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1.
The South Altyn orogen in West China contains ultra high pressure (UHP) terranes formed by ultra‐deep (>150–300 km) subduction of continental crust. Mafic granulites which together with ultramafic interlayers occur as blocks in massive felsic granulites in the Bashiwake UHP terrane, are mainly composed of garnet, clinopyroxene, plagioclase, amphibole, rutile/ilmenite, and quartz with or without kyanite and sapphirine. The kyanite/sapphirine‐bearing granulites are interpreted to have experienced decompression‐dominated evolution from eclogite facies conditions with peak pressures of 4–7 GPa to high pressure (HP)–ultra high temperature (UHT) granulite facies conditions and further to low pressure (LP)–UHT facies conditions based on petrographic observations, phase equilibria modelling, and thermobarometry. The HP–UHT granulite facies conditions are constrained to be 2.3–1.6 GPa/1,000–1,070°C based on the observed mineral assemblages of garnet+clinopyroxene+rutile+plagioclase+amphibole±quartz and measured mineral compositions including the core–rim increasing anorthite in plagioclase (XAn = 0.52–0.58), core–rim decreasing jadeite in clinopyroxene (XJd = 0.20–0.15), and TiO2 in amphibole (TiM2/2 = 0.14–0.18). The LP–UHT granulite facies conditions are identified from the symplectites of sapphirine+plagioclase+spinel, formed by the metastable reaction between garnet and kyanite at <0.6–0.7 GPa/940–1,030°C based on the calculated stability of the symplectite assemblages and sapphirine–spinel thermometer results. The common granulites without kyanite/sapphirine are identified to record a similar decompression evolution, including eclogite, HP–UHT granulite, and LP–UHT granulite facies conditions, and a subsequent isobaric cooling stage. The decompression under HP–UHT granulite facies is estimated to be from 2.3 to 1.3 GPa at ~1,040°C on the basis of textural records, anorthite content in plagioclase (XAn = 0.25–0.32), and grossular content in garnet (XGrs = 0.22–0.19). The further decompression to LP–UHT facies is defined to be >0.2–0.3 GPa based on the calculated stability for hematite‐bearing ilmenite. The isobaric cooling evolution is inferred mainly from the amphibole (TiM2/2 = 0.14–0.08) growth due to the crystallization of residual melts, consistent with a temperature decrease from >1,000°C to ~800°C at ~0.4 GPa. Zircon U–Pb dating for the two types of mafic granulite yields similar protolith and metamorphic ages of c. 900 Ma and c. 500 Ma respectively. However, the metamorphic age is interpreted to represent the HP–UHT granulite stage for the kyanite/sapphirine‐bearing granulites, but the isobaric cooling stage for the common granulites on the basis of phase equilibria modelling results. The two types of mafic granulite should share the same metamorphic evolution, but show contrasting features in petrography, details of metamorphic reactions in each stage, thermobarometric results, and also the meaning of zircon ages as a result of their different bulk‐rock compositions. Moreover, the UHT metamorphism in UHP terranes is revealed to represent the lower pressure overprinting over early UHP assemblages during the rapid exhumation of ultra‐deep subducted continental slabs, in contrast to the cause of traditional UHT metamorphism by voluminous heat addition from the mantle.  相似文献   

2.
U–Pb analyses of rutile and titanite commonly yield ages that constrain the timing of cooling rather than the timing of their crystallization. Rutile which grew at or close to peak temperature conditions in a mafic granulite, intermediate granulite and mafic amphibolite within juxtaposed litho/tectonostratigraphic units in the Greater Himalayan Sequence (GHS) of NW Bhutan yield LA–MC–ICP–MS U–Pb lower intercept cooling ages of 10.1 ± 0.4, 10.8 ± 0.1 and 10.0 ± 0.3 Ma, respectively. Numerical finite‐difference diffusion models constrained by previously published temperature–time and Pb diffusion data suggest that these ages are best explained by rapid cooling from peak temperature conditions of ～800 °C at 14 Ma in the granulite‐bearing unit and ～650 °C at 12 Ma in the amphibolite‐bearing unit. The good fit between the model and analysed ages confirms the relatively high retention of Pb in rutile suggested by the experimental data. Titanite that grew during an exhumation‐related amphibolite facies overprint on an eclogite facies mineral assemblage from the neighbouring Jomolhari Massif yields a U–Pb lower intercept cooling age of 14.6 ± 1.2 Ma. Diffusion modelling suggests that this age is too old to be consistent with the temperature–time paths inferred for the rutile‐bearing samples. Instead, the titanite age suggests cooling from ～650 °C at an earlier time of 17–15 Ma, implying that the high‐grade rocks in the Jomolhari Massif experienced a different cooling history from the rest of the GHS in NW Bhutan. Together these data show that high‐grade rocks from three apparently different structural levels of the GHS in NW Bhutan experienced rapid cooling at >40 °C Ma?1 at varying times. The highest grade granulite facies rocks were exhumed from deeper structural levels that are not exposed, not preserved, or not yet recognized west of eastern Nepal. A progressive along‐strike change in tectonic regime, metamorphic history and/or exhumation mechanism across the orogen is implied by these thermochronologic data.  相似文献   

