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1.
The partitioning of Sr between calcite, dolomite and liquids is essentially independent of temperature between 150° and 350° C. The partition coefficients corrected for number of cation sites are b calc=0.096 and b dol= 0.048 for 1 mol cations/6 mol H2O liquid. Upon dilution the partition coefficients increase, but their ratio stays constant at about 2∶1. This ratio is due to the fact that calcite has twice as many Ca-sites for Sr-substitution as dolomite. The 2∶1 relationship is also observed in natural calcite and dolomite which have undergone diagenesis. The temperature independence of partitioning is caused by the relatively small thermal expansion of calcite and dolomite. Thermal expansion between 25° and 400° C was found to follow the equations V calc=7.0·10−4 T(°C)+36.95 and V dol=6.9·10−4 T(°C)+32.24, V: cm3/mol. Therefore calcite and dolomite cannot serve as a temperature indicator. To have an ideal geothermometer a mineral pair with high and low thermal expansion is required. Literature date demonstrate that wurtzite, sphalerite, and galena are such minerals.  相似文献   

2.
Contrasting compositions and densities of fluid inclusions were revealed in siderite–barite intergrowths of the Dro?diak polymetallic vein hosted in Variscan basement of the Gemeric unit (Central European Carpathians). Primary two‐phase aqueous inclusions in siderite homogenized between 101 and 165 °C, total salinity ranged between 18 and 27 wt%, and CaCl2/(NaCl + CaCl2) weight ratios were fixed at 0.1–0.3. By contrast, mono‐ and two‐phase aqueous inclusions in barite exhibited total salinities between 2 and 22 wt%, and the CaCl2/NaCl ratios ranged from NaCl‐ to CaCl2‐dominated compositions. The aqueous inclusions in barite were closely associated with very high‐density (0.55–0.745 g cm?3) nitrogen inclusions, in some cases containing up to 16 mol.% CO2. Crystallization P–T conditions of siderite (175–210 °C, 1.2–1.7 kbar) constrained by the vertical oxygen isotope gradient along the studied vein, isochores of fluid inclusions and the K/Na exchange thermometer corresponded to minimal palaeodepths between 4.3 and 6.3 km, assuming lithostatic load and average crust density of 2.75 g cm?3. Maximum fluid pressure during barite crystallization attained 3.6–4.4 kbar at 200–300 °C, and the most dense nitrogen inclusions maintained without decrepitation the residual internal pressure of 2.2 kbar at 25 °C. Contrasting fluid compositions, increasing depths of burial (～4–14 km) and decreasing thermal gradients (～40–15 °C km?1) during initial mineralization stages of the Dro?diak vein reflect Alpine orogenic processes, rather than an incipient Permian rifting suggested in previous metallogenetic models. Siderite crystallized at rising P–T in a closed, rock‐buffered hydrothermal system developed in the Variscan basement during the north‐vergent Cretaceous thrusting and thickening of the Gemeric crustal wedge. Variable salinities of the barite‐hosted inclusions reflect a fluid mixing in open hydrothermal system, and re‐equilibration textures (lengths of decrepitation cracks proportional to fluid inclusion sizes) correspond to retrograde crystallization trajectory coincidental with transpression or unroofing. Maximum recorded fluid pressures indicate ～12‐km‐thick pile of imbricated nappe units accumulated over the Gemeric basement during the Cretaceous collision.  相似文献   

