首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 625 毫秒
1.
Many mid-ocean ridge basalts (MORBs) might be ultimately derived from primary magmas that are very depleted in Na2O and TiO2. These very depleted primary magmas have 0.60 to 1.50 wt.% Na2O and 0.10 to 0.50 wt.% TiO2 compared to MORBs, which typically have > 1.90% Na2O and >0.60% TiO2. Evidence for these depleted primary magma compositions is obtained from megacrysts in MORBs, from glass inclusions within these megacrysts, and from the highly calcic plagioclases (An91–96) and depleted clinopyroxenes (Na2O mostly between 0.10 and 0.35) in certain abyssal peridotites.Cumulate ultramanfi and gabbroic rocks from the North Arm Mountain Massif of the Bay of Islands ophiolite complex show a progressive increase in the Na2O and TiO2 abundances in clinopyroxene crystals with stratigraphic height in the ophiolite. The use of mineral-liquid distribution coefficients and cumulate mineral compositions indicate that the liquids from which these minerals crystallized had 0.10 to 0.20 wt.% TiO2 and 0.60 to 0.80 wt.% Na2O for the lowermost cumulate ultramafic rocks, with TiO2 and Na2O abundances of liquids increasing progressively to normal MORB abundances during crystallization of higher-level gabbroic cumulates. These data clearly demonstrate that primary basalts that are very depleted in Na2O and TiO2 can differentiate to form residual magmas that are indistinguishable from MORBs.  相似文献   

2.
The Neoarchean Bundelkhand greenstone sequences at Mauranipur and Babina areas within the Bundelkhand Gneissic Complex preserve a variety of magmatic rocks such as komatiitic basalts, basalts,felsic volcanic rocks and high-Mg andesites belonging to the Baragaon, Raspahari and Koti Formations.The intrusive and extrusive komatiitic basalts are characterized by low SiO_2(39-53 wt.%), high MgO(18-25 wt.%).moderately high Fe_2O_3(7.1-11.6 wt.%), Al_2O_3(4.5-12.0 wt.%), and TiO_2(0.4-1.23 wt.%)with super to subchondritic(Gd/Yb)N ratios indicating garnet control on the melts. The intrusive komatiitic suite of Ti-enriched and Al-depleted type possesses predominant negative Eu and positive Nb, Ti and Y anomalies. The chemical composition of basalts classifies them into three types with varying SiO_2, TiO_2, MgO, Fe_2O_3, Al_2O_3 and CaO. At similar SiO_2 content of type Ⅰ and Ⅲ basalts, the type II basalts show slightly high Al_2O_3 and Fe_2O_3 contents. Significant negative anomalies of Nb, Zr, Hf and Ti, slightly enriched LREE with relatively flat HREE and low ∑REE contents are observed in type Ⅰ and Ⅱ basalts. TypeⅢ basalts show high Zr/Nb ratios(9.8-10.4), TiO_2(1.97-2.04 wt.%), but possess strikingly flat Zr, Hf, Y and Yb and are uncontaminated. Andesites from Agar and Koti have high SiO_2(55-64 wt.%), moderate TiO_2(0.4-0.7 wt.%), slightly low Al_2O_3(7-11.9 wt.%), medium to high MgO(3-8 wt.%) and CaO contents(10-17 wt.%). Anomalously high Cr, Co and Ni contents are observed in the Koti rhyolites. Tholeiitic to calc alkaline affinity of mafic-felsic volcanic rocks and basalt-andesite dacite-rhyolite differentiation indicate a mature arc and thickened crust during the advanced stage of the evolution of Neoarchean Bundelkhand greenstone belt in a convergent tectonic setting where the melts were derived from partial melting of thick basaltic crust metamorphosed to amphibolite-eclogite facies. The trace element systematics suggest the presence of arc-back arc association with varying magnitudes of crust-mantle interaction. La/Sm, La/Ta,Nb/Th, high MgO contents(20 wt.%), CaO/Al_2O_3 and(Gd/Yb)_N 1 along with the positive Nb anomalies of the komatiite basalts reflect a mantle plume source for their origin contaminated by subductionmetasomatized mantle lithosphere. The overall geochemical signatures of the ultramafic-mafic and felsic volcanic rocks endorse the Neoarchean plume-arc accretion tectonics in the Bundelkhand greenstone belt.  相似文献   

