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1.
Fine‐grained and coarsely oolitic kaolinite clayrocks that closely resemble in composition, texture, and structure those of the Garie Formation in the southern part of the Sydney Basin are described from the Western Blue Mountains of New South Wales. The kaolinite clayrocks form part of a fine‐grained unit, here designated the Docker Head Claystone Member. It is concluded that the kaolinite clayrocks are the equivalent of the Garie Formation and represent fluviatile accumulations of detritus derived from the same highly weathered source rocks that gave rise to the Garie Formation. 相似文献
2.
R. A. Callen 《Australian Journal of Earth Sciences》2013,60(3-4):151-169
In the Lake Frome area of South Australia there is a sedimentary sequence of non‐marine (or possibly distant marginal marine) pale‐green to grey, fine elastics and carbonates (Namba Formation). The base of these deposits is Medial Miocene in age and they are overlain unconformably by Pleistocene (and ? Pliocene) sediments. The Miocene sequence is equivalent to the Etadunna Formation of the Lake Eyre Basin, and the clay mineralogy is similar. Combining evidence from mineralogy, palynology, and vertebrate palaeontology, a warm high‐rainfall climate operating on a subdued topography is indicated for the lower part of the Miocene Lake Frome sequence. This caused the illite‐chlorite‐kaolinite suite of the largely Precambrian provenance to be transformed to smectite and randomly‐interstratified clay. A palygorskite‐dolomite assemblage accumulated in alkaline lakes of extreme marginal marine situation during periods of seasonal dry intervals superposed on the previous climate. A change to illite‐dominated clay, stratigraphically about halfway up the sequence, occurred simultaneously with initial uplift of the Flinders Ranges. These ranges were previously represented by, at the most, a region of low hills. Uplift, without intervention of climatic change, is sufficient to alter the clay mineralogy by promoting increased leaching. Higher in the sequence, and correlated with the major phase of uplift in the Flinders Ranges, smectite re‐appears. In this case the clay suite is believed to have resulted from increased aridity. The smectite‐rich sediments accumulated above the water table in extensive fan and mud‐flow deposits. The Neogene sequence records a major palaeogeographic change from low energy rivers, swamps, and lakes in a low relief terrain, probably connected to the sea, to a landscape approaching that of the present during Miocene‐Pliocene times. When the Pleistocene Millyera Formation accumulated, the landscape resembled the present, though the ancestral Lake Frome was larger, and rainfall higher. 相似文献
3.
玄武岩风化是大气CO2 的一个主要碳汇过程,气候条件是影响玄武岩风化和固碳速率的重要因素。该文选择中国东
部不同气候带的新生代玄武岩典型风化剖面,进行了粘土矿物和常量元素分析。结果显示,在内蒙古-海南岛的采样区间内,
随着气候条件由干冷向暖湿转化,风化剖面中粘土矿物组合呈现蒙脱石+ 伊利石+ 高岭石→蒙脱石+ 高岭石→高岭石+ 三水
铝石的转变。剖面中土壤元素得失状况也显示出相应的规律,由于存在粉尘输入与风化淋滤作用的综合影响,在干冷的内
蒙古地区,粉尘对于Ca,K,Na,Si 等元素的输入量大于这些元素的淋失量;在山东地区,Ca,K,Na 元素开始快速淋失,
大于粉尘的输入量;在苏皖地区,Si 元素的淋失量开始小于粉尘输入量;而在湿热的海南地区,风化作用强烈,Si显示出
大量淋失的特点,碱性元素几乎全部流失。根据元素的相对得失率和北方粉尘平均组分的校正,初步估算了研究区内玄武
岩风化对大气CO2 的消耗速率,其数值在5.37~181.00 t（km2·a）之间,与Dessert 等（2003）的研究结果大致相当。 相似文献
4.
