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1.
Nodular chert from the middle and upper Arbuckle Group (Early Ordovician) in the Slick Hills, SW Oklahoma, was formed by selective replacement of grainstones, burrow fillings, algal structures, and evaporite nodules. Chert nodules are dominantly microquartz with minor fibrous quartz (both quartzine and chalcedony), megaquartz, and microflamboyant quartz. Lepisphere textures of an opal-CT precursor are preserved in many (especially in finely-crystalline) chert nodules. The δ18O values of microquartz chert range from +23.4 to + 28.80/00 (SMOW), significantly lower than those of Cenozoic and Mesozoic microquartz chert formed both in the deep sea and from near-surface sea water. The δ18O values of chert decrease with increasing quartz crystal size. Silicification in the Arbuckle Group occurred during early diagenesis, with the timing constrained by the relative temporal relationships among silicification, burial compaction, and early dolomite stabilization. Silica for initial chert nucleation may have been derived from both dissolution of sponge spicules and silica-enriched sea water. Chert nucleation appears to have been controlled by the porosity, permeability, and organic matter content of precursor sediments. This conclusion is based on the fact that chert selectively replaced both porous grainstones and burrows and algal structures enriched in organic matter. Growth of chert probably occurred by a maturation process from opal-A(?), to opal-CT, to quartz, as indicated by the presence of opal-CT precursor textures in many chert nodules. Although field and petrographic evidence argues for an early marine origin for chert in the Arbuckle Group, the light δ18O values are inconsistent with this origin. Meteoric resetting of the δ18O values of the chert during exposure of the carbonate platform best explains the light δ18O values because: (i) the δ18O values of chert nodules decrease with decreasing δ18O values of host limestones, and (ii) chert nodules from early dolomite, which underwent more extensive meteoric modification than associated limestones, have lighter δ18O values than chert nodules from limestones. Increasing recrystallization of chert nodules by meteoric water resulted in progressive 18O depletion and (quartz) crystal enlargement. 相似文献
2.
The early Pliocene Shirahama Limestone is a grainstone-packstone principally composed of fragments of algae, bryozoa, and echinoderm and subordinate volcanic rocks. The limestone was variously dolomitized and the regional distribution of dolomite is patchy. Dolomite occurs as isolated crystals filling pores, moulds, and solution vugs, and mosaic aggregates replacing bioclasts. Calcite occurs as rim and pore-filling sparry cements, and as calcareous skeletons. Isotopically, the dolomites are classified into a heavy oxygen group (?2 to ? 3.5%0 PDB) and a light oxygen group (?5.5 to ? 7.5%0 PDB). Calcite associated with heavy oxygen dolomite has δ18O of ? 6.5 to ?8.5%0 PDB, whereas those associated with light oxygen dolomite have a wide range from ?7.5 to ?14%0 PDB. Calcite in dolomite-free limestone has an oxygen isotopic composition of ?2 to ?8.5%0 PDB. Textures, chemistry, and isotopic evidence indicate that heavy oxygen calcite formed in freshwater, and heavy oxygen dolomite in a meteoric-marine mixture of 10–30% seawater. Light oxygen calcite and dolomite precipitated from modified hydrothermal fluids at approximately 30–65°C. Petrographic features, and both isotopic and chemical evidence suggest that the Shirahama Limestone was exposed to freshwater soon after deposition. Subsequently blocky calcite precipitated (Stage I). The limestone was locally submerged in the meteoric-marine mixture due to gradual subsidence or eustatic movement. This led to the precipitation of heavy oxygen, zoned dolomite and dolospar (Stage II). Hydrothermal alterations occurred in the area a few Myr ago, and related hydrothermal fluids and mixed meteoric-hydrothermal waters caused dedolomitization of some zoned dolomite, partial dissolution of vuggy dolomite, precipitation of limpid dolomite and recrystallization of some earlier dolomites (Stage III). Zeolites were also precipitated from these fluids. Finally, the Shirahama Limestone was exposed again to freshwater and sparry calcite precipitated to plug some of the remaining pores (Stage IV). 相似文献
3.
