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1.
Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na2O/K2O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al2O3–CaO* + Na2O–K2O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.  相似文献   

2.
通过水下浅层及近岸钻探取样,对样品的pH值与Eh值,有机碳、细菌、孔隙水化学组份、自生矿物标型特征以及碳氧同位素等的分析。研究了沉积物孔隙水的化学反应过程,及其离子交换与反应物的关系。对早期成岩作用过程与机理进行了探讨.提出河口地区以泥质为主和以沙质为主的两种早期成岩作用基本类型及其特征与标志。为研究古代类似沉积物早期成岩作用的识别提供了依据。  相似文献   

3.
Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE3+:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720°C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ± chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by—or zircon entrainment in—a less evolved melt from the one in which the zircons had previously resided.  相似文献   

4.
Relatively old ages of chondrites(normally around 4.5Ga)suggest that their parent bodies did not experience any mely-fractionation under high temperature and high pressure conditions pertaining to the interior of terrestrial plaets.Therefore,it is reasonable to take chondrites as starting materials in the study of the chemical evolution of the early earth.The sillicate phase in the Jilin chondrite (H5)was chosen for this purpose because it possesses a chemical composition similar to that of the primitive mantle.The melting experiment was carried out at 20-30 k bar and has rsulted in a product which contains1-5% melts in addition to solid cryustal phase.The chemical composition of the melt phases and the partitioning of various elements between the coexisting silicate melts are geochemically similar to those of anatectic rocks on the earth.This can thus serve as the basis for discussing the chemical evolution of the early upper mantle.  相似文献   

5.
We investigated the geochemical characteristics of major, trace and rare earth elements and Sr–Nd isotope patterns of bed sediments from the headwaters and upper reaches of the six large rivers draining the Tibetan Plateau (the Jinsha River—Yangtze, Lancang River—Mekong, Nujiang River—Salween, Huang He—Yellow, Indus, and Yarlung Tsangpo—Brahmaputra). By using Ca/Al versus Mg/Al, La/Sc versus Co/Th, and 87Sr/86Sr versus εNd (0) binary differentiation diagrams of provenance, some typical contributors to the different catchment sediments can be identified. In the Three-River (the Jinsha, Lancang, and Nujiang Rivers) tectonomagmatic belt, acidic–intermediate-acidic volcanic rocks are very important provenance of sediments. Carbonate rocks and Permian Emeishan basalts are dominant in the Jinsha River. The Yellow River sediments have similar geochemical characteristics with loess in catchments. The Indus and Yarlung Tsangpo Rivers sediments are mainly from ultra-K volcanic rocks and Cenozoic granitoids widely distributed in the Indus–Yarlung suture. The intensity of chemical weathering in these river catchments is evaluated by calculating the chemical indices of alteration (CIA) of sediments and comparing them with bedrocks. The CIA values of the six river sediments are from 46.5 to 69.6, closing to those of bedrocks in the corresponding catchment, which indicates relatively weak chemical weathering intensity. Lithology, climate, and topography affect the chemical weathering intensity in these river catchments.  相似文献   

6.
Comprehensive microthermometric investigations revealed similar temperature ranges (280–120°C) for the formation of late carbonates in the Khokhlovskoe, Semizbai, and Malinovskoe deposits of the West Siberian uranium ore region. A close chemical similarity was definitely established between the solutions of fluid inclusions and thermal nitrogen-methane waters with elevated CO2 concentrations typical of this region in general. It was noted that such CO2-rich mineral waters (Yessentuki no. 4 type) are common in the Mesozoic sequences of the Shadrinsk region, where Transuralian uranium deposits occur, and are similar in composition and temperature to the modern CO2-rich formation waters of the host sequences of the Khokhlovskoe deposit. The mineralogical and geochemical features of newly formed late minerals and uranium ores were considered as the most probable reflection of the exfiltration of such thermal solutions into the host levels. Two late mineral assemblages were distinguished: (1) hematite-calcite and (2) goethite-berthierine and goethite-smectite-chlorite with siderite or goethite-kaolinite-illite with siderite; they occur both in the host sequences and in the underlying basement rocks. The development of the latter assemblage causes a significant change in rock color (bleaching); it is widespread and was observed in all the deposits. It was shown that these altered rocks and uranium ores (especially high-grade) are very similar in mineral and chemical composition to the products of acid leaching and accompanying mineralization, which could be related to low-temperature argillization. It was suggested that exogenic epigenetic processes of ancient soil-bedrock oxidation contributed certainly to the development of uranium mineralization, and the modern character of the uranium ores and their host rocks is related to a large extent to the influence of hydrothermal CO2-rich solutions related to the neotectonic activation of the region. This resulted in the development of their specific mineral and chemical compositions and corresponding technological characteristics. It seems expedient to estimate the possible contributions of exogenic and endogenic factors to the formation of the uranium mineralization rather than oppose the roles of these processes of different stages.  相似文献   

