首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Inclusion trails in garnet and albite porphyroblasts in the Fleur de Lys Supergroup preserve successive generations of microstructures, some of which correlate with equivalent microstructures in the matrix. Microstructure–porphyroblast relationships provide timing constraints on a succession of seven crenulation cleavages (S1–S7) and five stages of porphyroblast growth. Significant destruction and alteration of early fabrics has occurred during the microstructural development of the rock mass. Garnet porphyroblasts grew episodically through four growth stages (G1–G4) and preserve a succession of five fabrics (S1–S5) as inclusion trails. Garnet growth during each of the four growth phases did not occur on all pre-existing porphyroblasts, resulting in contrasting growth histories between individual garnet porphyroblasts from the same outcrop. Albite porphyroblasts grew during a single stage of growth and have overgrown microstructures continuous with the matrix. The garnet and albite porphyroblast inclusion trails record a succession of crenulation cleavages without any rotation of the porphyroblasts relative to other porphyroblasts in the population.
Complex microstructural histories are best resolved by preparing multiple oriented thin sections from a large number of samples of different rock types within the area of study. The succession of matrix foliations must be understood, as it provides the most useful time-frame against which to measure the relative timing of phases of porphyroblast growth. Comparable microstructures must be identified in different porphyroblasts and in the rock matrix.  相似文献   

2.
Abstract In the Fleur de Lys Supergroup, western Newfoundland, inclusion trails in garnet and albite porphyroblasts indicate that porphyroblasts overgrew a crenulation foliation, without rotation, probably during the deformation event that produced the crenulations. Further deformation of the matrix resulted in strong re-orientation and retrograde metamorphism of the matrix foliation, which is consequently highly oblique to the crenulation foliation preserved in the porphyroblasts. The resulting matrix foliation locally preserves relics of the early crenulations, and also has itself been crenulated later in places. Thus the porphyroblasts grew before the later stages of deformation, rather than during the final stage, as had been suggested previously. The new interpretation is consistent with available 40Ar/39Ar cooling ages which indicate a late Ordovician-early Silurian metamorphic peak, rather than the Devonian peak suggested by previous workers. The inclusion patterns and microprobe data indicate normal outward growth of garnet porphyroblasts from a central nucleus, rather than as a series of veins as proposed by de Wit (1976a, b). However, the observations presented here support growth of porphyroblasts without rotation, which is implied by the de Wit model.  相似文献   

3.
Chemical zoning in the outer few 10s of microns of garnet porphyroblasts has been investigated to assess the scale of chemical equilibrium with matrix minerals in a pelitic schist. Garnet porphyroblasts from the Late Proterozoic amphibolite facies regional metamorphic mica schists from Glen Roy in the Scottish Highlands contain typical prograde growth zoning patterns. Edge compositions have been measured via a combination of analysis of traverses across the planar edges of porphyroblast surfaces coupled to X-ray mapping of small areas within polished thin sections at the immediate edge of the porphyroblasts. These approaches reveal local variation in garnet composition, especially of grossular (Ca) and almandine (Fe) components, with a range at the edge from <7 mol.% grs to >16 mol.% grs, across distances of less than 50 µm. This small-scale patchy compositional zoning is as much variation as the core–rim compositional zoning across the whole of a 3 mm porphyroblast. Ca and Fe heterogeneity occurs on a scale suggesting a combination of inefficient diffusive exchange across grain boundaries during prograde growth and the evolving microtopography of the porphyroblast surface control garnet composition. The latter creates haloes of compositional zoning adjacent to some inclusions, which typically extend from the inclusion towards the porphyroblast edge during further growth. The lack of a consistent equilibrium composition at the garnet edge is also apparent in the internal zoning of the porphyroblast and so processes occurring during entrapment of some mineral inclusions have a profound influence on the overall chemical zoning. Garnet compositions and associated zoning patterns are widely used by petrologists to reconstruct P–T–t paths for crustal rocks. The evidence of extremely localized (10–50 µm scale) equilibrium during growth further undermines these approaches.  相似文献   

