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1.
Abstract The variation of sulphur isotopic composition during the 2000 eruption of the Miyakejima Volcano was examined in order to monitor the temporal change of the volcanic activity. The δ34 S values of water-soluble sulphate leached from volcanic ash effused during intermittent eruptions from July to September 2005 range from +5 to +11‰ with a fluctuation of ca 3‰ within a single eruption. The δ34 S value of sulphuric acid mist collected with 'Cu-metal trap' placed on the flank of the volcano from December 2000 to January 2001 is +6.2‰. These sulphur isotopic compositions of sulphate, which were isotopically equilibrated in the subvolcanic hydrothermal system, indicate that the temperature of the hydrothermal system beneath the caldera increased after the period of intermittent phreatic and phreatomagmatic eruptions. Then, the δ34 S value of sulphuric acid trapped from January to March 2001 was +9.0‰ and the δ34 S value of water-soluble sulphate on volcanic ash emitted with minor eruption in May 2001 was +11.0‰, suggesting a decrease in temperature of the subvolcanic hydrothermal system. 相似文献
2.
Abstract We collected free-gas and in situ fluid samples up to a depth of 200.6 m from the Sagara oil field, central Japan (34°44'N, 138°15'E), during the Sagara Drilling Program (SDP) and measured the concentrations and stable carbon isotopic compositions of CH4 and C2 H6 in the samples. A combination of the CH4 /C2 H6 ratios with the carbon isotope ratios of methane indicates that the hydrocarbon gases are predominantly of thermogenic origin at all depths. The isotope signature of hydrocarbon gases of δ13 < δ13 suggests that these gases in the Sagara oil field are not generated by polymerization, but by the decomposition of organic materials. 相似文献
3.
Recovery of hydrocarbons commonly is associated with coproduction of water. This water may be put to beneficial use or may be reinjected into subsurface aquifers. In either case, it would be helpful to establish a fingerprint for that coproduced water so that it may be tracked following discharge on the surface or reintroduction to geologic reservoirs. This study explores the potential of using δ13 C of dissolved inorganic carbon (DIC) of coalbed natural gas (CBNG)–coproduced water as a fingerprint of its origin and to trace its fate once it is disposed on the surface. Our initial results for water samples coproduced with CBNG from the Powder River Basin show that this water has strongly positive δ13 CDIC (12‰ to 22‰) that is readily distinguished from the negative δ13 C of most surface and ground water (−8‰ to −11‰). Furthermore, the DIC concentrations in coproduced water samples are also high (more than 100 mg C/L) compared to the 20 to 50 mg C/L in ambient surface and ground water of the region. The distinctively high δ13 C and DIC concentrations allow us to identify surface and ground water that have incorporated CBNG-coproduced water. Accordingly, we suggest that the δ13 CDIC and DIC concentrations of water can be used for long-term monitoring of infiltration of CBNG-coproduced water into ground water and streams. Our results also show that the δ13 CDIC of CBNG-coproduced water from two different coal zones are distinct leading to the possibility of using δ13 CDIC to distinguish water produced from different coal zones. 相似文献
4.
《Ground Water Monitoring & Remediation》2001,21(2):108-116
Pore water collected from piezometers installed in a thick clay-rich till were used to compare and evaluate four techniques for obtaining δD and δ18 O values in these media. The techniques included mechanical squeezing, centrifugation, azeotropic distillation, and a direct soil-water equilibration technique. Direct CO2 -core equilibration yielded sufficiently accurate and reproducible δ18 O results of pore water in clay-rich tills. In addition, this method eliminated the need for labor-intensive complete extraction of water from the geologic media. Mechanical squeezing and centrifugation produced results similar to direct equilibration. However, both of these methods exhibited a greater degree of variability and were laborious and more time consuming. Small differences in δ18 O values between piezometer water and equilibrated, squeezed, and centhfuged samples suggested that each method collected different fractions of the clay-water reservoir. Although these subtle differences were not conclusive, they did suggest the presence of weakly bound water and highlighted the difference between these three techniques for determining the stable isotopic composition of pore water in clay-rich aquitards. Azeotropic distillation produced a high level of discrepancy in δD andδ18 O results compared to the other methods. Incomplete extraction was considered the most probable cause of this error. The results of this study suggested that direct equilibration is the best method for determining detailed δD and δ18 O values of pore water in clay-rich aquitards. 相似文献
5.