3.
Melt loss and the preservation of granulite facies mineral assemblages   总被引：29，自引：3，他引：29  
The loss of a metamorphic fluid via the partitioning of H2O into silicate melt at higher metamorphic grade implies that, in the absence of open system behaviour of melt, the amount of H2O contained within rocks remains constant at temperatures above the solidus. Thus, granulite facies rocks, composed of predominantly anhydrous minerals and a hydrous silicate melt should undergo considerable retrogression to hydrous upper amphibolite facies assemblages on cooling as the melt crystallizes and releases its H2O. The common occurrence of weakly retrogressed granulite facies assemblages is consistent with substantial melt loss from the majority of granulite facies rocks. Phase diagram modelling of the effects of melt loss in hypothetical aluminous and subaluminous metapelitic compositions shows that the amount of melt that has to be removed from a rock to preserve a granulite facies assemblage varies markedly with rock composition, the number of partial melt loss events and the P–T conditions at which melt loss occurs. In an aluminous metapelite, the removal of nearly all of the melt at temperatures above the breakdown of biotite is required for the preservation of the peak mineral assemblage. In contrast, the proportion of melt loss required to preserve peak assemblages in a subaluminous metapelite is close to half that required for the aluminous metapelite. Thus, if a given proportion of melt is removed from a sequence of metapelitic granulites of varying composition, the degree of preservation of the peak metamorphic assemblage may vary widely.  相似文献   

4.
The petrogenetic relations among Ti‐rich minerals in high‐grade metabasites is illuminated here through a detailed petrological investigation of an anatectic garnet–clinopyroxene granulite from the Grenville Province, Ontario, Canada containing rutile, titanite and ilmenite in distinct microtextural settings. Garnet porphyroblasts exhibit zoned Ti concentrations (up to 0.15 wt% TiO2 in their cores), as well as a variety of rutile inclusion types, including clusters of small, variably elongate grains and thin (≤1 μm) oriented needles. Calcite inclusions in garnet, commonly observed surrounding garnet cores containing quartz and clinozoisite, indicate the presence of evolving C–O–H fluids during garnet growth and suggest that the rutile clusters may have formed from subsequent Ti diffusion and rutile precipitation within existing fluid inclusions. Titanite forms large subhedral crystals and typically occurs where the primary garnet–clinopyroxene assemblage is in contact with leucosome containing megacrystic hornblende, silvialitic scapolite and calcic plagioclase. Many titanite crystals exhibit marginal subgrains that correspond with sharp changes in their major and trace element composition, likely related to a dissolution–precipitation or recrystallization process following primary crystallization. Clinopyroxene–ilmenite symplectite coronas surround titanite in most locations, likely forming from reaction with the hornblende‐plagioclase matrix (±fluids/melt). Integration of multi‐equilibria thermobarometry and Zr thermometry in rutile and titanite with phase equilibrium modelling allows definition of a clockwise P–T path evolving to peak pressures of ~1.5 GPa at ~750°C during garnet and rutile growth, followed by peak temperature conditions of ~1.2 GPa and ~820–880°C associated with melt‐present titanite growth, and finally cooling and decompression to regional amphibolite facies conditions (~1.0 GPa and ~750°C) associated with the formation of clinopyroxene–ilmenite symplectites surrounding titanite. P–T pseudosections calculated for the pristine (leucosome‐ and titanite ‐free) metabasite bulk composition reproduce much of the prograde phase relations, but predict rutile as the stable Ti‐rich mineral at the peak thermal conditions associated with melt‐present titanite growth. The P–M(CaO) and T–M(CaO) models show that bulk CaO concentrations have a significant effect on the stability ranges of titanite and rutile. Increased bulk CaO tends to stabilize titanite to higher pressure and temperature at the expense of rutile, with a ≥15% increase in CaO producing the observed titanite‐bearing assemblage at high‐P granulite facies conditions. Thus, the model results are consistent with the textural observations, which suggest that titanite stability is associated with a chemical exchange between the host metabasite and a Ca‐rich melt.  相似文献   

