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1.
The Platypus Tuff Bed in the Permian Moranbah Coal Measures provides a basin‐wide marker horizon traceable for over 300 km along strike. The bed is a tephra event unit, the product of a large‐scale volcanic eruptive episode involving a pyroclastic volume > 10 km3. The relatively even thickness (～1–1.5 m) of the tuff across the entire northern Bowen Basin (～10 000 km2) implies a distant source. The tuff is ash‐rich and its original geochemistry has been compromised by diagenetic alteration. Crystal content (10–15%) is dominated by quartz, suggesting a rhyolitic association. SHRIMP U–Pb analysis of zircons indicates an age of 258.9 ± 2.7 Ma for the Platypus Tuff Bed, confirming the Late Permian age that has generally been assigned to the Blackwater Group. The age framework now apparent for the coal‐bearing Blackwater Group suggests an average depositional rate ranging from ～133 m/106 years for its eastern depocentre in the northern Bowen Basin to ～70 m/106 years in more marginal settings to the west.  相似文献   

2.
青藏高原冈底斯带发育有大量的岩浆岩,本文对中拉萨地块西段南缘革吉县西南麻木地区的花岗斑岩和流纹质晶屑凝灰岩进行了详细的岩石学、岩石地球化学、锆石微量元素和锆石Hf同位素研究,综合讨论了其岩浆成因及源区深部过程。麻木研究区内的花岗斑岩和流纹质晶屑凝灰岩属于早白垩世同期岩浆作用的产物,均属于钾玄质岩石,富集大离子亲石元素和轻稀土元素,亏损高场强元素和Eu,具有较高负值的εHf(t)值,分别为-9.57～-3.43和-8.79～-4.80,以及较古老的Hf同位素地壳模式年龄tDM2,分别为1 774～1 388 Ma和1 727～1 477 Ma。研究区早白垩世岩浆岩源于古老下地壳物质的重熔,并有少量地幔物质的加入,经历了岩浆混合后角闪石、长石和黑云母等矿物的分离结晶,最终形成了花岗斑岩和流纹质晶屑凝灰岩。结合前人和本文的研究认为研究区早白垩世岩浆作用的主要诱发机制可能为南向俯冲的班公湖-怒江洋板片回转。  相似文献   

3.
本文对右江盆地北缘晚二叠世大隆组、早三叠世罗楼组中的凝灰岩夹层开展地质分析研究。镜下岩石学鉴定显示其为一套玻屑、晶屑凝灰岩;而其主量元素特征分析表明属流纹质、安山质凝灰岩,具高硅、高铝、高钾特征。结合稀土元素球粒陨石标准化分布型式图及微量元素原始地幔标准化蛛网图形态特征,Y、Nb、Rb、La、Pb及Ce等稀土、微量元素的比值特征,认为凝灰岩的岩浆来源与该时期发生在凭祥一带的中—酸性火山弧活动密切相关。构造背景属于古特提斯洋向北往华南陆块之下俯冲时,形成活动大陆边缘岛弧,弧后陆壳发生伸展活动形成右江盆地。岩浆来源于洋壳俯冲发生部分熔融,且尚未与地幔发生作用,在上升过程中与陆壳物质发生混染,由火山弧的活动喷发而来。  相似文献   

4.
松辽盆地营城组两类酸性火山岩地球化学特征与成因   总被引：4，自引：2，他引：2  
孟凡超  路玉林  刘嘉麒  崔岩 《岩石学报》2013,29(8):2731-2745
松辽盆地断陷期营城组发育一套厚层火山岩,钻井岩心及薄片观察发现,火山岩以流纹岩、英安岩、流纹质凝灰岩及熔结凝灰岩等酸性火山岩为主,中基性岩相对较少。在对样品精细挑选基础上,开展了岩石主量元素、微量元素及Sr-Nd同位素测试分析。结果显示,该套酸性火山岩依据TiO2含量可明显分为两类,其中高Ti酸性火山岩(TiO2>0.45%),规模较小,SiO2含量介于64.87%～68.79%之间,其主量元素、微量元素与亚碱性中基性岩呈连续变化趋势且具有相似的Sr-Nd同位素组成;低Ti酸性火山岩(TiO2<0.4%)SiO2含量为68.93%～76.69%,该类岩石为营城组酸性火山岩主体,与碱性基性岩呈双峰式组合,元素含量及同位素比值变化范围较大。研究表明,两类酸性火山岩的形成都与晚中生代东北地区受古太平洋板块俯冲引起的岩石圈拆沉减薄软流圈上涌有关。在板块俯冲影响下,被富集的亏损地幔源区发生部分熔融,在岩浆演化过程中经历了一定分离结晶作用形成了少量高Ti酸性火山岩岩浆。与此同时,在底侵作用下新生地壳与下地壳物质发生混合熔融,受上地壳不同程度混染后形成了大规模的低Ti酸性火山岩岩浆。  相似文献   