4.
The sequence of growth of garnet, staurolite and aluminosilicate in Fe-rich metapelitic rocks from the Canigou massif, Pyrenees, is established using evidence of inclusion, reaction and pseudomorphing textures between the different minerals, compositional zoning patterns in garnet and staurolite (that can be related to the KFMASH reaction grid), and the geometric relations between inclusion trails in the porphyroblasts and the matrix microstructures. The evidence indicates that garnet and staurolite commenced growth before aluminosilicate in all cases, even where all three are in textural equilibrium. Interpretation of the reaction textures between the porphyroblasts and of the compositional zoning in garnet and staurolite in terms of the KFMASH reaction grid indicates the importance of continuous reactions in the development of these phases. Some garnet and staurolite porphyroblasts underwent renewed growth during breakdown, producing rims enriched in Mn and Zn respectively. The presence of aluminosilicate in these assemblages (i.e. the absence of a clear andalusite-absent zone in the field) is attributed to a strong pressure-dependence for the aluminosilicate-producing reactions. Porphyroblast-matrix microstructural relations indicate that Hercynian metamorphism in the massif was synchronous with the development of the regional subhorizontal foliation (S3).  相似文献   

5.
Results from the modeling of compositional zoning patterns in garnet porphyroblasts from the medium-grade metapelitic schist of northern Ladoga area are considered. The P-T pseudosections in the model KMnFMASH system were calculated for this purpose using THERMOCALC software (Powell et al., 1998). Particular emphasis is placed upon the effect of garnet growth kinetics on the model zoning profiles for Mn (Gulbin, 2013). They fit the observed profiles if intergranular diffusion-controlled growth is assumed for porphyroblasts. Additionally, a model of metamorphic fractional crystallization is used to characterize the oscillations in both the garnet core and rim. Starting from the assumption that a reservoir, where garnet grows, consists of chlorite, and that this mineral is intensely replaced with biotite and staurolite at the onset of crystallization, a partial release of Mn from the chlorite structure and the concentration of this component in intergranular space is inferred. In terms of the model under consideration, the coefficient of the Mn partition between garnet and reservoir temporarily increases at the early stage of garnet growth, giving rise to the enrichment of the intermediate zone of porphyroblasts in Mn. In addition to the modeling of garnet growth zoning, its subsequent diffusion modification is estimated on the basis of intracrystalline diffusion profile simulation. The reverse zoned, Mn-rich and Mg-poor garnet rims are related to retrograde growth of garnet at the late stage of porphyroblast formation. The data obtained are used to constrain metamorphic evolution and the P-T-t path of staurolite-bearing rocks in the northern domain of the studied area.  相似文献   

6.
Abstract Albite porphyroblasts are widely distributed in pelitic and semi-pelitic schists of the Fleur de Lys Supergroup, western Newfoundland. Textures and mineral assemblages indicate that albite grew during nearly isothermal decompression from P-T conditions of about 500° C, 9 kbar, to conditions of 550° C, 6.5 kbar. Three compositional varieties of albite-bearing schists, here termed PMAQ (paragonite-muscovite-albite-quartz), MMAQ (microcline-muscovite-albite-quartz), and PMMQ (paragonite-muscovite-margarite-quartz), can be distinguished on the basis of pre-porphyroblast mineral assemblages. Analysis of these assemblages in terms of the composition of the coexisting fluid [log a (Na+/H+) versus log a (K+/H+)] suggests that, as pressure and temperature changed, the stability field of albite expanded at the expense of coexisting matrix phyllosilicates. This promoted growth of albite on pre-existing or newly formed nuclei. Late oligoclase in PMAQ and PMMQ samples is associated with replacement of matrix garnet by plagioclase + mica ° Chlorite, particularly in strongly sheared samples.  相似文献   

