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1.
Chemistry of Aerosols over Chukchi Sea and Bering Sea 总被引：2，自引：0，他引：2
The contents of elements in aerosols sampled during the First Chinese Arctic Research Expedition (CHINARE-1) show great differences from one element to another. Na, K,Ca, Mg, A1, F, and Cl are the major components in the aerosols, whose contents are larger than 30 ng/m^3. The chemical elements whose contents vary between 0.1 - 30 ng/m^3 are Br,Sr, Cr, Ni, and Zn. The chemical elements whose contents are close to or slightly higher than 0.1 ng/m^3 are Rb, Ba, Zr, Th, and Pb. The contents of As, Sb, W, Mo, Au, La, Ce, Nd,Sin, Eu, Tb, Yb, Lu, Sc, Co, Hf, Ta, and Cd are less than 0.1 ng/m^3. The mass concentration data for the same element, as observed during CHINARE-1, are almost accordant, but much lower than what is observed in the China‘ s seas or the coasts of China. The enrichment factor and electron microscopic analyses and lead isotope tracing were used to distinguish their sources.Four groups of sources can be classified as follows: anthropogenic: As, Sb, W, F, Mo, Au,Cu, Pb, Cd, V; crustal: La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Fe, Sc, Cr, Co, Ba, Zr, Hf,Ta, Cs, Mn, Th, U; oceanic:Na, K, Ca, and Mg; and mixing: Rb, Sr, Ca, and Mg. 相似文献
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本文对河南济源盆地大峪槐疙瘩岭二叠系上石盒子组(P3sh)、孙家沟组(P3s)和三叠系刘家沟组(T1l)剖面岩石样品进行了元素、频率磁化率、碳酸盐以及总有机质等的分析研究,结果表明在二叠系孙家沟组(P3s)底部济源动物群化石层、以及三叠系刘家沟组(T1l)底部界线(P/T)附近,其微量和常量元素发生了较明显的变化。化石层中Ba,Cr,Hf,Nb,Th,Ti,V,Y,Tl,Zn,Cu,Ga,Pb,Ni,La,Rb,Nd,以及K2O,Al2O3,Fe2O3含量相对较高,Zr,W,Sr,Bi,Co,Ce,以及SiO2,Na2O含量较低,MgO,CaO,Mn则没有明显的变化。Ba,Hf,Nb,Th,Ti,V,Y,W,K2O,Al2O3,SiO2,Na2O,Bi,Fe2O3,Ni,Co,La,Nd,Ce,及有机碳含量在三叠系底部含量明显上升,Cu,Ga,Pb,Tl,Zn,Cr,Zr,Sr,MgO,CaO,以及岩石频率磁化率Xfd、碳酸盐含量则明显下降。该剖面不仅记录了二叠—三叠纪的生物灭绝事件,而且有明显的二叠—三叠系界线,事件及界线的形成可能与沉积环境和古气候有关,水体的变浅、炎热气候和风化作用加强可能是直接的原因。石盒子组(P3sh)主要为河流—三角洲沉积环境,古气候相对温暖湿润;孙家沟组(P3s)为三角洲平原相,前期和后期有强烈风化作用,并且炎热多雨。中期则水平面上升,水下三角洲前缘砂质沉积为主;三叠系刘家沟组(T1l)则水体进一步扩张,气温相对下降。 相似文献
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《Scientia Geologica Sinica》1999,(1)
1.IntroductionForelandbasin,thesedimentarybasinlyingbetweenthefrontofanorogenandtheadjacentcraton,isanimportantaspectforthestudyonlithospheretectonicevolutionoforogen(e.g.,Tankard,1986,Ren,etal.,1991;Li,1992,Chen,etal.,1992,Liu,etal.,1994,LihouandAlien,1996,Li,etal.,1997,DongandZhang,1997).Currently,itisdividedintotwogenetictoes,i.e.,peripheralforelandbasinsituatedagainsttheouterarcoftheorogenduringcontinent-continentcollisionandretro-arcforelandbasinbehindamagmaticarclinkedwithsubductiono… 相似文献
