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1.
Recently Wilson and Flesch (Boundary-Layer Meteorology, 84, 411-426, 1997) suggested that the average increment d z to the orientation = arctan(w/u) of the Lagrangian velocity-fluctuation vector can be used to distinguish the better Lagrangian stochastic models within the well-mixed class. Here it is demonstrated that the specification of d z constitutes neither a sufficient or universally applicable criterion to distinguish the better Lagrangian stochastic models within the well-mixed class. The hypothesis made by Wilson and Flesch that Lagrangian stochastic models with /PE irrotational are zero-spin models, having d z=0, is proven  相似文献   

2.
In a recent paper, the author introduced a new viscous boundary layer, called the mesolayer, in turbulent shear flow. Its importance stems from its location between the inner and outer regions which are controlled by the law of the wall and Reynolds number similarity, respectively. This intrusion prevents the classical overlap assumption which appears to be fundamental in the derivation of the classical logarithmic behavior. The mesolayer has a thickness proportional to Taylor's microscale . This, and the analogy between the energy equation for the spectrum function of isotropic turbulence and the momentum equation for shear flow, suggest the existence of a similar region in wavenumber space with wavenumber k ~ -1. This mesoregion separates the inner region k ~ k s(where k s-1 and is the Kolmogorov length) and the outer region k k e(where k e -1 and l is the energy-containing eddy size) and again invalidates the overlap assumption which appears to be fundamental in the derivation of the classical k -5/3-behavior of the inertial subrange.Incorporation of the mesoregion into the argument leads to a new theory with k -5/3-behavior in two regions (-1 k k s) and (k e k -1) although with two different coefficients of proportionality (Kolmogorov constants). This leads to a wandering of the spectrum curve about the classical k -5/3 line similar to a wandering in turbulent shear flow about the logarithmic curve. This is clearly indicated by the data for the variation of the Kolmogorov constant.Other data support the new theory. In particular, the location of the point k mwhere the curve of the nonlinear energy-transfer function goes through zero shows agreement with the theory, i.e., k m-1.  相似文献   

3.
Summary The influence of agricultural management on the CO2 budget of a typical subalpine grassland was investigated at the Swiss CARBOMONT site at Rigi-Seebodenalp (1025m a.s.l.) in Central Switzerland. Eddy covariance flux measurements obtained during the first growing season from the mid of spring until the first snow fall (17 Mai to 25 September 2002) are reported. With respect to the 10-year average 1992–2001, we found that this growing season had started 10 days earlier than normal, but was close to average temperature with above-normal precipitation (100–255% depending on month). Using a footprint model we found that a simple approach using wind direction sectors was adequate to classify our CO2 fluxes as being controlled by either meadow or pasture. Two significantly different light response curves could be determined: one for periods with external interventions (grass cutting, cattle grazing) and the other for periods without external interventions. Other than this, meadow and pasture were similar, with a net carbon gain of –128±17g Cm–2 on the undisturbed meadow, and a net carbon loss of 79±17g Cm–2 on the managed meadow, and 270±24g Cm–2 on the pasture during 131 days of the growing season, respectively. The grass cut in June reduced the gross CO2 uptake of the meadow by 50±2% until regrowth of the vegetation. Cattle grazing reduced gross uptake over the whole vegetation period (37±2%), but left respiration at a similar level as observed in the meadow.  相似文献   

4.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

5.
The carbon isotopic ratio of atmospheric carbon dioxide at Tsukuba,Japan   总被引：1，自引：0，他引：1  
To find out the secular and seasonal trends of the 13C value and CO2 concentration in the surface air and the determination of the 13C in the atmospheric CO2 collected at Tsukuba Science City was carried out during the period from July 1981 to October 1983. The monthly average of the 13C value of CO2 in the surface air collected at 1400 LMT ranged from -7.52 to \s-8.45 with an average of -7.96±0.25 and the CO2 concentration in the air varied from 334.5 l 1-1 to 359 l 1-1 with an average of 347.2±6.3 l 1-1. The 13C value is high in summer and low in winter and is negatively correlated with the CO2 concentration. In general, the relationship between the 13C and the CO2 concentration is explainable by a simple mixing model of two different constant carbon isotopic species but the relationship does not always follow the model. The correlation between the 13C value and the CO2 concentration is low during the plant growth season and high at other times. The observed negative deviation of the 13C value from the simple mixing model in the plant growth season is partly due to the isotopic fractionation process which takes place in the land biota.  相似文献   

