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1.
胶东罗山金矿床成矿流体来源:蚀变岩型和石英脉型矿石载金黄铁矿稀土与微量元素特征约束 总被引：3，自引：0，他引：3
罗山金矿床是胶东玲珑金矿田最大的金矿床之一,同时发育蚀变岩型矿化和石英脉型矿化。本研究在系统的野外和镜下工作基础上,利用电感耦合等离子体质谱(ICP-MS)技术分析了载金黄铁矿的微量和稀土元素,对比了蚀变岩型和石英脉型矿石载金黄铁矿稀土和微量元素特征,探讨了成矿流体的性质与来源。黄铁矿稀土总含量较低,多呈较明显的"右倾"式稀土配分模式,总体表现出负Eu异常,基本无Ce异常; Hf/Sm、Th/La、Nb/La值均<1,推断成矿流体为富Cl的还原性流体。Co/Ni比值范围在0. 08～3. 77,平均值为1. 09; Co/Ni值以及Co、Ni、Bi、Cu和Zn含量均与变质热液型金矿平均含量相近; Y/Ho比值范围总体在21～32之间,与中国东部大陆地壳Y/Ho比值(20～35)基本重合;结合个别样品的弱正Eu异常以及前人的研究成果,推断成矿流体与变质热液类似,主要来源于古太平洋板块俯冲板片脱水和脱碳作用,且可能有长英质岩浆流体和地壳流体的混入。蚀变岩型和石英脉型矿石内的载金黄铁矿的稀土、微量元素组成没有明显区别,Y/Ho、Nb/Ta和Zr/Hf比值变化范围均很小,表明两类矿石的载金黄铁矿为同一期热液活动作用的产物。 相似文献
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川西呷村超大黑矿型矿床成矿流体烯土元素组成 总被引：20，自引：5，他引：15
本文用ＩＣＰ－ＭＳ首次测定了呷村银多金属黑矿型矿床矿石流体包裹体中的稀土元素含量,研究表明,主成矿期流体稀土元素配分模式均为轻稀土富集,Ｅｕ具明显正异常,通过初步对比,本区主成矿期流体与东太平洋脊、大西洋脊等现代高温酸性地热系统热液具有相似的稀土模式,反映了它们物化条件的相似性;但前者∑ＰＥＥ高于后者,且两者Ｅｕ／Ｅｕ＾＊值不同,经过分析,本区成矿流体Ｅｕ正异常主要为Ｔ、ｐＨ、ｆｏ２控制,另外,围 相似文献
3.
哀牢山金矿带成矿流体稀土元素地球化学 总被引：24，自引：2，他引：22
本项研究测定了矿石、蚀变围岩和相应未蚀变岩石的稀土元素组成。通过对这些地质体稀土元素地球化学特征的对比研究发现,在成矿流体的演化过程中,镇沅和墨江两个金矿床成矿流体的稀土模式具明显的变化,而大坪金矿成矿流体的稀土模式则保持相对不变。因此,大坪金矿的稀土模式（轻稀土高度富集、弱负Ｅｕ异常和较强负Ｃｅ异常）可以代表初始成矿流体的稀土模式。研究表明,具有这种稀土模式的流式,可能是由地幔去气作用产生的地幔 相似文献
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REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration. 相似文献
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云南大平掌铜多金属矿床稀土元素地球化学特征 总被引：1，自引：0，他引：1
滇西大平掌铜多金属矿床具典型的“双层结构”。对上部盆地相的块状硫化物和下部通道相的细脉浸染状硫化物的稀土元素分析表明,前者具正Eu异常的球粒陨石标准化配分模式,后者具负Eu异常的配分模式。这种变化与成矿流体演化有关。通过与大西洋中脊TAG热液活动区表层沉积硫化物和黑烟囱流体等的稀土元素配分模式对比,可以认为成矿是火山喷流沉积作用的结果。 相似文献
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贵州水银洞金矿构造蚀变体稀土元素地球化学特征 总被引：3，自引：0，他引：3
水银洞金矿构造蚀变体(SBT)为产出于茅口租(P2m)和龙潭组(P3l)之间不整合面上的一套强硅化灰岩、灰岩角砾岩、硅化粘土岩组合.呆用ICP-MS测定钻孔岩芯中构造蚀变体样品稀土元素组成,对比研究SBT围岩、区域岩浆岩及现代海底热水系统流体稀土元素组成.结果显示,SBT的轻重稀土分馏明显[LREE/HREE=4.92～17.51,(La/Yb)N=5.94～38.37],曲线右倾型;轻稀土分异明显,曲线右倾程度大;重稀土分异不明显,曲线平坦;负Eu(0.61～0.94)、Ce(0.52～1.07)异常明显;SBT及围岩均具有明显W型稀土元素四分组效应,而不同于区域岩浆岩和现代海底热水系统流体,表明热液流体来源以壳源为主. 相似文献
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MAO Guangzhou HUA Renmin GAO Jianfeng ZHAO Kuidong LONG Guangming LU Huijuan YAO Junming 《《地质学报》英文版》2010,84(3):614-623