Determining fluid source and possible pathways during burial dolomitization of Maryville Limestone (Cambrian), Southern Appalachians, USA 总被引：2，自引：0，他引：2
Detailed petrographic analyses along a depositional transect from a carbonate platform to shale basin reveals that dolomite is the principal burial diagenctic mineral in the Maryville Limestone. This study examines the role of burial dolomitization of subtidal carbonates. Dolomite occurs as a replacement of precursor carbonate and as inter- and intraparticle cements. Four different types of dolomite are identified based on detailed petrographic and gcochemical analyses. Type I dolomite occurs as small, irregular disseminations typically within mud-rich facies.Type II dolomite typically occurs as inclusions of planar euhedral rhombs (ferroan), 5–300 μm in size, in blocky clear ferroan calcite (meteoric) spar. Type II dolomite is non-luminescent. Type I and II dolomite formed during shallow to intermediate burial diagenesis. Type III dolomite consists of subhedral to anhedral crystals 10–150 μm in size occurring as thin seams along stylolites and as thick bands a few millimetres in width. This dolomite consists of dominantly non-luminescent rhombs and, less commonly, orange luminescent and zoned rhombs. Type IV dolomite consists of baroque or saddle-shaped, 100–1500 μm crystals, and is non-luminescent. Type IV dolomite formed during the period of maximum burial. Types III and IV dolomite increase in abundance downslope. Type III dolomite contains 1.2–2.6 wt% Fe and a maximum of 1000 ppm Mn. The distribution of these elements displays no distinct vertical or lateral trends. In contrast, Fe and Mn distributions in Type IV dolomite exhibit distinct spatial trends, decreasing from 3.5–4.5 wl% Fe and 0.1–0.3 wt% Mn in the west (slope/basin) to 1.5–2.5 wt% Fe and less than 600 ppm Mn in the east (shelf margin), a distance of approximately 60 km. Spatial trends in Fe and Mn distributions in Type IV saddle dolomite, suggest a west-east fluid flow during late burial diagenesis. Types III and IV dolomite have a mean δ18O value of - 7.8%00 and a mean δ13C value of + 1.1%00 (relative to the PDB standard). Based on a range of assumed basinal water composition of 2.8%00 SMOW, temperatures calculated from δ18O values of Types III and IV dolomite range between 75 and 160°C. 87Sr/86Sr data for Types III and IV dolomite range from 0.7111 to 0.7139. These values are radiogenic when compared to Cambrian marine values and are consistent with the presence of a diagenetic fluid that interacted with siliciclastic sediments. The distribution of Palaeozoic facies in the southern Appalachians indicates a Cambrian shale source for the fluids, whilst burial curves suggest a Middle Ordovician age for burial fluid movement. 相似文献
4.
《International Geology Review》2012,54(10):949-954
High δ13C values up to 11%PDB occur in Paleoproterozoic dolostones from the Aravalli Supergroup, western India. Correlation of high δ13C with high δ18O up to 23%SMOW in the studied carbonates suggests that pre-metamorphic δ13C values were above 10%PDB. The data are consistent with worldwide positive excursions in the δ13C of marine bicarbonate. The positive excursion was contemporaneous with sedimentation. 相似文献
5.
Three major types of dolomite occur in the Trenton Formation (Mid-Ordovician) of the Michigan Basin. These are: (1) ‘regional dolomite’ which is confined to the extreme western edge of the basin; (2) ‘cap dolomite’ which occurs in the upper portion of the Trenton and is confined to the basin's southern margin; and (3) ‘fracture-related’ dolomite which occurs in association with both large- and small-scale faults and fractures. These three dolomite types can be distinguished from one another by their major element chemistry, oxygen isotope ratios and rock texture. The regional dolomite is fine-grained, has <0.34 mol% FeCO3, and mean δ18O of ?6·8‰OPBD. The cap dolomite is texturally similar to regional dolomite but contains 3–13·0 mol% FeCO3 and has a mean δ18O of ?7·7‰. Fracture-related dolomites are coarse-grained, low in iron, and have the most depleted δ18O ratios (x?=–9·0%PDB). Petrographic relationships imply that the regional dolomite, formed prior to the cap dolomite probably during early diagenesis. The cap dolomite formed at relatively shallow depths as a result of the interaction of the overlying Utica Shale and the Trenton Limestone. Fracture-related dolomites post-date the cap dolomite and formed during deeper burial. A temperature of precipitation of approximately 80°C was calculated for fracture-related dolomites using oxygen isotope data. The distribution of the cap dolomite was controlled by the availability of Fe2? which was in turn controlled by the availability of S2?. In the centre of the basin Trenton-Utica deposition was continuous. The upper Trenton contained relatively high concentrations of organic matter which was used by sulphate reducing bacteria to produce H2S from seawater sulphate. The precipitation of iron sulphides (pyrite + iron monosulphide) followed and used up most of the available Fe2?. As a result only small amounts of ferroan dolomite formed. On the periphery of the basin, subaerial exposure resulted in the oxidation of most of the available organic matter. Sulphate reducing bacteria were therefore limited and produced limited amounts of H2S. As a result only a minor amount of iron sulphide (iron monosulphide) formed. The remaining Fe2- was then available for the formation of the ferroan cap dolomite. This model is supported by the following: (1) In the southern margin of the basin, the contact between Trenton cap dolomite and the overlying Utica Shale is sharp and probably unconformable. In the centre of the basin the contact is gradational. (2) In the centre of the basin, the total organic carbon content in the upper Trenton is an order of magnitude higher than in the cap dolomite. (3) The whole-rock concentration of iron is high in both the cap dolomite and in slightly dolomitized equivalent beds in the basin centre. (4) Iron sulphides are abundant in the centre of the basin and mostly in the form of pyrite. In the cap dolomite, iron sulphide is minor and primarily in the form of iron monosulphide. 相似文献
6.