Joshua Griffiths Richard H. Worden Luke J. Wooldridge James E. P. Utley Robert A. Duller Rhiannon L. Edge 《Sedimentology》2019,66(6):2011-2047
The spatial distribution of clay minerals in sandstones, which may both enhance or degrade reservoir quality, is poorly understood. To address this, clay mineral distribution patterns and host‐sediment properties (grain size, sorting, clay fraction abundance and bioturbation intensity) have, for the first time, been determined and mapped at an unprecedentedly high‐resolution in a modern estuarine setting (Ravenglass Estuary, UK). Results show that the estuary sediment is dominated by illite with subordinate chlorite and kaolinite, although the rivers supply sediment with less illite and significantly more chlorite than found in the estuary. Fluvial‐supplied sediment has been locally diluted by sediment derived from glaciogenic drift deposits on the margins of the estuary. Detailed clay mineral maps and statistical analyses reveal that the estuary has a heterogeneous distribution of illite, chlorite and kaolinite. Chlorite is relatively most abundant on the northern foreshore and backshore and is concentrated in coarse‐grained inner estuary dunes and tidal bars. Illite is relatively most abundant (as well as being most crystalline and most Fe–Mg‐rich) in fine‐grained inner estuary and central basin mud and mixed flats. Kaolinite has the highest abundance in fluvial sediment and is relatively homogenous in tidally‐influenced environments. Clay mineral distribution patterns in the Ravenglass Estuary have been strongly influenced by sediment supply (residence time) and subsequently modified by hydrodynamic processes. There is no relationship between macro‐faunal bioturbation intensity and the abundance of chlorite, illite or kaolinite. Based on this modern‐analogue study, outer estuarine sediments are likely to be heavily quartz cemented in deeply‐buried (burial temperatures exceeding 80 to 100°C) sandstone reservoirs due to a paucity of clay grade material (<0·5%) to form complete grain coats. In contrast, chlorite‐enriched tidal bars and dunes in the inner estuary, with their well‐developed detrital clay coats, are likely to have quartz cement inhibiting authigenic clay coats in deeply‐buried sandstones. 相似文献
5.
SONG Eping ZHANG Kexin CHEN Jiangjun WANG Chaowen JIANG Gaolei YIN Ke HONG Hanlie CHURCHMAN Jock Gordon 《《地质学报》英文版》2014,88(5):1579-1591
This study collected the early Oligocene to middle Miocene sediments from the Gerze Basin of Tibet, and used X-Ray diffraction （XRD） and Scanning Electron Microscope （SEM） to discuss their clay mineralolgy, clay indices, better understand the clay mineralogy and its paleoclimatic significance. The results show that clay minerals of the Gerze Basin sediments are mainly composed of iilite and chlorite, with minor amounts of smectite and kaolinite, and their relative content varies along the section. Variations of relative contents and clay indices suggest that the Gerze Basin has experienced three-stage evolution of paleoclimate： I ） high ilUte and chlorite contents, with fluctuant smectite and low （I＋Ch）/（K＋S） ratio, indicative of a dominant seasonal arid climate from the early Oligoeene to late Oligocene; Ⅱ） higher illite and chlorite contents and larger （I＋Ch）/（K＋S） ratio but absence of kaolinite, indicating a colder and drier climate from the late Oligocene to early Miocene; Ⅲ） high iilite and chlorite contents with fluctuant （I＋Ch）/（K＋S） ratios and occasional occurrence of kaolinite, suggesting that the climate became warmer and more humid compared with that of stage Ⅱ in the mid-Miocene. These conclusions were also reinforced by the clay morphology, which suggests that physical weathering dominated in stage Ⅱ, while relatively strong chemical weathering was dominant in stages Ⅰ and Ⅲ Clay minerals of the sediments mainly consist of illite and chlorite, indicating that the source rock played a significant role in clay origin. It is inferred that global cooling and the enhancement of denudation and obstruction of northward moisture due to the uplift of the Qinghai-Tibet Plateau were responsible for the provenance of iUite and chlorite under weak chemical weathering. Though the Qinghai-Tibet Plateau reached a certain elevation by the mid-Miocene, yet the mid-Miocene widespread warming might have largely impacted the Gerze climate. 相似文献
6.
闵桥油田阜三段油层电阻率较低,为低阻油层,在测井曲线上的响应特征与正常油层有明显的差别,通过对闵桥油田地质、粒度分析、压汞、粘土矿物分析等资料综合研究其低电阻率油层的成因。结果表明,引起低电阻率油层的原因是闵桥油田阜三段以粉砂岩、细砂岩为主,泥质含量较高,较高含量的泥质充填了颗粒的孔隙空间,由于粘土矿物的存在,使油层的粒间孔隙受到改造,引起孔隙直径变小且导致微孔隙发育,加之蒙脱石强烈的吸水能力,大量水被吸附于颗粒及粘土表面,同时由于较疏松的高岭石的迁移而堵塞孔喉了以孔喉为主的孔隙,使部分自由水成为束缚水,造成油层的束缚水含量较高,降低了油层电阻率;同时粘土矿物的附加导电作用也降低了油层电阻率;相对含量较高的导电矿物的存在是造成局部油层电阻率偏低的原因。利用声波时差和深感应电阻率交汇图可以对闵桥油田阜三段低阻油层进行有效的识别。 相似文献
7.