5.
云质岩储集层是准噶尔盆地乌—夏地区一套成因特殊的、富含油气的碳酸盐岩储集层。在分析乌—夏地区二叠系构造、沉积及火山活动等地质背景的基础上,根据风城组云质岩岩心宏观产状,将云质岩分为4种类型:波纹层状云质岩、团块状云质岩、丝絮状云质岩和星散状云质岩。镜下波纹层状云质岩晶粒细小,晶形差;团块状云质岩、丝絮状云质岩、星散状云质岩中白云石晶体以粉—细晶为主,普遍发育雾心亮边、环带交代残余结构。C、O同位素及微量元素等地化分析表明:白云岩化的成岩流体来自二叠系风城组半封闭湖湾的咸化沉积地层水以及下伏二叠系佳木河组、石炭系上涌的海相卤水。包裹体测温表明,蚀变方解石的形成温度为60～70℃,白云石的形成温度为85～105℃,白云石形成晚于蚀变方解石。波纹层状云质岩是准同生成因;团块状云质岩、丝絮状云质岩、星散状云质岩是后期成岩交代成因,交代的原岩是火山物质(凝灰岩)。成岩交代云质岩的成因机理是:火山凝灰物质中的火山玻璃容易发生水解蚀变,产物为蒙脱石、长石和石英;蒙脱石转化为伊利石、长石水解蚀变均可析出大量的Ca2+,结合CO2或CO32-形成蚀变产物方解石;方解石在富Mg2+流体交代下发生强烈白云岩化作用。  相似文献   

6.
Early Cretaceous rhyolitic tuffs, widely distributed on Port Island, provide insights into the volcanism and tectonic setting of Hong Kong. In this paper we present petrological, geochronological and geochemical data of the rhyolitic tuff to constrain the diagenesis age and petrogenesis of the rocks, tectonic setting and early Cretaceous volcanism of Hong Kong. The first geochronological data show that the zircons in the volcanic rocks have U-Pb age of 141.1–139.5 Ma, which reveals that the rhyolitic tuff on Port Island was formed in the early Cretaceous (K1). Geochemically, these acid rocks, which are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs), belong to the high K calc-alkaline to shoshonite series with strongly-peraluminous characteristic. The geochemical analyses suggest that the volcanic rocks were derived from deep melting in the continental crust caused by basaltic magma underplating. Based on the geochemical analysis and previous studies, we concluded that the rhyolitic tuffs on Port Island were formed in a back-arc extension setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.  相似文献   

7.
The elastic properties of two types of aluminosilicate (basaltic and rhyolitic) glasses have been studied using both Brillouin and Raman spectroscopy at ambient conditions. It has been found that the elastic moduli of the basaltic glasses decrease with increasing SiO2 concentration. The shear moduli displayed the least dependence on SiO2 content. The bulk moduli of the basaltic glasses strongly depend on the sum of the Q 3 and Q 4 anionic units. Among the modifiers, iron cations showed the strongest effect on the elastic properties of the rhyolitic glasses. For the elastic moduli of rhyolitic glasses, the major effect of alkaline earth cations is on shear modulus; however, both iron and alkali cations showed stronger effects on bulk modulus and similar relative contribution between bulk and shear moduli (based on the equivalent M+ cation). The dependences of elastic moduli on bulk NBO/T observed in both types of glasses suggest that the elastic modulus of an aluminosilicate glass depends on the concentration of effective modifying cations rather than the apparent concentration of all non-network-forming cations. An analysis of data also indicated that the ideal molar mixing model is failed in prediction of the elastic properties of the present multicomponent glasses by using the known parameters.  相似文献   