Authigenic calcite and dolomite and biogenic aragonite occur in Holocene pan sediments in a Mediterranean‐type climate on the western coastal plain of South Africa. Sediment was analysed from a Late Pleistocene coastal pan at Yzerfontein and four Holocene inland pans ranging from brackish to hypersaline. The pans are between 0·08 and 0·14 km2 in size. The δ18OPDB values of carbonate minerals in the pan sediments range from ?2·41 to 5·56‰ and indicate precipitation from evaporative waters. Covariance of total organic content and percentage carbonate minerals, and the δ13CPDB values of pan carbonate minerals (?8·85 to ?1·54‰) suggest that organic matter degradation is a significant source of carbonate ions. The precipitation of the carbonate minerals, especially dolomite, appears to be mediated by sulphate‐reducing bacteria in the black sulphidic mud zone found in the brine‐type hypersaline pans. The knobbly, sub‐spherical texture of the carbonate minerals suggests that the precipitation of the carbonate minerals, particularly dolomite, is related to microbial processes. The 87Sr/86Sr ratios of pan carbonate minerals (0·7108 to 0·7116) are slightly higher than modern sea water and indicate a predominantly sea water (marine aerosol) source for calcium (Ca2+) ions with relatively minor amounts of Ca2+ derived from the chemical weathering of bedrock. 相似文献
7.
Stable isotope evidence for the origin of diagenetic carbonate minerals from the Lower Jurassic Inmar Formation, southern Israel 总被引：1，自引：0，他引：1
The oxygen isotope compositions of diagenetic carbonate minerals from the Lower Jurassic Inmar Formation, southern Israel, have been used to identify porewater types during diagenesis. Changes in porewater composition can be related to major geological events within southern Israel. In particular, saline brines played an important role in late (Pliocene-Pleistocene) dolomitization of these rocks. Diagenetic carbonates included early siderite (δ18OSMOW=+24.4 to +26.5‰δ13CPDB=?1.1 to +0.8‰), late dolomite, ferroan dolomite and ankerite (δ18OSMOW=+18.4 to +25.8‰; δ13CPDB=?2.1 to +0.2‰), and calcite (δ18OSMOW=+21.3 to +32.6‰; δ13CPDB=?4.2 to + 3.2‰). The petrographic and isotopic results suggest that siderite formed early in the diagenetic history at shallow depths. The dolomitic phases formed at greater depths late in diagenesis. Crystallization of secondary calcite spans early to late diagenesis, consistent with its large range in isotopic values. A strong negative correlation exists between burial depth (temperature) and the oxygen isotopic compositions of the dolomitic cements. In addition, the δ18O values of the dolomitic phases in the northern Negev and Judea Mountains are in isotopic equilibrium with present formation waters. This behaviour suggests that formation of secondary dolomite post-dates the tectonic activity responsible for the present relief of southern Israel (Upper Miocene to Pliocene) and that the dolomite crystallized from present formation waters. Such is not the case in the Central Negev. In that locality, present formation waters have much lower salinities and δ18O values, indicating invasion of freshwater, and are out of isotopic equilibrium with secondary dolomite. Recharge of the Inmar Formation by meteoric water in the Central Negev occurred in the Pleistocene, and halted formation of dolomite. 相似文献
8.