Jonathan D. Karr William J. Showers Thomas H. Hinson 《Ground Water Monitoring & Remediation》2002,22(2):68-75
Nitrate-contaminated ground water beneath and adjacent to an intensive swine ( Sus scrofa domesticus ) production facility in the Middle Coastal Plain of North Carolina was analyzed for δ15 N of nitrate (δ15 N-NO3 ). Results show that the isotopic signal of animal waste nitrogen is readily identifiable and traceable in nitrate in this ground water. The widespread land application of animal wastes from intensive livestock operations constitutes a potential source of nitrogen contamination to natural water throughout large regions of the United States and other countries. The site of the present study has been suspected as a nitrate contamination source to nearby domestic supply wells and has been monitored for several years by government and private water quality investigators through sampling of observation wells, ditches, and streams. δ15 N of nitrate allowed direct identification of animal waste-produced nitrate in 11 of 14 wells sampled in this study, as well as recognition of nitrate contributions from non-animal waste agricultural sources in remaining wells. 相似文献
6.
Keika Horiguchi Sadato Ueki Yuji Sano Naoto Takahata Akira Hasegawa George Igarashi 《Island Arc》2010,19(1):60-70
In order to study the precise geographical distribution of helium isotope ratios in northeastern Japan and compare it with geophysical data, we collected 43 gas and water samples from hot and mineral springs in the region where the ratio had never been reported, and measured the 3 He/4 He and 4 He/20 Ne ratios of these samples. It was found that the 3 He/4 He ratios show clear contrasts between the forearc and the back-arc regions in the Tohoku district in northeastern Japan. In the forearc region, the ratios are smaller than 1 RA (1 RA = 1.4 × 10−6 ; RA means the 3 He/4 He ratio of the atmosphere). On the other hand, those along the volcanic front and in the back-arc region are apparently higher. Moreover, we found a variation in the 3 He/4 He ratios along the volcanic front. In Miyagi Prefecture (38–39°N), the ratios range from 2 to 5 RA . On the other hand, the ratios are less than 1 RA in and around the southern border between Iwate and Akita Prefectures (39–39.5°N). Comparing the distribution of helium isotope ratios to results of recent geophysical studies, we found that the features in geographical distribution of helium isotope ratios are similar to those of seismic low-velocity zone distributions and high Qp−1 distributions in the uppermost mantle. These observations strongly suggest that the helium isotope ratios reflect the distribution of melts in the uppermost mantle and are a useful tool for investigating the origin, behavior, and distribution of deep fluids and melts. 相似文献
7.
Abstract Stratigraphic productivity variations of radiolarians below the Permian-Triassic boundary are examined with Ishiga Diagrams in bedded chert sequences of southwest Japan. The diagrams of two different outcrops, drawn from the thickness variation of chert beds, show common stratigraphic variation, which indicates the diagram is a useful tool for correlation of bedded chert sequence. The common stratigraphic productivity variation is also well correlated to a compiled δ13 C excursion of shallow carbonate sequences. Bedded chert records a dramatic extinction event in a shallow surface zone of oceans below the Permian-Triassic boundary. The Permian-Triassic mass extinction is divided into three intervals based on the Ishiga Diagrams, the stratigraphic lithological variation of bedded chert sequences, and the δ13 C curve. The preceding extinction interval in the late Djulfian stage was not as serious an event and the biosphere soon recovered. The event of the main extinction interval commenced in the Dorashamian stage and caused a serious destruction of the biosphere. An event of the aftermath interval during the Early Triassic caused a delay in the recovery from the main extinction interval. 相似文献
8.
Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. 3 He/4 He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10−6 ), indicating a release of mantle He through the basement. The highest value of 8.2 × 10−6 is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic 4 He, resulted in a low 3 He/4 He ratio of 0.5 × 10−6 . 4 He/20 Ne and 40 Ar/36 Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented. 相似文献
9.
Abstract 40 Ar–39 Ar analysis of phlogopite separated from a plagioclase lherzolite of the Horoman Peridotite Complex, Hokkaido, Japan, has yielded a plateau age of 20.6 ± 0.5 Ma in an environment where the metamorphic fluid was characterized by an almost atmospheric Ar isotopic ratio. The age spectrum is slightly saddle-shaped, implying some incorporation of excess 40 Ar during the formation of the phlogopite at a depth. As the phlogopite has been inferred to have formed in veins and/or interstitials during exhumation of the peridotite body, metasomatic fluids, to which ground- and sea water might have contributed, were probably involved in the formation of phlogopite in the crustal environment. A total 40 Ar–39 Ar age of 129 Ma of a whole rock sample of the plagioclase lherzolite, from which the phlogopite was separated and is representative of the main lithology of the Horoman Peridotite Complex, indicates the occurrence of excess 40 Ar. Hence, the age has no geological meaning. 相似文献
10.