8.
黑龙江省先锋北山金矿床地处完达山造山带西南段,矿体主要赋存在流纹岩、岩屑晶屑凝灰岩和流纹质角砾岩中。文章系统研究了与成矿密切相关的火山岩的地球化学特征,同时,对其进行了LA-ICP-MS锆石U-Pb测年。与成矿相关的火山岩(流纹岩、岩屑晶屑凝灰岩、流纹质角砾岩)表现出高硅、富碱,贫铝、镁、钙的特征,属碱性系列岩石;具有弱的Eu负异常;富集大离子亲石元素K、Rb、Th等;亏损高场强元素Ta、Nb、P、Ti等。同时,Ba、Sr、Eu等元素亦表现为亏损,具有典型的同碰撞环境的地球化学特征。LA-ICP-MS锆石U-Pb测年显示,流纹岩、流纹质角砾岩和石英闪长玢岩的206Pb/238U谐和年龄分别为(116.98±0.47)Ma、(116.98±0.42)Ma和(108.48±0.99)Ma。结合矿区侵入接触关系,限定先锋北山金矿床的形成时间介于(116.98±0.47)Ma~(108.48±0.99)Ma,即早白垩世晚期。该矿床的形成与太平洋板块的俯冲和佳木斯与完达山地块的拼合有着密切的关系,系古太平洋板块构造体制由挤压变为伸展背景下的产物。  相似文献   

9.
The solubility of CO2 in dacitic melts equilibrated with H2O-CO2 fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO2 is dissolved in dacitic glasses as molecular CO2 and carbonate. The quantification of total CO2 in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm−1 can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO2 species concentrations from the MIR spectra we have measured total CO2 contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO2 solubility in dacitic melts on xfluidCO2,total shows a strong positive deviation from linearity with almost constant CO2 solubility at xCO2fluid > 0.8 (maximum CO2 solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO2. A similar nonlinear variation of CO2 solubility with xCO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO2 (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO2 molecules.A thermodynamic model describing the dependence of the CO2 solubility in hydrous rhyolitic and dacitic melts on T, P, fCO2 and the mol fraction of water in the melt (xwater) has been developed. An exponential variation of the equilibrium constant K1 with xwater is proposed to account for the nonlinear dependence of xCO2,totalmelt on xCO2fluid. The model reproduces the CO2 solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low xCO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO2 at low pressures (a Henrian behavior of the CO2 solubility is observed at low pressure and low H2O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the xCO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO2 is much lower in rhyolitic melts (31.7 cm3/mol) than in dacitic melts (46.6 cm3/mol). The dissolution enthalpy for CO2 in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO2 solubility in silicic melts.  相似文献   

10.
Relicts of silicate-iron fluid media were found in the Early Cretaceous rhyolites of the Nilginskaya depression, Central Mongolia. They are localized in matrix cavities and in the inclusions in quartz and sanidine phenocrysts. The mineral composition of rhyolites and aggregates of silicate-iron phases has been studied. Calculations showed that crystallization of ilmenite and magnetite in a matrix occurred within a temperature range of 593–700°C and oxygen fugacity $\Delta \log f_{O_2 }$ NNO from ?2.29 to 1.68. The average compositions of the rhyolites and residual glasses in melt inclusions (MI) have A/CNK index of 1.03–1.05. The compositions of MI glasses define a trend from agpaitic to plumasitic types (A/NK and A/CNK change from 0.8–0.9 to 1.1–1.2). According to calculations, the rhyolitic melt was solidified at 640–750°C. Based on cathodoluminescent study, inclusions with silicate-iron phases are observed separately or together with MI in the early and intermediate growth zones of quartz and sanidine crystals. Aggregates found in the inclusions are represented by loose matter consisting of silica with small admixture of Al, Na, K, and Cl; silicate-iron aggregates with wide variations of Fe and Si; essentially Fe-rich micaceous and mica-silicate-iron aggregates. They usually have variable composition (wt %): 30–60 SiO2, 10–25 Al2O3, 10–30 FeO, up to 3 TiO2, 1.5–4 MgO, up to 3 CaO, up to 3 Na2O, up to 3 K2O, and up to 4 P2O5. They presumably contain up to 10–15 wt % H2O. Some inclusions comprise large segregations of siderophyllite enriched in F (3–10 wt %) and Cl (0.1–3.3 wt %). Evolution of the rhyolitic melt from magmatic chamber to its vitrification after ejection led to the decrease of F content. The highest F content (1–1.8 wt %) is typical of MI glasses, while the lowest content (0.05–0.1 wt %) was found in the glassy matrix and rhyolitic samples. The melt degassing was accompanied by the release of F-rich fluid containing up to 1.3 wt % F (based on partition coefficient fluid/meltDF) or 0.2–0.8 mol/dm3 HF (based on composition of micas from matrix and inclusions). Segregations of silicate-iron media existed in the rhyolitic magma. During formation of rhyolitic pile, these media were in a liquid state. The silicate-iron fluid media captured in MI could not be true fluids or silicate melts. They were likely formed during fluid-magmatic interaction and transformation of fluid phases of different density (vapor and liquid true solutions) that existed in a F-rich melt. The high concentrations of F and Cl and elevated alkalinity of fluids contribute their enrichment in silica and other elements, which could lead to the formation of hydrosilicate liquids. It is suggested that such liquids (gels) in dispersed (colloidal) state extracted F and many trace elements (P, Ti, Mg, Ca, REE, As, Nb, Th, and V) from surrounding rhyolitic magma.  相似文献   