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中國礦産賦藏,原非少數,其重要者如煤,鐵,石油,錳,鎢,銻,鉛,鋅,錫,金,鋁以及其他金屬非金屬等,多所發现。然其價值之詳細認識,则尚未敢遽言。近年經地質調查所之努力進行,關於重要礦藏量之估計,多有增進,茲就已得部份列如第一表。計有煤,鐵,石油,鎢,銻,鋁,螢石及菱鎂礦等。 相似文献
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《Scientia Geologica Sinica》1999,(3)
1.IntroductionTheChineseAltaidorogenicbeltislocatedinnorthemXinjiang,ChinaandisthemiddleportionofamoreextensiveorogeninthecentralAsia,namedAltaidorogen,whichextendsfromwesternMongolia,throughnorthwesternChina,toeastemKazakhstan.IntermsofitsstratigraPhy,magmatism,metamorphismandsmictufalpattems,theChineseAltaidorogenicbeltcanreflectsthegeodynamicevolutionofthewholeAltaidorogen.BasedonthegeologicalfeaturesoftheChineseA1taidorogenicbelt,amodelofgeodynamicevolution,calledaccretionaryarcoroge… 相似文献
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《Continental Dynamics》1997,(1)
ForaPrecambriancratoncomposedofcompositeterranes,orblocks,andbelts,whichexperiencedcomplexpolyphasedeformationandmetamorphism,thefinaltectonothermaleventismoresignificantthantheearlieronesinthelightofplatetectonics,becausethefinaltectonothermaleventresultedfromamalga-mationofthecraton.Although,generally,aworkinghypothesisofpolyphasedeformationandmetamorphismiswidelyappliedtoahigh-gradeterrane,dis-cernmentofitsfinaltectonothermalepisodeisvitaltounderstandingitsgeologicalhistory.Inrecentyears,an… 相似文献
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一.热液硫化矿床的一些分散元素热液矿床包括多数最重要的金属矿床,如Cu,Pb,Zn,Ag,Sb,Hg,Mo,W,U,Au等。除最后三种元素外,其余都以硫化物为主要存在方式。这些硫化矿物,除含上列元素外,还常常含有一些稀少的元素,如Cd,Ga,In,Tl,Gl,Re,Se,Te等,后者的含量和硫化物中 相似文献
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《地下水科学与工程》2021,(1)
正Aims and Scope Journal of Groundwater Science and Engineering aims to be an innovative,high-impact and authoritative academic journal for researchers across the hydrogeology,environmental geology,engineering geology,ecology and environment community.It mainly reports the latest and most important achievements in cutting-edge and emerging topics,as well as the traditional topics referring to new methodology,technology,applications and theoretical research in groundwater science and engineering.Papers published involve various aspects of research concerning groundwater,such as hydrogeology,environmental geology,engineering geology,urban geology,climate change,environmental change,ecology,water cycle,water resources,geochemistry,geothermy,agriculture,groundwater development and utilization,groundwater pollution,and research with supporting disciplines:Geophysics,geobiology,mathematics,numerical modeling,economics, 相似文献
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以钛白副产绿矾和氯化钾为原料 ,采取硫酸铁钾转化法制备硫酸钾。该工艺既具有反应时间短、操作控制方便、产品质量符合国标要求等优点 ,又治理了钛白粉厂环境污染 ;既具有一定的经济效益 ,又有一定的社会效益。 相似文献