STELIOS NICOLAIDES 《Sedimentology》1997,44(1):143-157
The Miocene Port Campbell Limestone in the Otway Basin (Port Campbell Embayment), south-eastern Australia, is a shallowly buried (<350 m), temperate carbonate grainstone which consists primarily of benthonic foraminifera, bryozoans, brachiopods, echinoids and planktonic foraminifera. Volumetrically insignificant calcite cements include scalenohedral, blocky and syntaxial overgrowths. Dolomite is present in variable amounts (1–25%), scattered throughout the unit as euhedral rhombs, usually comprising <2% of the whole rock volume. The dolomite post-dates the calcite cements and is mainly an interparticle cement with crystal size varying between 10 and 150 μm (mean 50 μm). Under cathodoluminescence the dolomite rhombs have a dull core and a nonluminescent outer rim. The dolomite is nonstoichiometric, Ca-rich (Ca54–62Mg38–46), with high trace element concentrations. The Mn concentrations range from 0 to 310 p.p.m. in the crystal cores (mean 140 p.p.m.) and 80–240 p.p.m. in the crystal rims (mean 140 p.p.m.). The Fe concentrations increase from the crystal cores (range 640–5690 p.p.m.; mean 2030 p.p.m.) to the crystal rims (range 2840–9440 p.p.m.; mean 6040 p.p.m.), whereas the Sr concentrations decrease from the crystal cores (range 690–1510 p.p.m.; mean 1280 p.p.m.) to the crystal rims (620–1240 p.p.m.; mean 930 p.p.m.). The δ13CPDB values of the dolomite range between +2.5 and +2.6%, whereas the δ18OPDB values range from +0.3% to+0.6%. This dolomite occurrence supports the idea that marine or near-marine dolomite can form not only syndepositionally, but also in the shallow subsurface of temperate units, soon after sediment deposition, under reducing conditions. The fine-grained, low-permeability nature of the Port Campbell Limestone contributed to the reducing conditions at shallow depth, the high trace element concentrations of the dolomite (especially in Fe) and the near marine composition of the dolomitizing fluids, as large volumes of meteoric water were inhibited. 相似文献
9.
Well-developed dissolution pores occur in the dolomites of the Sinian Dengying Formation, which is an important oil and gas reservoir layer in the Sichuan Basin and adjacent areas in southern China. The pores are often filled with quartz, and some dolomites have been metasomatically altered to siliceous chert. Few studies have documented the characteristics, source or origin of silica-rich fluids and their effects on the dolomite reservoir. The peak homogenisation temperatures(T_h) of fluid inclusions in pore-filling quartz are between 150℃ and 190℃, with an average of 173.7℃. Gases in the inclusions are mainly composed of CO_2, CH_4 and N_2. Compared with host dolomite, pore-filling quartz and metasomatic chert contain higher amounts of Cr, Co, Mo, W and Fe, with average concentrations of 461.58, 3.99, 5.05, 31.43 and 6666.83 ppm in quartz and 308.98, 0.99, 1.04, 13.81 and 4703.50 ppm in chert, respectively. Strontium levels are lower than that in the host dolomite, with average concentrations in quartz and chert of 4.81 and 11.06 ppm, respectively. Rare earth element compositions in quartz and chert display positive Eu anomalies with a maximum δEu of 5.72. The δD_(SMOW) values of hydrogen isotopes in water from quartz inclusions vary from-85.1‰ to-53.1‰ with an average of-64.3‰, whereas the δ~(18)O_(SMOW) values range from 7.2‰ to 8.5‰ with an average of 8.2‰. The average ~(87)Sr/~(86)Sr ratios in quartz and chert are 0.711586 and 0.709917, respectively, which are higher than that in the host dolomite. The fluid inclusions, elemental and isotopic compositions demonstrate that the formation of quartz and chert was related to silica-rich hydrothermal fluid and that the fluid was the deep circulation of meteoric water along basement faults. Interactions with silica-rich hydrothermal fluids resulted in densification of dolomite reservoirs in the Dengying Formation through quartz precipitation and siliceous metasomatism. However, it increased the resistance of the host dolomite to compaction, improving the ability to maintain reservoir spaces during deep burial. Evidence for silica-rich hydrothermal activity is common in the Yangtze Platform and Tarim Basin and its influence on deep dolomite reservoirs should be thoroughly considered. 相似文献
10.