3.
N. Hald  C. Tegner   《Lithos》2000,54(3-4):207-233
The Paleozoic–Mesozoic Jameson Land Basin (East Greenland) is intruded by a sill complex and by a swarm of ESE trending dykes. Together with dykes of the inner Scoresby Sund fjord, they form a regional Early Tertiary intrusive complex located 200–400 km inland of the East Greenland rifted continental margin. Most of the intrusive rocks in the Jameson Land Basin are geochemically coherent and consist of evolved plagioclase–augite–olivine saturated, uncontaminated high-Ti basalt with 48.5–50.2 wt.% SiO2, 2.2–3.2 wt.% TiO2, 5.1–7.4 wt.% MgO, 9–17 ppm Nb and La/YbN=2.8–3.6. Minor tholeiitic rock types are: (a) low-Ti basalt (49.7 wt.% SiO2, 1.7 wt.% TiO2, 6.8 wt.% MgO, 2.6 ppm Nb and La/YbN=0.5) akin to oceanic basalts; (b) very-high-Ti basalt (48.6 wt.% SiO2, 4.1 wt.% TiO2, 5.1 wt.% MgO and 21 ppm Nb); and (c) plagioclase ultraphyric basalt. The tholeiitic dolerites are cut by alkali basalt (43.7–47.3 wt.% SiO2, 4.1–5.1 wt.% TiO2, 4.9–6.2 wt.% MgO, 29–46 ppm Nb and La/YbN=16–17) sills and dykes.Modelling of high-field-strength and rare-earth elements indicate that the high-Ti basalts formed from 6–10% melting of approximately equal proportions of garnet- and spinel-bearing mantle of slightly depleted composition beneath thick continental lithosphere. Conversely, dolerite intrusions and flood basalts of similar compositional kindred from adjacent but more rift-proximal occurrences in Northeast Greenland formed from shallower melting of dominantly spinel-bearing mantle beneath extended and thinned continental lithosphere. These variations in lithospheric thickness suggest the continent–ocean transition of the East Greenland rifted volcanic margin is sharp and narrow.40Ar–39Ar dating and paleomagnetism show that the high-Ti dolerites were emplaced at 53–52 Ma (most likely during C23r) and hence surprisingly postdate the main flood volcanism by 2–5 Ma and the inception of seafloor spreading between Greenland and Europe by 1–2 Ma. The formation of tholeiitic and alkaline magmas emplaced into the Jameson Land Basin corroborates to the importance of post-breakup magmatism along the East Greenland volcanic rifted margin. Upwelling of the ancestral Iceland mantle plume under central Greenland at 53–52 Ma (rather than under the active rift), perhaps accompanied by a failed attempt to shift the rift zone westward towards the plume axis, may have triggered post-breakup continental magmatism of the Jameson Land Basin and the inner Scoresby Sund region, along preexisting structural lineaments.  相似文献   

4.
MORB suites display variations in their chemical differentiation trends which are closely related to the incompatible element enrichment of the basalts. We examine suites of primitive to evolved basalts from the Pacific-Nazca Ridge at 28° S (mostly depleted); from the Juan Fernandez microplate region (depleted) and from the Explorer Ridge, northeast Pacific (mostly enriched). Trends for incompatible element enriched MORBs consistently show less depletion of Al2O3 and less enrichment of FeO when plotted on MgO variation diagrams.Least squares modeling indicates that enriched basalts have undergone less plagioclase crystallization than depleted basalts especially in the early stages of differentiation. Using thermodynamic modelling, we show that variations between MORB differentiation trends result largely from differences in the major element chemistry and H2O content of primary magmas. Our chosen enriched and depleted near-primary magmas are similar in major element chemistry but the enriched near-primary magma has higher H2O and lower Al2O3 than the depleted near-primary magma. The MORB crystallization sequence is: olivineolivine+plagioclase olivine+plagioclase+high-Ca pyroxene; and the separate and combined effects of lower Al2O3 and higher H2O are to cause plagioclase to crystallize later (lower temperature), and to make the interval of olivine+plagioclase crystallization shorter. As a result, enriched differentiates have higher Al2O3 and lower FeO than depleted MORBs at a given MgO content, even though their parents' Al2O3 is lower. Crystallization of enriched basalts at higher pressure than depleted basalts is not able to account for differences between the differentiation trends because the proportion of plagioclase is higher during three-phase crystallization at high pressure.The variations in trends do not depend on geographic location and thus are superimposed on any regional variations in MORB chemistry or mantle source. Nor are they related to spreading rate. Depleted basalts from the fast-spreading 28° S and Juan Fernandez ridges have differentiation trends similar to depleted basalts from the medium-spreading Galapagos Spreading Center, whereas differentiation trends for enriched basalts from the medium-spreading Explorer Ridge are quite different. Fe3+/Fetotal is similar (and quite low) for enriched and depleted basalts, indicating that neither oxidation state nor early magnetite crystallization are important.  相似文献   

