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1.
The purpose of this work was to reinvestigate the existing hydrogeological conceptual model of the basin of Madrid, Spain. A cumulative chemical isotopic diagram which enabled the distinction between different groups of water as well as calculation of the mode of their blending was used for this investigation. It was found that the groups of discharge were lighter in their isotopic composition than that of recharge. The previous explanation of this fact, backed by carbon-14 dating, was the long residence time due to flow lines going down to depths of more than 1000 m. This flow model assumes homogenous conditions to these depths. This assumption can not be supported by evidence from deep wells. Thus a modified model is suggested which maintains homogenous conditions only to about 300 m and a deep confined aquifer below containing paleowater. The higher degree of depletion of this water has been explained by a colder climate on top of an altitude effect. Another interesting observation was the correlation between the isotopic composition of the rains, the month of the rain event and the composition of the recharge group groundwater. It could be seen that the winter rains resemble the groundwater composition, which shows that practically all the spring and summer rains were evapotranspirated.  相似文献   

2.
拒马源泉群作为拒马河的源头,受到了较多专家和学者的关注。但这些研究多集中在地下水的水化学、水位动态、泉流量等特征上,对地下水氢氧同位素特征的分析几乎没有,且对北海泉的成因解释多为粗略的定性概述。为了说明涞源北盆地地下水的氢氧同位素特征,详细揭示北海泉的形成模式,首次系统地采集了不同含水岩组的地下水样品,测定了水样的氢氧同位素组分。结果表明:样品点δD和δ18O值均落在区域大气降水线上或附近,大气降水是研究区地下水的主要补给来源;白云岩、灰岩含水岩组高程效应较明显,径流途径长,松散含水层径流途径短,受蒸发作用较强;白云岩、灰岩含水岩组和松散含水层氘盈余d值分别为6.0‰～11.6‰、4.2‰～11.2‰、3.8‰～8.0‰,较大气降水大部分偏小,表明岩溶水和松散孔隙水经历了不同的流动过程;白云岩、灰岩含水岩组从补给区向排泄区各自流动过程中,在小西庄、香炉屯村附近断裂带发生沟通混合,然后在向盆地中心径流过程中受断层阻水上升,上升过程中又接受了松散孔隙水的补给,最后在松散岩层中出露成泉,形成北海泉。在孔隙水混入前,两者的平均补给比例大约为48.4%～57.6%和42.4%～51.6%。  相似文献   

3.
Potassium chloride (KCl) and potassium bromide (KBr) tracers were used to explore the role of geologic structure on groundwater recharge and flow at the Fractured Rock Research Site in Floyd County, Virginia, USA. Tracer migration was monitored through soil, saprolite, and fractured crystalline bedrock for a period of 3 months with chemical, physical, and geophysical techniques. The tracers were applied at specific locations on the ground surface to directly test flow pathways in a shallow saprolite and deep fractured-rock aquifer. Tracer monitoring was accomplished with differential electrical resistivity, chemical sampling, and physical monitoring of water levels and spring discharge. KCl, applied at a concentration of 10,000 mg/L, traveled 160 m downgradient through the thrust fault aquifer to a spring outlet in 24 days. KBr, applied at a concentration of 5,000 mg/L, traveled 90 m downgradient through the saprolite aquifer in 19 days. Tracer breakthrough curves indicate diffuse flow through the saprolite aquifer and fracture flow through the crystalline thrust fault aquifer. Monitoring saline tracer migration through soil, saprolite, and fractured rock provided data on groundwater recharge that would not have been available using other traditional hydrologic methods. Travel times and flowpaths observed during this study support preferential groundwater recharge controlled by geologic structure.  相似文献   