5.
Zircon from a lower crustal metapelitic granulite (Val Malenco, N‐Italy) display inherited cores, and three metamorphic overgrowths with ages of 281 ± 2, 269 ± 3 and 258 ± 4 Ma. Using mineral inclusions in zircon and garnet and their rare earth element characteristics it is possible to relate the ages to distinct stages of granulite facies metamorphism. The first zircon overgrowth formed during prograde fluid‐absent partial melting of muscovite and biotite apparently caused by the intrusion of a Permian gabbro complex. The second metamorphic zircon grew after formation of peak garnet, during cooling from 850 °C to c. 700 °C. It crystallized from partial melts that were depleted in heavy rare earth elements because of previous, extensive garnet crystallization. A second stage of partial melting is documented in new growth of garnet and produced the third metamorphic zircon. The ages obtained indicate that the granulite facies metamorphism lasted for about 20 Myr and was related to two phases of partial melting producing strongly restitic metapelites. Monazite records three metamorphic stages at 279 ± 5, 270 ± 5 and 257 ± 4 Ma, indicating that formation ages can be obtained in monazite that underwent even granulite facies conditions. However, monazite displays less clear relationships between growth zones and mineral inclusions than zircon, hampering the correlation of age to metamorphism. To overcome this problem garnet–monazite trace element partitioning was determined for the first time, which can be used in future studies to relate monazite formation to garnet growth.  相似文献   

6.
Mobilization and migration of the heat‐producing elements (HPE) during anatexis is a critical process in the development of orogenic systems, the evolution of continental crust and the stabilization of cratons. In many crustal rocks the accessory minerals are the dominant hosts of Th and U, and the behaviour of these minerals during partial melting controls the concentrations of these elements in draining melt and residue. We use phase equilibrium modelling to evaluate if loss of melt saturated in the essential structural constituents of the accessory minerals can explain the concentrations of Th and U in residual metasedimentary migmatites and granulites along two well‐characterized crustal transects in the Ivrea zone, Italy and at Mt Stafford, Australia. While an equilibrium model of accessory mineral breakdown and melt loss approximates the depletion of U in the residual crust along both transects, it does not explain the relative enrichment of Th. We propose that the high Th concentrations in residual crust may be explained by either inhibition of monazite dissolution by kinetic factors or near‐peak growth of new high Th grains and overgrowth rims on undissolved monazite due to migration of melt through the orogenic crust. Retention of the HPE in the middle and deep orogenic crust may allow metasedimentary granulites to overcome the enthalpy barrier of melting to achieve ultrahigh temperature conditions and may be partly responsible for the slow cooling of many granulite terranes. Lastly, although the mantle was warmer and crustal heat production was higher in the past, peak temperatures and apparent thermal gradients of high‐temperature (HT)–ultrahigh temperature (UHT) granulite terranes have not decreased significantly since the Neoarchean. However, the pressure of HP granulite facies metamorphism has increased gradually from the Archean to the Phanerozoic, which suggests that the lithosphere became stronger as secular cooling of the mantle enabled plate collisions to form thicker orogens. Thus, as the lithosphere became stronger, the proportion of HT–UHT metamorphism associated with thin lithosphere and mantle heat has decreased, whereas the proportion associated with the formation of thick crust and radiogenic heat has increased.  相似文献   

7.
At first sight, experimental results and observations on rocks suggest that the Zr content in rutile, where equilibrated with quartz and zircon, should be a useful thermometer for metamorphic rocks. However, diffusion data for Zr in rutile imply that thermometry should not, for plausible rates of cooling, give the high temperatures commonly observed in high‐grade metamorphic rocks. It is suggested here that such observations can be accounted for by high‐T diffusive closure of Si in rutile, causing the interior of rutile grains to become insensitive to the thermometer equilibrium well above the temperature of Zr diffusive closure. Paired with comparatively slow grain boundary diffusion and problematic zircon nucleation, this allows for cases of Zr retention in rutile through temperatures where Zr is still diffusively mobile within rutile grains. Other observations that may be accounted for in this context are large inter‐grain ranges of rutile Zr contents uncorrelated with rutile grain size, and flat Zr profiles across individual rutile grains, counter to what would be expected from diffusive closure. A consequence is that it is unlikely that Zr‐in‐rutile thermometry will be useful for estimating rock cooling rates.  相似文献   

