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1.
Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H2O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (≪50 molecular layers) is found to occur with zeroth-order kinetics characterized by a surface binding energy, E des, of 5773 ± 60 K, and a pre-exponential factor, A , of 1030 ± 2 molecules cm−2 s−1. These results imply that, in the dense interstellar medium, thermal desorption of H2O ice will occur at significantly higher temperatures than has previously been assumed.  相似文献   

2.
The chemical desorption of an adsorbed CO molecule in the vicinity of H2-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H2. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H2 formation energy in the vicinity of H2-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H2-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (1013 s) and that for H2 forming in the vicinity of an adsorbed CO molecule (more than 2×1013 s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.  相似文献   

3.
To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H2O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H2O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H2O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H2O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.  相似文献   

4.
We present 20–110 µm absorbance spectra of H2O ice, deposited on amorphous carbon and silicate substrates, obtained over the 10–140 K temperature range. The measurements have been carried out in a manner that simulates the deposition, warming and cooling of H2O ice mantles on interstellar and circumstellar grains. For H2O ice films deposited on these substrates we find (i) similar 44-µm-band peak wavelength temperature dependences, (ii) no bandshape differences in the respective spectra, and (iii) a structural phase transition occurring between 120 and 130 K. In comparison with published data obtained using a polyethylene substrate, the 52-µm feature (the longitudinal optical mode) observed in our spectra is less prominent. This suggests the presence of material-dependent substrate effects that can alter the appearance of the H2O far-infrared spectrum. The crystallization temperature of H2O ice films deposited on our amorphous silicate substrate is significantly different from that reported by Moore et al. (1994) , who found crystallization temperatures down to < 20 K for ice also deposited on an amorphous silicate substrate. This is attributed to differences in the surface structures of the respective substrates. This may indicate that, at least in the context of laboratory measurements, substrate material composition is not as significant as substrate surface structure.  相似文献   

5.
We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H2SO4 ·  n H2O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.  相似文献   

6.
The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 106–7 yr). The abundances of those surface species, such as H2O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH3OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1.  相似文献   

7.
The formation of molecular hydrogen  (H2)  in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during gravitational collapse and star formation. Thus, the evaluation of the production rate of hydrogen molecules and its dependence on the physical conditions in the cloud are of great importance. Interstellar dust grains exhibit a broad size distribution in which the small grains capture most of the surface area. Recent studies have shown that the production efficiency strongly depends on the grain composition and temperature as well as on its size. In this paper, we present a formula that provides the total production rate of  H2  per unit volume in the cloud, taking into account the grain composition and temperature as well as the grain size distribution. The formula agrees very well with the master equation results. It shows that for a physically relevant range of grain temperatures, the production rate of  H2  is significantly enhanced due to their broad size distribution.  相似文献   

8.
Recent laboratory experiments on interstellar dust analogues have shown that H2 formation on dust-grain surfaces is efficient in a range of grain temperatures below 20 K. These results indicate that surface processes may account for the observed H2 abundance in cold diffuse and dense clouds. However, high abundances of H2 have also been observed in warmer clouds, including photon-dominated regions (PDRs), where grain temperatures may reach 50 K, making the surface processes extremely inefficient. It was suggested that this apparent discrepancy can be resolved by chemisorption sites. However, recent experiments indicate that chemisorption processes may not be efficient at PDR temperatures. Here we consider the effect of grain porosity on H2 formation, and analyse it using a rate-equation model. It is found that porosity extends the efficiency of the recombination process to higher temperatures. This is because H atoms that desorb from the internal surfaces of the pores may re-adsorb many times and thus stay longer on the surface. However, this porosity-driven extension may enable efficient H2 formation in PDRs only if porosity also contributes to significant cooling of the grains, compared to non-porous grains.  相似文献   

9.
The specific catalytic effect of a silica grain on the formation of methanol via the sequential addition of H atoms to CO adsorbed on the surface is investigated. A negatively charged defect on a siliceous edingtonite surface is found to reduce the gas phase barriers for the H + COads and H + H2C=Oads reactions by 770 and 399 K, respectively, when compared to the same reactions in the gas phase. The catalytic effect of negatively charged surface sites could also be applicable to the hydrogenation of other adsorbed unsaturated species. However, the activation energies on the surface defect are still too large (1150 and 2230 K) for CH3OH to form efficiently at 10–20 K in the interstellar medium via a classical mechanism. It is therefore suggested that quantum mechanical tunnelling through the activation barrier is required for these hydrogen addition reactions to proceed at such temperatures. The calculations show that because the adsorption energies of CO and H2C=O on the negatively charged defect are substantial, CH3OH may form efficiently during the warm-up period in star-forming regions.  相似文献   