7.
New data strongly suggest that the classical spiral garnet porphyroblasts of south-east Vermont, USA, generally did not rotate, relative to geographical coordinates, throughout several stages of non-coaxial ductile deformation. The continuity of inclusion trails (Si) in these porphyroblasts is commonly disrupted by planar to weakly arcuate discontinuities, consisting of truncations and differentiation zones where quartz–graphite Si bend sharply into more graphitic Si. Discontinuous, tight microfold hinges with relatively straight axial planes are also present. These microstructures form part of a complete morphological gradation between near-orthogonally arranged, discontinuous inclusion segments and smoothly curving, continuous Si spirals. Some 2700 pitch measurements of well-developed inclusion discontinuities and discontinuous microfold axial planes were taken from several hundred vertically orientated thin sections of various strike, from specimens collected at 28 different locations around the Chester and Athens domes. The results indicate that the discontinuities have predominantly subvertical and subhorizontal orientations, irrespective of variations in the external foliation attitude, macrostructural geometry and apparent porphyroblast-matrix rotation angles. Combined with evidence for textural zoning, this supports the recent hypothesis that porphyroblasts grow incrementally during successive cycles of subvertical and subhorizontal crenulation cleavage development. Less common inclined discontinuities are interpreted as resulting from deflection of anastomosing matrix foliations around obliquely orientated crystal faces prior to inclusion. Most of the idioblastic garnet porphyroblasts have a preferred crystallographic orientation. Dimensionally elongate idioblasts also have a preferred shape orientation, with long axes orientated normal to the mica folia, within which epitaxial nucleation occurred. Truncations and differentiation zones result from the formation of differentiated crenulation cleavage seams against porphyroblast margins, in association with progressive and selective strain-induced dissolution of matrix minerals and locally also the porphyroblast margin. Non-rotation of porphyroblasts, relative to geographical coordinates, suggests that deformation at the microscale is heterogeneous and discontinuous in the presence of undeformed, relatively large and rigid heterogeneities, which cause the progressive shearing (rotational) component of deformation to partition around them. The spiral garnet porphyroblasts therefore preserve the most complete record of the complex, polyphase tectonic and metamorphic history experienced in this area, most of which was destroyed in the matrix by progressive foliation rotation and reactivation, together with recrystallization.  相似文献   

8.
Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe3+ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.  相似文献   

9.
Deformation-induced garnet zoning   总被引：1，自引：0，他引：1  
Hyeong Soo Kim   《Gondwana Research》2006,10(3-4):379-388
Compositional zoning patterns in garnet porphyroblasts from kyanite-bearing samples of the Devonian Littleton Formation, north-central Massachusetts, reveal complex patterns of growth that are related to multiple deformation and metamorphic events. Garnet porphyroblasts exhibit asymmetrical and irregular zoning patterns in XMn, XCa and Fe/(Fe + Mg). Zoning reversals in Mn and Fe/(Fe + Mg) and patch distribution in Ca appear to occur around the boundaries of the textural zones. Also, the compositions of the garnet at the textural boundaries are variable for all traverses. These observations suggest that the garnet zoning was not only modified from diffusion processes, but was also influenced by pre-existing microfabrics through the effects of preferential dissolution and resorption in partial disequilibrium. Relationships between chemical and textural truncations indicate that the zoning patterns of garnet were strongly modified from preferential dissolution and precipitation during the development of successive foliations that occurred in zones of high strain/stress (cleavage seams) and zones of low strain/stress, respectively.  相似文献   