3.
Thirty‐three samples, including 22 eclogites, collected from the Dabie ultrahigh‐pressure (UHP) metamorphic belt in eastern China, have been studied for seismic properties. Compressional (Vp) and shear wave (Vs) velocities in three mutually perpendicular directions under hydrostatic pressures up to 1.0 GPa were measured for each sample. At 1.0 GPa, Vp (7.5–8.4 km s?1), Vs (4.2–4.8 km s?1), and densities (3.2–3.6 g cm?3) in the UHP eclogites are higher than those of UHP orthopyroxenite (7.3–7.5 km s?1, 4.1–4.3 km s?1, 3.2–3.3 g cm?3, respectively) and HP eclogites (7.1–7.9 km s?1, 4.0–4.5 km s?1, 3.1–3.5 g cm?3, respectively). Kyanitites (with 99.5% kyanite) show extremely high velocities and density (9.37 km s?1, 5.437 km s?1, 3.581 g cm?3, respectively). The eclogites show variation of Vp‐ and Vs‐anisotropy up to 9.70% and 9.17%, respectively. Poisson’s ratio (σ) ranges from 0.218 to 0.278 (with a mean of 0.255) for eclogites, 0.281–0.298 for granulites and 0.248 to 0.255 for amphibolites. The σ values for serpentinite (0.341) and marble (0.321) are higher than for other lithologies. The elastic moduli K, G, E of kyanitite were obtained as 163, 102 and 253 GPa, respectively. The Vp and density of representative UHP metamorphic rocks (eclogite & kyanitite) were extrapolated to mantle depth (15 GPa) following a reasonable geotherm, and compared to the one dimension mantle velocity and density model. The comparison shows that Vp and density in eclogite and kyanitite are greater than those of the ambient mantle, with differences of up to ΔVp > 0.3 km s?1 and Δρ > 0.3–0.4 g cm?3, respectively. This result favours the density‐induced delamination model and also provides evidence in support of distinguishing subducted high velocity materials in the upper mantle by means of seismic tomography. Such ultra‐deep subduction and delamination processes have been recognized by seismic tomography and geochemical tracing in the postcollisional magmatism in the Dabie region.  相似文献   

4.
We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp3‐bonded carbon, in most cases centred between 1332 and 1330 cm?1, with a full width at half maximum between 3 and 5 cm?1. Several spectra show Raman bands typical for disordered graphitic (sp2‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO2 and CH4 in polyphase inclusions. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.  相似文献   

5.
The partitioning of Fe and Zn between coexisting fahlore and sphalerite and fluid inclusions in sphalerite from the Darasun gold deposit have been studied. These data were used to estimate the formation temperature of the minerals by the sphalerite–fahlore geothermometer. The calculated crystallization temperature of 175–355°С is close to the homogenization temperature of fluid inclusions in sphalerite of 225–385°С.The estimated pressure for fluid inclusion trapping ranged from 340 to 1420 bar. The sulfur fugacity obtained from the FeS content in sphalerite associated with pyrite and the calculated temperature ranges from 10–5.5 to 10–11 bar.  相似文献   

6.
Simultaneous measurements of compressional and shear wave velocities, Vp and Vs, in acidic and basic igneous rocks and volcanic glasses, were made up to 900°C and at 10–20 kbar.The effects of pressure and temperature on Vp and Vs in glasses and glassy rocks change at about 600°C, presumably the glass transition temperature. These effects are directly related to the silica content in the samples. and for obsidian are negative at room temperature and 245°C, but are positive at 655°C. The velocity—pressure relations for obsidian display an obvious hysteresis phenomena. for basalt glass is slightly negative, but is positive for usual substances at room temperature, and for obsidian and glassy andesite are positive up to about 600°C but are negative above that temperature. However, for basalt glass as well as other crystalline rocks, and are negative at all temperatures. Glass once heated above the glass transition temperature Tg under pressure P1 retains the memory of pressure P1 after it is cooled down below Tg and while subjected to another pressure P2. An abrupt shift of the velocities correlating to pressure P2 occurs when the glass is again heated to Tg. Vp−T and Vs−T relations for obsidian, glassy andesite, and basalt glass clearly exhibit this pressure memory.  相似文献   

7.
Raman peaks of various hydrates in the H20-NaCl-CaCl2 system have been previously identified, but a quantitative relationship between the Raman peaks and XNaCl （i.e.,NaCl/ （NaCl＋CaCl2）） has not been established, mainly due to the difficulty to freeze the solutions. This problem was solved by adding alumina powder to the solutions to facilitate nucleation of crystals. Cryogenic （-185℃） Raman spectroscopic studies of alumina-spiced solutions indicate that XNaCl is linearly correlated with the total peak area fraction of hydrohalite. Capsules of solutions made from silica capillary were prepared to simulate fluid inclusions. Most of these artificial fluid inclusions could not be totally frozen even at temperatures as low as -185℃, and the total peak area fraction of hydrohalite is not correlated linearly with XNaCI. However, the degree of deviation （△XNaCl） from the linear correlation established earlier is related to the amount of residual solution, which is reflected by the ratio （r） of the baseline ＂bump＂ area, resulting from the interstitial unfrozen brine near 3435 cm^-1, and the total hydrate peak area between 3350 and 3600 cm^-1. A linear correlation between △XNaCl and r is established to estimate XNaCl from cryogenic Raman spectroscopic analysis for fluid inclusions.  相似文献   