4.
The deterioration of groundwater quality, particularly due to salinization, because of the overexploitation of groundwater in the Lower Central Plain of Thailand remains a major concern. With increasing demand for water there is a growing need for sustainable management of the resource, which would benefit from an improved understanding of the sources of chloride contamination. Thus, a hydrochemical and isotopic study was carried out to chemically characterize groundwater and to investigate possible sources of salinization, and in particular of chloride contamination, in the multi-layered Bangkok aquifer system. Groundwater samples were taken from four topmost aquifers (Bangkok, Phra Pradaeng, Nakhon Luang, and Nonthaburi). Additionally, short-term rainwater sampling, as well as river and seawater sampling was performed and later analyzed for ionic composition and stable water isotopes. Ionic and isotopic data indicate at least three different recharge sources for groundwater. The major recharge source is rainwater. The influence of seawater is limited to the coastal region and tidally influenced areas of the two main rivers (Chao Phraya and Tha Chin). Bromide data also suggest the influence of saline water in deeper aquifers due to trapped water. Most importantly, although the influence of seawater on groundwater is recognizable, the surrounding geology contributes a significant number of dissolved ions detected in the groundwater.  相似文献   

5.
河水入渗补给是傍河水源地的主要补给来源,确定河水补给强度对于促进水源地长期安全的开采具有十分重要的意义。以沈阳黄家水源地为研究区,通过对比研究区河水、地下水的水化学及氢氧稳定同位素特征,分析了水源地地下水的补给来源及强度。结果表明:傍河水源地地下水主要接受河水的入渗补给和区域地下水的侧向补给;受河床沉积物和含水介质的岩性及结构在空间上的差异影响,河水入渗补给后在向地下水位漏斗中心流动的过程中具有浅层和深层两条地下水流路径,深层地下水与河水的水力联系更为紧密;河水对地下水的补给强度具有明显的时空变化特点,表现为雨季河水入渗强度明显大于旱季,并且随着与辽河距离的增加,水源地地下水获得的河水补给量呈逐渐减小的趋势。  相似文献   

6.
Rock water interactions play an important role in the flow of groundwater. Groundwater samples were collected from deep production wells with depths ranging from 120 to 230 m. Complete chemical analysis of 40 groundwater samples was collected from the fractured limestone aquifer including major cations (Na+, K+, Ca2+, Mg2+) and major anions (Cl?, SO4 2?, HCO3 ?, CO3 2?). A geochemical modeling (NETPATH Software) was applied for environmental simulate net geochemical mass-balance reactions between initial and final waters along a hydrologic flow path. This program simulates selected evolutionary waters for every possible combination of the plausible phases that account for the composition of a selected set of chemical constraints in the system. The groundwater of the Eocene aquifer mainly belongs to fairly fresh water with salinity contents ranging from 228 to 3595 ppm. The measured groundwater levels range between 8 and 25 m near the river Nile to the limestone plateau (eastwards). Consequently, groundwater flows from east to westward toward the river Nile. Groundwater aquifer in the study area is mainly composed of fractured limestone; the saturated states of the PCO2, calcite, aragonite, dolomite, siderite, gypsum, anhydrite, hematite, and goethite in addition to H2 gas were estimated. The undersaturated state of carbon dioxide reflects closed conditions and very low probability of recent recharge, and it reveals also the high tendency of water to precipitates carbonate species. Undersaturation by carbonate minerals is only restricted to some pockets distributed on the different places of the aquifer in the study area. The majority of groundwater samples of Eocene aquifer in the study area indicated that groundwater is not suitable for irrigation with treatment and requires good drainage.  相似文献   

7.
A hydrochemical investigation was conducted in the Ejina Basin to identify the hydrochemical characteristics and the salinity of groundwater. The results indicate that groundwater in the area is brackish and are significantly zonation in salinity and water types from the recharge area to the discharge area. The ionic ration plot and saturation index (SI) calculation suggest that the silicate rock weathering and evaporation deposition are the dominant processes that determine the major ionic composition in the study area. Most of the stable isotope δ18O and δD compositions in the groundwater is a meteoric water feature, indicating that the groundwater mainly sources from meteoric water and most groundwater undergoes a long history of evaporation. Based on radioactive isotope tritium (3H) analysis, the groundwater ages were approximately estimated in different aquifers. The groundwater age ranges from less than 5 years, between 5 years and 50 years, and more than 50 years. Within 1 km of the river water influence zone, the groundwater recharges from recent Heihe river water and the groundwater age is about less than 5 years in shallow aquifer. From 1 km to 10 km of the river water influence zone, the groundwater sources from the mixture waters and the groundwater age is between 5 years and 50 years in shallow aquifer. The groundwater age is more than 50 years in deep confined aquifer.  相似文献   