10.
A prograde pressure–temperature (P–T) path is estimated for pelitic schists from the latest Precambrian Kokchetav ultrahigh-pressure massif, Kazakhstan, using compositional zoning and mineral inclusions in coarse-grained and inclusion-rich garnets. Ti-bearing inclusions are abundant in garnet and display a zonal distribution. Ilmenite occurs in the inner-core, where most of it makes a composite inclusion with rutile, whereas monomineralic rutile occurs in the outer-core to mantle domains. In the rim region both ilmenite and rutile are present, although in small amounts. Application of the ilmenite-garnet thermometer yields a systematic temperature increase towards rim from 500 to 750 °C. The pressure-sensitive reaction: 3 Fe-Ilm (in Ilm) + Ky + 2 Qtz = 3 Rt + Alm (in Grt) yielded pressures of 1.2–1.3 GPa for the outer-core inclusions.A petrogenetic grid in the K2O–CaO–FeO–MgO–Al2O3–SiO2–H2O model system was used to estimate the equilibrium compositions of the garnet. The change of the grossular component along the model P–T path expected from the forward modelling is close to the observed compositional profile of the outer-core to rim domains. No constraint is available from thermobarometry in the inner-core; however, the forward modelling of garnet zoning provides information on the early stage of the P–T path during the garnet growth.The estimated P–T path is counter-clockwise in the prograde stage with a steep bend at around 700 °C and 1.2–1.5 GPa. This is similar to the metamorphic P–T gradient of the Kokchetav massif. This result contrasts markedly with the traditional clockwise P–T path in many collisional metamorphic terranes, and is regarded to represent a subduction geotherm at the Precambrian–Cambrian boundary. The P–T path proposed in this study also supports the models for the recovery of the “snowball Earth” from late-Proterozoic glaciation through effect of water in the solid Earth mantle.  相似文献   

11.
The deformed and metamorphosed middle Pennsylvanian to Early Triassic (?) rocks of the Pyeongan Supergroup, occurring in northeastern flank of the Paleozoic Taebaeksan Basin, east central South Korea, record the impact of the Late Permian–Triassic Songrim (Indosinian) collisional orogeny in the eastern Eurasia margin. Analysis of meso- and microstructures and their relationship with porphyroblast growth has revealed that these metasedimentary rocks were affected by four deformation events (D1–D4). During the polyphase deformations, successive foliations with alternately steep (S1 and S3) and flat-lying (S2 and S4) orientations were produced with growth of chloritoid, andalusite and kyanite porphyroblasts during D1 and D2, and growth of garnet, staurolite and andalusite porphyroblasts during D3 and D4. SHRIMP U–Pb detrital zircon ages (330–310 Ma) from metapelites in the oldest unit of the Pyeongan Supergroup in the study area, combined with the previous data on sandstone compositions, indicate magmatic activity that was contemporaneous with the initial deposition of the Pyeongan Supergroup. This also suggests that the Pyeongan Supergroup was deposited in an arc-related foreland basin at an active continental margin during the Late Carboniferous and Permian time. Two contractional deformation events (D1 and D3) and two events related to gravitational flattening (D2 and D4), along with Barrovian-type medium-pressure regional metamorphism, may have resulted from the Late Permian–Triassic Songrim orogeny, related to collision between the North and South China blocks and/or collision between the Eastern Eurasia margin and the proto-Japan terrane.  相似文献   

12.
Metamorphic equilibration requires chemical communication between minerals and may be inhibited through sluggish volume diffusion and or slow rates of dissolution in a fluid phase. Relatively slow diffusion and the perceived robust nature of chemical growth zoning may preclude garnet porphyroblasts from readily participating in low‐temperature amphibolite facies metamorphic reactions. Garnet is widely assumed to be a reactant in staurolite‐isograd reactions, and the evidence for this has been assessed in the Late Proterozoic Dalradian pelitic schists of the Scottish Highlands. The 3D imaging of garnet porphyroblasts in staurolite‐bearing schists reveals a good crystal shape and little evidence of marginal dissolution; however, there is also lack of evidence for the involvement of either chlorite or chloritoid in the reaction. Staurolite forms directly adjacent to the garnet, and its nucleation is strongly associated with deformation of the muscovite‐rich fabrics around the porphyroblasts. “Cloudy” fluid inclusion‐rich garnet forms in both marginal and internal parts of the garnet porphyroblast and is linked both to the production of staurolite and to the introduction of abundant quartz inclusions within the garnet. Such cloudy garnet typically has a Mg‐rich, Mn‐poor composition and is interpreted to have formed during a coupled dissolution–reprecipitation process, triggered by a local influx of fluid. All garnet in the muscovite‐bearing schists present in this area is potentially reactive, irrespective of the garnet composition, but very few of the schists contain staurolite. The staurolite‐producing reaction appears to be substantially overstepped during the relatively high‐pressure Barrovian regional metamorphism reflecting the limited permeability of the schists in peak metamorphic conditions. Fluid influx and hence reaction progress appear to be strongly controlled by subtle differences in deformation history. The remaining garnet fails to achieve chemical equilibrium during the reaction creating distinctive patchy compositional zoning. Such zoning in metamorphic garnet created during coupled dissolution–reprecipitation reactions may be difficult to recognize in higher grade pelites due to subsequent diffusive re‐equilibration. Fundamental assumptions about metamorphic processes are questioned by the lack of chemical equilibrium during this reaction and the restricted permeability of the regional metamorphic pelitic schists. In addition, the partial loss of prograde chemical and textural information from the garnet porphyroblasts cautions against their routine use as a reliable monitor of metamorphic history. However, the partial re‐equilibration of the porphyroblasts during coupled dissolution–reprecipitation opens possibilities of mapping reaction progress in garnet as a means of assessing fluid access during peak metamorphic conditions.  相似文献   