Vertical depth profiles of pore water isotopes (δD and δ18 O) in clay-rich aquitards have been used to show that solute transport is dominated by molecular diffusion, to define the timing of geologic events, and to estimate vertical hydraulic conductivity. The interpretation of the isotopic profiles in these studies was based on pore water samples collected from piezometers installed in nests (typically 4 to 15 piezometers) over depths of 10 to 80 m. Data from piezometer nests generally have poor vertical resolution (meters), raising questions about their capacity to reveal the impact of finer scale heterogeneities such as permeable sand bodies or fractured till zones on solute transport. Here, we used high-resolution (30-cm) depth profiles of δD and δ18 O from two continuously cored boreholes in a till aquitard to provide new insights into the effects of sand bodies on solute transport. High-resolution core-derived profiles indicate that such heterogeneities can cause major deviations from one-dimensional diffusion profiles. Further, comparison of piezometer-measured values with best-fit diffusion trends shows subtle deviations, suggesting the presence of heterogeneities that should not be ignored. High-resolution profiles also more clearly defined the contact between the highly fractured oxidized zone and the underlying unoxidized zone than the piezometers. 相似文献
11.
Masaaki Okuda Hiroomi Nakazato Norio Miyoshi Takeshi Nakagawa Hiroko Okazaki Saneatsu Saito Asahiko Taira 《Island Arc》2006,15(3):338-354
Abstract The 250-m Choshi core (CHOSHI-1), drilled from hemipelagic muds of the Inubo Group, has been physically, geochemically and tephrochronologically analyzed back to 1 Ma. We provide pollen results for the 19–169 m section of the core (400–780 ka) bracketed by the marker tephra Ty1 (equivalent to J4) and the Brunhes–Matuyama paleomagnetic boundary. The results show good agreement with the corresponding oxygen isotope (δ18 O) profile, with high δ18 O intervals dominated by boreal conifers Picea , Abies , Pinus (subgen. Haploxylon ) and Tsuga ( diversifolia ), whereas low δ18 O intervals are dominated by temperate conifers Cryptomeria , Taxaceae-Cephalotaxaceae-Cupressaceae and Sciadopitys . In order to confirm pollen-climate relations for the relevant taxa, a modern surface pollen dataset for the Japanese archipelago was consulted. In this analysis, the ratios of Cryptomeria / Picea and temperate/boreal conifers serve as proxies for the 100-kyr glacial/interglacial cycle during the Middle Pleistocene. Distinct signals for marine isotope stages (MIS) 11, 12, 13–15, 16, 17 and 18–19 are recognized in accordance with the tephrochronology and δ18 O of the same core. Application of the criteria to an independent pollen record from Lake Biwa provides an integrated pollen stratigraphy for mid-latitude Japan during the past 800 ky. Some degree of uncertainty remains in the chronology of the MIS13–15 interval, relating to the uncertainty in the eruption age of widespread tephra Ks11. 相似文献
12.
Koji Kameo Makoto Okada Moamen El-Masry Toshio Hisamitsu Saneatsu Saito Hiroomi Nakazato Naohiko Ohkouchi Minoru Ikehara Hisato Yasuda Hiroshi Kitazato Asahiko Taira 《Island Arc》2006,15(3):366-377
Abstract A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ18 O and δ13 C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area. 相似文献
13.
Abstract Isotopic compositions of He, Ne and Ar were measured on Plio–Quaternary alkaline basalts of Marib–Sirwah and Shuqra volcanic fields in Yemen, south-western Arabian Peninsula. Very high 3 He/4 He isotope ratios were found in olivine phenocrysts of some Quaternary alkaline basalts in both volcanic fields, located on the margin of the dispersed Afar mantle plume, compared with the Afar–Ethiopian province in the center of the mantle plume. This suggests that the Afar mantle plume source may consist of common component (C or focal zone (FOZO)) with variable primordial 3 He/4 He ratio rather than high μ mantle (HIMU) component. The three component mixing C as the Afar mantle plume, depleted mantle (DM) as upper mantle and lithospheric mantle with a hybrid enriched mantle I–II (EM I–EM II) characteristics may be adequate to explain He–Sr–Nd–Pb isotope variation for the Afar–Arabian Cenozoic volcanics. The occurrence of high 3 He/4 He ratios in the Marib–Sirwah volcanic field appears to show that the primitive basaltic magma, derived from the margin of the dispersed trous-like Afar mantle plume during 15–0 Ma, was not by contamination of lithospheric and upper mantle materials in comparison with that from the center of the Afar mantle plume as a result of relatively low thermal anomaly. 相似文献
14.
