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1.
A recent theoretical investigation by Terzieva & Herbst of linear carbon chains, C n where n  ≥ 6, in the interstellar medium has shown that these species can undergo efficient radiative association to form the corresponding anions. An experimental study by Barckholtz, Snow & Bierbaum of these anions has demonstrated that they do not react efficiently with molecular hydrogen, leading to the possibility of detectable abundances of cumulene-type anions in dense interstellar and circumstellar environments. Here we present a series of electronic structure calculations which examine possible anionic candidates for detection in these media, namely the anion analogues of the previously identified interstellar cumulenes C n H and C n −1CH2 and heterocumulenes C n O (where n  = 2–10). The extraordinary electron affinities calculated for these molecules suggest that efficient radiative electron attachment could occur, and the large dipole moments of these simple (generally) linear molecules point to the possibility of detection by radio astronomy.  相似文献   

2.
In a recent paper, Elmegreen has made a cogent case, from an observational point of view, that the lifetimes of molecular clouds are comparable to their dynamical time-scales. If so, this has important implications for the mechanisms by which molecular clouds form. In particular, we consider the hypothesis that molecular clouds may form not by in situ cooling of atomic gas, but rather by the agglomeration of the dense phase of the interstellar medium, much, if not most, of which is already in molecular form.  相似文献   

3.
The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH2→HNC+H, and N+CH2→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.  相似文献   

4.
Theoretical predictions by Farebrother et al. and Meijer et al. of rovibrational excitation probabilities in H2 arising from formation by Eley-Rideal processes on a graphite surface are incorporated into a model of the chemistry and excitation of interstellar H2. The model includes the usual radiative and collisional pumping of H2 rotational and vibrational states, in addition to the formation processes. Predictions are made for HH2 rovibrational emission line intensities for representative points in diffuse and in dark interstellar clouds. We find that – if all the interstellar HH2 is formed by this Eley-Rideal process – then the consequences of formation pumping, as distinct from collisional and radiative pumping, should be clearly evident in both cases. In particular, we predict a clear spectral signature of this direct HH2 formation process on graphite, distinct from radiative and collisional pumping; this signature should be evident in both diffuse and dark clouds; but the emissivity for dark clouds is predicted to be some 500 times greater than that in diffuse clouds in which the dense material may be embedded. An observational search for this signature in two dark cloud sources was made, but a preliminary analysis of the data did not yield a detection. The implications of and possible reasons for this preliminary conclusion are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

5.
We review the current observational knowledge of the interstellar magnetic field within ∼150 pc ofthe Galactic center. We also discuss the various theoretical scenarios that have been put forward to explain the existing observations. Our critical overview leads to two important conclusions: (1) The interstellar magnetic field near the GC is approximately poloidal on average in the diffuse intercloud medium and approximately horizontal in dense interstellar clouds. (2) In the general intercloud medium, the field is relatively weak and probably close to equipartition with cosmic rays (B ∼ (6–20) μ G), but there exist a number of localized filaments where the field is much stronger (some filaments could possibly have B ≳ 1 mG). In dense interstellar clouds, the field is probably rather strong, with typical values ranging between a few 0.1 mG and a few mG (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

6.
Transient microstructure in the diffuse interstellar medium (ISM) has been observed towards Galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a molecular component to the transient microstructure. In this paper, we explore the chemistry that may arise in such microstructure. We use a photodissociation region (PDR) code to model the conditions of relatively high density, low temperature, very low visual extinction and very short elapsed time that are appropriate for these objects. We find that there is a well-defined region of parameter space where detectable abundances of molecular species might be found. The best matching models are those where the interstellar microstructure is young (<100 yr), small (∼100 au) and dense  (>104 cm−3)  .  相似文献   

7.
The possibility of nitrogen isotopic fractionation owing to ion–molecule exchange reactions involving the most abundant N-containing species in dense interstellar clouds has been explored. We find that exchange reactions between N atoms and N-containing ions have most influence on the fractionation, although the extent of fractionation is too small to be readily detectable.  相似文献   

8.
We present ultra-high-resolution ( R = 900 000) observations of interstellar Na  i and K  i absorption lines towards κ Vel (HD 81188) which show clear evidence for temporal variation between 1994 and 2000. Specifically, the column densities of K0 and Na0 in the main velocity component have increased by 40 and 16 per cent, respectively, over this period. Earlier work had suggested that this component actually consists of two unresolved sub-components; this result is confirmed here, and the overall line profile is found to be consistent with only one of these sub-components having increased in strength since 1994. We argue that this variation is consistent with the line of sight gradually probing a cold, dense interstellar filament of the kind recently proposed by Heiles to explain other observations of small-scale structure in the interstellar medium.  相似文献   