8.
永定河对北京西山岩溶水和玉泉山泉的影响   总被引：1，自引：0，他引：1  
岩溶介质赋水各向异性使岩溶含水层具有不均一性和复杂性,增加了刻画地下水流场的难度和不确定性。为深入理解岩溶水系统不均一性,基于水化学和同位素数据研究了西山岩溶水系统补径排路径,为厘清岩溶水流场特征提供了新的依据。水化学和同位素证据表明西山岩溶区有3个补给源区:军庄、潭柘寺降水补给区和永定河渗漏补给区,每个补给区各自具有独立的径流通道。军庄补给区为降水和河水补给,降水补给向温泉-永丰屯方向径流;入渗河水补给沿永定河断裂向南东方向径流,在古城一带转向北东方向补给玉泉山泉。潭柘寺降水补给沿八宝山断裂北侧经回民公墓,八宝山朝四季青方向径流。自北而南可分为军庄-永丰屯径流带、永定河-香山径流带、潭柘寺-八宝山-四季青径流带。潭柘寺和永定河是西山岩溶水和重要补给源区,对玉泉山泉有直接影响。  相似文献   

9.
地下水的补排主要包括垂向的地面入渗补给、蒸发排泄（蒸发可视为入渗的负值）及侧向的地表水补给、排泄。水文地质学最基本的问题之一——地下水可持续开釆量的评价准则,涉及补给的增量与排泄的减量,因此地下水开采的预测模型必须包含上述两类的补给、排泄因素,否则不能满足要求。然而,经典的Theis不稳定井流模型,即使在傍河抽水,也只有侧边界的补给、排泄作用,而不涉及上边界的地面入渗补给。这样一来,这个解析模型基本上不能够用于预测,而只能在旱季用于井流试验求取含水系统的参数。为此,文章的目标是发展具地面入渗补给的Theis不稳定潜水井流模型。对于潜水流问题,不能再用承压水流的以水头为应变量的方程来建立,应采用第二类线性化方法的势函数来建立潜水流问题。对于既有降雨入渗补给,又有抽水井作用的复杂的水文地质问题所概化数学模型的求解,采取的方法是把它分解成若干个简单的子模型问题求解,然后将其合成为原来复杂数学模型的解。基于质量守恒原理,假定渗流服从Darcy定律并满足Dupuit徦定建立了水流基本微分方程。然后对于两平行河流及一河流平行一隔水边界形成的两类条形区域,具地面均匀稳定入渗补给的井流问题,获得通用水位方程和几类常见的特定条件水位方程及其流量方程。此外,提出并采用“边界对边界的反映法”用以求解一河流平行一隔水边界条形区域的同一问题,减少了许多推导过程。最后,作为上述理论成果的初步应用,也是一个重要的应用,即在河水水质不能满足要求的河流附近,设有一口抽水井,计算该抽水井在不汲取河水的前提下的临界流量方程,获得具重要意义的结构简洁的关系式。该方程也可以用于滨海区的抽水井,在不发生海水入侵前提下的临界抽水流量计算。给出了上述条件不稳定井流过程某时刻的地下水流网图,其流网与文献中常见的傍河井流的流网相比,具显明的特征。  相似文献   

10.
The present work was conducted in the Sinai Peninsula (1) to identify the recharge and flow characteristics and to evaluate the continuity of the Lower Cretaceous Nubian Sandstone aquifer; and (2) to provide information for the aquifer's rational appraisal. Isotopic and hydrochemical compositions combined with the geological and hydrogeological settings were used for this purpose. A considerable depletion in isotopic content (oxygen-18 and deuterium) and low d-excess values exist in the studied groundwater, reflecting the contribution of old meteoric water that recharged the aquifer in pluvial times. Modern recharge also occurs from precipitation that falls on the aquifer outcrops. The wide scatter of the data points around the two meteoric lines, the global meteoric water line (GMWL) and Mediterranean meteoric water line (MMWL), in the δ18O–δD diagram indicates considerable variation in recharge conditions (amount, altitude, temperature, air masses, distances from catchment, overland flow, etc.). The isotopic composition in the El-Bruk area is minimum (18O=–9.53‰), very close to the average value of the Western Desert Nubian Sandstone (18O=–10‰), where the local structural and lithologic conditions retard groundwater flow and the main bulk of water becomes noncyclic. The continuity of the aquifer in northern and central Sinai is evidenced by the isotopic similarity between samples taken from above and below the central Sinai Ragabet El-Naam fault, the distribution of potentiometric head, and hydrogeological cross sections. The combination of isotopic composition in terms of 18O and chemical composition in terms of TDS and salt contents is the basis for separating the studied groundwater into groups that reflect the recharge sources and isotopic and chemical modifications during flow. Electronic Publication  相似文献   