6.
Summary The performance of evaporation schemes with and approach and their combination within resistance representation of evaporation from bare soil surface is discussed. For this purpose nine schemes, based on different functions of or , on the ratio of the volumetric soil moisture content and its saturated value are used.The quality of the chosen schemes has been evaluated using the results of time integration by the coupled soil moisture and surface temperature prediction model, BARESOIL, using in situ data. A sensitivity analysis was made using two sets of data derived from the volumetric soil moisture content of the top soil layer. One with values below the wilting point (0.17 m3m–3) and the second with values above 0.20m3m–3. Data sets were obtained at the experimental site Rimski anevi, Yugoslavia, from the bare surface of a chernozem soil.With 4 Figures  相似文献   

7.
Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m–3 at each of these stations: 0.107±0.011 g m–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of 210Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with 7Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.  相似文献   

8.
A mass-flux approach is applied to observational data obtained in a convective boundary layer topped with stratocumulus clouds. The observational data were obtained from aircraft measurements during the Atlantic Stratocumulus Transition Experiment (ASTEX). A conditional sampling method is used to calculate average updraft and downdraft values. The vertical fluxes calculated with the mass-flux approach are found to be proportional to the real (measured) fluxes, with a proportionality factor being about 0.6. This value is predicted by theory for two variables having a joint Gaussian distribution function; proportionality factor = 2-1 0.637. The horizontal fractional entrainment and detrainment rates calculated from the data ( 1–2 × 10-2 m-1) are an order of magnitude higher than the rates obtained by large eddy simulations for cumulus convection ( 2–3 × 10-3 m-1) and two orders of magnitude higher than those used in modelling cumulus convection with a mass-flux scheme in an operational weather forecast model ( 3 × 10-4 m-1). A numerical mass-flux model for the thermodynamics was developed and showed that results are in good agreement when compared with measured profiles of the liquid water content.  相似文献   

9.
Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.  相似文献   

10.
Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO2 concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO2, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO2. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= cw for CO2, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux c w. Thus, when the net flux of CO2 is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., c w = – c w. Corrections for the mean convective flux are particularly significant for CO2 because cw and c w are often of similar magnitude. The correct measurement of the net CO2 flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.  相似文献   

11.
Stable Isotope Ratios: Hurricane Olivia   总被引：1，自引：0，他引：1  
The oxygen and hydrogen isotopic compositions of rains from HurricaneOlivia (1994) in the eastern Pacific were measured. The rains werecollected on 24 and 25 September during airplane flights conducted at anelevation of 3 km. Hurricane Olivia peaked in intensity to a category-4storm between the two dates. Isotope ratios of rains from HurricaneOlivia were markedly lower ( 18O = –13.9to –28.8) than that of rain collected from a thunderstormat an elevation of 2.3 km outside the influence of Olivia (18O = –3.8). A distinct decrease in isotoperatios from the first day to the next ( 18O =–18.4 to –21.9) in Hurricane Olivia wasattributed to decreased updraft velocities and outflow aloft. Thisshifted the isotopic water mass balance so that fewer hydrometeors werelifted and more ice descended to flight level. A decrease in the averagedeuterium excess from the first day to the next (d = 15.5 to 7.1)was attributed to an increase in the relative humidity of the watervapor `source' area. We hypothesize that the `source' region for therain was in the boundary layer near the storm center and that becausethe hurricane was at peak intensity prior to the second day the relative humidity was higher.  相似文献   