9.
We give an elementary model for the evolution of dust in galaxies, based on abundance arguments. The model takes account of grain core production in both supernovae and giant stars, and includes mantle growth in the interstellar medium. Destruction of grain cores does not appear to be a dominant effect. We show that a self-consistent picture can be made in which the interstellar dust mass is an approximately constant fraction of the heavy element mass in the interstellar medium. This result is demonstrated to be essentially independent of outflow or inflow of interstellar material.  相似文献   

10.
We explore the role of anisotropic thermal conduction on the evolution of supernova remnants (SNRs) through interstellar media with a range of densities via numerical simulations. We find that a remnant expanding in a dense environment can produce centre-bright hard X-ray emission within 20 kyr, and centre-bright soft X-ray emission within 60 kyr of the supernova event. In a more tenuous environment, the appearance of a centre-bright structure in hard X-rays is delayed until about 60 kyr. The soft X-ray emission from such a remnant may not become centre bright during its observable lifetime. This can explain the observations that show that mixed-morphology SNRs preferentially occur close to denser, molecular environments. Remnants expanding into denser environments tend to be smaller, making it easier for thermal conduction to make large changes in the temperatures of their hot gas bubbles. We show that the lower temperatures make it very favourable to use high-stage ions as diagnostics of the hot gas bubbles in SNRs. In particular, the distribution of O  viii transitions from shell bright at early epochs to centre bright at later epochs in the evolution of an SNR expanding in a dense interstellar medium when the physics of thermal conduction is included.  相似文献   

11.
We present isophot spectrophotometry of three positions within the isolated high-latitude cirrus cloud G 300.2−16.8, spanning from the near- to far-infrared (NIR to FIR). The positions exhibit contrasting emission spectrum contributions from the unidentified infrared bands (UIBs), very small grains (VSGs) and large classical grains, and both semi-empirical and numerical models are presented. At all three positions, the UIB spectrum shapes are found to be similar and the large grain emission may be fitted by an equilibrium temperature of  ∼17.5 K  . The energy requirements of both the observed emission spectrum and optical scattered light are shown to be satisfied by the incident local interstellar radiation field (ISRF). The FIR emissivity of dust in G 300.2−16.8 is found to be lower than in globules or dense clouds and is even lower than model predictions for dust in the diffuse interstellar medium (ISM). The results suggest physical differences in the ISM mixtures between positions within the cloud, possibly arising from grain coagulation processes.  相似文献   

12.
We investigate shattering and coagulation of dust grains in turbulent interstellar medium (ISM). The typical velocity of dust grain as a function of grain size has been calculated for various ISM phases based on a theory of grain dynamics in compressible magnetohydrodynamic turbulence. In this paper, we develop a scheme of grain shattering and coagulation and apply it to turbulent ISM by using the grain velocities predicted by the above turbulence theory. Since large grains tend to acquire large velocity dispersions as shown by earlier studies, large grains tend to be shattered. Large shattering effects are indeed seen in warm ionized medium within a few Myr for grains with radius   a ≳ 10−6  cm. We also show that shattering in warm neutral medium can limit the largest grain size in ISM  ( a ∼ 2 × 10−5 cm)  . On the other hand, coagulation tends to modify small grains since it only occurs when the grain velocity is small enough. Coagulation significantly modifies the grain size distribution in dense clouds (DC), where a large fraction of the grains with   a < 10−6 cm  coagulate in 10 Myr. In fact, the correlation among   RV   , the carbon bump strength and the ultraviolet slope in the observed Milky Way extinction curves can be explained by the coagulation in DC. It is possible that the grain size distribution in the Milky Way is determined by a combination of all the above effects of shattering and coagulation. Considering that shattering and coagulation in turbulence are effective if dust-to-gas ratio is typically more than ∼1/10 of the Galactic value, the regulation mechanism of grain size distribution should be different between metal-poor and metal-rich environments.  相似文献   

13.
Charge‐transfer is the main process linking neutrals and charged particles in the interaction regions of neutral (or partly ionized) gas with a plasma. In this paper we illustrate the importance of charge‐transfer with respect to the dynamics and the structure of neutral gas‐plasma interfaces. We consider the following phenomena: (1) the heliospheric interface ‐ region where the solar wind plasma interacts with the partly‐ionized local interstellar medium (LISM) and (2) neutral interstellar clouds embedded in a hot, tenuous plasma such as the million degree gas that fills the so‐called “Local Bubble”. In (1), we discuss several effects in the outer heliosphere caused by charge exchange of interstellar neutral atoms and plasma protons. In (2) we describe the role of charge exchange in the formation of a transition region between the cloud and the surrounding plasma based on a two‐component model of the cloud‐plasma interaction. In the model the cloud consists of relatively cold and dense atomic hydrogen gas, surrounded by hot, low density, fully ionized plasma. We discuss the structure of the cloud‐plasma interface and the effect of charge exchange on the lifetime of interstellar clouds. Charge transfer between neutral atoms and minor ions in the plasma produces X‐ray emission. Assuming standard abundances of minor ions in the hot gas surrounding the cold interstellar cloud, we estimate the X‐ray emissivity consecutive to the charge transfer reactions. Our model shows that the charge‐transfer X‐ray emission from the neutral cloud‐plasma interface may be comparable to the diffuse thermal X‐ray emission from the million degree gas cavity itself (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