11.
In the region between Mersin and Tarsus cities, located along the Mediterranean Sea coast in southern Turkey, the demand for groundwater has increased dramatically as the available surface water supplies have already been developed. Fundamental information is required to characterize the existing groundwater system in this area in order to establish a sustainable groundwater-use policy. For this purpose, hydrochemical and environmental isotopic data were collected and integrated with available geological and hydrogeological information to develop a conceptual model of the system. Results, backed up mainly by depleted stable isotope composition and infinitesimal tritium content, suggest that most of the groundwater along the coastal zone is supplied by the neighboring mountain belt while local precipitation has also contributes to aquifer recharge. The validation of the conceptual perspective by a steady-state numerical groundwater flow model reveals that about 90% of the recharge to the aquifer system is supplied by the deep flow of karstic groundwater fed from the Taurus Mountains. Monitoring of changes in the recharge regime of the mountain sector seems to be critical in establishing future groundwater use policies.  相似文献   

12.
长武黄土塬区土地利用变化对潜水补给的影响   总被引：2，自引：0，他引：2       下载免费PDF全文
通过长武黄土塬区不同土地利用方式下深剖面土壤水分的长期定位监测以及氢氧稳定同位素示踪技术的使用,分析了该区域土地利用变化对地下潜水补给的影响。结果表明:① 降水补给地下水过程中存在着活塞流和优先流两种机制,由活塞流补给的地下水量,以休闲地居高,低产农田次之,最后是高产农田;② 随着该区域农田生产力大幅提升以及大面积农田转换为果园,地下水活塞流补给量逐年减少,加之地下水开采量增加,导致地下水位逐年下降,年均降幅达0.3 m;③ 同位素证据表明,目前长武塬区地下水补给以优先流形式为主。为了实现黄土塬区潜水资源的有效补给与可持续利用,需要合理调控土地利用结构,保持适度生产力水平。  相似文献   

13.
The Quaternary coastal plain aquifer down gradient of the Wadi Watir catchment is the main source of potable groundwater in the arid region of south Sinai, Egypt. The scarcity of rainfall over the last decade, combined with high groundwater pumping rates, have resulted in water-quality degradation in the main well field and in wells along the coast. Understanding the sources of groundwater salinization and amount of average annual recharge is critical for developing sustainable groundwater management strategies for the long-term prevention of groundwater quality deterioration. A combination of geochemistry, conservative ions (Cl and Br), and isotopic tracers (87/86Sr, δ81Br, δ37Cl), in conjunction with groundwater modeling, is an effective method to assess and manage groundwater resources in the Wadi Watir delta aquifers. High groundwater salinity, including high Cl and Br concentrations, is recorded inland in the deep drilled wells located in the main well field and in wells along the coast. The range of Cl/Br ratios for shallow and deep groundwaters in the delta (∼50–97) fall between the end member values of the recharge water that comes from the up gradient watershed, and evaporated seawater of marine origin, which is significantly different than the ratio in modern seawater (228). The 87/86Sr and δ81Br isotopic values were higher in the recharge water (0.70,723 < 87/86Sr < 0.70,894, +0.94 < δ81Br < +1.28‰), and lower in the deep groundwater (0.70,698 < 87/86Sr < 0.70,705, +0.22‰ < δ81Br < +0.41‰). The δ37Cl isotopic values were lower in the recharge water (−0.48 < δ37Cl < −0.06‰) and higher in the deep groundwater (−0.01 < δ37Cl < +0.22‰). The isotopic values of strontium, chloride, and bromide in groundwater from the Wadi Watir delta aquifers indicate that the main groundwater recharge source comes from the up gradient catchment along the main stream channel entering the delta. The solute-weighted mass balance mixing models show that groundwater in the main well field contains 4–10% deep saline groundwater, and groundwater in some wells along the coast contain 2–6% seawater and 18–29% deep saline groundwater.A three-dimensional, variable-density, flow-and-transport SEAWAT model was developed using groundwater isotopes (87Sr/86Sr, δ37Cl and δ81Br) and calibrated using historical records of groundwater level and salinity. δ18O was used to normalize the evaporative effect on shallow groundwater salinity for model calibration. The model shows how groundwater salinity and hydrologic data can be used in SEAWAT to understand recharge mechanisms, estimate groundwater recharge rates, and simulate the upwelling of deep saline groundwater and seawater intrusion. The model indicates that most of the groundwater recharge occurs near the outlet of the main channel. Average annual recharge to delta alluvial aquifers for 1982 to 2009 is estimated to be 2.16 × 106 m3/yr. The main factors that control groundwater salinity are overpumping and recharge availability.  相似文献   