8.
The position of the Raman methane (CH4) symmetric stretching band (ν1) over the range 1-650 bar and 0.3-22 °C has been determined using a high-pressure optical cell mounted on a Raman microprobe. Two neon emission lines that closely bracket the CH4 band were collected simultaneously with each CH4 spectrum. The peak position was determined after least squares fitting using a summed Gaussian-Lorentzian method, resulting in a precision of ≈±0.02 cm−1 in peak position determination. The CH4ν1 band position shifts to lower wave number with increasing pressure. At a given pressure, the band shifts to lower wave number with decreasing temperature, and the magnitude of the temperature shift increases with increasing pressure. The relationship between the Raman CH4ν1 band position and temperature and pressure determined here may be used to estimate the internal pressure in natural or synthetic CH4-bearing fluid inclusions. This information, in turn, may be used to determine the density of pure CH4 fluid inclusions and the salinity of CH4-bearing aqueous inclusions.  相似文献   

9.
The eclogite-facies metasedimentary rocks in the Münchberg gneiss complex (T=630±30° C/P17–24 kbar) locally contain CO2–N2-rich fluid inclusions of extremely low molar volumes (32 cm3/mol) in quartz. These fluid compositions are mainly found in rocks intercalated with calcsilicate bands. Densities were determined from low-temperature phase transitions like stable or metastable homogenization (L+VL), partial homogenization (S+L+VS+L) and the transition S+LL (L = liquid, V = vapour, S = solid). The high fluid densities are in agreement with eclogite-facies pressure and temperature and subsequent amphibolite facies. CO2–N2 inclusions were not observed in adjacent eclogites nor in non-calcareous metasediments. These rock types contain predominantly H2O-rich inclusions correlating with amphibolite-facies conditions. The variation of fluid composition with lithological differences indicates local fluid gradients and speaks against a pervasive fluid flow during eclogite-facies metamorphism.  相似文献   

10.
Three-phase NaCl-H2O fluid inclusions featuring halite dissolution temperature（Tm）higher than vapor bubble disappearance temperature（Th） are commonly observed in porphyry copper/molybdenum deposits,skarn-type deposits and other magmatic- hydrothermal ore deposits.Based on |ΔV1|（the absolute value of volume variation of NaCl-H2O solution in a heating or cooling process of inclusions）= |ΔVs|（the absolute value of volume variation of the halite crystal in a heating or cooling process of inclusions） and on the principle of conservation of the mass of NaCl and H2O,we systematically calculated the densities of NaCl-H2O solutions in the solid-liquid two-phase field for temperatures（Th） from 0.1℃ to 800℃ and salinities from 26.3 wt%to 99.2wt%.Consequently for the first time we obtained the upper limit of the density of NaCI-H2O solutions in the solid-liquid twophase field for Tbm inclusions with variant salinities.The results indicate that for inclusions of the Thm type with the same Th,the higher the Tm or salinity is,the higher the density of the NaClsaturated solution will be.If a group of fluid inclusions were homogeneously trapped,they must have the same Th value and the same Tm or salinity value.This may be used to distinguish homogeneous,inhomogeneous,and multiple entrapments of fluid inclusions.  相似文献   

11.
Raman microspectroscopy on carbonaceous material (RSCM) from the eastern Tauern Window indicates contrasting peak‐temperature patterns in three different fabric domains, each of which underwent a poly‐metamorphic orogenic evolution: Domain 1 in the northeastern Tauern Window preserves oceanic units (Glockner Nappe System, Matrei Zone) that attained peak temperatures (Tp) of 350–480 °C following Late Cretaceous to Palaeogene nappe stacking in an accretionary wedge. Domain 2 in the central Tauern Window experienced Tp of 500–535 °C that was attained either within an exhumed Palaeogene subduction channel or during Oligocene Barrovian‐type thermal overprinting within the Alpine collisional orogen. Domain 3 in the Eastern Tauern Subdome has a peak‐temperature pattern that resulted from Eo‐Oligocene nappe stacking of continental units derived from the distal European margin. This pattern acquired its presently concentric pattern in Miocene time due to post‐nappe doming and extensional shearing along the Katschberg Shear Zone System (KSZS). Tp values in the largest (Hochalm) dome range from 612 °C in its core to 440 °C at its rim. The maximum peak‐temperature gradient (≤70 °C km?1) occurs along the eastern margin of this dome where mylonitic shearing of the Katschberg Normal Fault (KNF) significantly thinned the Subpenninic‐ and Penninic nappe pile, including the pre‐existing peak‐temperature gradient.  相似文献   