12.
Aerosol chemical composition and trace gas measurements were made at twolocations on the northeastern peninsula of Tenerife during the ACE-2HILLCLOUD experiment, between 28 June and 23 July 1997. Measurementswere made of coarse (#gt;2.5 m aerodynamic diameter) and fine (#lt; 2.5m) aerosol Cl–, NO3 –,SO4 2–, non-sea saltSO4 2– (NSSS),CH3SO3 – (MSA) andNH4 +, and gas phase dimethylsulphide (DMS), HCl,HNO3, SO2, CH3COOH, HCOOH andNH3. Size distributions were measured using a cascadeimpactor. Results show that in marine air masses NSSS and MSA wereformed via DMS oxidation, with additional NSSS present in air massescontaining a continental component. Using a Eulerian box model approachfor aerosols transported between upwind and downwind sites, a mean NSSSproduction rate of 4.36 × 10–4 gm–3 s–1 was calculated for daytimeclear sky periods (highest insolation), with values for cloudy periodsduring daytime and nighttime of 3.55 × 10–4 and2.40 × 10–4 g m–3s–1, respectively. The corresponding rates for MSA were6.23 × 10–6, 8.49 × 10–6and 6.95 × 10–6 g m–3s–1, respectively. Molar concentration ratios forMSA/NSSS were 8.7% (1.8–18.2%) and 1.9%(1.3–3.5%) in clean and polluted air masses, respectively.Reactions occurring within clouds appeared to have a greater influenceon rates of MSA production, than of NSSS, while conversely daytime gasphase reactions were more important for NSSS. For MSA, nighttimein-cloud oxidation rates exceeded rates of daytime gas phase productionvia OH oxidation of DMS. NSSS, MSA and ammonium had trimodal sizedistributions, with modes at 0.3, 4.0 and >10.0 m (NSSS andNH4 +), and 0.3, 1.5 and 4.0 m (MSA). Nosignificant production of other aerosol species was observed, with theexception of ammonium, which was formed at variable rates dependent onneutralisation of the aerosol with ammonia released from spatiallynon-uniform surface sources. Seasalt components were mainly present incoarse particles, although sub-micrometre chloride was also measured.Losses by deposition exceeded calculated expectations for all species,and were highest for the seasalt fraction and nitrate.  相似文献   

13.
Dimethylsulfide (DMS) in surface seawater and the air, methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO4 2–) in aerosol, and radon-222 (Rn-222) were measured in the northern North Pacific, including the Bering Sea, during summer (13 July – 6 September 1997). The mean atmospheric DMS concentrations in the eastern region (21.0 ± 5.8 nmole/m3 (mean ± S.D.), n=30) and Bering Sea (19.9 ± 9.8 nmole/m3, n=10) were higher than that in the western region (11.1 ± 6.4 nmole/m3, n=31) (p<0.05), although these regions did not significantly differ in the mean DMS concentration in surface seawater. Mean sea-to-air DMS flux in the eastern region (21.0 ± 10.4 mole/m2/day, n=19) was larger than those in the western region (11.3 ± 16.9 mole /m2/day, n=22) and Bering Sea (11.2 ± 7.8 mole/m2/day, n=7) (p<0.05). This suggests that the longitudinal difference in atmospheric DMS was produced by that in DMS flux owing to wind speed, while the possible causes of the higher DMS concentrations in the Bering Sea include (1) later DMS oxidation rates, (2) lower heights of the marine boundary layer, and (3) more inactive convection. The mean MSA concentrations in the eastern region (1.18 ± 0.84 nmole/m3, n=35) and Bering Sea (1.17 ± 0.87 nmole/m3, n=13) were higher than that in the western region (0.49 ± 0.25 nmole/m3, n=28) (p < 0.05). Thus the distribution of MSA was similar to that of DMS, while the nss-SO4 2– concentrations were higher near the continent. This suggests that nss-SO4 2– concentrations were regionally influenced by anthropogenic sulfur input, because the distribution of nss-SO4 2– was similar to that of Rn-222 used as a tracer of continental air masses.  相似文献   