14.
华北平原地下水年龄校正   总被引：3，自引：0，他引：3  
郭娇  石建省  王伟 《地球学报》2007,28(4):396-404
地下水14C年龄一般指地下水和土壤CO2隔绝至今的年代.地下水测年在地下水水文学中占有特殊的位置,地下水测年可以用来确定补给区,估算地下水流速度、流量、补给速率、水力传导系数和有效孔L隙度,而且年龄数据还可以用来完善地下水流模型.本研究选择华北平原为重点研究区,利用地下水中的同位素和化学组分的测试结果,应用水文地球化学及同位素水文学等相关知识,通过六种传统模型和反向质量平衡模型(NETPATH)对华北平原地下水年龄进行校正.根据年龄校正结果,分析了深层地下水的年龄变化特点,确定了水流路径上发生的水文地球化  相似文献   

15.
The present study was conducted to delineate the pollution vulnerability of the Quaternary aquifer in two areas, Imbaba and Shobra El-Khima, near Cairo, Egypt. Environmental isotopes combined with hydrochemistry were used for this purpose. The groundwater in the Imbaba area (average total dissolved solids about 900 mg/L; sodium/chloride, sulfate, and bicarbonate water types) is more mineralized than groundwater in the Shobra El-Khima area (average total dissolved solids 500 mg/L; calcium and sodium/bicarbonate water type). A high nitrate content and significant mineralization in the groundwater are probably due to contamination of recharge to the aquifer by irrigation drainage, deteriorated sewage networks, and septic tanks. The deuterium and oxygen-18 compositions of the groundwater are depleted compared to Nile River water, which is the main source of aquifer recharge. This less isotopically enriched water probably represents older Nile water recharge that flooded the region before construction of the Aswan High Dam in 1963, or it is a mixture of a young water and originally deposited paleowater that was in deeper horizons at a time of cooler and more humid climate. Intensive pumping has moved the paleowater higher in the aquifer. Groundwater in the Shobra El-Khima area has higher residence time, based on the tritium concentration, than groundwater in the Imbaba area. The percentage of the isotopically depleted water equals 75% in the Shobra El-Khima and 35% in Imbaba, and the thickness of the clay cap above the aquifer is 38 m in Shobra El-Khima and 20 m in Imbaba. These factors are indicative of the rate of recharge to the aquifer and were used to evaluate the pollution vulnerability in the two areas. Electronic Publication  相似文献   