11.
The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO3 type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ13CVPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO2 gases. According to the δ34SCDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na+, Ca2+, Mg2+, Cl?, and HCO3 ?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.  相似文献   

12.
The Nopal I uranium deposit of the Sierra Peña Blanca, Mexico, has been the focus of numerous studies because of its economic importance and its use as a natural analog for nuclear-waste disposal in volcanic tuff. Secondary uranyl minerals such as uranophane, Ca[(UO2)(SiO3OH)]2(H2O)5, and weeksite, (K,Na)2[(UO2)2(Si5O13)](H2O)3, occur in the vadose zone of the deposit and are overgrown by silica glaze. These glazes consist mainly of opal A, which contains small particles of uraninite, UO2, and weeksite. Close to a fault between brecciated volcanic rocks and welded tuff, a greenish silica glaze coats the altered breccia. Yellow silica glazes from the center of the breccia pipe and from the high-grade pile coat uranyl-silicates, predominantly uranophane and weeksite. All silica glazes are strongly zoned with respect to U and Ca, and the distribution of these elements indicates curved features and spherical particles inside the coatings. The concentrations of U and Ca correlate in the different zones and both elements inversely correlate with the concentration of Si. Zones within the silica glazes contain U and Ca in a 1:1 ratio with maximum concentrations of 0.08 and 0.15 at.% for the greenish and yellow glazes, respectively, suggesting trapping of either Ca1U1-aqueous species or -particles in the colloidal silica. X-ray photoelectron spectroscopy (XPS), Fourier-transform infra-red spectroscopy (FTIR), and oxygen-isotope ratios measured by secondary-ion mass spectrometry (SIMS) indicate higher U6+/U4+ ratios, higher proportions of Si-OH groups and lower δ18O values for the greenish silica glaze than for the yellow silica glaze. These differences in composition reflect increasing brecciation, porosity, and permeability from the center of the breccia pipe (yellow silica glaze) toward the fault (green silica glaze), where the seepage of meteoric water and Eh are higher.  相似文献   

13.
Ala?at? tuff has been used extensively as a source of building stone for outdoor and indoor decorations since the historical times in and around the tourist town of Ala?at? (western Turkey). The use of the Alacati tuff in buildings has been made compulsory by the Ala?at? municipality, for preserving the historical appearance of the buildings, after 2005 in Ala?at?. It has been noticed that, evident deteriorations developed in tuff surfaces of the stone buildings and garden walls within 5?C6?years of their emplacement. Durability properties of the Ala?at? tuff are evaluated by determining the mineralogical, chemical, and physico-mechanical properties of the fresh tuff samples obtained from the only operative quarry in the area. Ageing tests such as Na2SO4 and MgSO4 salt crystallization, freezing?Cthawing, and wetting?Cdrying were conducted on the fresh tuff samples to assess their durability. Additionally, the durability of the tuff is also evaluated by determining its average pore diameter, saturation coefficient, wet-to-dry strength ratio, static rock and slake-durability indices. Fresh Ala?at? tuff has high porosity and low unit weight and strengths and are classified to be very poor to moderately durable stone based on the test results of different durability assessment methods. Mineralogical and geochemical analyses have also been carried out on the deteriorated tuff samples collected from the surfaces of the stone buildings to determine the effect of weathering on tuff and the test results have been compared with those of the fresh tuff samples. There is no major difference observed between the mineralogy and chemistry of the fresh and weathered tuff samples thus, it has been concluded that physical weathering has been dominant in the area in deterioration of tuff.  相似文献   