STELIOS NICOLAIDES 《Sedimentology》1995,42(2):249-266
The Early to Middle Cambrian Red Heart Dolomite and lower Arthur Creek Formation of the southern portion of the Georgina Basin, Australia, is an entirely dolomitized succession of shallow-water evaporitic mudflat and deeper-water subtidal lithologies. Three types of dolomite have been identified and are interpreted as: (1) syndepositional dolomite; (2) regional replacement dolomite; and (3) void-filling dolomite (cement). Syndepositional dolomite, derived from saline pore fluids developed in a sabkha environment, is a minor dolomite type with very fine crystal mosaics and has a mottled, non-zoned cathodoluminescence. The widespread regional replacement dolomite ranges from fine- to medium-crystalline forming mainly planar-s and non-planar-a crystal mosaics, and displays blotchy, mottled, non-zoned cathodoluminescence. Void-filling dolomite commonly forms planar-s to planar-e, medium to very coarse crystal mosaics. Rare non-planar-c, very coarsely crystalline saddle dolomite also exists. Void-filling dolomite has a successively zoned cathodoluminescence pattern from non-, to brightly, to dully luminescent. Geochemically, the syndepositional dolomite has δ18O (PDB) values ranging between ? 5.3 and ? 8.6%o. Regional replacement dolomites exhibit a wide range of δ18O values from ? 3.3 to ? 10.9%o whereas void-filling dolomite has δ18O values ranging from ? 10.8 to ? 14.3%o. All three dolomite types have similar δ13C (PDB) values, in the range between +1.7 and ?1.7%o. Three initial dolomitization episodes are interpreted: (1) a sabkha stage, forming the syndepositional dolomite and dolomitizing the evaporitic mudflat lithologies; (2) a brine-reflux stage, replacing the subtidal lithologies; and (3) a burial stage, forming the void-filling dolomite type. Final dolomite stabilization occurred during burial, at elevated temperatures, in the presence of basinal fluids, resulting in progressive recrystallization and stabilization of the earlier-formed syndepositional and replacement dolomites. Both textural and geochemical evolution should be taken into account when studying the origin of dolomites, based on their present geochemical composition. Sulphates are represented by very fine-crystalline syndepositional anhydrite in association with the syndepositional dolomite, and coarse to very coarse anhydrite cement. Evaportic mudflat (sabkha) and burial environments are inferred for the origin of the former and the latter anhydrite types, respectively. Evaporite dissolution breccias, indicative of the former presence of evaporites, are common throughout the succession. 相似文献
11.
Chert nodules of the Drunka Formation (Lower Eocene) are mostly spherical, have diameters from 40 to 120 cm, are quasi-uniformly spaced 2–3 m apart in the plane of bedding, have concentric internal structure and, except for rare small (<6 cm) solid chert nodules, are less than 85% chertified. Nodules formed after moderate alteration of limestone by meteoric water (δ18Ocalcite = –4 to –8‰) at shallow (<100 m) burial depths; more extensive alteration of limestone (δ18O = –10 to –16‰) by meteoric water followed nodule growth. Chertification was by low-temperature meteoric water (δ18Oquartz = +18‰ in margins to +22‰ in nuclei) at shallow burial depths. Meteoric water may have invaded the Drunka Formation in association with shelf progradation during the Early Eocene, or during the development of a Middle Eocene unconformity. Replacement of carbonate mud by microcrystalline quartz was the dominant chertification process, but fossils were replaced in part by fine-grained equant megaquartz, quartzine and chalcedony; the last of these occurs in places as beekite. Opal A-secreting marine organisms are the inferred source of silica, but none are preserved. There is no compelling evidence of an opal-CT precursor, so quartz may have formed by direct precipitation. Self-organization processes of enigmatic character established the spacing pattern of the nodules and also the Liesegang-banded internal structure of the chert nodules. Nodules grew chiefly by diffusive supply of silica, although one locality has elongate nodules that grew when there was some porewater advection. Chertification patterns and δ18O values of both calcite and quartz indicate that nodule growth was complex and variable. Some nodules probably grew from the centre outwards. Many nodules, however, initially grew simultaneously across the entire nodule, but late-stage growth was predominantly at the outer margins or at selective internal sites. 相似文献
12.