13.
Quantitative compositional and microstructural analysis of garnet porphyroblasts in kyanite–staurolite–garnet grade rocks from the northeastern flank of the Pelham dome, north central Massachusetts, distinguishes the effects of Acadian deformation and metamorphism from extensive overprinting Alleghanian shearing. The P–T conditions and the metamorphic path during the Acadian were determined using samples preserving well defined stages in a lengthy tectonic history revealed by a succession of five foliation intersection axis trends preserved within porphyroblasts (FIAs). This Acadian succession extends at least 120 km to the north into rocks where no evidence has been found of an Alleghanian overprint. For each sample where garnet first nucleated during one of these stages in the tectonic history, the PT of core growth was determined by plotting the intersection of the Mn, Fe and Ca isopleths calculated for the core composition on a P–T pseudosection for that sample using THERMOCALC. Combining the PT data from all these samples indicates that the temperature and pressure increased throughout Acadian orogenesis, causing episodic garnet growth. During the Alleghanian, locally intense shearing, especially against the margin of the Pelham dome, formed the dominant schistosity, which truncated all foliations defined by inclusion trails in porphyroblasts and obliterated all remains of Acadian deformation and metamorphism in the rock matrix. Shearing was accompanied by near complete homogenization of the compositional zoning in garnet porphyroblasts and an associated apparent increase in the temperature of the matrix to 700°C in those rocks lying directly adjacent to the Pelham dome, and resulted from the rocks of the Northfield syncline being thrust a large distance southwards over the gneisses in the dome.  相似文献   

14.
Garnet porphyroblasts in sillimanite‐bearing pelitic schists contain complex textural and compositional zoning, with considerable variation both within and between adjacent samples. The sillimanite‐bearing schists locally occur in regional Barrovian garnet zone assemblages and are indicative of a persistent lack of equilibrium during prograde metamorphism. Garnet in these Dalradian rocks from the Scottish Highlands preserves evidence of a range of metamorphic responses including initial growth and patchy coupled dissolution–reprecipitation followed by partial dissolution. Individual porphyroblasts each have a unique and variable response to prograde metamorphism and garnet with mainly flat compositional profiles co‐exists with those containing largely unmodified characteristic bell‐shaped Mn profiles. This highlights the need for caution in applying traditional interpretations of effective volume diffusion eliminating compositional variation. Cloudy garnet with abundant fluid inclusions is produced during incomplete modification of the initial porphyroblasts and these porous garnet are then particularly prone to partial replacement in sillimanite‐producing reactions. The modification of garnet via a dissolution–reprecipitation process releases Ca into the effective whole‐rock composition, displacing the pressure–temperature positions of subsequent isograd reactions. This represents the first report of internal metasomatism controlling reaction pathways. The behaviour of garnet highlights the importance of kinetic factors, especially deformation and fluids, in controlling reaction progress and how the resulting variability influences subsequent prograde history. The lack of a consistent metamorphic response, within and between adjacent schists, suggests that on both local and regional scales these rocks have largely not equilibrated at peak metamorphic conditions.  相似文献   