华池油田华152区低渗透砂岩储层敏感性及其形成机理 总被引：1，自引：0，他引：1
华池油田华152区长3油层组储层为曲流河三角洲粉-细粒长石砂岩、岩屑长石砂岩,矿物成分成熟度低,结构成熟度中等,填隙物含量较高,孔隙结构以中孔细喉型为主,物性较差,属低渗透储层。主要成岩矿物（伊利石、绿泥石、伊／蒙混层、高岭石、方解石、白云石等）使储层对外来流体有不同程度的敏感性反应。“五敏”实验结果表明,储层速敏和碱敏均为弱-中等偏弱,部分伊/蒙混层、绿泥石、碳酸盐矿物含量高的样品表现出强水敏、强酸敏、强盐敏的特征;油田水结垢实验表明,注入水与地层水、储层岩石不配伍产生盐垢CaCO3,CaSO4,实验为开采过程中回注地层水和注气开采等工艺提供油层保护的理论依据。 相似文献
8.
9.
山西、河南高铝粘土铝土矿矿床矿物学研究 总被引：5，自引：0，他引：5
耐火材料工业把Al2O3>46%（熟料）的耐火粘土称为“高铝粘土”。从理论上应把铝硅比≥2.6的称为耐火用铝土矿,惟我国《储量规范》为了勘探工作方便仍称其为高铝粘土。而普通耐火粘土（熟料Al2O3<46%,但实际应用扩大到50%）与高铝粘土中的易熔杂质总量不超过6%,灼减一般不大于16%,Fe2O3一般不大于3%或3.5%。 相似文献
10.
Ahmed Al-Futaisi Ahmad Jamrah Amer Al-Rawas Saif Al-Hanai 《Environmental Geology》2007,51(8):1317-1327
In this paper, Shuwaymiyah palygorskite in the Sultanate of Oman has been characterized mineralogically by X-ray diffraction
(XRD) and electron microscopy, chemically by oxide compositions, structural formulae, and cation exchange capacity (CEC),
and physically by specific surface area and adsorption isotherms. Batch adsorption studies were performed to evaluate the
adsorption performance of methylene blue (MB) basic dye on the local clay mineral. The quantitative XRD analysis indicates
that the purity of some selected samples of palygorskite clay is very high (about 70% of the clay minerals are palygorskite
and 30% kaolinite). The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images clearly support
this conclusion. The adsorption equilibrium revealed that Shuwaymiyah palygorskite clay can uptake up to 51 mg of MB per 1 g
mass of clay. MB adsorption is best fitted by Langmuir isotherm, and a pseudo-second-order kinetic model can be efficiently
used to predict the kinetic of adsorption of MB by the palygorskite. The results obtained from these laboratory-scale adsorption
tests indicate the promising adsorption capability of the Omani palygorskite. 相似文献
11.
Ian A. Navarrete Kiyoshi Tsutsuki Victor B. Asio Renzo Kondo 《Environmental Geology》2009,58(6):1257-1268
This study was conducted to evaluate the physical, chemical, and mineralogical characteristics of rain forest soils derived
from late Quaternary basaltic rocks in Leyte, Philippines. Four sites along a catena were selected at an elevation of 75–112 m
above sea level with an average annual rainfall of 3,000 mm and an average temperature of 28°C. Results indicate that the
soils are deep, clayey, and reddish in color, which is indicative of the advanced stage of soil development. They also posses
excellent physical condition (friable and highly porous) although they are plastic and sticky when wet as is usual for clayey
soils. In terms of chemical characteristics, the soils are acidic with low CEC values and generally low in organic matter
and nutrient contents. The clay mineralogy of the soils is dominated by halloysite and kaolinite with minor amounts of goethite
and hematite, and they also have generally high dithionite-extractable Fe contents confirming the advanced stage of their
development. The soils in the more stable slope positions (PL-1, PL-2, and PL-4) have generally similar characteristics and
appeared more developed than the one in the less stable position (PL-3). The most important pedogenic processes that formed
the soils appear to be weathering, loss of bases and acidification, desilification, ferrugination, clay formation and translocation,
and structure formation. The nature of the parent rock and climatic conditions prevailing in the area as well as slope position
appear to have dominant effects on the development of the soils. 相似文献
12.