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研究了以钛白副产硫酸亚铁和氯化钾为原料,采用钾石膏法,经过共沉淀、酸化、加热转化生成硫酸钾的新工艺。该工艺流程简捷,反应时间短,操作控制方便,无二次污染,产品质量符合国标要求。该方法既能处置钛白粉厂的副产硫酸亚铁,又能给企业带来一定的经济效益,是处理钛白副产硫酸亚铁的一种效理想的方法之一。 相似文献
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The use of suspensions of nanoparticles of titanium dioxide in photocatalytic degradation of dye solution has disadvantages of inconvenient separation of fine particles for reuse and limited penetration of light for effective degradation. These problems can be minimized by supporting titanium dioxide on various inert supports. The present study involves the preparation of immobilized titanium dioxide films by three different techniques and characterization of the prepared films. The immobilized films of nanocrystals of titanium dioxide were prepared using sol?Cgel technique, polyvinyl alcohol?Cformaldehyde binder and acrylic emulsion. The photocatalytic performance of the prepared films for degradation of amaranth dye has also been evaluated and compared. Combination of photodegradation and adsorption processes induces strong beneficial effects on removal of dyes. Addition of high adsorption capacity activated carbon to photoactive titanium dioxide in photodegradation of dyes improves the efficiency of dye mineralization. The activated carbon has also been immobilized along with titanium dioxide in the present work to examine the dual effect of photodegradation and adsorption in the removal of amaranth. The films formed with the help of polyvinyl alcohol?Cformaldehyde binder showed better dye degradation capabilities. 相似文献
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钛矿是我国对外依存度较高的矿种之一,对我国战略性新兴产业的发展起着重要的支撑作用,对全球钛矿行业的发展现状进行分析与研究,能够为我国钛矿资源安全提供重要研究依据.本文对全球钛资源的储量及分布状况、钛资源的生产和消费情况进行了分析.分析结果显示,我国是钛资源大国,钛储量位居世界第一;但多为共伴生矿,品位不高.钛精矿进口量... 相似文献
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M. M. S. Sanad E. A. Abdel-Aal H. M. Osman A. T. Kandil 《International Journal of Environmental Science and Technology》2018,15(11):2459-2472
The photoreduction efficiency of toxic hexavalent chromium into non-toxic trivalent chromium was studied using local low-cost material and modern technology. The materials involved different iron–titanium oxide nanopowders synthesized via simple hydrothermal–hydrolysis process. X-ray diffraction and high-resolution transmission electron microscope were employed to study the structural properties of the as-prepared samples. The effects of molar ratio (Fe/Ti) and hydrothermal temperature on spectroscopic properties have been investigated using