10.
We report the discovery of high-velocity dense gas from a bipolar outflow source near NGC 2068 in the L1630 giant molecular cloud. CO and HCO+ J =3→2 line wings have a bipolar distribution in the vicinity of LBS 17-H with the flow orientated roughly east–west and perpendicular to the elongation of the submillimetre dust continuum emission. The flow is compact (total extent ∼0.2 pc) and contains of the order of 0.1 M⊙ of swept-up gas. The high-velocity HCO+ emission is distributed over a somewhat smaller area <0.1 pc in extent.
A map of C18O J =2→1 emission traces the LBS 17 core and follows the ambient HCO+ emission reasonably well, with the exception of the direction towards LBS 17-H where there is a significant anticorrelation between the C18O and HCO+. A comparison of beam-matched C18O and dust-derived H2 column densities suggests that CO is depleted by up to a factor of ∼50 at this position if the temperature is as low as 9 K, although the difference is substantially reduced if the temperature is as high as 20 K. Chemical models of collapsing clouds can account for this discrepancy in terms of different rates of depletion on to dust grains for CO and HCO+.
LBS 17-H has a previously known water maser coincident with it but there are no known near-infrared, IRAS or radio continuum sources associated with this object, leading to the conclusion that it is probably very young. A greybody fit to the continuum data gives a luminosity of only 1.7 L⊙ and a submillimetre-to-bolometric luminosity ratio of 0.1, comfortably satisfying the criteria for classification as a class 0 protostar candidate.  相似文献   

11.
An upper limit of the column density of the C5 linear molecule in translucent interstellar clouds is estimated from high-resolution ( R =80 000) and very high signal-to-noise ratio (∼1000) echelle spectra. It is 1012 cm−2 per E ( B − V )=1 (two orders of magnitude lower than that of C2).  相似文献   

12.
We have computed optical absorption-line profiles of CH+ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C+(H2, H)CH+. Whilst CH+ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH+3(e−, H2)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH+ and CH line profiles is found to be no more than approximately 2 km s−1, which is smaller than has previously been assumed. We also investigate OH and HCO+, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.  相似文献   

13.
In order to interpret H2 quasar absorption-line observations of damped Lyα systems (DLAs) and subDLAs, we model their H2 abundance as a function of dust-to-gas ratio, including H2 self-shielding and dust extinction against dissociating photons. Then, we constrain the physical state of the gas by using H2 data. Using H2 excitation data for DLAs with H2 detections, we derive a gas density  1.5 ≲ log n (cm−3) ≲ 2.5  , temperature  1.5 ≲ log T (K) ≲ 3  , and an internal ultraviolet (UV) radiation field (in units of the Galactic value)  0.5 ≲ log χ≲ 1.5  . We then find that the observed relation between the molecular fraction and the dust-to-gas ratio of the sample is naturally explained by the above conditions. However, it is still possible that H2 deficient DLAs and subDLAs with H2 fractions less than  ∼10−6  are in a more diffuse and warmer state. The efficient photodissociation by the internal UV radiation field explains the extremely small H2 fraction  (≲10−6)  observed for  κ≲ 1/30  (κ is the dust-to-gas ratio in units of the Galactic value); H2 self-shielding causes a rapid increase in, and large variations of, H2 abundance for  κ≳ 1/30  . We finally propose an independent method to estimate the star formation rates of DLAs from H2 abundances; such rates are then critically compared with those derived from other proposed methods. The implications for the contribution of DLAs to the cosmic star formation history are briefly discussed.  相似文献   

14.
The formation of H2 on a pristine olivine surface [forsterite (010)] is investigated computationally. Calculations show that the forsterite surface catalyzes H2 formation by providing chemisorption sites for H atoms. The chemisorption route allows for stepwise release of the reaction exothermicity and stronger coupling to the surface, which increases the efficiency of energy dissipation. This suggests that H2 formed on a pristine olivine surface should be much less rovibrationally excited than H2 formed on a graphite surface. Gas-phase H atoms impinging on the surface will first physisorb relatively strongly  ( E phys= 1240 K)  . The H atom can then migrate via desorption and re-adsorption, with a barrier equal to the adsorption energy. The barrier for a physisorbed H atom to become chemisorbed is equal to the physisorption energy, therefore there is almost no gas-phase barrier to chemisorption. An impinging gas-phase H atom can easily chemisorb  ( E chem= 12 200 K)  , creating a defect where a silicate O atom is protonated and a single electron resides on the surface above the adjacent magnesium ion. This defect directs any subsequent impinging H atoms to chemisorb strongly (39 800 K) on the surface electron site. The two adjacent chemisorbed atoms can subsequently recombine to form H2 via a barrier (5610 K) that is lower than the chemisorption energy of the second H atom. Alternatively, the adsorbed surface species can react with another incoming H atom to yield H2 and regenerate the surface electron site. This double chemisorption 'relay mechanism' catalyzes H2 formation on the olivine surface and is expected to attenuate the rovibrational excitation of H2 thus formed.  相似文献   

15.
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol−1, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ3( A v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.  相似文献   