8.
Low-pressure granulite facies metasedimentary gneisses exposed in MacRobertson Land, east Antarctica, include hercynitic spinel-bearing metapelitic gneisses. Peak metamorphic mineral assemblages include spinel + rutile + ilmenite + sillimanite + garnet, spinel + ilmenite + sillimanite + garnet + cordierite, ortho-pyroxene + magnetite + ilmenite + garnet, spinel + cordierite + biotite + ilmenite and orthopyroxene + cordierite + biotite, each with quartz, K-feldspar and melt. The presence of garnet + biotite- and cordierite + orthopyroxene-bearing assemblages implies crossing tie-lines in AFM projection for the K2O-FeO-MgO-Al2O3-SiO2-H2O (KFMASH) system. This apparent contradiction, and the presence of spinel, rutile and ilmenite in the assemblages, is acounted for by using the KFMASH-TiO2-O2 system, i.e. AFM + TiO2+ Fe2O3. We derive a petrogenetic grid for this system, applicable to low-pressure granulite facies metamorphic conditions. Retrograde assemblages are interpreted from corona textures on hercynitic spinel and Fe-Ti oxides. The relative positions of the peak and retrograde metamorphic assemblages on the petrogenetic grid suggest that corona development occurred during essentially isobaric cooling.  相似文献   

9.
As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA-ICP-MS and sensitive high-resolution ion microprobe trace element data with electron back-scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile-poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain-free rutile (~600–860°C) and by Zr concentration measurements on low-angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low-angle boundaries relative to strain-free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re-equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid-crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high-strain zones. U–Pb age data obtained from the strain-free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post-deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.  相似文献   

10.
Exposed cross‐sections of the continental crust are a unique geological situation for crustal evolution studies, providing the possibility of deciphering the time relationships between magmatic and metamorphic events at all levels of the crust. In the cross‐section of southern and northern Calabria, U–Pb, Rb–Sr and K–Ar mineral ages of granulite facies metapelitic migmatites, peraluminous granites and amphibolite facies upper crustal gneisses provide constraints on the late‐Hercynian peak metamorphism and granitoid magmatism as well as on the post‐metamorphic cooling. Monazite from upper crustal amphibolite facies paragneisses from southern Calabria yields similar U–Pb ages (295–293±4 Ma) to those of granulite facies metamorphism in the lower crust and of intrusions of calcalkaline and metaluminous granitoids in the middle crust (300±10 Ma). Monazite and xenotime from peraluminous granites in the middle to upper crust of the same crustal section provide slightly older intrusion ages of 303–302±0.6 Ma. Zircon from a mafic to intermediate sill in the lower crust yields a lower concordia intercept age of 290±2 Ma, which may be interpreted as the minimum age for metamorphism or intrusion. U–Pb monazite ages from granulite facies migmatites and peraluminous granites of the lower and middle crust from northern Calabria (Sila) also point to a near‐synchronism of peak metamorphism and intrusion at 304–300±0.4 Ma. At the end of the granulite facies metamorphism, the lower crustal rocks were uplifted into mid‐crustal levels (10–15 km) followed by nearly isobaric slow cooling (c. 3 °C Ma?1) as indicated by muscovite and biotite K–Ar and Rb–Sr data between 210±4 and 123±1 Ma. The thermal history is therefore similar to that of the lower crust of southern Calabria. In combination with previous petrological studies addressing metamorphic textures and P–T conditions of rocks from all crustal levels, the new geochronological results are used to suggest that the thermal evolution and heat distribution in the Calabrian crust were mainly controlled by advective heat input through magmatic intrusions into all crustal levels during the late‐Hercynian orogeny.  相似文献   