7.
The peculiarities of the chemical composition and the isotopic characteristics of Triassic alkaline aegirine-riebeckite rocks composing several small massifs in the Eastern Magnitogorsk Zone of the Southern Urals were found. These massifs are located along two meridional shift zones. Alkaline rocks from all massifs are similar in their concentration of major and minor elements and are divided into three intrusion phases: (1) monzodiorite; (2) alkaline syenite; (3) alkaline granosyenite and alkaline granite. It was established that rocks of the eastern zone are distinguished by higher potassium and iron concentrations.  相似文献   

8.
曹小虎 《地下水》2009,31(4):36-38,116
地下水的化学特征是围岩矿物和水流之间内在关系所形成的结果,决定于地下水运动时接触的围岩成分,水文地质条件和氧化还原环境等。地下水的水化学成份及不同离子含量的多少,与其赋存条件有着十分密切的关系。通过对矿区主要含水层水样常规水质分析,研究矿区地下水的水化学成份及其背景含量特征,研究和分析矿区不同地下水含水层水化学特征,从而揭示矿区水文地质条件。  相似文献   

9.
Quantitative mineralogy correlates with major-, minor- and trace-element chemistry for 387 samples of A-horizon and deeper soils collected from east–west and north–south transects across the USA and Canada, where the deeper soils were collected beneath the A-horizon samples. Concentrations of the major elements correlate with specific mineral phases. Minor- and trace-element concentrations correlate with the same phases as the major elements with which they share similar geochemical behavior. Concentrations of quartz and feldspar correlate with precipitation trends east of the Rocky Mountains, and are independent of the underlying rock type and age, indicating that the weathering of soils in this region may have reached a steady-state mineralogy. Other trends in mineralogy relate to physiographic province. The combination of quantitative mineralogy and chemical analysis yields a much richer portrait of soils than can be gained from chemistry alone, because the origins of chemical trends and the chemical availability of specific elements are related to mineralogy.  相似文献   

10.
吉林省南部元古宙宇宙尘的某些特征及其意义   总被引：2，自引：0，他引：2  
吉林省南部元古宙宇宙尘的某些特征及其意义徐光荣梁宜林张林（长春工业高等专科学校，长春１３００２１）林文蔚陈克樵梁细荣王安平（中国地质科学院矿床地质研究所，北京１０００３７）（长春科技大学，长春１３００２６）关键词宇宙尘高铬特征共轭性吉林作者在吉林省南...  相似文献   

11.
The REE distribution in alluvial, deltaic, liman, and lacustrine oolitic iron ores in the northern Aral region is analyzed. In general, the iron ores are relatively enriched in LREE. The REE distribution patterns are sufficiently similar in different facies, although the contents may slightly vary owing to specific features of the mineral and chemical compositions.Translated from Litologiya i Poleznye Iskopaemye, No. 2, 2005, pp. 215–219.Original Russian Text Copyright © 2005 by Golubovskaya.  相似文献   

