn, Zn and Cr) once every month between August, 2012–August, 2013. Cluster analysis based on the physico-chemical parameters grouped the sites into two groups. Mukuvisi River sites formed their own grouping except for one site which was grouped with Gwebi River sites. Principal Component Analysis (PCA) was used to extract the physico-chemical parameters that account for most variations in water quality in the Mukuvisi and Gwebi Rivers. PCA identified sulphate, chloride, fluoride, iron, manganese and zinc as the major factors contributing to the variability of Mukuvisi River water quality. In the Gwebi river, sulphate, nitrate, fluoride and copper accounted for most of the variation in water quality. Canonical Correspondence Analysis (CCA) was used to explore the relationship between physico-chemical parameters and macroinvertebrate communities. CCA plots in both Mukuvisi and Gwebi Rivers showed significant relationships between macroinvertebrate communities and water quality variables. Phosphate, ammonia and nitrates were correlated with Chironomidae and Simulidae. Gwebi River had higher (P < 0.05, ANOVA) macroinvertebrates and fish diversity than Mukuvisi River. Clarias gariepinus from the Mukuvisi River had high liver histological lesions and low AChE activity and this led to lower growth rates in this river.  相似文献   

Effect of an acid mine drainage effluent on phytoplankton biomass and primary production at Britannia Beach, Howe Sound, British Columbia     

Levings CD  Varela DE  Mehlenbacher NM  Barry KL  Piercey GE  Guo M  Harrison PJ 《Marine pollution bulletin》2005,50(12):158-1594

We investigated the effect of acid mine drainage (AMD) from an abandoned copper mine at Britannia Beach (Howe Sound, BC, Canada) on primary productivity and chlorophyll a levels in the receiving waters of Howe Sound before, during, and after freshet from the Squamish River. Elevated concentrations of copper (integrated average through the water column >0.050 mg l⁻¹) in nearshore waters indicated that under some conditions a small gyre near the mouth of Britannia Creek may have retained the AMD from Britannia Creek and from a 30-m deep water outfall close to shore. Regression and correlation analyses indicated that copper negatively affected primary productivity during April (pre-freshet) and November (post-freshet). Negative effects of copper on primary productivity were not supported statistically for July (freshet), possibly because of additional effects such as turbidity from the Squamish River. Depth-integrated average and surface chlorophyll a were correlated to copper concentrations in April. During this short study we demonstrated that copper concentrations from the AMD discharge can negatively affect both primary productivity and the standing stock of primary producers in Howe Sound.  相似文献   

Evaluating channel response to an extreme sedimentation event in the context of historical range of variability: Upper Colorado River,USA   总被引：1，自引：0，他引：1  

Sara L. Rathburn  Zan K. Rubin  Ellen E. Wohl 《地球表面变化过程与地形》2013,38(4):391-406

In May 2003, a breach in a large irrigation ditch within Rocky Mountain National Park (RMNP) initiated a debris flow that entered Lulu Creek and the Colorado River, where 36 000 m³ of sediment substantially altered channel forms and processes. We present a proof of concept to understand whether the 2003 disturbance is within the historical range of variability (HRV), and whether the recovery potential of the system is sufficient to adapt to the disturbance. Flow and sediment regimes, and channel morphology and stability were monitored on Lulu Creek and the Colorado River from 2004 to 2011. Dominant channel response following the debris flow within Lulu Creek included step development, bed armoring, and channel widening. Step height‐to‐length ratios (H/L) for three reaches on Lulu Creek are outside the HRV of reference channels, with one reach approaching reference conditions. Erosion of approximately 23% of the debris fan volume occurred as a result of the long duration 2011 peak flow. Sediment within the Lulu Creek fan will persist for ~30–190 years, assuming current maximum and mean removal rates. Planform changes on the Colorado River since the debris flow include an increase in single‐thread geometries, with braided reaches where bar deposition occurred. Bedload transport and grain‐size analysis of bedload indicate translational spreading of a sand wave front with a dispersive component in steeper reaches. Lulu Creek is returning to a condition of natural variability, but the Colorado River is outside the HRV expected for steep‐gradient, pool‐riffle channels. Applying HRV to a situation where management questions require a longer term perspective, and pre‐disturbance baseline data are limited, is a useful approach. The HRV analysis facilitates a better understanding of site variability and delineates the range of possibilities of channel form and process to achieve management goals. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Determination of background concentrations of hydrochemical parameters and water quality assessment in the Akhuryan River Basin (Armenia)     

《Physics and Chemistry of the Earth》2016

The determination of background values of hydrochemical parameters, to distinguish between natural concentration and anthropogenically-influenced concentrations, is highly relevant. In presented study, to estimate the background values of hydrochemical parameters in Akhuryan River Basin, log-normal probability functions on the hydrochemical parameters concentrations was applied. The study is carried out on the basis of hydrochemical data of surface water quality monitoring for the period of 2010–2013. This study highlights the usefulness of application of site-specific background concentrations for the evaluation, interpretation of surface water quality and for determination of pollution sources.  相似文献   