11.
Testing the fidelity of thermometers at ultrahigh temperatures   总被引：1，自引：0，他引：1  
A highly residual granulite facies rock (sample RG07‐21) from Lunnyj Island in the Rauer Group, East Antarctica, presents an opportunity to compare different approaches to constraining peak temperature in high‐grade metamorphic rocks. Sample RG07‐21 is a coarse‐grained pelitic migmatite composed of abundant garnet and orthopyroxene along with quartz, biotite, cordierite, and plagioclase with accessory rutile, ilmenite, zircon, and monazite. The inferred sequence of mineral growth is consistent with a clockwise pressure–temperature (P–T) evolution when compared with a forward model (P–T pseudosection) for the whole‐rock chemical composition. Peak metamorphic conditions are estimated at 9 ± 0.5 kbar and 910 ± 50°C based on conventional Al‐in‐orthopyroxene thermobarometry, Zr‐in‐rutile thermometry, and calculated compositional isopleths. U–Pb ages from zircon rims and neocrystallized monazite grains yield ages of c. 514 Ma, suggesting that crystallization of both minerals occurred towards the end of the youngest pervasive metamorphic episode in the region known as the Prydz Tectonic Event. The rare earth element compositions of zircon and garnet are consistent with equilibrium growth of these minerals in the presence of melt. When comparing the thermometry methods used in this study, it is apparent that the Al‐in‐orthopyroxene thermobarometer provides the most reliable estimate of peak conditions. There is a strong textural correlation between the temperatures obtained using the Zr‐in‐rutile thermometer––maximum temperatures are recorded by a single rutile grain included within orthopyroxene, whereas other grains included in garnet, orthopyroxene, quartz, and biotite yield a range of temperatures down to 820°C. Ti‐in‐zircon thermometry returns significantly lower temperature estimates of 678–841°C. Estimates at the upper end of this range are consistent with growth of zircon from crystallizing melt at temperatures close to the elevated (H2O undersaturated) solidus. Those estimates, significantly lower than the calculated temperature of this residual solidus, may reflect isolation of rutile from the effective equilibration volume leading to an activity of TiO2 that is lower than the assumed value of unity.  相似文献   

12.
This study investigates the behaviour of the Zr-in-rutile and Ti-in-zircon thermometers in granulite facies metapelites from the Ivrea-Verbano Zone lower crustal section. U–Pb ages of zircon constrain the timing of regional amphibolite–granulite facies metamorphism to 316 ± 3 Ma and record zircon recrystallisation and resetting of U–Pb ages at 276 ± 4 Ma and 258 ± 3 Ma. Zr-in-rutile thermometry records peak contact metamorphic temperatures related to intrusion of mafic magmatic rocks and gives peak temperatures between 900–930 °C and 1,000–1,020 °C that are consistent with the geological settings of the samples. Ti-in-zircon temperatures of 700–800 °C and 810–870 °C record growth or re-equilibration of zircon after cooling from peak temperatures. Ti-in-quartz thermometry for one sample records both peak and retrograde temperatures. Some rutiles in all samples record resetting of Zr-in-rutile temperatures at ~750–800 °C. Electron microprobe profiles across individual rutiles demonstrate that Zr expulsion occurred by recrystallisation rather than by diffusive exchange. Exsolution of small needles of baddelyite or zircon from rutile is an important method of Zr redistribution, but results in no net Zr loss from the grain. The demonstration that Zr-in-rutile thermometry can robustly record peak temperatures that are not recorded by any other thermometer emphasises the relevance of this technique to investigating the evolution of high-grade metamorphic terranes, such as those that characterise the lower crust.  相似文献   

13.
Lower crustal xenoliths erupted from an intraplate diatreme reveal that a portion of the New Zealand Gondwana margin experienced high‐temperature (HT) to ultrahigh‐temperature (UHT) granulite facies metamorphism just after flat slab subduction ceased at c. 110–105 Ma. P–T calculations for garnet–orthopyroxene‐bearing felsic granulite xenoliths indicate equilibration at ~815 to 910°C and 0.7 to 0.8 GPa, with garnet‐bearing mafic granulite xenoliths yielding at least 900°C. Supporting evidence for the attainment of HT and UHT conditions in felsic granulite comes from re‐integration of exsolution in feldspar (~900–950°C at 0.8 GPa), Ti‐in‐zircon thermometry on Y‐depleted overgrowths on detrital zircon grains (932°C ± 24°C at aTiO2 = 0.8 ± 0.2), and correlation of observed assemblages and mineral compositions with thermodynamic modelling results (≥850°C at 0.7 to 0.8 GPa). The thin zircon overgrowths, which were mainly targeted by drilling through the cores of grains, yield a U–Pb pooled age of 91.7 ± 2.0 Ma. The cause of Late Cretaceous HT‐UHT metamorphism on the Zealandia Gondwana margin is attributed to collision and partial subduction of the buoyant oceanic Hikurangi Plateau in the Early Cretaceous. The halt of subduction caused the fore‐running shallowly dipping slab to rollback towards the trench position and permitted the upper mantle to rapidly increase the geothermal gradient through the base of the extending (former) accretionary prism. This sequence of events provides a mechanism for achieving regional HT–UHT conditions in the lower crust with little or no sign of this event at the surface.  相似文献   