5.
Apatite preserves a record of the halogen and water fugacities that existed during the waning stages of crystallization of planetary magmas, when they became saturated in phosphates. We develop a thermodynamic formalism based on apatite-merrillite equilibria that makes it possible to compare the relative values of halogen and water fugacities in Martian, lunar and terrestrial basalts, accounting for possible differences in pressure, temperature and oxygen fugacities among the planets. We show that each of these planetary bodies has distinctive ratios among volatile fugacities at apatite saturation and that these fugacities are in some cases related in a consistent way to volatile fugacities in the mantle magma sources. Our analysis shows that the Martian mantle parental to basaltic SNC meteorites was dry and poor in both fluorine and chlorine compared to the terrestrial mantle. The limited data available from Mars show no secular variation in mantle halogen and water fugacities from ∼4 Ga to ∼180 Ma. The water and halogens found in present-day Martian surface rocks have thus resided in the planet’s surficial systems since at least 4 Ga, and may have been degassed from the planet’s interior during a primordial crust-forming event. In comparison to the Earth and Mars, the Moon, and possibly the eucrite parent body too, appear to be strongly depleted not only in H2O but also in Cl2 relative to H2O. Chlorine depletion is strongest in mare basalts, perhaps reflecting an eruptive process characteristic of large-scale lunar magmatism.  相似文献   

6.
Minor element abundances in olivines of the Sharps (H-3) chondrite   总被引：2，自引：0，他引：2  
Olivine crystals in 21 chondrules from the Sharps (H-3) chondrite were analyzed for CaO, Al2O3, Cr2O3, MnO, TiO2, NiO, and Na2O. The chondrules studied include representatives of all major types found in Sharps, and the mean fayalite contents of their olivine range from 1 to 28 %. Those olivines which contain less than 18 mol.% fayalite typically contain or occur with metallic nickel-iron; the others are metal-free.Na2O is below detectability (0.01 wt.%) in all cases, and the abundances of Al2O3, NiO and TiO2 are also typically very low. MnO varies simply and directly with FeO.Cr2O3 varies widely (0.03–0.21%) and several lines of evidence suggest that Cr is dominantly trivalent. It is concluded that FO 2 was rarely less than 10–11 atm. during the crystallization of the chondrules in Sharps.  相似文献   

7.
The chromiferous ultramafic rocks of Sukinda Valley (21°0'–21°5'N:85°43'–86°0'E) of Orissa are intrusive into the Iron-Ore Supergroup (2,950–3,200 Ma) at the eastern periphery of the Indian Precambrian shield. Both laterally and vertically, chromite occurs as persistent layers, lenses or pockets in the serpentinized and silicified dunite-peridotite extending over a strike length of 25 km. The ultramafic rocks and the chromitite layers are cofolded with the Iron-Ore Supergroup into a plunging syncline. Primary layering, ball and pillow structures, cross laminations, graded bedding etc. can also be detected. The different varieties of chromite ore present in the area are massive, banded and spotted, laminated and friable. The grain size of chromite varies between 0.25 and 4 mm, and the fineness of the grain increases from the bottom to the top layers. The cell dimension of chromite (8.23–8.32 Å) decreases with the increase of Al2O3.Cr2O3 in pure chromite varies between 48 to 61 wt. percent, Al2O3 is 7.10–15.09 wt. percent, whereas Fe2O3 is very low (0.03–3.20 wt. percent). The amount of RO to R2O3 varies within a narrow limit of 0.98–1.13, indicating that the chromite is chemically balanced. The FeO to MgO ratio is intermediate between the stratiform and alpine type. Fe3+ and Al3+ increase with respect to Cr3+ and Mg2+ in the upper chromitite layers. TiO2 lacks significant correlation with the major element composition of chromite.It is concluded that the Sukinda Valley chromitites of Orissa are predominantly stratiform in nature and were presumably formed in situ by crystal settling, the layering having been accentuated by the fluctuation of FO2. The geological features suggest a single magmatic cycle.  相似文献   

8.
The Betts Cove ophiolite, Newfoundland, consists of cumulate ultramafics, gabbro/clinopyroxenites, sheeted dikes and pillow lavas. The pillow lavas are divisible into three compositional groups: lower lavas (<0.25 wt.% TiO2), intermediate lavas (0.25–0.50 wt.% TiO2) and upper lavas (>0.7 wt.% TiO2). The lower and intermediate lavas are very depleted in Ti, Zr, Y, P, and REE and have high Al2O3/TiO2 ratios relative to normal oceanic tholeiite. The extreme depletion of these lavas and their dike equivalents (diabase and picrites) suggests they were derived by melting a severely depleted lherzolite. Conversely, the upper lavas, a volumetrically small part of the ophiolite, are compositionally similar to fractionated oceanic tholeiite and thus, their source material may be like that postulated for modern ocean floor basalts. Whereas the majority of basalts in the Betts Cove ophiolite are depleted in incompatible elements, most dikes and lavas from the Blow-MeDown ophiolite, western Newfoundland, are not and have incompatible element concentrations similar to modern oceanic tholeiite. The chemical differences between the two ophiolite massifs are related to melting of ultramafic source materials which are in different states of depletion brought about by previous melting episodes.  相似文献   