Abstract Geothermal waters in the Niigata Sedimentary Basin, central Japan, are divided into four groups based on their chemical composition (i.e. Na-SO4 -type, Na-SO4 -Cl-type, Na-Cl-type and Na-Cl-HCO3 -type). The Na-SO4 -type geothermal water forms as a consequence of water–rock interaction and generally occurs in the outer part of the basin. The Na-Cl-type geothermal water is further subdivided into the original Na-Cl-type geopressured thermal water and the mixed Na-Cl-type geothermal water, in terms of its geochemical and isotopic composition. The original Na-Cl-type geopressured thermal water originates from a geopressured hydrothermal system containing the altered fossil formation waters that are sealed at depth. It moves up to the upper part of the depositional succession or the ground, and generally does not mix with groundwater that is of meteoric origin. This type of water is cooled by heat conduction. The concentration of Cl– in this type of thermal water is very similar to that in seawater. The δD and δ18 O values are approximately constant and independent of temperature. The original Na-Cl-type geopressured thermal water is distributed mainly along anticlinal axes in folded Neogene formations. The mixed Na-Cl-type geothermal water is related to the expulsion activity of the geopressured hydrothermal system and occurs mostly along active faults. It is formed by shallow groundwater of meteoric origin being mixed with geopressured hydrothermal water when the geopressured hydrothermal system was expulsed along active faults by paroxysmal tectonic events. 相似文献
15.
Haixiang Zhang Hecai Niu Hiroaki Sato Xueyuan Yu Qiang Shan Boyou Zhang Jun'ichi Ito Takashi Nagao 《Island Arc》2005,14(1):55-68
Abstract Volcanic rocks consisting of adakite and Nb-enriched basalt are found in the early Devonian Tuoranggekuduke Group in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, northwest China. The geochemical characteristics of the andesitic and dacitic rocks in this area resemble that of adakites. The relatively high Al2 O3 , Na2 O and MgO content and Mg♯ values indicate that the adakites were generated in relation to oceanic slab subduction rather than the partial melting of basaltic crust. A slightly higher SrI and a lower ɛ Nd ( t = 375 Ma) compared to adakites of mid-oceanic ridge basalt (MORB) imply that slab sediments were incorporated into these adakites during slab melting. The Nb-enriched basalt lavas, which are intercalated in adakite lava suite, are silica saturated and are distinguished from the typical arc basalts by their higher Nb and Ti content (high field strength element enrichment). They are derived from the partial melting of the slab melt-metasomatized mantle wedge peridotite. Apparently, positive Sr anomalies and a slightly higher heavy rare earth element content in these adakites compared to their Cenozoic counterparts indicate that the geothermal gradient in the Paleo-Asian Oceanic subduction zone and the depth of the Paleo-Asian Oceanic slab melting are between those of their Archean and Cenozoic counterparts. The distribution of the adakites and Nb-enriched basalts in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, indicates that the Paleo-Asian Oceanic Plate subducted southward beneath the Kazakhstan-Junggar Plate in the early Devonian period. 相似文献
16.
Abstract Thick Middle (–Upper) Miocene turbiditic deposits filled very deep and narrow foredeep basins formed in the western margin of the Hidaka collision zone in central Hokkaido. Cobble- to boulder-sized clasts of eight monzogranites and a single granodiorite in the Kawabata Formation in the Yubari Mountains area yielded biotite K–Ar ages of 44.4 ± 1.0 to 45.4 ± 1.0 Ma and 42.8 ± 1.1 Ma, respectively. Major elemental compositions of the clasts all fall in the field of S-type granite on an NK/A (Na2 O + K2 O/Al2 O3 in molecule) versus A/CNK (Al2 O3 /CaO + Na2 O + K2 O in molecule) diagram, verifying their peraluminous granite character (aluminium saturation index (ASI): 1.12–1.19). These geochronological and petrographical features indicate that the granitoid clasts in the Kawabata Formation correlate with Eocene granitic plutons in the northeastern Hidaka Belt, specifically the Uttsudake (43 Ma) and Monbetsu (42 Ma) plutons. Foredeep basins are flexural depressions developed at the frontal side of thickened thrust wedges. The results presented here suggest that deposition of the Middle Miocene turbidites was coeval with rapid westward up-thrusting and exhumation of the Hidaka Belt. This early mountain building may have occurred in response to thrusting in the Tertiary fold-and-thrust system of central Hokkaido. 相似文献
17.
by James E. Landmeyer Paul M. Bradley Donald A. Trego Kevin G. Hale Joseph E. Haas II 《Ground water》2010,48(1):30-41
Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- 14 C-MTBE and U-14 C-TBA to 14 CO2 and the novel biodegradation of U- 14 C-TAME to 14 CO2 under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation. 相似文献
18.