对中国南方的3个水稻土样品进行了Cd、Pb单一离子和混合离子吸附特点的研究。结果表明,3个水稻土样品中Cd、Pb的吸附特点都相似,Langmuir等温方程可很好地描述Cd、Pb的吸附等温线。3个土壤样品中,有较高pH值和较低有机物、CEC浓度、粘土含量、高岭石含量的2个土壤样品对Cd、Pb有较大的吸附量,且其等温吸附拟合的最大吸附量（B）也较大。在两组分混合溶液中,尽管共存离子的存在影响了土壤对单一离子的吸附,同时土壤对Cd的吸附在一定程度上受影响的程度大,但3个土壤样品都表现出对Pb有强的吸附能力。在3个土壤样品中,Langmuir等温方程中Pb的健合能常数（K）都大于Cd的健合能常数（K）,混合溶液中的K值高于单一溶液的K值,表明2种金属离子对吸附位点的竞争提高了特定吸附位点的保持力,使金属离子在土壤中特定位点的吸附更加坚固。 相似文献
13.
水稻土中重金属元素Cd、Pb的竞争吸附
——以长株潭地区水稻土为例 总被引：3，自引：0，他引：3
对中国南方的3个水稻土样品进行了Cd、Pb单一离子和混合离子吸附特点的研究。结果表明,3个水稻土样品中Cd、Pb的吸附特点都相似,Langmuir等温方程可很好地描述Cd、Pb的吸附等温线。3个土壤样品中,有较高pH值和较低有机物、CEC浓度、粘土含量、高岭石含量的2个土壤样品对Cd、Pb有较大的吸附量,且其等温吸附拟合的最大吸附量(B)也较大。在两组分混合溶液中,尽管共存离子的存在影响了土壤对单一离子的吸附,同时土壤对Cd的吸附在一定程度上受影响的程度大,但3个土壤样品都表现出对Pb有强的吸附能力。在3个土壤样品中,Langmuir等温方程中Pb的健合能常数(K)都大于Cd的健合能常数(K),混合溶液中的K值高于单一溶液的K值,表明2种金属离子对吸附位点的竞争提高了特定吸附位点的保持力,使金属离子在土壤中特定位点的吸附更加坚固。 相似文献
14.
郑家-王庄地区沙一段粘土矿物特征及对储层敏感性影响 总被引：5，自引：0，他引：5
东营凹陷郑家—王庄地区沙一段砂岩储集层中蕴藏大量稠油油藏,但开发过程中粘土矿物的敏感性严重制约了该油类藏的有效开发。定向X射线衍射分析结果表明,本区沙一段砂岩储层中粘土矿物组成类型为伊/蒙无序间层矿物(S/I)、高岭石、伊利石和绿泥石,其中以伊/蒙无序间层矿物的相对含量居多。这就决定了研究区储层敏感性以水敏性为主,其余敏感性无或较弱。据定向X射线衍射谱图上S/I主峰d值大小,进一步识别出钙型S/I、钠型S/I及钙钠过渡型S/I。扫描电镜观察表明,S/I具有丝状、网状和蜂窝状三种形态,且大都包裹在岩石骨架颗粒的表面作为孔隙衬里而存在。阳离子交换容量和膨胀率研究结果显示,二者与样品中S/I含量和层间阳离子类型相关。膨胀率和阳离子交换量与S/I含量都呈较好的正相关关系。在S/I中蒙皂石层含量相当的情况下,钠型S/I的膨胀率和阳离子交换量值偏大,钙型偏小,钙钠过渡型居中。此外,粘土总量以及S/I产状对储层损害也有较大的影响。 相似文献
15.
论高岭石粘土和铝土矿研究的新进展 总被引：4，自引：0，他引：4
过去我国地质界向前苏联学习,把球粘土(Ballclay)作为高岭土或耐火粘土的一个变种,使我们找矿走入误区,以致后来从美国进口球粘土。其实球粘土的结晶性质这个内在因素与高岭土或耐火粘土常不相同,则派生的性能更不一样,应成为独立的矿种,还可与国际接轨。又过去国内外学者认为高岭石高度有序为热液型的,而沉积型的为无序高岭石。但笔者等的研究,我国高岭石高度有序而规模大且均匀稳定的,应算沉积型的紫矸(古生代高岭石软质粘土),可以作流动性好的造纸涂料。又我国硬水铝石岩溶铝土矿,应属于生物有机质成矿作用的沉积型铝土矿。 相似文献
16.