9.
The temperature effect on the exchange reaction Cr2O3(ol)=Cr2O3(px) was studied for coexisting olivine and both clino and ortho pyroxenes. The distribution of Cr between olivine and clinopyroxene in 31 coarse garnet lherzolites and 10 porphyroclastic garnet lherzolites from kinberlites, and in 17 coarse spinel lherzolites from basalts, obeys a van't Hoff relation (c.f. Stosch 1981) with the Wells two-pyroxene temperature: T(Kelvin)=8,787 (In D Cr+ 2.87) where D Cr(opx/ol)=wt.% Cr(clinopyroxene)/Cr(olivine). An analogous exchange for olivine and orthopyroxene with 0.7–1.6 wt.% Al2O3 in 41 garnet lherzolites from kimberlites shows considerable scatter about the following relation: T(Kelvin)=5,540/(ln D cr+1.86) where D cr(opx/ol)= wt.% Cr(orthopyroxene)/Cr(olivine). Spinel lherzolites and a garnet lherzolite from the Malaita alnöite do not obey the second relation. For orthopyroxene with 2.5–5.1 wt.% Al2O3, D cr(opx/ol) is 1.7 to 3 times higher, and for 0.1 wt.% Al2O3 is 2 times lower than for the garnet lherzolites. Experimental calibration is needed, especially to check the possible effect of Al on D cr(opx/ol).  相似文献   

10.
The 1.0-1.2 b.y. old rocks of the southeastern Llano Uplift, Texas include a 7 km thick sequence of amphibolite-grade, stratified, mafic metasedimentary rock (Packsaddle Schist) which is intruded by a varied suite of syntectonic and late-kinematic intrusions. The metasediments contain large blocks of serpentinized peridotite (Coal Creek serpentinite) and coarse hornblendite and metagabbro. Prior to the end of maximum deformation, the sequence was intruded by low to medium-K2O tholeiitic basalts (0.40-0.72% K2O). Late-kinematic low-K2O tholeiitic basalts (0.38-0.40% K2O) were intruded as dikes into the folded rocks. The Coal Creek serpentinite contains both syntectonic and late-kinematic low-K2O tholeiitic metabasalts (0.13–0.36% K2O). The Llano metabasalts and metagabbros are characterized by low Cr (67–378 ppm) and Ni (36–170 ppm), variable Rb (1.5–14.7 ppm), Sr (140–1229 ppm), TiO2 (0.40–2.20%), P (568–2707 ppm), and Zr (18–230 ppm), and Y (16–45 ppm), Co (40–57 ppm), and Sc (36–49 ppm) similar to modern MORB. The metabasalts have La abundances from 7 to 39 times chondritic and exhibit light REE enrichment with ¦La/Sm¦N from 1.13 to 1.45 and ¦La/Yb¦N from 1.12 to 2.99. The metabasalts show a strong correlation of increasing Zr, Ti, and Y and decreasing Eu/Eu* (1.56–1.00), CaO/TiO2, Al2O3/TiO2, and MgO/ MgO+FeO* with increasing REE enrichment (LaN). The Llano metabasalts and metagabbros have initial 87Sr/86Sr=0.7029±0.0001. A likely petrogenetic model for these metabasalts is an island arc in which events from early arc development to final late-kinematic intrusion were dominated by tholeiitic volcanism and intrusion. The chemical systematics of the Llano mafic metaigneous rocks suggest they are products of fractionation of olivine, clinopyroxene, and plagioclase from more primitive basaltic magmas generated beneath the island arc complex.  相似文献   

11.
月球表面的元素和物质成分分布是理解月球成岩与地质演化历史的重要线索。嫦娥一号干涉成像光谱仪(IIM)是我国首台月球探测成像光谱仪器,其获得的大量月球高光谱数据已成为我国未来探测月球成分与地质演化研究的宝贵基础数据。本文利用探月工程地面应用系统发布的IIM B版本2C级数据,开发出一套数据再定标流程,获得了较为可靠的月表相对反射率数据。我们在新校正数据的基础上开展月球表面FeO、TiO_2的反演建模,获得了全月FeO和TiO_2分布图,这些图件是进行月球地质填图的基础。校正数据反演的FeO和TiO_2分布与前人对Clementine UVVIS数据的反演结果相近,表明干涉成像光谱仪数据具有较大的应用潜力。高地的低铁岩石成分(一般小于8%)佐证了月球月壳形成的过程中的岩浆洋分异假说,而月海玄武岩的TiO_2成分变化范围较大(0~13%)则表明月海玄武岩来源于不同的月幔源区。根据嫦娥一号干涉成像光谱仪全月FeO分布图,可将月球表面物质类型总体划分为高地斜长岩和月海玄武岩,而根据TiO_2分布可以进一步将月海玄武岩划分为5种不同钛含量的玄武岩岩石类型。FeO和TiO_2在全月范围内的分布表明Apollo和Luna返回的月球样品不能够代表全月范围内的矿物成分多样性,月球岩浆演化历史比前人认为的要复杂。未来月球样品返回任务(如嫦娥五号)如能赴这些特殊地区进行取样,将很有可能返回重要的月球科学研究发现和成果。  相似文献   