14.
Summary The standard equations for the theory of atmospheric tides are solved here by an integral representation on the continuous spectrum of free oscillations. The model profile of back-ground temperature is that of the U.S. Standard Atmosphere in the lower and middle atmosphere, and in the lower thermosphere, above which an isothermal top extends to arbitrarily great heights. The top is warm enough to bring both the Lamb and the Pekeris modes into the continuous spectrum.Computations are made for semidiurnal lunar tidal pressure at sea level at the equator, and the contributions are partitioned according to vertical as well as horizontal structure. Almost all the response is taken up by the Lamb and Pekeris modes of the slowest westward-propagating gravity wave. At sea level, the Lamb-mode response is direct and is relatively insensitive to details of the temperature profile. The Pekeris mode at sea level has an indirect response-in competition with the Lamb mode-and, as has been known since the time of its discovery, it is quite sensitive to the temperature profile, in particular to stratopause temperature. In the standard atmosphere the Lamb mode contributes about +0.078 mb to tidal surface pressure at the equator and the Pekeris mode about –0.048 mb.The aim of this investigation is to illustrate some consequences of representing the tide in terms of the structures of free oscillations. To simplify that task as much as possible, all modifying influences were omitted, such as background wind and ocean or earth tide. Perhaps the main defect of this paper's implementation of the free-oscillation spectrum is that, in contrast to the conventional expansion in the structures of forced oscillations, it does not include dissipation, either implicity or explicity, and thus does not satisfy causality. Dissipation could be added implicity by means of an impedance condition, for example, which would cause up-going energy flux to exceed downgoing flux at the base of the isothermal top layer. To achieve complete causality, however, the dissipation must be modeled explicity. Nevertheless, since the Lamb and Pekeris modes are strongly trapped in the lower and middle atmosphere, where dissipation is rather weak (except possibly in the surface boundary layer), more realistic modeling is not likely to change the broad features of the present results.Symbols a earth's mean radius; expansion coefficient in (5.3) - b recursion variable in (7.4); proximity to resonance in (9.2) - c sound speed in (2.2); specific heatc p in (2.2) - f Coriolis parameter 2sin in (2.2) - g standard surface gravity - h equivalent depth - i ; discretization index in (7.3) - j index for horizontal structure - k index for horizontal structure; upward unit vectork in (2.2) - m wave number in longitude - n spherical-harmonic degree; number of grid layers in a model layer - p tidal pressure perturbation; background pressurep 0 - q heating function (energy per mass per time) - r tidal state vector in (2.1) - s tidal entropy perturbation; background entropys 0 - t time - u tidal horizontal velocityu - w tidal vertical component of velocity - x excitation vector defined in (2.3); vertical coordinate lnp */p 0 [except in (3.8), where it is lnp /p 0] - y vertical-structure function in (7.1) - z geopotential height - A constant defined in (6.2) - C spherical-harmonic expansion coefficient in (3.6) - D vertical cross section defined in (5.6) and (5.9) - E eigenstate vector - F vertical-structure function for eigenstate pressure in (3.2) [re-defined with WKB scaling in (7.2)] - G vertical-structure function for eigenstate vertical velocity in (3.2) [re-defined with WKB scaling in (7.2)] - H pressure-scale height - I mode intensity defined in (8.1) - K quadratic form defined in (4.4) - L quadratic form defined in (4.4); horizontal-structure magnification factor defined in (5.11) - M vertical-structure magnification factor defined in (4.6) - P eigenstate pressure in (3.2); tidal pressure in (6.2) - R tidal state vector in (5.1) - S eigenstate entropy in (3.2); spherical surface area, in differential dS - T background molecular-scale (NOAA, 1976) absolute temperatureT 0 - U eigenstate horizontal velocityU in (3.2); coefficient in (7.3) - V horizontal-structure functionV for eigenstate horizontal velocity in (3.2); recursion variable in (7.3) - W eigenstate vertical velocity in (3.2) - X excitation vector in (5.1) - Y surface spherical harmonic in (3.7) - Z Hough function defined in (3.6) - +dH/dz - (1––)/2 - Kronecker delta; Dirac delta; correction operator in (7.6) - equilibrium tide elevation - (square-root of Hough-function eigenvalue) - ratio of specific gas constant to specific heat for air=2/7 - longitude - - - background density 0 - eigenstate frequency in (3.1) - proxy for heating functionq =c P/t - latitude - tide frequency - operator for the limitz - horizontal-structure function for eigenstate pressure in (3.2) - Hough function defined in (6.2) - earth's rotation speed - horizontal gradient operator - ()0 background variable - ()* surface value of background variable - () value at base of isothermal top layer - Õ state vector with zerow-component - , energy product defined in (2.4) - | | energy norm - ()* complex conjugate With 10 Figures  相似文献   