<正>Jinshan gold deposit is located in northeastern Jiangxi,South China,which is related to the ductile shear zone.It has a gold reserve of more than 200 tons,with 80%of gold occurring in pyrite. The LREE of gold-bearing pyrite is as higher as 171.664 ppm on average,with relatively higher light rare earth elements(LREE;159.556 ppm) and lower HREE(12.108 ppm).TheΣLREE/ΣHREE ratio is 12.612 and(La/Yb)_N is 11.765.These indicate that pyrite is rich in LREE.The(La/Sm)_N ratio is 3.758 and that of(Gd/Yb)_N is 1.695.These are obvious LREE fractionations.The rare earth element(REE) distribution patterns show obvious Eu anomaly with averageδEu values of 0.664,andδCe anomalies of 1.044.REE characteristics are similar to those of wall rocks(regional metamorphic rocks),but different from those of the Dexing granodiorite porphyry and Damaoshan biotite granite.These features indicate that the ore-forming materials in the Jinshan gold deposit derived from the wall rocks, and the ore-forming fluids derived from metamorphic water.The Co/Ni ratio(average value 0.38) of pyrite suggests that the Jinshan gold deposit formed under a medium-low temperature.It is inferred from the values of high-field strength elements,LREE,Hf/Sm,Nb/La,and Th/La of the pyrite that the ore-forming fluids of the Jinshan gold deposit derived from metamorphic water with ClF. 相似文献
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文中对浪都矿床夕卡岩中石榴子石进行了主量和稀土元素研究。分析结果表明研究区石榴子石为钙铁榴石-钙铝榴石固溶体系列,成分变化于Ad_(87)Gr_(13)-Ad_(92)Gr_8之间,以钙铁榴石为主。与世界上很多夕卡岩矿床中石榴子石REE配分模式截然不同,研究区石榴子石稀土元素总量较低、配分模式表现为轻稀土富集,重稀土亏损,并且具有明显的Eu正异常。研究显示,浪都矿床钙铁榴石是在水/岩比值较高的环境下快速形成,其与流体之间并没有完全达到REE平衡。岩浆热液中REE的配分模式、表面吸附可能为制约石榴子石REE含量及配分模式的主要因素。Eu~(2+)(r=1.25 A)与其他REE~(3+)相比具有更大的离子半径,更容易被吸附在石榴子石晶体表面,可能是形成浪都矿床中石榴子石Eu正异常的主要原因。 相似文献
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黔东八克金矿床毒砂和黄铁矿微量元素地球化学研究 总被引：2，自引：0，他引：2
八克金矿床以矿体和围岩广泛出现毒砂为典型特征,毒砂、黄铁矿为金的主要共生矿物。对矿体及其围岩中毒砂、黄铁矿进行稀土和微量元素地球化学研究,结果显示矿体中毒砂和黄铁矿的稀土元素总量明显低于围岩的毒砂、黄铁矿,从矿体—近矿围岩—远矿围岩,毒砂、黄铁矿都出现铕的明显负异常,铈无明显异常,反映成矿流体具弱还原性;毒砂、黄铁矿微量元素含量呈现出随着成矿流体从早期到晚期的演化而减少,并普遍亏损高场强元素,富集LREE的特征;通过对黄铁矿、毒砂Hf/Sm、Nb/La和Th/La比值分析,表明八克金矿床成矿流体为富Cl型流体;从研究毒砂、黄铁矿Y/Ho、Zr/Hf和Nb/Ta比值变化范围,表明作用于围岩、矿体中的成矿流体从早期-晚期发生了改变,推测晚期成矿流体可能遭受了外来热液的混入;应用毒砂、黄铁矿中的Co/Ni比值,结合已有数据,表明成矿热液具有多来源的特点,成矿流体来源于大气降水与岩浆水不均匀混合。八克金矿是岩浆热液型的含金石英脉型金矿床。 相似文献
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REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan 总被引：3，自引：1，他引：3
Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas. 相似文献
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REE and Trace Element Geochemistry of Yinachang Fe-Cu-REE Deposit, Yunnan Province, China 总被引：3，自引：0，他引：3