12.
Abstract Standard petrographic, microthermometric and Raman spectroscopic analyses of fluid inclusions from the metamorphosed massive sulphide deposits at Ducktown, Tennessee, indicate that fluids with a wide range of compositions in the C–O–H–N–S–salt system were involved in the syn- to post-metamorphic history of these deposits. Primary fluid inclusions from peak metamorphic clinopyroxene contain low-salinity, H2O–CH4 fluids and calcite, quartz and pyrrhotite daughter crystals. Many of these inclusions exhibit morphologies resembling those produced in laboratory experiments in which confining pressures significantly exceed the internal pressures of the inclusions. Secondary inclusions in metamorphic quartz from veins, pods, and host matrix record a complex uplift history involving a variety of fluids in the C–O–H–N–salt system. Early fluids were generated by local devolatilization reactions while later fluids were derived externally. Isochores calculated for secondary inclusions in addition to the chronology of trapping and morphological features of primary and secondary fluid inclusions suggest an uplift path which was concave toward the temperature axis over the P–T range 6–3 kbar and 550–225° C. Immiscible H2O–CH4–N2–NaCl fluids were trapped under lithostatic to hydrostatic pressure conditions at 3–0.5 kbar and 215 ± 20° C. Entrapment occurred during Alleghanian thrusting, and the fluids may have been derived by tectonically driven expulsion of pore fluids and thermal maturation of organic material in lower-plate sedimentary rocks which are thought to underlie the deposits. Episodic fracturing and concomitant pressure decreases in upper-plate rocks, which host the ore bodies, would have allowed these fluids to move upward and become immiscible. Post-Alleghanian uplift appears to have been temperature-convex. Uplift rates of 0.10–0.05 mm year?1 from middle Ordovician to middle Silurian – late Devonian, and 0.07–0.12 mm year?1 from middle Silurian – late Devonian to late Permian are suggested by our uplift path and available geochronological data.  相似文献   

13.
The Polaris deposit is one of the largest Mississippi Valley-type deposits in the world, with 22 million tonnes of ore at 14% Zn and 4% Pb contained in a single, compact orebody surrounded by dolomitized host rocks. Using detailed sampling of carbonates in the orebody and the dolostone halo, this paper aims to characterize the temporal and spatial evolution of the mineralizing system, and to understand the mechanisms that controlled the accumulation of this large, compact Zn–Pb deposit. Five types of dolomite have been distinguished, including three replacement (RD) and two pore-filling dolomites (PD). The paragenetic order is RD1, RD2, RD3, PD1, and PD2. Pore-filling calcite (PC) postdates all other minerals. In most cases, sulfides and dolomite did not co-precipitate, but sphalerite and galena largely overlap with RD3 and PD1. Various dolomites are dissolved or replaced by sulfide-precipitating fluids; sulfides in turn can be overgrown by dolomites. Colloform texture in sphalerite is widespread. Fluid inclusions were studied in RD3, PD1, PD2, sphalerite, and PC. The overall ranges of homogenization temperatures (T h) and last ice-melting temperatures (T m-ice) for fluid inclusions in dolomites and sphalerite are from 67 to 141 °C and from −46.7 to −27.0 °C, respectively, consistent with warm basinal brines with high salinities and Ca/Na ratios. Gas chromatographic analysis of these fluid inclusions indicates low concentrations of hydrocarbons (<0.06 mol%). C, O, and Sr isotopes were analyzed for all dolomites and PC, as well as for the fine-grained host limestone and early diagenetic calcite (SC–RC). The isotopic values of RD2, RD3, PD1, and PD2 cluster tightly and form largely overlapping domains. With respect to the host limestone, they are depleted in 18O, similar in δ13C, and slightly enriched in 87Sr. There are no regular spatial variations for fluid inclusion and isotope data, indicating an overall geochemical homogeneity in the hydrothermal system. However, certain samples close to the fracture zones in the orebody with slightly elevated T h and 87Sr/86Sr values and depleted δ18O values suggest that the fracture zone was the conduit for the hot brines. Based on the geological and geochemical characteristics of the deposit, we propose that sulfide precipitation at Polaris was caused by mixing of a reduced, metal-rich, sulfur-poor fluid with a reduced, metal-poor, sulfur-rich fluid at the site of mineralization. The metal-carrying fluid ascended along fractures from below the deposit and was hotter than the host rocks, whereas the reduced sulfur-carrying fluid was delivered to the site of mineralization laterally and was in thermal equilibrium with the host rocks. This model can readily explain the dissolution of dolomite during sulfide precipitation and the abundance of colloform sphalerite, as well as the low concentrations of hydrocarbons in fluid inclusions. Accepted: 20 December 1999  相似文献   