14.
Experimental studies have been performed to constrain sulfur behavior during apatite crystallization and to determine sulfur partition coefficient between apatite and melt (KdSapatite/melt) at oxidizing conditions. Crystallization experiments have been conducted with a hydrous rhyolitic melt and different bulk sulfur contents (0.15 to 2 wt.% S) at 900 and 1,000°C, 200 MPa and Δlog =NNO+3.6. The sulfur content in the glass increases with increasing amount of added S. Anhydrite crystallizes for S added = 0.75 wt.% (0.10 and 0.13 wt.% SO3 in glass at 900 and 1,000°C, respectively). The amount of anhydrite increases and the amount of apatite decreases with increasing amount of added sulfur. The sulfur exchange reaction in apatite is influenced by the bulk composition of the melt (e.g., P content). However, changing melt composition has only little effect on KdSapatite/melt for the investigated rhyolitic composition. The KdSapatite/melt does not depend directly on temperature, decreases from 14.2 to 2.7 with increasing S content in glass from SO3=0.03 to 0.19 wt.%, respectively, and can be predicted from the following equation: ln Kd = −0.0025×S in melt (in ppm)+2.9178. The combination of experimental data obtained for rhyolitic and andesitic melts reveals that the sulfur partition coefficient tends toward a value of 2 for high-sulfur content in the glass (>0.2 wt.% SO3). Using S in apatite as proxy for determining S content in melt is promising but additional experimental data are needed to clarify the individual effects of T, , and P and Ca content in the melt on S partitioning.  相似文献   

15.
The Loch Ba ring-dyke in the Tertiary igneous central complex of Mull, N.W. Scotland is composed predominantly of a banded rhyolitic welded tuff. The rhyolite contains numerous inclusions of dark aphanitic rock. The textural relationships between the different rocks indicate rapid, violent and intimate mixing during emplacement of the dyke. The dark glassy component varies continuously from basaltic andesite to andesite, dacite and rhyolite. These glasses are enriched in FeO and depleted in MgO at a given SiO2 content in comparison to other tholeiitic highly differentiated volcanic rocks. The rhyolite contains an average of 4% phenocrysts and is associated with the mineral assemblage plagioclase (An32 to An21)-sanidine(Or50–60)-hedenbergite-fayalite-magnetite-ilmenite-apatite-zircon. Mineral aggregates involving either plagioclase-hedenbergite-ilmenite or plagioclase-fayalite-magnetite are common, but aggregates containing fayalite and hedenbergite together are scarce. The dark glassy components are either phenocryst free or contain less than 0.2% phenocrysts. The main phenocrysts associated with the dark glasses are plagioclase (An65-An30), high calcium clinopyroxene ranging continuously from augite to pure hedenbergite, pigeonite, magnetite, ilmenite and rare apatite. Zoning in minerals is generally weak or absent. The plagioclase feldspar, high calcium clinopyroxenes and pigeonites have similar compositional ranges to the minerals observed in the Middle and Upper Zones of the Skaergaard Intrusion. The mineral compositions are systematically related to SiO2 content and Mg number of the glasses. The data demonstrate that mineral compositions and assemblages similar to the Skaergaard form from silica-rich andesitic to rhyolitic liquids. The various mafic glasses are interpreted to have been derived from a zoned magma chamber underlying an upper layer of rhyolitic magma. Differentiation is attributed to fractional crystallization of the observed mineral assemblages causing SiO2 enrichment and FeO depletion. However, glasses with less than 57% SiO2 have unusual compositions with very low MgO and P2O5 as well as variable Al2O3 and TiO2. Their peculiarities could be explained by andesitic magmas assimilating cumulate mineral aggregates precipitated from more differentiated dacite and rhyolite magmas. The bulk compositions of these cumulates have high FeO, low SiO2 and negligible MgO and P2O5. It is suggested that the high density of the mineral aggregates containing fayalite-hedenbergite-magnetite and ilmenite caused them to settle through the zoned chamber to be assimilated by high temperature, less differentiated magmas.  相似文献   