西藏尼洋河水环境特征多元统计分析   总被引：2，自引：1，他引：1  

刘海平  钟国辉  叶少文  张良松  张惠娟  范丽卿  巴桑  李钟杰 《湖泊科学》2015,27(6):1187-1196

自2008年11月到2009年10月按照月份监测西藏林芝地区尼洋河水环境特征.结果显示,根据Pearson相关性矩阵,可将尼洋河26项理化指标分为3大类,分别是低度相关性理化指标、中度相关性理化指标和高度相关性理化因子.析因分析显示,可将26项理化指标分为4大类,第1类为尼洋河水体常规的理化指标、第2类为尼洋河水体硬度相关指标、第3类为海拔及第4类为影响水生生物生长的水质理化指标.PCA分析发现,平水期、丰水期以及枯水期水环境特征明显不同,以上3期各自聚为一类,而尼洋河沿程方面,水环境特征则不存在差异.构建了尼洋河海拔、底层水温与相关理化因子的一元回归方程.建议加强对尼洋河水环境的监测工作,积极推进尼洋河水域生态环境的可持续发展进程.  相似文献   

The relationship of Irgarol and its major metabolite to resident phytoplankton communities in a Maryland marina, river and reference area     

Lenwood W. Hall Jr.  Ronald D. Anderson  Richard Balcomb 《Marine pollution bulletin》2009,58(6):803-3847

The objectives of this study were to: (1) measure water column concentrations of Irgarol 1051 and its major metabolite GS26575 annually (2004-2006) during mid-June and mid-August at 14 sites in a study area comprised of three sub-regions chosen to reflect a gradient in Irgarol exposure (Port Annapolis marina, Severn River and Severn River reference area); (2) use a probabilistic approach to determine ecological risk of Irgarol and its major metabolite in the study area by comparing the distribution of exposure data with toxicity-effects endpoints; and (3) measure both functional and structural resident phytoplankton parameters concurrently with Irgarol and metabolite concentrations to assess relationships and determine ecological risk at six selected sites in the three study areas described above. The three-year summer mean Irgarol concentrations by site clearly showed a gradient in concentrations with greater values in Back Creek (400-500 ng/L range), lower values in the Severn River sites near the confluence with Back Creek (generally values less than 100 ng/L) and still lower values (<10 ng/L) at the Severn River reference sites at the confluence with Chesapeake Bay. A similar spatial trend, but with much lower concentrations, was also reported for GS26575. The probability of exceeding the Irgarol plant 10th centile of 193 ng/L and the microcosm NOEC (323 ng/L) suggested high ecological risk from Irgarol exposure at Port Annapolis marina sites but much lower risk at the other sites. There were no statistically significant differences among the three site types (marina, river and reference) with all years combined or among years within a site type for the following functional and structural phytoplankton endpoints: algal biomass, gross photosynthesis, biomass normalized photosynthesis, chlorophyll a, chlorophyll a normalized photosynthesis and taxa richness. Therefore, based on the above results, Irgarol adverse effects predicted from the plant 10th centile and the microcosm NOEC in the high Irgarol exposure area (Back Creek/Port Annapolis marina) were not confirmed with the actual field data for the receptor species (phytoplankton). These results also highlight the importance of unconfined field studies with a chemical gradient in providing valuable information regarding the responses of resident phytoplankton to herbicides.  相似文献   

Floodplain storage of mine tailings in the belle fourche river system: A sediment budget approach     

Donna C. Marron 《地球表面变化过程与地形》1992,17(7):675-685

Arsenic-contaminated mine tailings that were discharged into Whitewood Creek at Lead, South Dakota, from 1876 to 1978, were deposited along the floodplains of Whitewood Creek and the Belle Fourche River. The resulting arsenic-contaminated floodplain deposit consists mostly of overbank sediments and filled abandoned meanders along White-wood Creek, and overbank and point-bar sediments along the Belle Fourche River. Arsenic concentrations of the contaminated sediments indicate the degree of dilution of mine tailings by uncontaminated alluvium. About 13 per cent of the 110 × 10⁶ Mg of mine tailings that were discharged at Lead were deposited along the Whitewood Creek floodplain. Deposition of mine tailings near the mouth of Whitewood Creek was augmented by an engineered structure. About 29 per cent of the mine tailings delivered by Whitewood Creek were deposited along the Belle Fourche River floodplain. About 60 per cent of that sediment is contained in overbank deposits. Deposition along a segment of the Belle Fourche River was augmented by rapid channel migration. The proportions of contaminated sediment stored along Whitewood Creek and the Belle Fourche River are consistent with sediment storage along the floodplains of perennial streams in other, similar sized watersheds.  相似文献   

Survivorship and growth of Fucus gardneri after transplant to an acid mine drainage-polluted area     