14.
文中对南阿尔金高压-超高压变质带巴什瓦克地区的高压麻粒岩中的金红石进行了电子探针和薄片原位LA ICP MS微量元素分析。数据结果显示,运用电子探针和薄片原位LA ICP MS两种实验方法测得巴什瓦克高压麻粒岩中的金红石Zr含量在误差范围内基本一致。对比研究表明,经过压力校正的Thomkins等(2007)的金红石Zr含量温度计算公式更适合本区高压麻粒岩温度的计算,而采用Zack等(2004)和Watson等(2006)的公式计算的温度分别比前人通过传统温度计获得的温度结果偏高和偏低。按照Thomkins等(2007)的金红石Zr含量温度计算公式,以压力为2 GPa计算获得,巴什瓦克地区新鲜高压麻粒岩样品中金红石Zr含量温度为890~962 ℃,被解释为代表了高压麻粒岩峰期的变质温度;而以压力为1 GPa计算得出,退变高压麻粒岩样品中金红石Zr含量温度为764~822 ℃,代表了晚期中温麻粒岩相退变质阶段的变质温度。以上结果进一步证实南阿尔金高压-超高压变质带巴什瓦克地区的高压麻粒岩经历了峰期超高温/高压麻粒岩相变质作用和晚期中温麻粒岩相退变质作用的叠加。  相似文献   

15.
Mafic granulite, generated from eclogite, occurs in felsic granulite at Kle?, Blanský les, in the Bohemian Massif. This is significant because such eclogite is very rare within the felsic granulite massifs. Moreover, at this locality, strong interaction has occurred between the mafic granulite and the adjacent felsic granulite producing intermediate granulite, such intermediate granulite being of enigmatic origin elsewhere. The mafic granulite involves garnet from the original eclogite, containing large idiomorphic inclusions of omphacite, plagioclase and quartz, as well as rutile. The edge of the garnet is replaced by a plagioclase corona, with the garnet zoned towards the corona and also the inclusions. The original omphacite–quartz–?plagioclase matrix has recrystallized to coarse‐grained polygonal (‘equilibrium’‐textured) plagioclase‐diopsidic clinopyroxene–orthopyroxene also with brown amphibole commonly in the vicinity of garnet. Somewhat larger quartz grains are embedded in this matrix, along with minor ilmenite, rutile and zircon. Combining the core garnet composition with core inclusion compositions gives a pressure of the order of 18 kbar from assemblage and isopleths on a P?T pseudosection, with temperature poorly constrained, but most likely >900 °C. From this P?T pseudosection, the recrystallization of the matrix took place at ~12 kbar, and from Zr‐in‐rutile thermometry, at relatively hot conditions of 900–950 °C. It is largely at these conditions that the eclogite/mafic granulite interacted with the felsic granulite to make intermediate granulite (see next paper).  相似文献   

16.
A detailed investigation of the compositional variation in garnet has been undertaken in a garnet–pyroxene‐bearing granulite from the high‐grade Gföhl Unit, Moldanubian Zone, Lower Austria. Textural observations, together with the interpretation of the preserved garnet chemistry, enables the recognition of both prograde core and peak metamorphic garnet mantle growth stages, an extremely rare feature in high‐P–T granulite facies rocks. Initial thermobarometric calculations undertaken across whole garnet zoning profiles show how correct interpretation of a zoning profile is essential if the maximum peak metamorphic P–T conditions are to be recovered. The effect of retrograde decompression‐ and cooling‐driven reactions on inclusion and host garnet compositions has also been assessed. The results indicate that caution should be exercised when utilizing inclusion and adjacent garnet compositions for the thermobarometric evaluation of peak metamorphic equilibration conditions. Peak P–T conditions were determined by the TWEEQU thermobarometric method, utilizing the core compositions of matrix phases combined with the interpreted high‐P–T garnet mantle composition, to give 15.6 kbar and 1090 °C, consistent with previously determined results for Moldanubian granulites. Similar high‐P–T estimates are also provided by a re‐evaluation of previously published results for a granulite sample from the same lithological unit, using a modified interpretation of garnet and plagioclase compositional data. The new estimates presented confirm the previously disputed idea that the Gföhl Unit underwent a high‐pressure granulite facies stage and is therefore distinctly different from the underlying tectonostratigraphic units. It is emphasized that any interpretation of the peak metamorphic conditions in high‐grade rocks must be based on detailed petrographic observations combined with a thorough understanding of the co‐existing equilibrium mineral compositions.  相似文献   