16.
High-resolution spectra of comet 8P/Tuttle were obtained in the frequency range 3449.0–3462.2 cm−1 on 2008 January 3 ut using CGS4 with echelle grating on United Kingdom Infrared Telescope. In addition to observing solar pumped fluorescent lines of H2O, the long integration time (152 min on target) enabled eight weaker H2O features to be assigned, most of which had not previously been identified in cometary spectra. These transitions, which are from higher energy upper states, are similar in character to the so-called SH lines recorded in the post Deep Impact spectrum of comet Tempel 1. We have identified certain characteristics that these lines have in common, and which in addition to helping to define this new class of cometary line give some clues to the physical processes involved in their production. Finally, we derive an H2O rotational temperature of     and a water production rate of  (1.4 ± 0.3) × 1028  molecules s−1.  相似文献   

17.
We have used the Mopra Telescope to search for glycine and the simple chiral molecule propylene oxide in the Sgr B2 (LMH) and Orion KL, in the 3-mm band. We have not detected either species, but have been able to put sensitive upper limits on the abundances of both molecules. The 3σ upper limits derived for glycine conformer I are  3.7 × 1014 cm−2  in both Orion-KL and Sgr B2 (LMH), comparable to the reported detections of conformer I by Kuan et al. However, as our values are 3σ upper limits rather than detections we conclude that this weighs against confirming the detection of Kuan et al. We find upper limits for the glycine II column density of  7.7 × 1012 cm−2  in both Orion-KL and Sgr B2 (LMH), in agreement with the results of Combes et al. The results presented here show that glycine conformer II is not present in the extended gas at the levels detected by Kuan et al. for conformer I. Our ATCA results have ruled out the detection of glycine (both conformers I and II) in the compact hot core of the LMH at the levels reported, so we conclude that it is unlikely that Kuan et al. have detected glycine in either Sgr B2 or Orion-KL. We find upper limits for propylene oxide abundance of  3.0 × 1014 cm−2  in Orion-KL and  6.7 × 1014 cm−2  in Sgr B2 (LMH). We have detected fourteen features in Sgr B2 and four features in Orion-KL which have not previously been reported in the interstellar medium, but have not been able to plausibly assign these transitions to any carrier.  相似文献   

18.
We present consistent modelling of line and continuum infrared (IR) spectra in the region close to the Galactic Centre. The models account for the coupled effect of shocks and photoionization from an external source. The results show that the shock velocities range between ∼65 and 80 km s−1 and the pre-shock densities between 1 cm−3 in the interstellar medium (ISM) to 200 cm−3 in the filamentary structures. The pre-shock magnetic field increases from 5 × 10−6 G in the surrounding ISM to ∼8 × 10−5 G in the arched filaments. The stellar temperatures are ∼38 000 K in the Quintuplet cluster and ∼27 000 K in the Arches Cluster. The ionization parameter is relatively low (<0.01) with the highest values near the clusters, reaching a maximum >0.01 near the Arches Cluster. Depletion from the gaseous phase of Si is found throughout the whole observed region, indicating the presence of silicate dust. Grains including iron are concentrated throughout the arched filaments. The modelling of the continuum spectral energy distribution in the IR range indicates that a component of dust at temperatures of ∼100–200 K is present in the central region of the Galaxy. Radio emission appears to be thermal bremsstrahlung in the E2–W1 filaments crossing strip; however, a synchrotron component is not excluded. More data are necessary to resolve these questions.  相似文献   

19.
The formation of CO2 in the gas phase and on a polyaromatic hydrocarbon surface (coronene) via three possible pathways is investigated with density functional theory. Calculations show that the coronene surface catalyses the formation of CO2 on model grain surfaces. The addition of 3O to CO is activated by 2530 K in the gas phase. This barrier is lowered by 253 K for the Eley–Rideal mechanism and 952 K for the hot-atom mechanism on the surface of coronene. Alternative pathways for the formation of CO2 are the addition of 3O to the HCO radical, followed by dissociation of the HCO2 intermediate. The O + HCO addition is barrierless in the gas phase and on the surface and is more than sufficiently exothermic to subsequently cleave the H–C bond. The third mechanism, OH + CO addition followed by H removal from the energized HOCO intermediate, has a gas-phase exit barrier that is 1160 K lower than the entrance barrier. On the coronene surface, however, both barriers are almost equal. Because the HOCO intermediate can also be stabilized by energy dissipation to the surface, it is anticipated that for the surface reaction the adsorbed HOCO could be a long-lived intermediate. In this case, the stabilized HOCO intermediate could react, in a barrierless manner, with a hydrogen atom to form H2+ CO2, HCO2H, or H2O + CO.  相似文献   

20.
Transient microstructure in the diffuse interstellar medium (ISM) has been observed towards Galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a molecular component to the transient microstructure. In this paper, we explore the chemistry that may arise in such microstructure. We use a photodissociation region (PDR) code to model the conditions of relatively high density, low temperature, very low visual extinction and very short elapsed time that are appropriate for these objects. We find that there is a well-defined region of parameter space where detectable abundances of molecular species might be found. The best matching models are those where the interstellar microstructure is young (<100 yr), small (∼100 au) and dense  (>104 cm−3)  .  相似文献   

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