15.
This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.  相似文献   

16.
Summary A radiative transfer model has been used to determine the large scale effective 6.6 GHz and 37 GHz optical depths of the vegetation cover. Knowledge of the vegetation optical depth is important for satellite-based large scale soil moisture monitoring using microwave radiometry. The study is based on actual observed large scale surface soil moisture data and observed dual polarization 6.6 and 37 GHz Nimbus/SMMR brightness temperatures over a 3-year period. The derived optical depths have been compared with microwave polarization differences and polarization ratios in both frequencies and with Normalized Difference Vegetation Index (NDVI) values from NOAA/AVHRR. A synergistic approach to derive surface soil emissivity from satellite observed brightness temperatures by inverse modelling is described. This approach improves the relationship between satellite derived surface emissivity and large scale top soil moisture fromR 2=0.45 (no correction for vegetation) toR 2=0.72 (after correction for vegetation). This study also confirms the relationship between the microwave-based MPDI and NDVI earlier described and explained in the literature.List of Symbols f frequency [Hz] - f i(p) fractional absorption at polarizationp - h surface roughness - h h cos2 - H horizontal polarization - n i complex index of refraction - p polarization (H orV) - R s microwave surface reflectivity - T B(p) brightness temperature at polarizationp - T * normalized brightness temperature - T polarization difference (T v-T H) - T s temperature of soil surface - T c temperature of canopy - T max daily maximum air temperature - T min daily minimum air temperature - V vertical polarization - soil moisture distribution factor; also used for the constant to partition the influence of bound and free water components to the dielectric constant of the mixture - empirical complex constant related to soil texture - microwave transmissivity of vegetation (=e –) - * effective transmissivity of vegetation (assuming =0) - microwave emissivity - s emissivity of smooth soil surface - rs emissivity of rough soil surface - vs emissivity of vegetated surface - soil moisture content (% vol.) - K dielectric constant [F·m–1] - K fw dielectric constant of free water [F·m–1] - K ss dielectric constant of soil solids [F·m–1] - K m dielectric constant of mixture [F·m–1] - K o permittivity of free space [8.854·10–12 F·m–1] - high frequency limit ofK wf [F·m–1] - wavelength [m] - incidence angle [degrees from nadir] - polarization ratio (T H/T V) - b soil bulk density [gr·cm–3] - s soil particle density [gr·cm–3] - R surface reflectivity in red portion of spectrum - NIR surface reflectivity in near infrared portion of spectrum - eff effective conductivity of soil extract [mS·cm–1] - vegetation optical depth - 6.6 vegetation optical depth at 6.6 GHz - 37 vegetation optical depth at 37 GHz - * effective vegetation optical depth (assuming =0) - single scattering albedo of vegetation With 12 Figures  相似文献   

