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1.
The chemical composition of bottom sediments in the Chukchi and, partly, East Siberian Seas was studied. In the south and west of the Chukchi Sea, a zone has been detected with the accumulation of sediments rich in organic carbon, an increased background content and anomalies of sulfophile metals (Mo, Zn, Hg, Ag, Au), iron-group metals (V, Ni, Co), and some PGE (Ru, Pt). This zone is confined to the neotectonic active system of rift troughs extending from the Bering Strait and eastern Chukchi Peninsula to the continental slope, where it is bounded by the Cenozoic Charlie rift basin of the Canadian hollow. The geochemical features of the carbon-enriched sediments evidence that they formed under oxygen-deficient conditions and, sometimes, in suboxic and anoxic environments near endogenic water and gas sources. The high carbon and metal contents suggest that the very fine-grained sediments in the rift troughs of the Chukchi Sea are a possible analog of some types of ancient highly carbonaceous sediments belonging to black shales.  相似文献   

2.
Ferromanganese nodules from the floors of the Chukchi and East Siberian seas were examined by means of analytical electron microscopy and plasmic and chemical analysis. It was found that the nodules consisted of aggregates of colloform and poorly crystallized matter of globular and irregular shapes, in which the minerals of iron and manganese were mainly presented by hematite, vernadite, and asbolane. The samples from the Chukchi Sea contained single micrograins of native gold. The tested nodules were comparable to oceanic ones in iron content. The contents of manganese, ore elements, and most of microelements are well below those of the ocean. The comparison of the composition of bottom sediments and considered nodules showed that the latter were enriched during their formation by factors of 100–200 in manganese, of 10–18 in cobalt, and of 4–8 in iron, nickel, and zinc. However, the process of diagenetic accumulation of metals by nodules in the marine environment is less effective than in the open ocean with the sediments of higher con-tent of mobile element forms and of higher exposure time compared to marine sediments.  相似文献   

3.
The REE distribution was studied in the bottom sediments of the East Arctic shelf of Russia. It is established that sediments of the Laptev and western East Siberian seas are significantly enriched in REEs, the contents of which are much higher than those of other near-continental basins. The main REE sources are runoff of the Lena River, the basin of which comprises ancient crystalline shields and magmatic rocks enriched in LREEs with significant contribution from the coastal erosion of the ice complex from the Laptev Sea and western East Siberian Sea. The terrigenous flux with a specific REE composition is supplied to the Chukchi Sea through the Bering Strait.  相似文献   

4.
Study of biogeochemical processes in water and sediments of the Chukchi Sea in August 2004 revealed atypical maximums of the concentration of biogenic elements (N, P, and Si) and the rate of microbial sulfate reduction in the surface layer (0–3 cm) of marine sediments. The C: N: P ratio in the organic matter (OM) of this layer does not fit the Redfield-Richards stoichiometric model. Specific features of biogeochemical processes in sea are likely related to the complex dynamics of water, high primary productivity (110–1400 mg C/(m2 day)), low depth of basin (<50 m in 60% of the water area), reduced food chain due to low population of zooplankton, high density of zoobenthos (up to 4230 g m?2), and high activity of microbial processes. Drastic decrease in the concentration of biogenic elements, iodine, total alkalinity (Alk), and population of microorganisms beneath the 0–3 cm layer testify to a large-scale OM decay at the water-seafloor barrier. Our original experimental data support the high annual rate of OM mineralization at the bottom of the Chukchi Sea.  相似文献   

5.
The analysis of the concentrations and distribution of mercury in bottom sediments of marginal seas in northeastern Asia revealed that its maximum contents are characteristic of areas with an active geodynamic regime and some areas of the Amur Bay in the Sea of Japan subjected to anthropogenic impact. The geochemical associations of mercury with other chemical elements and its background concentrations in bottom sediments of these sea basins are defined.  相似文献   

6.
For the first time, the reconstruction of variations in the duration over several hundred years was conducted on the basis of models developed by comparing hydrometeorological observations and detailed scanning of the chemical composition of bottom sediments accumulated during the corresponding period. The gauge models for the reconstruction of air temperature and ice cover of the water area for three sites in the northern part of the Chukchi Sea have been developed. During the reconstruction, an insignificant increase in the duration of the ice-free period during the Little Ice Age was established, which does not coincide with the changes in the temperature regime that took place. It is concluded that the dynamics of the inflow of warm Pacific waters through the Bering Strait had the predominant influence on the ice regime of the Chukchi Sea.  相似文献   