12.
The Karoo volcanic sequence in the southern Lebombo monocline in Mozambique contains different silicic units in the form of pyroclastic rocks, and two different basalt types. The silicic units in the lower part of the Lebombo sequence are formed by a lower unit of dacites and rhyolites (67–80 wt.% SiO2) with high Ba (990–2500 ppm), Zr (800–1100 ppm) and Y (130–240 ppm), which are part of the Jozini–Mbuluzi Formation, followed by a second unit, interlayered with the Movene basalts, of high-SiO2 rhyolites (76–78 wt.%; the Sica Beds Formation), with low Sr (19–54 ppm), Zr (340–480 ppm) and Ba (330–850 ppm) plus rare quartz-trachytes (64–66 wt.% SiO2), with high Nb and Rb contents (240–250 and 370–381 ppm, respectively), and relatively low Zr (450–460 ppm). The mafic rocks found at the top of the sequence are basalts and ferrobasalts belonging to the Movene Formation. The basalts have roughly flat mantle-normalized incompatible element patterns, with abundances of the most incompatible elements not higher than 25 times primitive mantle. The ferrobasalt has TiO2  4.7 wt.%, Fe2O3t = 16 wt.%, and high Y (100 ppm), Zr (420 ppm) and Ba (1000 ppm). The Movene basalts have initial (at 180 Ma) 87Sr/86Sr = 0.7052–0.7054 and 143Nd/144Nd = 0.51232, and the Movene ferrobasalt has even lower 87Sr/86Sr (0.70377) and higher 143Nd/144Nd (0.51259). The silicic rocks show a modest range of initial Sr-(87Sr/86Sr = 0.70470–0.70648) and Nd-(143Nd/144Nd = 0.51223–0.51243) isotope ratios. The less evolved dacites could have been formed after crystal fractionation of oxide-rich gabbroic cumulates from mafic parental magmas, whereas the most silica-rich rhyolites could have been formed after fractional crystallization of feldspars, pyroxenes, oxides, zircon and apatite from a parental dacite magma. The composition of the Movene basalts imply different feeding systems from those of the underlying Sabie River basalts.  相似文献   

13.
Eighteen flows from a basal stratigraphic sequence on the Aleutian Island of Atka were analyzed for major elements, trace elements and initial 87Sr/86Sr ratios. Petrographically, these lavas contain abundant plagioclase (24–45%) and lesser amounts of olivine (<7%), magnetite and clinopyroxene phenocrysts. Compositionally, the lavas are high-alumina (20wt%) basalts (48–51 wt% SiO2) with low TiO2 (<1%) and MgO (<5%). Within the section, compositional variations for all major elements are quite small. While MgO content correlates with olivine phenocryst contents, no such relationship exists between the other oxides and phenocryst content. These lavas are characterized by 8–10 ppm Rb, high Sr (610–669 ppm), 308–348 ppm Ba and very constant Zr (23–29 ppm) and Sc (23–29 ppm) abundances. Ni and Cr display extremely large compositional ranges, 12–118 ppm and 12–213 ppm, respectively. No correlation exists between trace element concentrations and phenocryst contents. Strontium isotopic ratios show a small but significant range (0.70314–0.70345) and are slightly elevated with respect to typical MORB. No systematic correlation between stratigraphic position and petrography or geochemistry is evident. REE abundances measured on six samples are LREE enriched ((La/ Yb)N = 2.20–2.81) and display similar chondrite normalized patterns. One sample has a slight positive Eu anomaly but the other lavas do not. Compared to other Aleutian basalts of similar silica content, these lavas are less LREE enriched and have lower overall abundances. The geochemical characteristics of these basalts suggest they represent true liquid compositions despite their highly porphyritic nature. Published phase relations indicate fractionation of a more MgO-rich magma could not have produced these lavas. The high Al2O3 and low MgO and compatible element abundances suggest a predominantly oceanic crustal source for parental high-alumina basalts.  相似文献   

14.
Major element analyses of nineteen Luna 20 glass particles indicate that most of the Luna 20 glasses have Al2O3 contents greater than 21 wt.% and compositions similar to Apollo 10 and Luna 20 rocks and soils. Three of the glass particles have low Al2O3 (< 13 wt.%) and high FeO (> 18 wt.%) contents and were probably derived from one of the adjacent maria. The low glass content of the Luna 20 soil indicates that it is relatively young or less mature than most mare soils that have been studied.  相似文献   