14.
Potentiometric measurements were performed in the Cd(NO3)2-KCl-H2O system at 25°C and 1–1000 bar using an isothermal cell with a liquid junction and equipped with a solid contact Cd-selective electrode. At 1 bar, the stepwise equilibrium constant of the fourth cadmium chloride complex CdCl42− has been determined (log K40 = −0.88 ± 0.25). The pressure-dependent stability constants for all cadmium chloride complexes have been experimentally established for the first time. As pressure increases from 1 to 1000 bar, the stability constants for the first, third, and fourth complexes change by less than 0.05 logarithmic units, whereas that for the second complex decreases by 0.33 logarithmic units. On the basis of these data, the partial molar volumes of four cadmium chloride complexes have been determined under standard state conditions: V 0(CdCl+) = 2.20 ± 3, V 0(CdCl2 (aq)) = 42.21 ± 5, V 0(CdCl3−) = 63.47 ± 10, and V 0(CdCl42−) = 81.35 ± 15 cm3mol−1. The linear correlation between the nonsolvation contributions of molar volumes and the number of ligands corresponds to the change in coordination from octahedral in Cd2+ and CdCl+ to tetrahedral in CdCl2 (aq), CdCl3−, and CdCl42− complexes. Using theoretical correlations, the HKF parameters allowing calculation of the volumetric properties of cadmium chloride complexes in a wide range of temperature and pressure have been obtained. The pressure effect on cadmium concentration in sphalerite in equilibrium with the H2O-NaCl hydrothermal fluid has been estimated. It is shown that the Cd content in sphalerite increases with pressure.  相似文献   

15.
Acadian (Late Silurian to Early Devonian) metamorphism in the Central Maine Terrane (CMT) in central Massachusetts is characterized by an early low-P, high-T (Buchan-type) metamorphism followed by thickening at high temperature (>650d? C) and then by cooling to 100-200d? C below peak recorded temperatures before eventual unroofing. Mineralogical and textural evidence for this path includes sillimanite pseudomorphs after early andalusite, abundant cordierite in pelitic lithologies, replacement of low-P cordierite-bearing assemblages by high-P garnet-bearing assemblages, and recrystallization of mylonites associated with late shear zones to form lower-T and higher-P assemblages. Peak conditions in the highest grade rocks were 685-780d? C and 5-6 kbar; the cooling path passed through 550d? C at about 6.5 kbar. The well-constrained P-T path documented from geological and mineralogical evidence for the CMT offers an unusual opportunity to examine characteristics of fluid inclusions that have experienced a long-lived metamorphic event spanning a broad range of P-T conditions. Fluid inclusion data from the CMT document a range of fluid compositions (CO2-rich, mixed CO2-N2-rich, N2-rich and H2O-rich) and densities during metamorphism. Densities of CO2 fluid inclusions range from 0.20 to 1.03 g cm-3. Medium-density CO2 fluid inclusions are contained in quartz inclusions within garnets in partial melt leucosomes, and in quartz grains within migmatites. Fluid inclusions within the quartz inclusions indicate trapping conditions of 650-700d? C at pressures below 5 kbar. Other CO2 fluid inclusions from matrix quartz yield isochores which pass through 700d? C and 5.2 kbar. The highest density inclusions associated with rocks containing the late high-P assemblages have isochores which pass below the estimated P-T conditions for recrystallization of the mylonite. Fluid inclusion evidence suggests an early low-P heating event, followed by thickening at high temperature, and then by nearly isobaric cooling to about 500d? C with later decompression. This interpretation is also consistent with previously published petrological models and supports an anticlockwise P-T path for the CMT of south-central Massachusetts.  相似文献   