12.
We report bulk chemical compositions and physical properties for a suite of 94 objects, mostly chondrules, separated from the Mokoia CV3ox carbonaceous chondrite. We also describe mineralogical and petrologic information for a selected subset of the same suite of chondrules. The data are used to examine the range of chondrule bulk compositions, and to investigate the relationships between chondrule mineralogy, texture and bulk compositions, as well as oxygen isotopic properties that we reported previously. Most of the chondrules show minimal metamorphism, corresponding to petrologic subtype <3.2. In general, elemental fractionations observed in chondrule bulk compositions are reflected in the compositions of constituent minerals. For chondrules, mean bulk compositions and compositional ranges are very similar for large (>2 mg) and small (<2 mg) size fractions. Two of the objects studied are described as matrix-rich clasts. These have similar bulk compositions to the chondrule mean, and are potential chondrule precursors. One of these clasts has a similar bulk oxygen isotopic composition to Mokoia chondrules, but the other has an anomalously high value of Δ17O (+3.60‰).Chondrules are diverse in bulk chemical composition, with factor of 10 variations in most major element abundances that cannot be attributed to secondary processes. The chondrules examined show evidence for extensive secondary oxidation, and possible sulfidization, as expected for an oxidized CV chondrite, but minimal aqueous alteration. Some of the bulk chondrule compositional variation might be the result of chemical (e.g. volatilization or condensation) or physical (e.g. metal loss) processes during chondrule formation. However, we suggest that it is mainly the result of significant variations in the assembly of particles that constituted chondrule precursors. Precursor material likely included a refractory component, possibly inherited from disaggregated CAIs, an FeO-poor ferromagnesian component such as olivine or pyroxene, an oxidized ferromagnesian component, and a metal component. Bulk oxygen isotope ratios of chondrules can be explained if refractory and ferromagnesian precursor materials initially shared similar oxygen isotopic compositions of δ17O, δ18O around −50‰, and then significant exchange occurred between the chondrule and surrounding 16O-poor gas during melting.  相似文献   

13.
The eastern region of the Amazon is home to the most important kaolin bauxite producing district in Brazil, referred to as the Paragominas-Capim kaolin bauxite district, which has a reserve of at least 1.0 billion tons of high-quality kaolin used in the paper coating industry. The kaolin deposits are closely related to sedimentary rocks of the Parnaíba basin and their lateritic cover. Two large deposits are already being mined: IRCC (Ipixuna) and PPSA (Paragominas). The geology of the IRCC mine is comprised of the kaolin-bearing lower unit (truncated mature laterite succession derived from the Ipixuna/Itapecuru formation) and the upper unit (immature lateritized Barreiras formation). The lower kaolin unit is characterized by a sandy facies at the bottom and a soft (ore) with flint facies at the top. It is formed by kaolinite, quartz, some iron oxi-hydroxides, mica and several accessories and heavy minerals. The <2 μm kaolinite crystallites only correspond to 41.3–58.3% of the soft kaolin, and large booklets of 15–300 μm are common. The degree of structure order of kaolinite decreases towards the flint kaolin. The chemical composition of the soft kaolin is similar to the theoretical chemical composition of kaolinite, with low iron content, and can be well correlated to most kaolin deposits in the region. The distribution pattern of chemical elements from sandy to flint kaolin (lower unit) suggests a lateritic evolution and erosive truncation. This is quite distinct from the upper unit, which has a mineralogical and chemical pathway relating it to a complete immature lateritic profile. The geological evolution of the IRCC kaolin is similar to that of other deposits in the eastern Amazon region, being comprised of: parent rocks formed in an estuarine marine and fluvio-laccustrine environment during the early Cretaceous; establishment of mature lateritization with the formation of kaolin in the Eocene; marine transgression and regression – (Pirabas and Barreiras formation) with kaolin profile erosion and forward movement of deferruginization and flintization during the Miocene after partial mangrove covering; and immature lateritization – partial kaolin ferruginization during the Pleistocene.  相似文献   

14.
Chemical weathering of basalts in the Putorana Plateau, Central Siberia, has been studied by combining chemical and mineralogical analysis of solids (rocks, soils, river sediments and suspended matter) and fluid solution chemistry in order to quantify CO2 consumption and to assess the major factors controlling basic rock weathering under permafrost-dominated taiga climate. The chemical status of  40 major and trace elements (TE) in pristine boreal rivers and interstitial solutions of permafrost soils has been investigated using in-field ultrafiltration procedure. This revealed strong relationships between concentration of TE and that of major inorganic components of colloids, i.e., Fe or Al. Decomposing plant litter and permafrost thawing are considered important sources of most major and trace elements in Arctic rivers during summertime.  相似文献   

15.
The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U3O8, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide.  相似文献   

16.
Methane-hydrogen gas seeps with mantle-like C and noble gas isotopic characteristics issue from partially serpentinized ultramafic rocks in the Zambales ophiolite, Philippines. New measurements of noble gas and 14C isotope abundances, rock/mixed-volatile equilibrium calculations, and previous chemical and isotopic data suggest that these reduced gases are products of periodotite hydration. The gas seeps are produced in rock-dominated zones of serpentinization, and similar gases may be ubiquitous in ultramafic terranes undergoing serpentinization.  相似文献   