14.
The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 106–7 yr). The abundances of those surface species, such as H2O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH3OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1.  相似文献   

15.
Intermediate-resolution (60 000 R 120 000) observations of interstellar Na  i lines towards 29 stars in the general direction of the Lupus molecular clouds (330°≲ l ≲350°; 0°≲ b ≲25°) are presented. Previously published spectra towards an additional seven stars are also included. Based on the Hipparcos distances to these stars, and the minimum distance at which strong interstellar Na  i lines appear in the spectra, I obtain a distance of ~150±10 pc to the Lupus molecular complex. While in agreement with a number of other independent estimates, this result is at odds with the value of 100 pc recently obtained by Knude & Høg from a Hipparcos -based study of interstellar extinction. A possible explanation for this discrepancy is discussed, and it is concluded that the value of 150±10 pc obtained here is to be preferred. In addition, these observations have some other implications for the structure of the interstellar medium in this direction, and these are briefly considered.  相似文献   

16.
We present spectropolarimetry of the solid CO feature at 4.67 μm along the line of sight to Elias 16, a field star background to the Taurus dark cloud. A clear increase in polarization is observed across the feature with the peak of polarization shifted in wavelength relative to the peak of absorption. This shows that dust grains in dense, cold environments (temperatures ∼20 K or less) can align and produce polarization by dichroic absorption. For a grain model, consisting of a core with a single mantle, the polarization feature is best modelled by a thick CO mantle, possibly including 10 per cent water-ice, with the volume ratio of mantle to bare grain of ∼5. Radiative torques could be responsible for the grain alignment provided the grain radius is at least 0.5 μm. This would require the grain cores to have a radius of at least 0.3 μm, much larger than grain sizes in the diffuse interstellar medium. Sizes of this order seem reasonable on the basis of independent evidence for grain growth by coagulation, as well as mantle formation, inside dense clouds.  相似文献   

17.
The early-stage structure and evolution of a supernova remnant (SNR) depends largely on its ambient interstellar medium, so the interstellar medium becomes the valid probe for investigating the evolution of SNRs. We have observed the 12CO (J = 1 − 0) line emission around the remnant of SN 1572 with the 13.7m millimeter-wave telescope at the Qinghai Station of PMO, in order to investigate the distribution of the CO molecular gas around SN 1572 and provide some observational basis for studying the relationship of SN 1572 with its ambient molecular gas and the evolution of this SNR. The observed result indicates that the molecular gas in the velocity range of VLSR = −69∼ −58 km/s is associated with SN 1572, and this velocity component comes from a large-scale molecular cloud. The molecular gas is distributed along the periphery of the radio shell, continually but not uniformly, and forms a semi-closed molecular shell around the SNR. The enhanced emission exists in its whole eastern half, especially the CO emission is strongest on the northeastern edge. At the emission peak position, the spectral line exhibits a broadened velocity feature (>5 km/s). Combining with available observations in the optical, infrared, X-ray and other wavebands, it is demonstrated that the fast shock wave and ejecta are expanding into the molecular gas on the northeastern edge, and interacting with the dense gas. This interaction will have an important influence on the future evolution of SN 1572.  相似文献   

18.
The simulation or solution of the supernova remnant evolution may be scaled from one interstellar environment to another. We systematically examine this scalability, the use of which is so far still very limited in astrophysical literature. We show how the scalability is affected by various constraints imposed by physical processes and initial conditions, and demonstrate the use of the scaling as a powerful tool to explore the interdependence among relevant parameters, based on a minimum set of simulations. In particular, we devise a scaling scheme that can be used to adaptively generate numerous seed remnants and plant them into 3D hydrodynamic simulations of the supernova-dominated interstellar medium.  相似文献   

19.
We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H2SO4 ·  n H2O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.  相似文献   

20.
We discuss fragmentation processes which induce star formation in the dense walls of expanding shells. We test the influence of the energy input, the interstellar medium scaleheight and the speed of sound in the ambient medium, and formulate the condition for the gravitational fragmentation of expanding shells: if the total surface density of the disc is higher than a certain critical value, the shells are unstable. The value of the critical density depends on the energy of the shell and the sound speed in the interstellar medium.  相似文献   

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