1IntroductionThebehaviorsoftherare earthelements (REE)duringmagmatism ,metamorphismandmeta somationareofgreatgeologicalinterestbecauseoftheirapplicationsingeochronologyandgeochemi caltracing (e .g .reviewsbyFaure ,1 986;LipinandMckay ,1 989) .Becauseoftheirsimilargeo chemicalbehaviorsandlowsolubilitiesinwater,theREEshaveprovedthemselvestobeapowerfultoolforthecharacterizationofprovenanceswhenappliedtosedimentaryrocks (McDanieletal.,1 994) .Althoughtheirbehaviorsunderhydrothermalconditionsar… 相似文献
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晴隆锑矿床中萤石的稀土元素特征及其指示意义 总被引：18，自引：0，他引：18
本文系统地研究了黔西南晴隆锑矿床中萤石的稀土元素地球化学,表明不同颜色、不同矿物组合的萤石的稀土元素含量变化较大,但具有固定的REE分配模式,以明显的负Ce异常、富MREE、分配曲线相对平缓为特征;这种配分模式主要是受其晶体化学因素的控制,而与溶液中REE络合物的稳定性关系不大。萤石的稀土元素组成与其矿物共生组合关系不大,但与其颜色关系较密切。萤石的Ce、Eu异常主要是受氧逸度的控制,流体源区的氧逸度较高,矿物沉淀场所的氧逸度相对较低,从而导致该矿中萤石呈明显的负Ce异常,或正或负的Eu异常。晴隆锑矿床形成于开放体系条件下,水/岩反应很可能是导致萤石发生沉淀的主要机制。萤石中的Ca部分来自茅口组灰岩,部分来自大厂层玄武岩;而矿化剂F可能主要来自外部。 相似文献
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萤石经常以脉石矿物存在于各类金属矿床中,但以矿石矿物与金属矿物共存较为少见。布拖小洞子铅锌矿体和萤石矿体是赋存在震旦系灯影组不同部位的典型矿床,受四开-交际河断裂的次级断层带控制,是该区较为特殊,研究程度较低的一类矿床。其中萤石矿床产于与黑色燧石条带白云岩相关的断裂构造,矿石矿物以萤石为主。本文通过对震旦系灯影组下部萤石矿床开展稀土元素地球化学研究,结果表明轻稀土元素富集,重稀土元素略亏损,LREE/HREE介于0.96~1.61,(La/Yb)_N为1.19~3.23,稀土元素配分图表现出略微右倾的特征,具Eu正异常和Ce负异常特征。Tb/Ca-Tb/La、Y/Ho-La/Ho及La/Yb-∑REE等图解表明小洞子萤石矿床主要为同一体系不同阶段的热液产物,破碎带充填交代型矿床成因,其成矿物质来源与灯影组地层和峨眉山玄武岩热液有关。 相似文献
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1 Introduction Alunite [KAl3(SO4)2(OH)6] is a very important non-ferrous metal resource, so many countries throughout the world have made great investments in research on the mechanism of its formation, its geological characteristics and applications. O… 相似文献
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位处华北板块北缘东段的辽吉裂谷带内发育有多处中、小型铅锌矿床,其中,同时发育层状和脉状铅锌矿的青城子矿床是典型的代表。为了探讨青城子层状铅锌矿和脉状铅锌矿矿质来源及成因的异同及其所代表的地质意义,利用ICP-MS对层状铅锌矿及其围岩、脉状铅锌矿及其围岩和后期穿矿脉岩进行了稀土元素测试。结果表明,所有样品均具有轻稀土元素（LREE）富集和明显分异的特点。层状铅锌矿及其围岩具有Eu正异常和较弱的Ce负异常,表明其成矿物质均来自上升的深部热水流体与海水的混合热液,在高温、还原流体和海水的参与下成矿。脉状铅锌矿及其围岩稀土元素配分模式与层状铅锌矿及其围岩相似,但其Eu为负异常和Ce异常不明显,部分样品出现较弱的Ce正异常,对比分析穿矿脉岩明显的Eu负异常和Ce正异常以及二者稀土元素总量稍大于层状铅锌矿的特点,文章认为青城子层状矿石为沉积成矿,成矿热液为深部热水流体与海水的混合热液,但后期受到岩浆侵入叠加改造的影响而在局部形成脉状铅锌矿体,引起了Eu负异常和局部Ce正异常的出现以及稀土元素总量的增加。 相似文献
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Rare earth element (REE) geochemistry on monomineral has been widely used in various fields of geosciences to reveal the origin
of ore-forming materials and fluid. Quartz are ubiquitous mineral in the Shihu gold deposit that is situated in central shear