17.
New data is presented for five evolved, low-Ti lunar mare basalt meteorites from the LaPaz Icefield, Antarctica, LAP 02205, LAP 02224, LAP 02226, LAP 02436, and LAP 03632. These basalts have nearly identical mineralogies, textures, and geochemical compositions, and are therefore considered to be paired. The LaPaz basalts contain olivine (Fo64-2) and pyroxene (Fs32Wo8En60 to Fs84-86Wo15En2-0) crystals that record extreme chemical fractionation to Fe-enrichment at the rims, and evidence for silicate liquid immiscibility and incompatible element enrichment in the mesostasis. The basalts also contain FeNi metals with unusually high Co and Ni contents, similar to some Apollo 12 basalts, and a single-phase network of melt veins and fusion crusts. The fusion crust has similar chemical characteristics to the whole rock for the LaPaz basalts, whereas the melt veins represent localized melting of the basalt and have an endogenous origin. The crystallization conditions and evolved nature of the LaPaz basalts are consistent with fractionation of olivine and chromite from a parental liquid similar in composition to some olivine-phyric Apollo 12 and Apollo 15 basalts or lunar low-Ti pyroclastic glasses. However, the young reported ages for the LaPaz mare basalts (∼2.9 Ga) and their relative incompatible element enrichment compared to Apollo mare basalts and pyroclastic glasses indicate they cannot be directly related. Instead, the LaPaz mare basalts may represent fractionated melts from a magmatic system fed by similar degrees of partial melting of a mantle source similar to that of the low-Ti Apollo mare basalts or pyroclastic glasses, but which possessed greater incompatible element enrichment. Despite textural differences, the LaPaz basalts and mare basalt meteorite NWA 032 have similar ages and compositions and may originate from the same magmatic system on the Moon.  相似文献   

18.
徐小军  赵子福  郑永飞  魏春生 《地球科学》2005,30(6):721-728,770
大量的同位素地质年代学和地球化学研究表明,大别山中生代中酸性岩为俯冲扬子陆壳再循环的产物．REE配分的定量模拟计算结果表明,与基性下地壳相似的北大别基性闪长质片麻岩部分熔融并经过结晶分异能够形成与天柱山中性岩类似的稀土元素组成,而与中性地壳相似的北大别中性灰色片麻岩部分熔融能够形成与天柱山花岗岩类似的稀土元素组成．残留相微量元素定量计算结果表明,大别山现今出露的中基性麻粒岩不是部分熔融后形成的残留体．早白垩世地幔超柱事件热扰动所引起的加厚地壳部分熔融后的残留体可能由于比重较大而拆离进入地幔,从而发生去山根作用和造山带的大面积隆起．  相似文献   

19.
N has a controlling effect on litter biodegradation in the forest floor, while stabilization of organic matter in the mineral soil may be influenced by physical parameters related to soil texture. In this study, in order to understand the processes involved in soil organic matter (SOM) formation, the chemical composition of SOM was followed and evaluated with regards to N contents and soil texture. Samples were taken on sites covered with Norway spruce and displaying contrasting values of C/N ratios in the forest floor. The chemical structure of OM was characterized using solid-state CPMAS 13C and 15N nuclear magnetic resonance (NMR) spectroscopy, along with Proton Spin Relaxation Editing (PSRE) sequences. Four groups of sampling sites were defined based on the NMR spectra of Oh and A horizons. In each group displaying similar NMR characteristics, N content and soil texture could be highly different among sites. Some Oh horizons with similar NMR spectra had very different N contents. Highly humified OM in Oh horizons were observed mainly on sites with low N contents. Some A horizons with different soil texture displayed similar OM chemical structure. High contents of O-alkyl C in some A horizons could originate from higher fresh root material input.  相似文献   

20.
On the basis of complex studies of tephra layers (morphology of volcanic glass particles, chemical composition of glass particles and minerals, and REE distribution), marker tephra layers (K2, K3) were distinguished in the stratigraphic columns in the area of the Sea of Okhotsk. The areas of distribution of tephra layers and their age datings were determined. Tephra layers are shown to be similar in their chemical composition. They are correlated with strong explosive eruptions in the Nemo caldera complex on Onekotan Island (northern part of the Kuril Islands) in the Late Pleistocene.  相似文献   

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