16.
Two representative geologic sections of the late Mesozoic ‘Nanyuan Formation’ volcanic rocks in eastern Fujian Province have been dated by SHRIMP zircon U–Pb techniques. The results identified two active volcanic stages at 162–150 Ma and 143–130 Ma. The rock association of the earlier period is composed of andesite‐dacitic crystal tuff‐rhyolitic ignimbrite. The rocks are enriched in alkali elements, Al2O3, large ion lithophile element (LILE) and light rare earth element (LREE), depleted in MgO, high field strength element (HFSE) and siderophile elements, and have similar ?Nd (t) values. These features indicate that the rocks were derived from a mantle source metasomatized by subduction‐related fluids, and their chemical variations indicate fractional crystalization during magmatic evolution. In contrast, the rock association of the later period consists of tholeiitic basalt‐rhyolitic crystal ignimbrites. The tholeiitic basalts have negative ?Nd (t) values (?3.4 to ?2.6) and exhibit fractionated REE pattern with weak negative Eu anomalies. These rocks are enriched in LREE and depleted in HFSE with ratios of Ce/Pb = 6.9–11.1, Th/U = 2.7–4.0, La/Nb = 2.2–3.0, suggesting that they were also subduction‐related and experienced proportional fractionation of olivine and clinoproxene along with significant crustal contamination. The rhyolitic crystal ignimbrites are generally characterized by rather high K, Rb, Th and relatively low Nb, Sr, Ti, P, with relatively low ?Nd (t) values (?5.3 to ?6.0), impling that they were derived from a different source from the tholeiitic basalt. Judging by extensive overthrust structures, the occurrence of the earlier rock association is considered to have been generated in a compressional tectonic environment during the early stage (>150 Ma) of Pacific plate subduction, In contrast, the later bimodal association was generated in an extensional tectonic setting during a later stage (<143 Ma ) of subduction.  相似文献   

17.
Basaltic lava flows and high-silica rhyolite domes form the Pleistocene part of the Coso volcanic field in southeastern California. The distribution of vents maps the areal zonation inferred for the upper parts of the Coso magmatic system. Subalkalic basalts (<50% SiO2) were erupted well away from the rhyolite field at any given time. Compositional variation among these basalts can be ascribed to crystal fractionation. Erupted volumes of these basalts decrease with increasing differentiation. Mafic lavas containing up to 58% SiO2, erupted adjacent to the rhyolite field, formed by mixing of basaltic and silicic magma. Basaltic magma interacted with crustal rocks to form other SiO2-rich mafic lavas erupted near the Sierra Nevada fault zone.Several rhyolite domes in the Coso volcanic field contain sparse andesitic inclusions (55–61% SiO2). Pillow-like forms, intricate commingling and local diffusive mixing of andesite and rhyolite at contacts, concentric vesicle distribution, and crystal morphologies indicative of undercooling show that inclusions were incorporated in their rhyolitic hosts as blobs of magma. Inclusions were probably dispersed throughout small volumes of rhyolitic magma by convective (mechanical) mixing. Inclusion magma was formed by mixing (hybridization) at the interface between basaltic and rhyolitic magmas that coexisted in vertically zoned igneous systems. Relict phenocrysts and the bulk compositions of inclusions suggest that silicic endmembers were less differentiated than erupted high-silica rhyolite. Changes in inferred endmembers of magma mixtures with time suggest that the steepness of chemical gradients near the silicic/mafic interface in the zoned reservoir may have decreased as the system matured, although a high-silica rhyolitic cap persisted.The Coso example is an extreme case of large thermal and compositional contrast between inclusion and host magmas; lesser differences between intermediate composition magmas and inclusions lead to undercooling phenomena that suggest smaller T. Vertical compositional zonation in magma chambers has been documented through study of products of voluminous pyroclastic eruptions. Magmatic inclusions in volcanic rocks provide evidence for compositional zonation and mixing processes in igneous systems when only lava is erupted.  相似文献   