7.
对2003年中国第二次北极科学考察所获得的部分表层沉积物样品进行了总水解氨基酸(THAA)、氨基糖(HA)的测定。不同区域氨基酸主要成分不同,楚科奇海站位的氨基酸主要成分为甘氨酸(Gly)、谷氨酸(Glu),位于加拿大海盆的B80、B11、P27站THAA的主要成分为丝氨酸(Ser)。沉积物的总有机碳(TOC)、总氮(TN)、THAA、HA含量等特征随区域不同有较大差别,白令海峡的BS11站TOC、HA含量最低,加拿大海盆的B80站THAA、TN含量最低。楚科奇海R03站TOC、TN为最高,THAA在R11含量达最大值,HA在楚科奇海台的P11站最高。初步讨论了楚科奇海—加拿大海盆表层沉积物中氨基酸的空间分布,根据氨基酸选择性降解和主成份分析结果引入DI”指标,并对七个站位表层沉积物有机质新鲜程度进行了比较,新鲜度由大至小顺序为C15>BS11>R11>S11>P11>R03>B80,这与表层沉积物来源、水动力条件等有关,由此推测楚科奇海陆架、白令海峡沉积物有机质较楚科奇海台、加拿大海盆较为新鲜。  相似文献   

8.
Satellite altimetry data, Bouguer anomalies, anomalous magnetic field, bottom topography, and Love wave tomography for the deepwater part of the Arctic Ocean Basin and East Siberian Sea have made it possible to detect several new regional tectonic elements. The basin area, 700 km wide and 1800 km long, extending from the Laptev Sea to the Chukchi Borderland is a dextral strike-slip zone with structural elements typical of shearing. The destruction of the Eurasian margin surrounding the Amerasia Basin occurs within this zone. The opening of the Amerasia Basin is characterized by intense plume magmatism superimposed on normal slow spreading in several areas of the paleospreading axis. Magma was supplied through three conduits with minor offsets, the activity of which waned partly or completely by the end of basin formation. The main central conduit formed the structure of the Alpha Ridge. The dextral strike-slip system, which displaces the Gakkel Ridge and structural elements in the basement of the Makarov Basin, most likely extends to the northern termination of the Chukchi Borderland.  相似文献   

9.
The quantitative mineral composition estimated using the Rietveld method and some geochemical features are considered for bulk samples of the ice-rafted sediments (IRS) from some Arctic regions. Layer silicates in the studied samples vary from ~20 to ~50%. They are dominated by micas and their decomposition products (illite and likely some part of smectites) at significant contents of kaolinite, chlorite, and transformation/decomposition products of the latter. A significant content of illite and muscovite among layer silicates in most IRS samples suggests that sources of the sedimentary material were mainly mineralogically similar to modern bottom sediments of the East Siberian and Chukchi seas, as well as presumably sediments of the eastern Laptev Sea. It is suggested that a significant kaolinite fraction in IRS samples from the North Pole area can be caused by the influx of ice-rafted fine-grained sedimentary material from the Beaufort or Chukchi seas, where kaolinite is supplied from the Bering Sea. Positions of IRS data points in the (La/Yb)N–Eu/Eu*, (La/Yb)N–(Eu/Sm)N, and (La/Yb)N–Th diagrams show that the studied samples contain variable proportions of erosion products of both mafic and felsic magmatic rocks and/or sufficiently mature sedimentary rocks. This conclusion is confirmed by localization of IRS data points in the Th/Co–La, Si/Al–Ce, and Si/Al–Sr diagrams.  相似文献   