zone of mesocenozoic Fuping metamorphic core complex in the middle-northern part of Taihang Mountains. Gold-bearing quartz
veins are their most important industrial orebodies. Rare earth element abundances in quartz from the Shihu gold mine, as
determined by laser ablation-indutively coupled plasma-mass spectrometry (LA-ICP-MS) analysis, are shown to be sensitive to
identify barren quartz and mineralized quartz. Amounts of REE concentrations in barren quartz and mineralized quartz are 97
× 10−9 and 85 × 10−9, respectively. The average (La/Yb)N and (La/Sm)N ratios for the barren quartz are 0.25 and 0.13, and the ratios for mineralized quartz are 0.28 and 0.19, respectively. There
is a pronounced positive correlation between (La/Yb)N and (La/Sm)N ratios. There is no obvious correlation between REE characteristics and sampling sites. The mineralized quartz show the most
pronounced negative Ce anomalies, whereas weak negative Ce anomalies are typical of barren quartz vein. A negative Eu anomaly
becomes more significant in mineralized quartz than barren quartz. δCe have a broadly positive correlation with δEu. Y/Ho
ratio of barren quartz and mineralized quartz are ranging from 2.14–28.75, and from 1.28–9.92, respectively. The REE characteristics
of quartz indicate that the ore-forming fluids of the gold deposit were derived from the deep fluid and its formation was
dually controlled by Precambrian metamorphic basement and Mesozoic granitoids. The results significantly enhance the usefulness
of quartz in tracing the sources of ore-forming fluid to discuss the genesis of the gold deposit, and as an indicator mineral
in mineral exploration in Taihang mountain region. 相似文献
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新疆蒙库铁矿床稀土元素地球化学及对铁成矿作用的指示 总被引：16，自引：4，他引：16
新疆富蕴县蒙库大型铁矿呈层状、似层状、透镜状赋存于下泥盆统康布铁堡组变质火山-沉积岩系中.矿体中发育矽卡岩,但矽卡岩并不产在侵入岩接触带上.绿帘石、石榴石和矿石的稀土配分模式具有相似性,均为轻稀土富集,正铕异常,基本上无铈异常,暗示它们之间存在成因联系.石榴石稀土配分模式呈折线型,具有明显的正铕异常,石榴石流体包裹体中熔融包裹体、熔流包裹体和气液包裹体共存,表明石榴石矽卡岩具有岩浆成因和热液成因的特征,形成于晶体 熔体 流体三相共存的岩浆-热液过渡阶段.矿床地质特征、矽卡岩矿物和矿石稀土特征表明蒙库铁矿为矽卡岩型矿床. 相似文献
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湖南香花铺钨矿床含钙矿物的稀土元素地球化学 总被引：9，自引：3，他引：6
香花铺矿床是湘南地区唯一的萤石-白钨矿型矿床。本文利用高精度LA-ICP-MS对该矿白钨矿和方解石中的稀土元素进行了原位分析。结果表明,该矿的白钨矿表现为LREE富集和正Eu异常特征,方解石则具有LREE富集型和相对平坦型两种稀土配分模式,且均呈现负Eu异常特征。该矿属于与岩浆活动有关的热液矿床,成矿流体在还原环境下的运移过程中,首先结晶出白钨矿和LREE富集型方解石,而后沉淀形成了具有相对平坦型REE模式的方解石。此外,稀土元素在该区矿物中的分布存在明显的不均一现象,在不同微区REE的含量、配分模式以及分异程度等均可能存在差异,其原因除了结晶过程中水动力学条件的变化,还可能与矿物结晶后颗粒外表层受流体作用的改造有关。 相似文献