16.
The Sanbagawa belt is one of the famous subduction‐related high‐pressure (HP) metamorphic belts in the world. However, spatial distributions of eclogite units in the belt have not yet satisfactorily established, except within the Besshi region, central Shikoku, southwest Japan because most eclogitic rocks were affected by lower pressure overprinting during exhumation. In order to better determine the areal distribution of the eclogite units and their metamorphic features, inclusion petrography of garnet porphyroblasts using a combination of electron probe microanalyser and Raman spectroscopy was applied to pelitic and mafic schists from the Asemi‐gawa region, central Shikoku. All pelitic schist samples are highly retrogressed, and include no index HP minerals such as jadeite, omphacite, paragonite, or glaucophane in the matrix. Garnet porphyroblasts in pelitic schists occur as subhedral or anhedral crystals, and show compositional zoning with irregular‐shaped inner segments and overgrown outer segments, the boundary of which is marked by discontinuous changes in spessartine. This feature suggests that a resorption process of the inner segment occurred prior to the formation of the outer segment, indicating discontinuous crystallization between the two segments. The inner segment of some composite‐zoned garnet grains displays Mn oscillations, implying infiltration of metamorphic fluid during the initial exhumation stage. Evidence for an early eclogite facies event was determined from mineral inclusions (e.g., jadeite, paragonite, glaucophane) in the garnet inner segments. Mafic schists include no index HP minerals in the matrix as with pelitic schists. Garnet grains in mafic schists show simple normal zoning, recording no discontinuous growth during crystal formation. There are no index HP mineral inclusions in the garnet, and thus no evidence suggesting eclogite facies conditions. Quartz inclusions in garnet of the pelitic and mafic schists show residual pressure values (?ω1) of >8.5 cm?1 and <8.5 cm?1 respectively. The combination of Raman geobarometry and conventional thermodynamic calculations gives peak P–T conditions of 1.6–2.1 GPa at 460–520°C for the pelitic schists. The ?ω1 values of quartz inclusions in mafic schists are converted to a metamorphic pressure of 1.2–1.4 GPa at 466–549°C based on Raman geothermometry results. These results indicate that a pressure gap definitely exists between the mafic schists and the almost adjacent pelitic schists, which have experienced a different metamorphic history. Furthermore, the peak P–T values of the Asemi‐gawa eclogite unit are compatible with those of Sanbagawa eclogite unit in the Besshi region of central Shikoku, suggesting that these eclogite units share a similar P–T trajectory. The Asemi‐gawa eclogite unit exists in a limited area and is composed of mostly pelitic schists. We infer that these abundant pelitic schists played a key role in buoyancy‐driven exhumation by reducing bulk rock density and strength.  相似文献   

17.
Fluid inclusions in quartz grains from five samples of high-grade rocks (two paragneisses, an amphibolite, a mafic gneiss and a tonalite dike) from the 2.7 Ga Kapuskasing structural zone (KSZ), Ontario, were examined with petrographic, microthermometric and laser Raman techniques. Three types of fluid inclusions were observed: CO2-rich, H2O-rich and mixed CO2-H2O. CO2-rich fluid inclusions are pseudosecondary or secondary in nature and are generally pure CO2; a few contain varying amounts of CH4·H2O-rich fluid inclusions are secondary in nature, contain variable amounts of dissolved salts, and generally contain daughter crystals. Mixed CO2-H2O fluid inclusions occur where trails of H2O-rich inclusions intersect trails of CO2-rich inclusions. Isochores for high density (p=1.03 g/cm3) pseudosecondary, pure CO2 inclusions intersect the lower pressure portion of the estimated P-T field for high-grade metamorphism, implying that pure CO2 was the peak metamorphic fluid. The variable CH4 content of CO2 inclusions within graphite-bearing samples suggests that CH4 was introduced locally after the formation of the CO2 inclusions; however the origin of the CH4 remains problematic. An aqueous fluid clearly penetrated the gneisses after the peak metamorphism (during uplift/erosion), forming secondary inclusions and contributing to the minor retrogressive hydration observed in these rocks. The presence of the pseudosecondary, high-density CO2 inclusions in quartz crystals in the KSZ rocks constrains the uplift/ erosion path for the KSZ to one of simultaneous decrease in pressure and temperature.  相似文献   