15.
In a Barrovian metamorphic sequence, garnetiferous mica schists document a heterogeneously developed superposition of sub‐orthogonal fabrics and multiple garnet growth episodes. In the variably deformed domains, four types of garnet porphyroblasts have been defined based on inclusion trail patterns. Modelled garnet zoning in the MnNCKFMASHTO system indicates a prograde evolution from 4–4.5 kbar and 490–510 °C to 5–6 kbar and 520–550 °C in the earliest subhorizontal fabric progressing towards 6.5–7.5 kbar and 560–590 °C in the subsequent subvertical foliation. This fabric is heterogeneously deformed into a shallow‐dipping retrograde foliation associated with garnet resorption. In situ electron backscatter diffraction measurements of ilmenite inclusions in individual garnet grains yield precise data on included planar and linear elements. Consistent orientations of internal foliations, lineations and foliation intersection axis sets indicate a superposition of three sub‐orthogonal foliation systems. Weak variations of internal records with increasing intensity of deformation suggest that a moderate buckling stage occurred, but apparent lack of porphyroblast rotation is interpreted as a result of dominant passive flow. Coupling the orientation of internal fabric sets with P–T estimates is used to complement the tectono‐metamorphic evolution of the thickened crust. We demonstrate that garnet porphyroblasts preserve features which reflect large‐scale tectonic processes in orogens.  相似文献   

16.
A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO2‐rich to H2O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO2‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H2O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.  相似文献   

17.
The strong partitioning of many trace elements into garnet and their slow diffusivities in both garnet and the rock matrix means that their distribution may record valuable petrogenetic information not documented by major elements in metamorphic rocks. Complex trace element growth zoning in garnet porphyroblasts from a garnet-grade metapelite from the Barrovian sequence of the Sikkim Himalaya is assessed using quantified LA-ICP-MS raster mapping coupled with X-ray micro-computed tomography. The data document systematic changes in the zoning patterns from early- to late-nucleated crystals, and also suggest that the REE+Y chemistry incorporated into garnet is dependent on persistent disequilibrium in the rock volume. There is evidence for HREE+Y diffusion haloes surrounding growing garnets and a heterogeneous HREE+Y distribution in the rock matrix. Annuli superimposed on oscillatory zoning are not consistent with formation during some rock-wide event, but are dependent on the spatial disposition of the garnet. Annuli are interpreted to reflect an integrated history of varying growth rates and the incorporation of pre-existing heterogeneities due to relatively slow matrix diffusivities. Conversely, smooth zoning of many transition metals indicate that their distribution in garnet may be controlled by equilibrium partitioning between garnet and the rock matrix. Significant rotation of garnet porphyroblasts during growth is revealed due to immobility of Cr over the duration of the crystallisation interval and overprinting of the heterogenous precursor Cr distribution. Strain rate estimates derived from this zoning are on the order of \(10^{-11}\)–\(10^{-12}\, \hbox {s}^{-1}\).  相似文献   