15.
Oxygen and iron isotope analyses of low-Ti and high-Ti mare basalts are presented to constrain their petrogenesis and to assess stable isotope variations within lunar mantle sources. An internally-consistent dataset of oxygen isotope compositions of mare basalts encompasses five types of low-Ti basalts from the Apollo 12 and 15 missions and eight types of high-Ti basalts from the Apollo 11 and 17 missions. High-precision whole-rock δ18O values (referenced to VSMOW) of low-Ti and high-Ti basalts correlate with major-element compositions (Mg#, TiO2, Al2O3). The observed oxygen isotope variations within low-Ti and high-Ti basalts are consistent with crystal fractionation and match the results of mass-balance models assuming equilibrium crystallization. Whole-rock δ56Fe values (referenced to IRMM-014) of high-Ti and low-Ti basalts range from 0.134‰ to 0.217‰ and 0.038‰ to 0.104‰, respectively. Iron isotope compositions of both low-Ti and high-Ti basalts do not correlate with indices of crystal fractionation, possibly owing to small mineral-melt iron fractionation factors anticipated under lunar reducing conditions.The δ18O and δ56Fe values of low-Ti and the least differentiated high-Ti mare basalts are negatively correlated, which reflects their different mantle source characteristics (e.g., the presence or absence of ilmenite). The average δ56Fe values of low-Ti basalts (0.073 ± 0.018‰, n = 8) and high-Ti basalts (0.191 ± 0.020‰, n = 7) may directly record that of their parent mantle sources. Oxygen isotope compositions of mantle sources of low-Ti and high-Ti basalts are calculated using existing models of lunar magma ocean crystallization and mixing, the estimated equilibrium mantle olivine δ18O value, and equilibrium oxygen-fractionation between olivine and other mineral phases. The differences between the calculated whole-rock δ18O values for source regions, 5.57‰ for low-Ti and 5.30‰ for high-Ti mare basalt mantle source regions, are solely a function of the assumed source mineralogy. The oxygen and iron isotope compositions of lunar upper mantle can be approximated using these mantle source values. The δ18O and δ56Fe values of the lunar upper mantle are estimated to be 5.5 ± 0.2‰ (2σ) and 0.085 ± 0.040‰ (2σ), respectively. The oxygen isotope composition of lunar upper mantle is identical to the current estimate of Earth’s upper mantle (5.5 ± 0.2‰), and the iron isotope composition of the lunar upper mantle overlaps within uncertainty of estimates for the terrestrial upper mantle (0.044 ± 0.030‰).  相似文献   

16.
Geological, geochemical, and isotope (Sr, Nd, and O) parameters of Early Devonian (405 Ma) volcanics of southeastern Gorny Altai (Aksai and Kalguty volcanotectonic structures) are discussed. The studied igneous rock association comprises magnesian andesitoids, Nb-enriched andesite basalts, and A-type peraluminous silicic rocks (dacites, rhyolites, granites, and leucogranites). Magnesian andesitoids (mg# > 50) are characterized by a predominance of Na among alkalies (K2O/Na2O ≈ 0.1-0.7), medium contents of TiO2 (~ 0.8-1.3 wt.%) and Al2O3 (~ 12-15 wt.%), enrichment in Cr (up to 216 ppm), and low Sr/Y ratios (4-15). The Nb-enriched (Nb = 10-17 ppm) andesite basalts have high contents of TiO2 (1.7-2.7 wt.%) and P2O5 (0.4-1.4 wt.%). The A-type granitoids are characterized by high contents of K(K2O/Na2O ≤ 60) and alumina (ASI ≤ 2.9) and depletion in Ba, Sr, P, and Ti. The magnesian andesitoids and Nb-enriched andesite basalts are products of melts generated in the metasomatized lithospheric mantle; silicic magmas were formed through the melting of Cambrian-Ordovician metaturbidites of the Gorny Altai Group and, partly, Early-Middle Cambrian island-arc metabasites. The above rock association might have resulted from a plume impact on the lithospheric substrates of the continental paleomargin during the evolution of the Altai-Sayan rift system.  相似文献   