18.
华南东部内陆地区在侏罗纪处于陆内伸展背景已逐渐成为学术界共识,但对于该时期东部陆缘的构造环境仍存在争议。本文以浙东南毛弄组火山岩为对象,开展了岩石学、SHRIMP锆石U-Pb年代学、锆石微量元素、全岩元素地球化学和Sr-Nd同位素等研究,为认识华南东部陆缘构造背景提供制约。浙江侏罗纪火山岩以松阳毛弄剖面较具代表性,总体上是一套以英安质晶屑凝灰岩和流纹质玻屑凝灰岩为主的火山岩组合。本次研究在毛弄组下段获得的流纹质玻屑凝灰岩的SHRIMP锆石U-Pb年龄为153±2Ma。综合前人研究表明,毛弄组火山岩主要形成于180～148Ma。毛弄组火山岩属于镁质钙碱性系列,且表现出明显的轻稀土元素富集特征,其中早侏罗世毛弄英安质凝灰岩Eu负异常不明显,而晚侏罗世毛弄流纹质凝灰岩具有显著的Eu负异常;两组凝灰岩均富集K、Rb和Th等大离子亲石元素,亏损Nb、Ta、Zr和Hf等高场强元素。毛弄英安质火山岩的源区残留相组合可能为"斜长石+石榴石+角闪石",而毛弄流纹质凝灰岩则可能为"斜长石+角闪石",这一差异可能代表它们具有不同的源区深度。毛弄组火山岩的Sr-Nd-Hf同位素特征与华夏陆块古元古代基底岩体相似,其可能主要起源于基底地壳物质的部分熔融,并有少量地幔新生物质的加入。结合构造背景分析认为,毛弄组火山岩等陆缘岩浆岩形成环境为相对低温的"安第斯型"俯冲环境。通过不同时代区域岩体锆石氧逸度计算发现,早侏罗世东南海域岩浆岩的氧逸度比大陆陆缘更高,且大陆陆缘岩浆岩的氧逸度从晚三叠世至晚侏罗世不断升高,可能标志着陆缘地区俯冲流体的影响有着从东南海域向大陆陆缘扩散的趋势。综合分析认为,在侏罗纪华南东部陆缘可能发育一个与古太平洋俯冲有关的"安第斯型"陆缘岩浆弧,其时代可能最早可以追溯到早侏罗世早期,并持续扩大到中-晚侏罗世。这一时期浙闽沿海地区总体处于弧后挤压主导的构造环境,与同期内陆地区构造伸展背景形成鲜明对比。  相似文献   

19.
舒家坝群(D2-3S)是西秦岭北带构造蚀变岩型金矿重要的赋矿地层,为一套浅变质的具类复理石沉积特征的细碎屑岩及少量碳酸盐岩组合,形成时代为中晚泥盆世。通过1∶5万区域地质调查,在西秦岭两当县北解板沟一带原划舒家坝群中新填绘出一套被断裂围限的火山岩-火山碎屑岩系,与舒家坝群的主体岩性差别明显。通过对该火山岩-火山碎屑岩系进行LA-ICP-MS锆石U-Pb测年,分别获得其中流纹质晶屑凝灰岩加权平均年龄为204±2 Ma,英安斑岩加权平均年龄为209±3 Ma,表明该火山岩-火山碎屑岩系形成于晚三叠世。据此,将其从原划舒家坝群中解体,暂划归华日组(T3hr)。  相似文献   

20.
A first experimental study was conducted to determine the equilibrium iron isotope fractionation between pyrrhotite and silicate melt at magmatic conditions. Experiments were performed in an internally heated gas pressure vessel at 500 MPa and temperatures between 840 and 1000 °C for 120-168 h. Three different types of experiments were conducted and after phase separation the iron isotope composition of the run products was measured by MC-ICP-MS. (i) Kinetic experiments using 57Fe-enriched glass and natural pyrrhotite revealed that a close approach to equilibrium is attained already after 48 h. (ii) Isotope exchange experiments—using mixtures of hydrous peralkaline rhyolitic glass powder (∼4 wt% H2O) and natural pyrrhotites (Fe1 − xS) as starting materials— and (iii) crystallisation experiments, in which pyrrhotite was formed by reaction between elemental sulphur and rhyolitic melt, consistently showed that pyrrhotite preferentially incorporates light iron. No temperature dependence of the fractionation factor was found between 840 and 1000 °C, within experimental and analytical precision. An average fractionation factor of Δ 56Fe/54Fepyrrhotite-melt = −0. 35 ± 0.04‰ (2SE, n = 13) was determined for this temperature range. Predictions of Fe isotope fractionation between FeS and ferric iron-dominated silicate minerals are consistent with our experimental results, indicating that the marked contrast in both ligand and redox state of iron control the isotope fractionation between pyrrhotite and silicate melt. Consequently, the fractionation factor determined in this study is representative for the specific Fe2+/ΣFe ratio of our peralkaline rhyolitic melt of 0.38 ± 0.02. At higher Fe2+/ΣFe ratios a smaller fractionation factor is expected. Further investigation on Fe isotope fractionation between other mineral phases and silicate melts is needed, but the presented experimental results already suggest that even at high temperatures resolvable variations in the Fe isotope composition can be generated by equilibrium isotope fractionation in natural magmatic systems.  相似文献   

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