10.
东海陆架泥质区沉积地球化学比较研究   总被引：38，自引：4，他引：34  
利用东海陆架泥质沉积区和周围砂质沉积区的表层沉积物元素含量和海水悬浮沉积物总量分析资料,对泥质区的沉积地球化学进行了比较研究。结果表明东海不同泥质区的沉积地球化学过程很不相同。浙江近岸泥质区沉积物元素以Fe、Mn、Zn的含量高,Na、Sr、Al、Ca的含量低为特征,其地球化学特征与长江沉积物非常一致。近岸泥质区的沉积物基本来源于长江输入海的沉积物,在台湾暖流的作用下沉积在浙江沿岸。远岸济州岛西南泥质区沉积物以Na、Sr的高含量,较高的Al、Ca含量和低的Fe、Mn、Zn含量为特征,其地球化学特征与黄河源沉积物有好的相关性,但有一定的混合源性质,该泥质区的沉积物主要来源于黄河源的细颗粒沉积物,由黄海沿岸流搬运到该区并沉积下来。沉积物在搬运沉积过程中,元素粒度分异作用明显。东海陆架泥质区沉积地球化学过程的控制性影响因子是东海环流系统和物源,其中台湾暖流对东海陆架远岸和近岸泥质区的沉积地球化学分区具有关键作用。  相似文献   

11.
Doklady Earth Sciences - The quantitative characteristics of the bottom sediment color of the Chukchi Sea is presented. The correlation relationships with the contents of grain-size fractions,...  相似文献   

12.
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13.
2003年夏季中国第二次北极科学考察期间,在北冰洋楚科奇海陆架、楚科奇海台、陆坡流区、门捷列夫海岭和加拿大海盆等不同区域进行了200 m以浅海水和部分观察站沉积物表层叶绿素a浓度的现场观测。结果表明,观测水体叶绿素α浓度变化范围为0.002～39.008 μg/dm3。表层浓度分布范围为0.037～4.644 μg/dm3,平均值为0.612 μg/dm3;高叶绿素α浓度出现在水深20～30 m的次表层水。叶绿素α浓度分布具有明显的区域性特征,水柱平均浓度的次序为楚科奇海陆架区>陆坡流区>楚科奇海台区>加拿大海盆区>门捷列夫海岭区。表层沉积物叶绿素α浓度从未能检出～3.978 μg/g(湿重),平均浓度为0.954 μg/g(湿重),表现为沉积物表层的浓度高于下层,陆架和陆坡流区的浓度高于海岭区以及海台和海盆区的分布特征。  相似文献   

14.
The problems of the origin of Au-rich horizons, which host all significant gold-ore deposits of the region, including valuable objects on a global level (Natalka and Nezhdaninskoe deposits), are considered, exemplified by Permian black shale deposits of the Ayan-Yuryakh anticlinorium of the Yana-Kolyma foldbelt and recent bottom sediments of the Chukchi Sea continental shelf.  相似文献   

15.
Geochemical studies of the ecosystems of 184 Siberian lakes in three largest zones of northern Asia (humid, arid, and semiarid) and in mountainous area were carried out. The contents of natural radionuclides, radiocesium, and rare-earth elements in conjugate components of the systems and the types of the main sources of the bottom sediment material have been determined.Dating of the bottom sediments was made by the activity of radioisotopes 137Cs and 210Pb, which permitted estimation of the sedimentation rates in lakes in different regions of Siberia: 0.35 cm/year in the south and 0.25–0.3 cm/year in the north.Six main ions have been determined in the waters of the studied lakes: Ca2+, Mg2+, Na+, HCO3?, SO42?, and Cl?. The distribution of natural radionuclides in the stratified sections of bottom sediments of Siberian lakes evidences the stable sedimentation and characterizes their contents in the soils of water-catchment areas, which can be considered background contents there. Sediments enriched in organic matter have higher concentrations of U and lower ones of Th and K. The Th/K ratio in the studied bottom sediments is the same as in the soils. The Th/U ratios are somewhat lower than those in the soils because U is accumulated by chemogenic and organic components. The overall 137Cs pollution of bottom sediments of Siberian lakes is close to the global background (40 mCi /km2 in 2000), but in the Altai Territory and Buryatia and Altai Republics it is twice higher. The uneven areal and temporal distribution of residual radiocesium is observed not only in the lacustrine sediments but also in the lake water areas. The REE patterns of bottom sediments of different mineral types are similar to those of continental crust and clays of the Russian Platform, though organogenic and carbonate sediments have higher absolute REE contents than terrigenous ones. Pelitic fraction is the main REE concentrator in the bottom sediments.  相似文献   