17.
Relict eclogites and associated high-pressure rocks are present in the Eastern Segment of the SW Swedish gneiss region (the tectonic counterpart of the Parautochthonous Belt of the Canadian Grenville). These rocks give evidence of Sveconorwegian eclogite facies metamorphism and subsequent pervasive reworking and deformation at granulite and amphibolite facies conditions. The best-preserved eclogite relics suggest a clockwise P–T –t history, beginning in the amphibolite facies, progressing through the eclogite facies, decompressing and partially reequilibrating through the high- and medium-pressure granulite facies, before cooling through the amphibolite facies. Textures demonstrate the former coexistence of the plagioclase-free assemblages garnet+clinopyroxene+quartz+rutile+ilmenite, garnet+clinopyroxene+ kyanite+rutile, and garnet+kyanite+quartz+rutile. The former existence of omphacite is evidenced by up to 45 vol.% plagioclase expelled as small grains within large clinopyroxene. Matrix plagioclase is secondary and occurs expelled from clinopyroxene or in fine-grained, granulite facies reaction domains formed during resorption of garnet and kyanite. Garnet shows preserved prograde growth zoning with rimward increasing pyrope content, decreasing spessartine content and decreasing Fe/(Fe+Mg) ratio, but is partly resorbed and reequilibrated at the rims. P–T estimates from microdomains with clinopyroxene+plagioclase+quartz+garnet indicate pressures of 9.5–12 kbar and temperatures of 705–795 °C for a stage of the granulite facies decompression. The preservation of the prograde zoning suggests that the rocks did not reside at these high temperatures for more than a few million years, and chemical disequilibrium and ‘frozen’ reaction textures indicate heterogeneous reaction progress and overstepping of reactions during the decompression through the granulite facies. Together these features suggest a rapid tectonic exhumation. The eclogite relics occur within a high-grade deformation zone with WNW–ESE stretching and associated oblique normal-sense, top-to-the-east (sensu lato) displacement, suggesting that extension was a main cause for the decompression and exhumation. Probable tectonic scenarios for this deformation are Sveconorwegian late-orogenic gravitational collapse or overall WNW–ESE extension.  相似文献   

18.
The metamorphic evolution of rocks cropping out near Stoer, within the Assynt terrane of the central region of the mainland Lewisian complex of NW Scotland, is investigated using phase equilibria modelling in the NCKFMASHTO and MnNCKFMASHTO model systems. The focus is on the Cnoc an t’Sidhean suite, garnet‐bearing biotite‐rich rocks (brown gneiss) with rare layers of white mica gneiss, which have been interpreted as sedimentary in origin. The results show that these rocks are polymetamorphic and experienced granulite facies peak metamorphism (Badcallian) followed by retrograde fluid‐driven metamorphism (Inverian) under amphibolite facies conditions. The brown gneisses are inferred to have contained an essentially anhydrous granulite facies peak metamorphic assemblage of garnet, quartz, plagioclase and ilmenite (±rutile, K‐feldspar and pyroxene) with biotite, hornblende, muscovite, chlorite and/or epidote as hydrous retrograde minerals. P–T constraints imposed by phase equilibria modelling imply conditions of 13–16 kbar at >900 °C for the Badcallian granulite facies metamorphic peak, consistent with the field evidence for partial melting in most lithologies. The white mica gneiss comprises a muscovite‐dominated matrix containing porphyroblasts of staurolite, corundum, kyanite and rare garnet. Previous studies have suggested that staurolite, corundum, kyanite and muscovite all grew at the granulite facies peak, with partial melting and melt loss producing a highly aluminous residue. However, at the inferred peak P–T conditions, staurolite and muscovite are not predicted to be stable, suggesting they are retrograde phases that grew during amphibolite facies retrograde metamorphism. The large proportion of mica suggests extensive H2O‐rich fluid‐influx, consistent with the retrograde growth of hornblende, biotite, epidote and chlorite in the brown gneisses. P–T conditions of 5.0–6.5 kbar at 520–550 °C are derived for the Inverian event. In situ dating of zircon from samples of the white mica gneiss yield apparent ages that are difficult to interpret. However, the data are permissive of granulite facies (Badcallian) metamorphism having occurred at c. 2.7–2.8 Ga with subsequent fluid driven (Inverian) retrogression at c. 2.5–2.6 Ga, consistent with previous interpretations.  相似文献   