WILLIAM J. MEYERS 《Sedimentology》1977,24(1):75-105
Chert distribution in the Lake Valley rocks is selective to mud-supported facies; it is not related to proximity to unconformities. The facies selectivity of the chertification is believed to be a function of the depositional distribution of indigenous silica as sponge spicules, an interpretation that is supported by high positive qualitative correlation of chert with spiculitic rocks. Petrography indicates that the spicules were all originally siliceous, and that they all went through a moldic stage during which many molds were compactively destroyed and distorted. Remaining molds were subsequently cemented by calcite or chalcedony. Chert distribution and spicule petrography argue for an intraformational source for much of the silica. Chert micro-fabrics are dominated by microquartz, a replacement of grains and lime mud; length-fast chalcedony, a pore-filling cement; and megaquartz, a post-chalcedony pore-filling cement. Petrography of compaction features within chert masses indicates that chertification occurred after some burial. Based on stratigraphic reconstruction this burial depth was a maximum of about 215 m. and was most likely a few metres to a few tens of metres. Petrography of chert-calcite cement relationships indicates that chertification occurred before and during first generation, pre-Pennsylvanian non-ferroan calcite cementation, and was completed before late-stage, post-Mississippian ferroan calcite precipitation. Petrography of chert clasts in basal Rancheria (Meramecian) and basal Pennsylvanian conglomerates proves these clasts derived from the Lake Valley Formation and were chertified before redeposition. Thus, some cherts in the Lake Valley are pre-Meramecian in age, but all are pre-Pennsylvanian in age. Furthermore, association of the cherts with the non-ferroan cements indicates the cherts were probably precipitated in meteoric phreatic lens established beneath the pre-Meramecian and pre-Pennsylvanian subaerial unconformities. 相似文献
13.
Carbon, oxygen and sulphur isotope data for transects across two pyrite-bearmg carbonate concretions, and their host sediments, from the Upper Lias of N.E. England show symmetrical zonation. δ13CPDB values of the calcite cement (?12.9 to ?15.4%.) indicate that most of it originated from organic matter by bacterial reduction of sulphate, augmented with marine and, to a lesser extent, fermentation derived carbonate. Organic carbon (δ13CPDB = ?26.1 to ?37.0%.). reflects the admixture of allochtho-nous terrestrial organic matter with marine material and the selective preservation of isotopically light organic material through microbiological degradation.Two phases of pyrite are present in each concretion. The earlier framboidal pyrite formed throughout the sediment prior to concretionary growth and has δ34SCD values of ?22 to ?26%. indicating formation by open system sulphate reduction. The later euhedral phase is more abundant and reaches values of ? 2.5 to ? 5.5%. at concretion margins. This phase of sulphate reduction provided the carbonate source for concretionary growth and occurred in a partially closed system. The δ13C and δ34S data are consistent with mineralogical and chemical evidence which suggest that both concretions formed close to the sediment surface. The δ18O values of the calcite in one concretion (δ18OPDB = 2.3 to ?4.8%.) indicate precipitation in pore waters whose temperature and isotopic composition was close to that of overlying seawater. The other concretion is isotopically much lighter (δ18OPDB?8.9 to ?9.9%.) and large δ18O differences between concretions in closely-spaced horizons imply that local factors control the isotopic composition of pore waters. 相似文献
14.
Carbon and oxygen isotope records for Shangsi Section in Northwest Sichuan Basin, South China can help investigating depositional environments and processes, including the burial rate and possible contribution of hydrothermal events. Samples from the lower Chihsian Formation show δ13CPDB and δ18OPDB values close to those of typical marine limestone. However, the overlying Permian middle-upper Chihsian, Wujiaping, and Maokou Formation samples reveal negative δ18OSMOW values and strong positive δ13CPDB values. These indicate high biological productivity and rapid burial of organic carbon. Samples from the Dalong Formation present both negative δ13CPDB and negative δ18OPDB values, which are quite different from the underlying Permian strata. These abnormal carbon and oxygen isotope characteristics in the Dalong Formation may suggest that hydrothermal processes contributed to deposition. 相似文献
15.
《International Geology Review》2012,54(7):593-606
In the basal section of the carbonates of the Maastrichtian Gramame Formation in the Pernambuco-Paraiba coastal basin of northeastern Brazil, major phosphate concentrations (P2O5 > 10%) were deposited in shallow-marine environments (inner shelf). In contrast, dolomite-associated phosphates are characterized by low P2O5 concentrations (<10%) and were deposited in the relatively deep water of a platform ramp, under conditions of limited oxygen availability. Calcite is the main carbonate phase remaining after the diagenesis that affected the phosphorite. A positive δ13C (up to +2%PDB), coupled with a positive MgO-δ180 correlation in the phosphate-enriched carbonates, suggests that upwelling currents were the early phosphogenic vectors during marine transgression, in contrast to warm superficial seawater that prevailed during the Maastrichtian elsewhere. The major phosphate concentrations are related to reworking and diagenesis in a shallow shelf environment during a regression pulse of sea level, followed by a dramatic drop of δ13C to negative values (down to ?6%PDB). This study suggests that carbon and oxygen isotopes can be used as potential tools for phosphorite prospecting elsewhere. 相似文献
16.