18.
X‐ray composition maps and quantitative analyses for Mn, Ca and Cr have been made for six pelitic and calc‐pelitic garnet crystals and Al, Fe and Cr analyses maps have been made for two kyanite crystals, from lower and mid/upper amphibolite facies rocks from the Grenville Province of western Labrador, using an electron microprobe analyser and a laser ablation ICP‐MS. Garnet with spiral (‘snowball’) internal fabrics (Si) has spiral zoning in major elements, implying that growth was concentrated in discrete regions of the crystal at any one time (spiral zoning). Cr zoning is parallel to Si in low amphibolite facies garnet with both straight and spiral internal fabrics, indicating that the garnet overprinted a fabric defined by Cr‐rich (mica±chlorite±epidote) and Cr‐poor (quartz±plagioclase) layers during growth (overprint zoning) and that Cr was effectively immobile. In contrast, in mid/upper amphibolite facies garnet porphyroblasts lacking Si, Cr zoning is concentric, implying that Cr diffusion occurred. Cr zoning in kyanite porphyroblasts appears superficially similar to oscillatory zoning, with up to three or four annuli of Cr enrichment and/or depletion present in a single grain. However, the variable width, continuity, Cr concentration and local bifurcation of individual annuli suggest that an origin by overprint zoning may be more likely. The results of this study explain previously observed nonsystematic Cr zoning in garnet and irregular partitioning of Cr between coexisting metamorphic mineral pairs. In addition, this study points to the important role of crystal growth rate in determining the presence or absence of inclusions and the type of zoning exhibited by both major and trace elements. During fast growth, inclusions are preferentially incorporated into the growing porphyroblast and slow diffusing elements such as Cr are effectively immobile, whereas during slow growth, inclusions are not generally included in the porphyroblast and Cr zoning is concentric.  相似文献   

19.
A detailed investigation of the compositional variation in garnet has been undertaken in a garnet–pyroxene‐bearing granulite from the high‐grade Gföhl Unit, Moldanubian Zone, Lower Austria. Textural observations, together with the interpretation of the preserved garnet chemistry, enables the recognition of both prograde core and peak metamorphic garnet mantle growth stages, an extremely rare feature in high‐P–T granulite facies rocks. Initial thermobarometric calculations undertaken across whole garnet zoning profiles show how correct interpretation of a zoning profile is essential if the maximum peak metamorphic P–T conditions are to be recovered. The effect of retrograde decompression‐ and cooling‐driven reactions on inclusion and host garnet compositions has also been assessed. The results indicate that caution should be exercised when utilizing inclusion and adjacent garnet compositions for the thermobarometric evaluation of peak metamorphic equilibration conditions. Peak P–T conditions were determined by the TWEEQU thermobarometric method, utilizing the core compositions of matrix phases combined with the interpreted high‐P–T garnet mantle composition, to give 15.6 kbar and 1090 °C, consistent with previously determined results for Moldanubian granulites. Similar high‐P–T estimates are also provided by a re‐evaluation of previously published results for a granulite sample from the same lithological unit, using a modified interpretation of garnet and plagioclase compositional data. The new estimates presented confirm the previously disputed idea that the Gföhl Unit underwent a high‐pressure granulite facies stage and is therefore distinctly different from the underlying tectonostratigraphic units. It is emphasized that any interpretation of the peak metamorphic conditions in high‐grade rocks must be based on detailed petrographic observations combined with a thorough understanding of the co‐existing equilibrium mineral compositions.  相似文献   

20.
严溶  杨建军 《岩石学报》2013,29(5):1621-1633
青龙山部分榴辉岩以含绿帘石、蓝晶石和滑石变斑晶为特征,但是其峰变质矿物组合由基质中细粒的石榴石+绿辉石+多硅白云母+柯石英+金红石+绿帘石构成,它们定向分布形成片理构造。相图中石榴石组成等值线温压计确定的峰变质组合为:石榴石+绿辉石+多硅白云母+蓝晶石+金红石+柯石英+硬柱石+滑石,与岩相学观察结果不符。这可能是超高压变质流体显著偏离计算相图假设的流体相为纯水所致。无定向的变斑晶切割片理,晚于峰变质组合结晶于弱剪切应力的环境。岩相学观察和相图模拟结果显示,变斑晶的形成顺序为蓝晶石-绿帘石-滑石。绿帘石在<2GPa大量生长形成变斑晶,它包含柯石英并不一定说明二者平衡共生,更可能是温压快速下降后峰变质组合被绿帘石变斑晶包含。由矿物组合限定的青龙山变斑状榴辉岩P-T路径为典型的"发卡式"。含水矿物出现于岩石的各个变质组合,并且沿退变质P-T路径陆续结晶数量增多,表明在退变质过程中不断有流体渗入岩石。  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号