18.
Fluid inclusion and sulphur isotope data for the discordant, metasediment-hosted massive sulphide deposit at Elura are consistent with a syntectonic origin of the orebodies. Thermometric and laser Raman microprobe analyses indicate that two-phase, primary fluid inclusions are low salinity and H2O-CO2-CH4 types. Inclusion fluids from quartz in ore yield homogenisation temperatures (Th) ranging from 298 ° to 354 °C (mean 320 °C). They are likely to have been trapped close to the solvus of the H2O-CO2-(CH4-NaCl) system and thus should give temperatures of the mineralising fluid. An additional, low Th population of later fluid inclusions is recognised in quartz from ore and syntectonic extension veins in the adjacent wallrock. Th's for these low CO2bearing inclusions range from 150 to 231 °C (mean 190 °C), and should be considerably lower than true trapping temperatures. Sulphur isotopic composition (34S) of pyrite, sphalerite, pyrrhotite and galena ranges from 4.7 to 12.6% and indicates a sulphur source from underlying Cobar Supergroup metasediments. An average temperature of 275 °C from the sphalerite-galena sulphur isotopic thermometer suggests isotopic re-equilibration below peak metamorphic temperatures.  相似文献   

19.
Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm?1, and additional vibrations at 480–485, 520–523 and 608 cm?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.  相似文献   

20.
The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing periods can be distinguished:the marine volcanic sedimentary PbZn mineralization period,and the metamorphic hydrothermal Cu mineralization period,which is further divided into an early bedded foliated quartz vein stage(Q1) and a late sulfide-quartz vein stage(Q2) crosscutting the foliation.Four types of fluid inclusions were recognized in the Q1 and Q2 quartz from the east orebodies of the Wulasigou deposit:H_2O-CO_2 inclusions,carbonic fluid inclusions,aqueous fluid inclusions,and daughter mineral-bearing fluid inclusions.Microthermometric studies show that solid CO_2 melting temperatures(T_(m,CO2)) of H_2O-CO_2 inclusions in Ql are from-62.3℃ to-58.5C,clathrate melting temperatures(T_(m,clath)l) are from 0.5 C to 7.5 C,partial homogenization temperatures(T_(h,CO2)) vary from 3.3℃ to 25.9℃(to liquid),and the total homogenization temperatures(T_(h,tot)) vary from 285℃ to 378℃,with the salinities being 4.9%-15.1%NaCl eqv.and the CO_2-phase densities being 0.50-0.86 g/cm~3.H_2O-CO_2 inclusions in Q2 have T_(m,CO_2) from-61.9℃ to-56.9℃,T_(m,clath)from 1.3℃ to 9.5℃,T_(h,CO2) from 3.4℃ to 28.7℃(to liquid),and T_(h,tot) from 242℃ to 388℃,with the salinities being 1.0%-15.5%NaCl eqv.and the CO_2-phase densities being 0.48-0.89 g/cm~3.The minimum trapping pressures of fluid inclusions in Q1 and Q2 are estimated to be 260-360 MPa and180-370 MPa,respectively.The δ~(34)S values of pyrite from the volcanic sedimentary period vary from2.3‰ to 2.8‰(CDT),and those from the sulfide-quartz veins fall in a narrow range of-1.9‰ to 2.6‰(CDT).The δD values of fluid inclusions in Q2 range from-121.0‰ to-100.8‰(SMOW),and theδ~(18)O_(H2O) values calculated from δ~(18)O of quartz range from-0.2‰ to 8.3‰(SMOW).The δD-δ~(18)O_(H2O)data are close to the magmatic and metamorphic fields.The fluid inclusion and stable isotope data documented in this study indicate that the vein-type copper mineralization in the Wulasigou Pb-Zn-Cu deposit took place in an orogenic-metamorphic enviroment.  相似文献   

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