Marsden AD  DeWreede RE  Levings CD 《Marine pollution bulletin》2003,46(1):65-73

Acid mine drainage (AMD) from an abandoned copper mine at Britannia Beach, British Columbia, Canada, enters the marine environment through Britannia Creek. The surrounding intertidal zone is devoid of rockweed, Fucus gardneri Silva, a seaweed that dominates nearby shores. Rockweed plants were transplanted to the intertidal zone near Britannia Creek and monitored for changes in percent cover, survivorship, growth rate and Cu content. Autumn and winter transplants to within 100 m of Britannia Creek resulted in negative growth rates and high mortality within 57 days of exposure to AMD, with Cu levels in rockweed surpassing 2,300 ppm in dry tissue. Summer transplants to sites 300-700 m from Britannia Creek showed no consistent differences between AMD-exposed rockweed and control plants, possibly because the plants were stressed by desiccation. The results are consistent with ecological effects observed in other studies, and provide strong evidence for the role of AMD in excluding rockweed from the shores near Britannia Creek.  相似文献   

Spatial–temporal variability in water quality and macro-invertebrate assemblages in the Upper Mara River basin,Kenya     

《Physics and Chemistry of the Earth》2014

Tropical rivers display profound temporal and spatial heterogeneity in terms of environmental conditions. This aspect needs to be considered when designing a monitoring program for water quality in rivers. Therefore, the physico-chemical composition and the nutrient loading of the Upper Mara River and its two main tributaries, the Amala and Nyangores were monitored. Initial daily, and later a weekly monitoring schedule for 4 months spanning through the wet and dry seasons was adopted. Benthic macro-invertebrates were also collected during the initial sampling to be used as indicators of water quality. The aim of the current study was to investigate the physico-chemical status and biological integrity of the Upper Mara River basin. This was achieved by examining trends in nutrient concentrations and analyzing the structure, diversity and abundance of benthic macro-invertebrates in relation to varying land use patterns. Sampling sites were selected based on catchment land use and the level of human disturbance, and using historical records of previous water quality studies. River water pH, dissolved oxygen, electrical conductivity (EC), temperature, and turbidity were determined in situ. All investigated parameters except iron and manganese had concentration values within allowable limits according to Kenyan and international standards for drinking water. The Amala tributary is more mineralized and also shows higher levels of pH and EC than water from the Nyangores tributary. The latter, however, has a higher variability in both the total phosphorus (TP) and total nitrogen (TN) concentrations. The variability in TP and TN concentrations increases downstream for both tributaries and is more pronounced for TN than for TP. Macro-invertebrate assemblages responded to the changes in land use and water quality in terms of community composition and diversity. The study recommends detailed continuous monitoring of the water quality at shorter time intervals and to identify key macro-invertebrate taxa that can be used to monitor changes of the water quality in rivers of the Mara basin as a result of anthropogenic changes.  相似文献   

Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton,Colorado     

Laurence E. Schemel  Marisa H. Cox  Robert L. Runkel  Briant A. Kimball 《水文研究》2006,20(13):2727-2743

The acidic discharge from Cement Creek, containing elevated concentrations of dissolved metals and sulphate, mixed with the circumneutral‐pH Animas River over a several hundred metre reach (mixing zone) near Silverton, CO, during this study. Differences in concentrations of Ca, Mg, Si, Sr, and SO₄^2? between the creek and the river were sufficiently large for these analytes to be used as natural tracers in the mixing zone. In addition, a sodium chloride (NaCl) tracer was injected into Cement Creek, which provided a Cl^? ‘reference’ tracer in the mixing zone. Conservative transport of the dissolved metals and sulphate through the mixing zone was verified by mass balances and by linear mixing plots relative to the injected reference tracer. At each of seven sites in the mixing zone, five samples were collected at evenly spaced increments of the observed across‐channel gradients, as determined by specific conductance. This created sets of samples that adequately covered the ranges of mixtures (mixing ratios, in terms of the fraction of Animas River water, %AR). Concentratis measured in each mixing zone sample and in the upstream Animas River and Cement Creek were used to compute %AR for the reference and natural tracers. Values of %AR from natural tracers generally showed good agreement with values from the reference tracer, but variability in discharge and end‐member concentrations and analytical errors contributed to unexpected outlier values for both injected and natural tracers. The median value (MV) %AR (calculated from all of the tracers) reduced scatter in the mixing plots for the dissolved metals, indicating that the MV estimate reduced the effects of various potential errors that could affect any tracer. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Geochemical evidence for peat bog contribution to the streamflow generation process: case study of the Vltava River headwaters,Czech Republic     

Jan Kocum  Filip Oulehle  Bohumír Janský  František Bůzek  Jakub Hruška  Lukáš Vlček 《水文科学杂志》2013,58(14):2579-2589

ABSTRACT

A geochemical approach using stable oxygen isotopes was used to understand streamflow generation processes in the highly peaty catchment of the Rokytka Brook in the headwaters of the Vltava River, Czech Republic. The contribution of water from peat bog areas to the total surface runoff was assessed using a hydrological time series, as well as geochemical, hydrochemical and isotope-hydrological approaches for unit hydrogram separation by means of anion deficiency. Using data from the hydrological year 2008, the role of an existing peat bog in the runoff formation dynamics of the Rokytka Brook catchment was determined, and the hydrological cycle was described and assessed using stable ¹⁸O/¹⁶O isotopes. The research findings strongly support the fact that peatland areas within the studied catchment do not significantly communicate hydraulically with surface streams, and their hydrological function in this region is insignificant.