16.
The Rajshahi city is the fourth largest metropolitan city in Bangladesh on the bank of the River Padma (Ganges). Here an upper semi-impervious layer overlies aquifer — the source for large-scale groundwater development. The groundwater resource study using Visual MODFLOW modeling shows that recharge occurs mainly due to infiltration of rainfall and urban return flow at low rate, and water level fluctuates seasonally in response to recharge and discharge. Hydraulic connection between river and aquifer which indicates inflow from high river water levels beyond its boundaries. The total groundwater abstraction in 2004 (15000 million liters) is lower than total input to aquifer reveals an ample potentiality for groundwater development with increasing demand. But groundwater shortage (1000 million liter/year) especially in the vicinity of the River Padma in dry season happens due to its increasing use and fall of river water level resulting in reduced inflows and hence decline in groundwater level. The conjunctive use of surface water-groundwater and its economic use will help for sustainable groundwater supply to avoid adverse impact.  相似文献   

17.
Groundwater flow in the Leon-Chinandega aquifer was simulated using transient and steady-state numerical models. This unconfined aquifer is located in an agricultural plain in northwest Nicaragua. Previous studies were restricted to determining groundwater availability for irrigation, overlooking the impacts of groundwater development. A sub-basin was selected to study the groundwater flow system and the effects of groundwater development using a numerical groundwater flow model (Visual MODFLOW). Hydrological parameters obtained from pumping tests were related to each hydrostratigraphic unit to assign the distribution of parameter values within each model layer. River discharge measurements were crucial for constraining recharge estimates and reducing the non-uniqueness of the model calibration. Steady-state models have limited usefulness because of the major variation of recharge and agricultural pumping during the wet and dry seasons. Model results indicate that pumping induces a decrease in base flow, depleting river discharge. This becomes critical during dry periods, when irrigation is highest. Transient modeling indicates that the response time of the aquifer is about one hydrologic year, which allows the development of management strategies within short time horizons. Considering further development of irrigated agriculture in the area, the numerical model can be a powerful tool for water resources management.  相似文献   

18.
Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.  相似文献   

19.

Particularly in arid and semiarid areas, more and more populations rely almost entirely on imported water. However, the extent to which intentional discharge into transiting river systems and unintentional leakage may be augmenting water resources for communities along and down gradient of the water transfer scheme has not previously been subject to research. The objective of this study was to assess both the potential of a large-scale water transfer (WT) scheme to increase groundwater availability by channel transmission losses in a large dryland aquifer system (2,166 km²) in Brazil, and the capability of the receiving streams to transport water downstream under a prolonged drought. An integrated surface-water/groundwater model was developed to improve the estimation of the groundwater resources, considering the spatio-temporal variability of infiltrated rainfall for aquifer recharge. Aquifer recharge from the WT scheme was simulated under prolonged drought conditions, applying an uncertainty analysis of the most influential fluxes and parameters. The annual recharge (66 mm/year) was approximately twice the amount of water abstracted (1990–2016); however, the annual recharge dropped to 13.9 mm/year from 2012 to 2016, a drought period. Under similar drought conditions, the additional recharge (6.89 × 106 m³/year) from the WT scheme did not compensate for the decrease in groundwater head in areas that do not surround the receiving streams. Actually, the additional recharge is counteracted by a decrease of 25% of natural groundwater recharge or an increase of 50% in pumping rate; therefore, WT transmission losses alone would not solve the issue of the unsustainable management of groundwater resources.

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20.
The unconfined High Plains (Ogallala) aquifer is the largest aquifer in the USA and the primary water supply for the semiarid southern High Plains of Texas and New Mexico. Analyses of water and soils northeast of Amarillo, Texas, together with data from other regional studies, indicate that processes during recharge control the composition of unconfined groundwater in the northern half of the southern High Plains. Solute and isotopic data are consistent with a sequence of episodic precipitation, concentration of solutes in upland soils by evapotranspiration, runoff, and infiltration beneath playas and ditches (modified locally by return flow of wastewater and irrigation tailwater). Plausible reactions during recharge include oxidation of organic matter, dissolution and exsolution of CO2, dissolution of CaCO3, silicate weathering, and cation exchange. Si and 14C data suggest leakage from perched aquifers to the High Plains aquifer. Plausible mass-balance models for the High Plains aquifer include scenarios of flow with leakage but not reactions, flow with reactions but not leakage, and flow with neither reactions nor leakage. Mechanisms of recharge and chemical evolution delineated in this study agree with those noted for other aquifers in the south-central and southwestern USA. Electronic Publication  相似文献   

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