17.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

18.
Summary ¶In order to better understand land-atmosphere interactions and increase the predictability of climate models, it is important to investigate the role of forest representation in climate modeling. Corresponding to the big-leaf model commonly employed in land surface schemes to represent the effects of a forest, a so called big-tree model, which uses multi-layer vegetation to represent the vertical canopy heterogeneity, was introduced and incorporated into the National Center for Atmospheric Research (NCAR) regional climate model RegCM2, to make the vegetation model more physically based. Using this augmented RegCM2 and station data for China during 1991 Meiyu season, we performed 10 experiments to investigate the effects of the application of the big-tree model on the summer monsoon climate.With the big-tree model incorporated into the regional climate model, some climate characteristics, e.g. the 3-month-mean surface temperature, circulation, and precipitation, are significantly and systematically changed over the model domain, and the change of the characteristics differs depending on the area. Due to the better representation of the shading effect in the big-tree model, the temperature of the lower layer atmosphere above the plant canopy is increased, which further influences the 850hPa temperature. In addition, there are significant decreases in the mean latent heat fluxes (within 20–30W/m2) in the three areas of the model domain.The application of the big-tree model influences not only the simulated climate of the forested area, but also that of the whole model domain, and its impact is greater on the lower atmosphere than on the upper atmosphere. The simulated rainfall and surface temperature deviate from the originally simulated result and are (or seem to be) closer to the observations, which implies that an appropriate representation of the big-tree model may improve the simulation of the summer monsoon climate.We also find that the simulated climate is sensitive to some big-tree parameter values and schemes, such as the shape, height, zero-plane displacement height and mixing-length scheme. The simulated local/grid differences may be very large although the simulated areal-average differences may be much lower. The area-average differences in the monthly-mean surface temperature and heat fluxes can amount to 0.5°C and 4W/m2, respectively, which correspond to maximum local/grid differences of 3.0°C and 40W/m2 respectively. It seems that the simulated climate is most sensitive to the parameter of the zero-plane displacement among the parameters studied.  相似文献   

19.
Summary The electromagnetic radiation of cloud discharge known as atmospheric radio noise field strength (ARNFS) shows a gradual fall from a frequency of 9 kHz to 81 kHz as studied over a period of two years at Calcutta, very close to Bay of Bengal. The main characteristic features of ARNFS at Calcutta are that-(i) ARNFS shows that midday median value is smaller than midnight median value in all months, (ii) level of daily minimum is higher in February and monsoon compared to other seasons, (iii) sunrise effect and sunset effect are well correlated with local sunrise and sunset times, (iv) the magnitude of sunrise fade and sunrise fade rate are maximum in April and lowest during winter period, (v) the magnitude of sunset fade is higher in premonsoon and postmonsoon while it is lowest in monsoon, (vi) number of occurrence of both sunrise effect and sunset effect is remark-ably smaller in monsoon. The positions of the sun and of atmospheric sources are jointly the causes of seasonal and diurnal variations. The missing of sunrise effect and sunset effect are due to local cloud activity and variation of electron density during geomagnetic storms.With 7 Figures  相似文献   

20.
A technique was developed that allows the determination of the stable carbon isotope ratio of isoprene in air. The method was used for a limited number of ambient measurements as well as laboratory studies of isoprene emitted from Velvet Bean (Mucana pruriens L. var. utilis), including the light and temperature dependence. The mean stable carbon isotope ratio ( 13C) of isoprene emitted from Velvet Bean (Mucana pruriens L. var. utilis) for all our measurements is –27.7 ± 2.0 (standard deviation for 23 data points). Our results indicate a small dependence of the stable carbon isotope ratios on leaf temperature and photosynthetic photon flux density (PPFD). The light dependence is 0.0026 ± 0.0012/( mol of photons m–2 s–1) for the studied range from 400 to 1700 mol of photons m–2 s–1. The temperature dependence is 0.16 ± 0.09/K. On average, the emitted isoprene is 2.6 ± 0.9 lighter than the leaf carbon. An uncertainty analysis of the possibility to use stable carbon isotope ratio measurements of isoprene for estimates of its mean photochemical age suggests that meaningful results can be obtained. This is supported by the results of a small number of measurements of the stable carbon isotope composition of ambient isoprene at different locations. The results range from approximately –29 to –16. They are consistent with vegetation emissions of isoprene that is slightly depleted in 13C relative to the plant material and enrichment of 13C in the atmosphere due to isotope fractionation associated with the reaction with OH-radicals. The stable carbon isotope ratio of ambient isoprene at locations directly influenced by isoprene emissions is very close to the values we found in our emission studies, whereas at sites located remote from isoprene emitting vegetation we find substantial enrichment of 13C. This suggests that stable carbon isotope ratio measurements will be a valuable, quantitative method to determine the extent of photochemical processing of isoprene in ambient air.  相似文献   

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