17.
The Xigaze ophiolite in the central part of the Yarlung–Zangbo suture zone, southern Tibet, has a well-preserved sequence of sheeted dykes, basalts, cumulates and mantle peridotites at Jiding and Luqu. Both the basalts and diabases at Jiding have similar compositions with SiO2 ranging from 45.9 to 53.5 wt%, MgO from 3.1 to 6.8 wt% and TiO2 from 0.87 to 1.21 wt%. Their Mg#s [100Mg/(Mg + Fe)] range from 40 to 60, indicating crystallization from relatively evolved magmas. They have LREE-depleted, chondrite-normalized REE diagrams, suggesting a depleted mantle source. These basaltic rocks have slightly negative Nb- and Ti-anomalies, suggesting that the Xigaze ophiolite represents a fragment of mature MORB lithosphere modified in a suprasubduction zone environment. The mantle peridotites at Luqu are high depleted with low CaO (0.3–1.2 wt%) and Al2O3 (0.04–0.42 wt%). They display V-shaped, chondrite-normalized REE patterns with (La/Gd)N ratios ranging from 3.17 to 64.6 and (Gd/Yb)N from 0.02 to 0.20, features reflecting secondary metasomatism by melts derived from the underlying subducted slab. Thus, the geochemistry of both the basaltic rocks and mantle peridotites suggests that the Xigaze ophiolite formed in a suprasubduction zone.Both the diabases and basalts have Pd/Ir ratios ranging from 7 to 77, similar to MORB. However, they have very low PGE abundances, closely approximating the predicted concentration in a silicate melt that has fully equilibrated with a fractionated immiscible sulfide melt, indicating that the rocks originated from magmas that were S-saturated before eruption. Moderate degrees of partial melting and early precipitation of PGE alloys explain their high Pd/Ir ratios and negative Pt-anomalies. The mantle peridotites contain variable amounts of Pd (5.99–13.5 ppb) and Pt (7.92–20.5 ppb), and have a relatively narrow range of Ir (3.47–5.01 ppb). In the mantle-normalized Ni, PGE, Au and Cu diagram, they are relatively rich in Pd and depleted in Cu. There is a positive correlation between CaO and Pd. The Pd enrichment is possibly due to secondary enrichment by metasomatism. Al2O3 and Hf do not correlate with Ir, but show positive variations with Pt, Pd and Au, indicating that some noble metals can be enriched by metasomatic fluids or melts carrying a little Al and Hf. We propose a model in which the low PGE contents and high Pd/Ir ratios of the basaltic rocks reflect precipitation of sulfides and moderate degrees of partial melting. The high Pd mantle peridotites of Xigaze ophiolites were formed by secondary metasomatism by a boninitic melt above a subduction zone.  相似文献   

18.
Two kimberlite pipes in Elliott County contain rare ultramafic xenoliths and abundant megacrysts of olivine (Fo85–93), garnet (0.21–9.07% Cr2O3), picroilmenite, phlogopite, Cr-poor clinopyroxene (0.56–0.88% Cr2O3), and Cr-poor orthopyroxene (<0.03–0.34% Cr2O3) in a matrix of olivine (Fo88–92), picroilmenite, Cr-spinel, magnetite, perovskite, pyrrhotite, calcite, and hydrous silicates. Rare clinopyroxene-ilmenite intergrowths also occur. Garnets show correlation of mg (0.79–0.86) and CaO (4.54–7.10%) with Cr2O3 content; the more Mg-rich garnets have more uvarovite in solution. Clinopyroxene megacrysts show a general decrease in Cr2O3 and increase in TiO2 (0.38–0.56%) with decreasing mg (0.87–0.91). Clinopyroxene megacrysts are more Cr-rich than clinopyroxene in clinopyroxene-ilmenite intergrowths (0.06–0.38% Cr2O3) and less Cr-rich than peridotite clinopyroxenes (1.39–1.46% Cr2O3). Orthopyroxene megacrysts and orthopyroxene inclusions in olivine megacrysts form two populations: high-Ca, high-Al (1.09–1.16% CaO and 1.16–1.18% Al2O3) and low-Ca, low-Al (0.35–0.46% CaO and 0.67–0.74% Al2O3). Three orthopyroxenes belonging to a low-Ca subgroup of the high-Ca, high-Al group were also identified (0.86–0.98% CaO and 0.95–1.01% Al2O3). The high-Ca, high-Al group (Group I) has lower mg (0.88–0.90) than low-Ca, low-Al group (Group II) with mg=0.92–0.93; low mg orthopyroxenes (Group Ia) have lower Cr2O3 and higher TiO2 than high mg orthopyroxenes (Group II). The orthopyroxene megacrysts have lower Cr2O3 than peridotite orthopyroxenes (0.46–0.57% Cr2O3). Diopside solvus temperatures indicate equilibration of clinopyroxene megacrysts at 1,165°–1,390° C and 1,295°–1,335° C for clinopyroxene in clinopyroxene-ilmenite intergrowths. P-T estimates for orthopyroxene megacrysts are bimodal: high-Ca, high-Al (Group I) orthopyroxenes equilibrated at 1,165°–1,255° C and 51–53 kb (± 5kb) and the low-Ca, low-Al (Group II) orthopyroxenes equilibrated at 970°–1,020°C and 46–56 kb (± 5kb). Garnet peridotites equilibrated at 1,240°–1,360° C and 47–49 kb. Spinel peridotites have discordant temperatures of 720°–835° C (using spinel-olivine Fe/Mg) and 865°–1,125° C (Al in orthopyroxene).Megacrysts probably precipitated from a fractionating liquid at >150 km depth. They are not disaggregated peridotite because: (1) of large crystal size (up to 1.5 cm), (2) compositions are distinctly different from peridotite phases, and (3) they display fractionation trends. The high mg, low T orthopyroxenes and the clustering of olivine rims near Fo89–90 reflect liquid changes to higher MgO contents due to (1) assimilation of wall-rock and/or (2) an increase in Fe3+/Fe2+ and subsequently MgO/FeO as a result of an increase in f o.  相似文献   