Dark grey, bituminous dolostones interbedded with marine-derived anhydrite horizons occur in the Triassic Reichenhall Formation of western Austria. Fossils are rare and indicate a hostile, hypersaline depositional environment. The dolomites are finely crystalline, fairly stoichiometric, well ordered and non-ferroan. Closely spaced samples (94 in total) of individual dolomite units have been analysed for their carbon and oxygen isotopic composition. The data indicate surprisingly low δ18O values (-5.7 to -2.1%0 PDB), whereas the δ13C values are comparable to the contemporary Triassic seawater (+0.2 to +2.6%0 PDB). Sedimentological evidence, including (i) lack of any evidence for extensive dissolution, (ii) distinct oxygen and carbon isotope ratios of individual dolomite units, (iii) covariance of carbon and oxygen isotopes within some dolomite layers and (iv) inclusions of celestite in dolomite, indicates a nearly closed system after early diagenesis. Combining this information with water-rock interaction calculations suggests that the lightest oxygen isotope compositions are the result of freshwater influx into the basin during very early dolomite formation. A secondary factor may be dolomite recrystallization at elevated temperatures during burial. 相似文献
17.
Geology and Isotope Geochemistry of the Yinchanggou-Qiluogou Pb-Zn Deposit, Sichuan Province, Southwest China 总被引：1，自引：0，他引：1
The Yinchanggou-Qiluogou Pb-Zn deposit,located in the western Yangtze Block,southwest China,is hosted by the Upper Sinian Dengying Formation dolostone.Ore bodies occur in the Qiluogou anticline and the NS-and NNW-trending faults.Sulfide ores mainly consist of sphalerite,pyrite,galena and calcite,with subordinate dolomite and quartz.Seventeen ore bodies have been discovered to date and they have a combined 1.0 million tons of sulfide ores with average grades of 2.27wt%Zn and 6.89wt%Pb.The δD_(H2O-SMOW) and δ~(18)O_(H2O-SMOW) values of fluid inclusions in quartz and calcite samples range from-68.9‰ to-48.7‰ and 7.3‰ to 15.9‰,respectively,suggesting that H_2O in the hydrothermal fluids sourced from metamorphic water.Calcite samples have δ~(13)C_(PDB) values ranging from-6.2‰ to-4.1‰ and δ~(18)O_(SMOW) values ranging from 15.1‰ to 17.4‰,indicating C and O in the hydrothermal fluids likely derived from a mixed source of metamorphic fluids and the host carbonates.The δ~(34)S_(CDT) values of sulfide minerals range from 5.5‰ to 20.3‰,suggesting that thermal chemical reduction of sulfate minerals in evaporates were the most probable source of S in the hydrothermal fluids.The ~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb ratios of sulfide minerals fall in the range of 18.11 to 18.40,15.66 to 15.76 and 38.25 to 38.88,respectively.The Pb isotopic data of the studied deposit plot near the upper crust Pb evolution curve and overlap with the age-corrected Proterozoic basement rocks and the Upper Sinian Dengying Formation hosting dolostone.This indicates that the Pb originated from a mixed source of the basement metamorphic rocks and the ore-hosting carbonate rocks.The ore geology and C-H-O-S-Pb isotopic data suggest that the YinchanggouQiluogou deposit is an unusual carbonate-hosted,strata-bound and epigenetic deposit that derived ore-forming materials from a mixed source of the underlying Porterozoic basements and the Sinian hosting carbonates. 相似文献
18.