Fourier transform infrared FT-IR spectroscopy. The photocatalytic performance of hexavalent chromium was systematically studied at various conditions including initial concentration of Cr(VI), hydrothermal temperature and Fe/Ti ratios of mixed iron–titanium oxide powders. It has been found that the highest photoreduction efficiencies of Cr(VI) were 95.7 and 86.2% at initial concentrations 10 and 60 ppm of Cr(VI), respectively. The synthesized mixed Fe2O3–TiO2 photocatalyst exhibited higher efficiency of about 88% under visible light irradiation. The as-prepared mixed oxide catalyst exhibited high photocatalytic conversion efficiency and recycling stability in comparison with different commercial catalysts. 相似文献
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采用HCl—HNO3-HF—HClO4,HCl—HNO3-HF—H2SO4敞口和HCl-HNO3-HF—HClO4,HCl-HNO3-HF—H2SO4微波消解4种方法溶矿,利用电感耦合等离子体发射光谱（ICP—AES）测定,建立了钛铁矿中钾、钠、钙、镁、钡、锶、锌等元素的同时测定方法。对电感耦合等离子体发射光谱仪测定的最佳仪器条件及分析谱线进行了选择,并对钛、铁基体的影响、溶矿提取酸度以及溶矿残渣进行了研究。实验结果表明：采用HCl-HNO3-HF-HClO4敞口溶矿,具有检出限低、灵敏度高,操作简便、快速等突出优点。该方法测定值与推荐值基本吻合,分析方法的精密度满足《地质矿产实验室测试质量管理规范》的要求。 相似文献
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大白石头沟地区位于中祁连托莱南山北缘,大地构造位置处于中祁连岩浆弧带,成矿区带属于加里东期钨、稀有金属、铜(钛、锑、金)成矿带.钛磁铁矿化体主要产于古元古代托赖岩群片麻岩段、中元古代湟中群磨石沟组片岩段和石英岩段内,矿化体受岩性控制明显,并具多期成矿的特点.通过对钛矿物的岩相观察、电子探针成分分析及人工重砂分析,厘定了钛矿物以钛磁铁矿为主,含少量钛铁矿和微量金红石等.通过深入研究钛磁铁矿成矿地质征及赋存状态,认为:1)矿化类型属于火山喷流-沉积型;2)伟晶岩体不是成矿物质来源,成矿物质最大可能来源于火山喷发带来的富钛质超基性-基性火山岩,且为早期分离结晶后堆晶而成.经大量文献资料查证,在中祁连大白石头沟地区发现钛磁铁矿化体尚属首次,因此本研究成果可为后续的勘查及相关工作提供理论依据. 相似文献
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钛迁移成矿地球化学模式新探索 总被引：5，自引：0，他引：5
通过对钛氢化物和钛合金氢化物的形成条件及理化特征、钛矿物的价态及化学成分、钛矿物的共伴生矿物组合、有关矿物中钛的固态包裹体及流体包裹体气相成分的研讨,考虑到氢在地球形成演化中的作用与重大贡献,认为:钛氢化物、钛合金氢化物是钛的重要迁移形式,它们随岩浆、热液从地球深部迁移至地球浅部,在较还原环境形成自然钛、低价钛矿物,在较氧化环境形成钛的高价矿物,并可在有利部位富集形成钛矿床。 相似文献
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地质年代学为地球与行星科学研究提供时间坐标,以定量解析地质过程先后关系和时间尺度。历经百余年发展,定年技术在研究对象、测试效率、空间分辨率和时间分辨率等维度均得到大幅度提高,地质年代学研究已从仅提供时代约束过渡到更加强调对地质过程时间尺度与节律的研究,进而约束地质事件的驱动机制和互馈机理。然而,基于放射性同位素衰变的绝对定年技术精度存在物理极限,不能无限提高,且其时间分辨率一般随年龄增加而变差,难以满足深时地质研究的高时间分辨率需求,发展时间分辨率不受绝对年龄约束的相对定年技术是地质年代学的重要发展方向。本文围绕扩散年代学这一具有重要发展前景的相对定年技术,在系统回顾其理论模型和测量技术的基础上,重点对制约扩散年代学准确性和精确性的问题,如扩散系数的不确定性、扩散初始条件假设、浓度曲线的测试质量以及误差评估等进行了探讨。本文还对扩散年代学近年来在岩浆储存与运移、成矿时间尺度与节律和变质过程等领域取得的部分重要进展予以评述。精确的扩散系数是开展扩散年代学研究的前提,以石英中的Ti为例,不同实验给出的扩散系数差异超过3个数量级,据此计算的花岗岩岩浆在固相线上的储存时间从几十年变化到百万年尺度,显著影响我们对岩浆储存状态的理解。高质量的元素浓度剖面测量是扩散年代学的关键,因石英Ti含量的高空间分辨率精准测量较为困难,CL灰度常被作为Ti含量的替代指标,但这需要考虑Al等元素对CL灰度的影响,并严格评估Ti含量校正曲线和扩散剖面空间尺度不匹配对定年结果的影响。高温变质过程U Pb定年通常给出较为离散的表观年龄,并被解释为变质过程具有较长的持续时间,这一定程度上可以通过高温下同位素体系因扩散引起的不封闭予以解释。展望未来,进一步完善扩散年代学在高温体系中的研究,拓展在中低温条件下的应用,并与绝对定年深度结合,是扩散年代学的重要发展方向,也是实现深时地质研究高时间分辨率解析的必由之路。 相似文献