19.
New data is presented for five evolved, low-Ti lunar mare basalt meteorites from the LaPaz Icefield, Antarctica, LAP 02205, LAP 02224, LAP 02226, LAP 02436, and LAP 03632. These basalts have nearly identical mineralogies, textures, and geochemical compositions, and are therefore considered to be paired. The LaPaz basalts contain olivine (Fo64-2) and pyroxene (Fs32Wo8En60 to Fs84-86Wo15En2-0) crystals that record extreme chemical fractionation to Fe-enrichment at the rims, and evidence for silicate liquid immiscibility and incompatible element enrichment in the mesostasis. The basalts also contain FeNi metals with unusually high Co and Ni contents, similar to some Apollo 12 basalts, and a single-phase network of melt veins and fusion crusts. The fusion crust has similar chemical characteristics to the whole rock for the LaPaz basalts, whereas the melt veins represent localized melting of the basalt and have an endogenous origin. The crystallization conditions and evolved nature of the LaPaz basalts are consistent with fractionation of olivine and chromite from a parental liquid similar in composition to some olivine-phyric Apollo 12 and Apollo 15 basalts or lunar low-Ti pyroclastic glasses. However, the young reported ages for the LaPaz mare basalts (∼2.9 Ga) and their relative incompatible element enrichment compared to Apollo mare basalts and pyroclastic glasses indicate they cannot be directly related. Instead, the LaPaz mare basalts may represent fractionated melts from a magmatic system fed by similar degrees of partial melting of a mantle source similar to that of the low-Ti Apollo mare basalts or pyroclastic glasses, but which possessed greater incompatible element enrichment. Despite textural differences, the LaPaz basalts and mare basalt meteorite NWA 032 have similar ages and compositions and may originate from the same magmatic system on the Moon.  相似文献   

20.
The late Archaean volcanic rocks of the Rwamagaza area in the Sukumaland Greenstone Belt consists of basalts and basaltic andesites associated with volumetrically minor rhyodacites and rhyolites. Most basalts and basaltic andesites yield nearly flat patterns (La/SmCN = 0.89–1.34) indicating derivation by partial melting of the mantle at relatively low pressure outside the garnet stability field. On primitive mantle normalized trace element diagrams, the basalts and basaltic andesites can be subdivided into two groups. The first group is characterised by moderately negative Nb anomalies (Nb/Lapm = 0.51–0.73, mean = 0.61 ± 0.08) with slight enrichment of LREE relative to both Th and HREE. The second group is characterised by nearly flat patterns with no Nb anomalies (Nb/Lapm = 0.77 ± 0.39). The observed Nb and Th anomalies in the Rwamagaza basalts and basaltic andesites, cannot be explained by alteration, crustal contamination or melt–solid equilibria. Rather, the anomalies are interpreted, on the basis of Nb–Th–La–Ce systematics, as having formed by partial melting of a heterogeneous mantle consisting of variable mixtures of components derived from two distinct sources. These sources are depleted mantle similar to that generating modern MORB and an LREE-enriched and HFSE-depleted source similar to that feeding volcanism along modern convergent margins.The rhyolites are characterised by high Na2O/K2O ratios (>1) and Al2O3 (>15 wt.%), low HREE contents (Yb = 0.24–0.68 ppm) leading to highly fractionated REE patterns (La/YbCN = 18.4–54.7) and large negative Nb anomalies (Nb/Lapm = 0.11–0.20), characteristics that are typical of Cenozoic adakites and Archaean TTG which form by partial melting of the hydrated basaltic crust at pressures high enough to stabilize garnet ± amphibole. The Rwamagaza basalts and basaltic andesites are geochemically analogous to the Phanerozoic Mariana Trough Back Arc Basin Basalts and the overall geochemical diversity of Rwamagaza volcanic rocks is interpreted in terms of a geodynamic model involving the interaction of a depleted mantle, a melting subducting oceanic slab in a back arc setting.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号