16.
The grain size distribution and fraction composition of bottom sediments (BS) in the Amur River are studied. The total composition of sediments, their clay subfractions—water-peptizable (WPC) and aggregated (AC) clays—and residue after clay elutriation were analyzed. It has been established that contents of Fe, Mn, Zn, and Cu in the clay subfractions are 2–4 times higher than in common bottom sediments and their residue left after the extraction of clay subfractions, confirming a significant role of clay minerals in the accumulation of elements mentioned above. It is shown that diatom algae participate in the accumulation and transport of Fe, Mn, Zn, and Cu in the river water-suspended matter-bottom sediments (clay minerals) system. It has been established that high Zr concentrations in bottom sediments are related to the presence of zircon therein.  相似文献   

17.
Data on electron microprobe X-ray analysis of mineral grains of base (Cu, Zn, Sn, Pb, Ni, Bi, and Mo) and precious metals (Ag, Au, Pd, and Pt) detected for the first time in the sediments of the Chukchi Sea are presented. The peculiarities of the morphology and chemical composition of the grains are considered along with their sources and distribution in the sediments.  相似文献   

18.
The specific chemical and mineral composition of discoid, cake-shaped, and platy ferromanganese nodules (FMNs) from the Chukchi Sea are considered. The main ore components of these FMNs are Fe, Mn, and P. The contents of trace elements (except for Ba and Sr) do not exceed hundredths of percent. Maximum concentrations of most of these elements are specific for the cake-shaped nodules. In general, Mn accumulates most intensely in FMNs. Next (in order of decrease) are Ag(?), Co, and Pb; Sr, Fe, P, Y, and Ca; and Ni, La, Zn, and Cu. As for Ba, Cr, Mg, and K, they do not accumulate in the FMNs. “Dilution” is typical of Si, Al, Na, and Ti. The main ore phases are strengite and amorphous Mn hydroxides. It has been revealed for the first time for the Chukchi Sea that Cu, Zn, Sn, Ni, Pb, W, Bi, Cr, Fe, Ti, Ag, Au, Y, Zr, and La–Nd lanthanides form individual mineral microphases in FMNs: native elements, intermetallic compounds, oxides, and, much more seldom, tungstates, silicates, and phosphates. Accessory ore mineralization is the best pronounced and most diverse in the platy nodules. Though the FMNs from the Chukchi Sea are diagenetic, high-temperature fluids are, most likely, the source of microinclusions of various accessory ore minerals.  相似文献   

19.
陕西潼关金矿区太峪河底泥重金属元素的含量及污染评价   总被引：3，自引：1，他引：2  
徐友宁  张江华 《地质通报》2008,27(8):1263-1671
通过对潼关金矿区太峪河和太峪水库底泥中重金属元素总量的调查,探讨了金矿开发活动中重金属元素对河流底泥的污染程度。研究结果表明,除As外,河流底泥中重金属元素的含量与尾矿渣中重金属元素的含量变化一致,表明其主要来源于尾矿渣,但又明显高于尾矿渣。在同一地点河流底泥中重金属元素的含量平均高出河水中的1048.61～666030.08倍,呈显著富集。以邻近地区不受工矿活动影响的河流底泥重金属元素的含量均值作为评价参比值,太峪河底泥受到了Hg、Pb、Cd、Cu、Zn元素的极度污染,单项污染超标倍数及综合污染指数法评价结果表明,Hg、Pb、Cd平均污染超标倍数达366.90、217.42和149.97,是底泥中最主要的污染元素。河流底泥重金属元素的综合污染指数高达278.97,表明河流的复合污染亦呈极度状态。太峪河底泥受重金属元素极度污染的现实提示,矿区的环境防治工作已刻不容缓。  相似文献   

20.
REE geochemical studies of surficial sediment samples from the Yellow Sea of China have shown:(1)The average content of RE2O3 in the Yellow Sea sediments is 175 ppm,close to that in the East China Sea sediments.The REE distribution patterns in the Yellow Sea sediments are also similar to anomalies.These REE characteristics are typical of the continental crust.(2)The contents of REE are controlled mainly by the sediment grain size,i.e.,REE contents increase gradually with decreasing sediment grain size.REE are present mainly in clay minerals.In addition,REE contents are controlled obviously by heavy minerals.REE abundances in heavy minerals are much greater than those in light minerals.(3)Correlation analysis shows that REE have a close relationship with siderophile elements,especially Ti,which has the largest correlation coefficient relative to REE.Terrigenous clastic materials subjected to weathering and transport are suggested to be the main source of REE in the Yellow Sea sediments.  相似文献   

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