Dolomitization,gypsum calcitization and silicification in carbonate–evaporite shallow lacustrine deposits 
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下载免费PDF全文 This paper describes and interprets the mineral and facies assemblages that occur in carbonate–evaporite shallow lacustrine deposits, considering the importance of the processes pathway (i.e. dolomitization, gypsum calcitization and silicification). The Palaeogene deposits of the Deza Formation (Almazán Basin, central‐northern Spain) are selected as a case study to determine the variety of physicochemical processes taking place in carbonate–evaporite shallow lakes and their resulting diagenetic features. Dolostones are the predominant lithology and are composed mainly of dolomite with variable amounts of secondary calcite (5 to 50%), which mainly mimic lenticular gypsum (pseudomorphs). Five morphological types of dolomite crystal were identified as follows: dolomite tubes, dolomite cylinders, rhombohedral dolomite, spheroidal and quasi‐rhombohedral dolomite, and cocoon‐shaped dolomite. The dolomite cylinders and tubes are interpreted as the dolomitized cells of a widespread microbial community. The sequence of diagenetic processes started with growth of microlenticular interstitial gypsum in a calcareous mud deposited on the playa margin mudflats, and that sometimes included microbial sediments. Immediately following growth of gypsum, dolomite replaced the original calcite (or possibly aragonite) muds, the microbial community and the gypsum. Partial or total replacement of gypsum by dolomite was related mainly to the biomineralization of endolithic microbial communities on gypsum crystals. Later calcitization took place under vadose, subaerial exposure conditions. The development of calcrete in distal alluvial settings favoured the release of silica and subsequent silicification on the playa margin mudflats. Stable isotope compositions of calcite range from ?9·02 to ?5·83‰ δ13CPDB and ?7·10 to 1·22‰ δ18OPDB; for the dolomite, these values vary from ?8·93 to ?3·96‰ δ13CPDB and ?5·53 to 2·4‰ δ18OPDB. Quartz from the cherts has δ18OSMOW values ranging from 27·1 to 31·1‰. Wide variation and relatively high δ18OSMOW values for dolomite indicate evaporitic and closed hydrological conditions; increased influx of meteoric waters reigned during the formation of secondary calcite spar. 相似文献
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《Journal of Asian Earth Sciences》2002,20(3):277-287
Radiolarian biostratigraphic research has been carried out along two continuous sections through the Xialu Chert, one of the accreted sheets included in the Yarlung-Zangbo Suture Zone. Six radiolarian zones have been identified as follows: Laxtorum(?) jurassicum Zone (Aalenian), Tricolocapsa plicarum Zone (Bajocian–lower Bathonian), Stylocapsa(?) spiralis Zone (upper Callovian–Oxfordian), Hsuum maxwelli Zone (Kimmeridgian), Pseudodictyomitra carpatica Zone (upper Tithonian–lower Valanginian), and Turbocapsula costata Zone (Aptian).A reconstructed stratigraphy of the Xialu Chert, based on lithological succession and radiolarian dating, indicates that the chert exhibits a long depositional history, at least from early Middle Jurassic (Aalenian) to late Early Cretaceous (Aptian). The separation of the Lhasa Block from the northern Gondwana margin must, therefore, be dated before the Aalenian. The absence of calcareous sediments in the Xialu Chert indicates that the oceanic basin was deeper than the CCD throughout the depositional history. The transition from chert to siliceous mudstone is recorded sometime in Early Cretaceous, most probably around the Barremian/Aptian boundary. This means that the oceanic plate had already started being consumed at a trench by that time. The accretion of the Xialu Chert occurred after the Aptian time. 相似文献
20.
Black shales and carbon isotopes in pelagic sediments from the Tethyan Lower Jurassic 总被引：5，自引：1，他引：5
Detailed sampling and analysis of Jurassic pelagic limestones and marls from Italy, Hungary and Switzerland have enabled construction of an isotope stratigraphy across the Pliensbachian-Toarcian boundary with resolution to the zonal level. The oxygen-isotope record is unremarkable. The carbon isotopes, however, show two positive excursions: one, relatively minor, during the Pliensbachian, margaritatus Zone, subnodosus Subzone, the other, more major, during the Toarcian. early falciferum Zone, where a maximum δ13C value of 4·52%PDB is attained. These intervals are known to be favoured periods of organic-rich sedimentation in diverse parts of the globe and the isotopic excursions are interpreted as a response to abnormally high rates of storage of organic carbon in the sedimentary record. A comparable phenomenon has been documented from the Cenomanian-Turonian boundary in the Cretaceous where it has been referred to the influence of an ‘Oceanic Anoxic Event’. Some Italian sections spanning this Lower Jurassic interval contain organic-rich shales in the falciferum Zone; the isotopic signatures from their included, locally manganiferous carbonate betray a considerable diagenetic overprint and they cannot therefore be incorporated in a composite isotopic curve. Carbon isotopes from the organic carbon itself are extremely negative, falling to –33δPDB and, in one section examined in detail, correlate with the calcium-carbonate content of the shales; they may reflect a partial change to a non-calcified planktonic biota during deposition of this lime-poor interval, possibly responding to upwelling and increased fertility of near-surface waters. The onset of upwelling may have been as early as spinatum-tenuicostatum Zone time, that is, at the Pliensbachian-Toarcian boundary. 相似文献