19.
The metamorphic rocks of the Ivrea Zone in NW Italy preserve a deep crustal metamorphic field gradient. Application of quantitative phase equilibria methods to metapelitic rocks provides new constraints on the P–T conditions recorded in Val Strona di Omegna, Val Sesia and Val Strona di Postua. In Val Strona di Omegna, the metapelitic rocks show a structural and mineralogical change from mica‐schists with the common assemblage bi–mu–sill–pl–q–ilm ± liq at the lowest grades, through metatexitic migmatites (g–sill–bi–ksp–pl–q–ilm–liq) at intermediate grades, to complex diatexitic migmatites (g–sill–ru–bi–ksp–pl–q–ilm–liq) at the highest grades. Partial melting in the metapelitic rocks is consistent with melting via the breakdown of first muscovite then biotite. The metamorphic field gradient in Val Strona di Omegna is constrained to range from conditions of ～3.5–6.5 kbar at ≈650 °C to ～10–12 kbar at >900 °C. The peak P–T estimates, particularly for granulite facies conditions, are significantly higher than those of most earlier studies. In Val Sesia and Val Strona di Postua, cordierite‐bearing rocks record the effects of contact metamorphism associated with the intrusion of a large mafic body (the Mafic Complex). The contact metamorphism occurred at lower pressures than the regional metamorphic peak and overprints the regional metamorphic assemblages. These relationships are consistent with the intrusion of the Mafic Complex having post dated the regional metamorphism and are inconsistent with a model of magmatic underplating as the cause of granulite facies metamorphism in the region.  相似文献   

20.
Although ophiolitic rocks are abundant in Anatolia (Turkey), only in rare cases have they experienced high‐grade metamorphism. Even more uncommon, in Anatolia and elsewhere are high‐grade meta‐ophiolites that retain an oceanic lithosphere stratigraphy from upper crustal mafic volcanic rocks through lower crustal gabbro to mantle peridotite. The Berit meta‐ophiolite of SE Turkey exhibits both features: from structurally higher to lower levels, it consists of garnet amphibolite (metabasalt), granulite facies metagabbro (as lenses in amphibolite inferred to be retrogressed granulite) and metaperidotite (locally with metapyroxenite layers). Whole‐rock major and trace‐element data indicate a tholeiitic protolith that formed in a suprasubduction setting. This paper presents new results for the metamorphic P–T conditions and path of oceanic lower crustal rocks in the Berit meta‐ophiolite, and an evaluation of the tectonic processes that may drive granulite facies metamorphism of ophiolite gabbro. In the Do?an?ehir (Malatya, Turkey) region, granulite facies gabbroic rocks contain garnet (Grt)+clinopyroxene (Cpx)+plagioclase (Pl)+corundum (Crn)±orthopyroxene (Opx)±kyanite (Ky)±sapphirine (Spr)±rutile. Some exhibit symplectites consisting of Crn+Cpx, Ky+Cpx and/or coronas of garnet (outer shell) around a polygonal aggregate of clinopyroxene that in some cases surrounds a polygonal aggregate of orthopyroxene. Coronitic and non‐coronitic textures occur in proximity in mm‐ to cm‐scale layers; corona structures typically occur in plagioclase‐rich layers. Their formation is therefore related primarily to protolith type (troctolite v. gabbro) rather than P–T path. Phase diagrams calculated for a kyanite‐rich granulite, a plagioclase‐rich non‐coronitic granulite, and a plagioclase‐rich coronitic granulite (taking into account changes in effective bulk composition during texture development) predict peak conditions of ~800°C, 1.1–1.5 GPa; these conditions do not require invoking an unusually high geothermal gradient. In the coronitic metagabbro, reaction textures formed along the prograde path: Crn–Cpx symplectites grew at the expense of garnet, sapphirine and plagioclase. Peak conditions were followed by isobaric cooling of ~150°C. Hornblende–plagioclase thermometry results for host amphibolite (Hbl+Pl±Crn±Grt±relict Cpx) indicate retrograde conditions of 620–675°C and 0.5–0.8 GPa accompanied by infiltration of H2O‐rich fluid. This anticlockwise P–T path differs from an isothermal decompression path previously proposed for these rocks based on the presence of symplectite. Metamorphism of the ophiolitic rocks was driven by closing of the southern Neotethys Ocean, as oceanic lithosphere was obducted (most SE Anatolian ophiolites) or underthrust (Berit meta‐ophiolite). This was followed by subduction of a continental margin, driving cooling of the Berit granulite after the thermal peak at depths of ~40 km.  相似文献   

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