Pumice samples from Fukutoku-oka-no-ba in the Izu–Bonin – Mariana (IBM) arc were analysed for 40 trace elements and Sr, Nd, and Pb isotopic compositions. These samples are shoshonites (59.4–61.8 wt% SiO2 ), characterized by high contents of K2 O (3.74–4.64 wt%), Ba (1274–1540 p.p.m.), Rb (91–105 p.p.m.), and light rare earth elements. The characteristics of alkali-element enrichment are similar to those of other parts of the Alkalic Volcano Province (AVP) in the northern Mariana and southernmost Volcano arcs. Sr (87 Sr/86 Sr = 0.7036–0.7038) and Pb isotopic compositions (206 Pb/204 Pb = 19.08–19.11, 207 Pb/204 Pb = 15.62–15.63, 208 Pb/204 Pb = 38.85–38.91) of Fukutoku-oka-no-ba pumice are relatively radiogenic, whereas Nd is unradiogenic (143 Nd/144 Nd = 0.51283–0.51286). Fukutoku-oka-no-ba is isotopically distinct from Iwo Jima and is similar to the Hiyoshi Volcanic Complex, suggesting that Fukutoku-oka-no-ba might have a magma source similar to that of the Hiyoshi volcanic complex. Plots of Pb and Nd isotopes for AVP lavas trend toward the fields of ocean island basalt (OIB) source and pelagic sediments, which are possible sources of AVP enrichments. 相似文献
19.
郯庐断裂带是中国东部最大的一个活动构造带,其内部结构非常复杂,不同区段表现出不同特征的构造样式.本文采用浅层地震反射波成像技术对郯庐断裂带宿迁段的近地表结构进行了高分辨率成像,利用该区已有的深地震反射剖面数据,采用初至波层析成像方法获得了郯庐断裂带的浅层P波速度结构.结果表明,郯庐断裂带宿迁段是一个由多条断裂以及凹陷和隆起构成的复杂构造带,且新生代地层厚度和地震波速分布明显受到断裂的影响与控制.郯庐断裂带的东、西两侧为基底隆起区,近地表速度结构呈现为明显的高速特征,新生代地层厚度小于200m.郯庐断裂带总体显示为低速凹陷结构,新生代地层厚度在300～600m之间变化,最厚处位于宿迁市的陵城镇附近.郯庐断裂带宿迁段主要由5条断裂构成,从这些断裂的上断点埋深和第四纪活动特征来看,郯庐断裂带的东边界断裂F_1和西边界断裂F_4的活动性相对较弱,为第四纪早期活动断裂.断裂F_2和F_3控制了郯庐断裂带内部的新生代凹陷,两者的活动时代分别为中更新世和晚更新世.安丘—莒县断裂F_5位于断裂F_1和F_2之间,由2条相向而倾的分支断层F_5和F_(5-1)构成,其活动时代分别为全新世和晚更新世.研究结果为进一步认识郯庐断裂带宿迁段的近地表特征及其活动性提供了新证据. 相似文献
20.
Abstract The Lower Sorachi Group of the Sorachi–Yezo Belt in central Hokkaido, Japan is a peculiar accretionary complex characterized by numerous occurrences of greenstones (metabasalts and diabases), which are mostly composed of aphyric basalts. Clinopyroxene-rich phenocryst assemblage in phyric basalts is different from olivine–plagioclase assemblage in mid-oceanic ridge basalts (MORB). The greenstones are geochemically uniform, and show a lower-Ti trend than MORB in an FeO*/MgO-TiO2 diagram, mostly plotting on the island arc tholeiite (IAT) field in a TiO2 −10MnO−10P2 O5 diagram. In a MORB-normalized spider diagram, the greenstones show a flat pattern from P to Y, which are lower than those of normal mid-oceanic ridge basalt (N-MORB). These indicate that the greenstones were derived by a higher degree of partial melting from a depleted mantle similar to a N-MORB source, and experienced olivine–clinopyroxene fractional crystallization. However, a positive spike of Nb in the spider diagram cannot be explained, and may be attributed to mantle heterogeneity. These characteristics are analogous to those of oceanic plateau basalts (OPB) such as in Ontong Java Plateau, Manihiki Plateau and Nauru Basin, suggesting that the greenstones in the Lower Sorachi Group are of oceanic plateau origin. The present study proposes new field divisions to distinguish OPB from MORB in the conventional FeO*/MgO–TiO2 and TiO2 −10MnO−10P2 O5 diagrams. 相似文献