Enuvie G. Akpokodje 《Engineering Geology》1987,23(3-4):193-211
A study of the engineering geological properties, distribution and classification of the major superficial soils of the Niger Delta was carried out as part of a study programme to provide the much needed information and data for the infrastructural development of the region. Four major superficial soil groups were recognized on the basis of similarity in geotechnical, geological and geomorphological characteristics. The soils are generally fine grained and their geotechnical properties revealed that they are essentially clays with varying proportions of sand, silt and organic matter. The clay, silt and organic contents increase seawards. The values of the various geotechnical parameters are mainly influenced by the amounts of clay (and/or sand) and organic matter. 相似文献
17.
REE Mineralization of Weathered Crust and Clay Sediment on Granitic Rocks in the Sanyo Belt,SW Japan and the Southern Jiangxi Province,China 总被引：1，自引：0，他引：1
Rare earth element (REE) geochemistry and mineralogy have been studied in the weathered crusts derived from the Early Yanshanian (Jurassic) biotite granites of Dabu and Dingnan, as well as in the Indosinian (Permian) muscovite–biotite granite of Aigao in southern Jiangxi province, China, and the weathered crusts and clay sediments on biotite granites in the Sanyo belt, SW Japan, that is, Okayama, Tanakami, and Naegi areas. In all of the weathered crusts, biotite and plagioclase commonly tend to decrease toward the upper part of the profile, whereas kaolinite and residual quartz and K‐feldspar increase. The weathered crusts of the Dingnan granites and some Naegi granites, which are characterized by the enrichment in light REE (LREE) in C horizons, have higher total REE (ΣREE) content than the parent REE‐enriched granites. Weathering of LREE‐bearing apatite and fluorocarbonates in the Dingnan granites and allanite and apatite in some Naegi granites may account for the leaching of LREE at the B horizons. The leached LREE must result in subsequent enrichment of LREE in the C horizons. The enrichment is probably associated with mainly adsorption onto kaolinite and partly formation of possible secondary LREE‐bearing minerals. In Japan it was found that REE mineralization occurs not in the weathered granitic crusts but in reworked clay sediments, especially kaolinite‐rich layers, derived mainly from the weathering materials of REE‐enriched granitic rocks. The clay sediments are more enriched in LREE, which likely adsorbed onto kaolinite. Concentration of heavy REE within almost all the weathered crusts and clay sediments, however, may reflect mainly residual REE‐bearing minerals such as zircon, which originated in the parent granitic rocks. The findings of the present study support the three processes for fractionation of the REE during weathering: (i) selective leaching of rocks containing both stable and unstable REE‐bearing minerals; (ii) adsorption onto clay minerals; and (iii) presence of possible secondary LREE‐bearing minerals. 相似文献
18.
The dynamics of turbulent, transitional and laminar clay-laden flow over a fixed current ripple 总被引：1，自引：0，他引：1
Most aqueous sedimentary environments contain varying concentrations of fine‐grained, often clay‐rich, sediment that is transported in suspension and may modify the properties of the flow and underlying mobile bed. This paper presents results from a series of laboratory experiments examining the mean and turbulent properties of clay‐laden (kaolinite) flows, of various volumetric sediment concentrations between 0·046% and 12·7%, moving over a fixed, idealized current ripple. As the kaolinite concentration was raised, with flow velocity and depth constant, four flow types were observed to occur: (i) turbulent flow, in which flow separation is dominant in the leeside of the ripple; (ii) turbulence‐enhanced transitional flow, in which turbulence in the leeside separation zone region is enhanced; (iii) turbulence‐attenuated transitional flow, in which turbulence along the separation zone shear layer and in the free flow above it becomes damped, eventually leading to a reduction in the size of the separation zone wake region; and (iv) laminar plug flow, in which turbulence is damped and flow is almost stagnant in the lee of the ripple. Such modulation of turbulence by increasing clay concentrations suggests that many paradigms of flow and bedform dynamics, which have been based on extensive past work in clear water flows, require revision. The present results highlight a need to fully characterize the boundary conditions for turbulence modulation as a function of clay type and applied flow conditions, and the effects of such flows on fully mobile cohesionless beds. 相似文献
19.
我国球粘土应成为独立矿种,湖沼球粘土中含“内胶体”的自生高岭石是生物有机质作用造成,水云母、I-M间层粘土矿物及有机质会增加可塑性、粘结性及干燥强度,钾、钠的增加可降低烧结温度。沉积球粘土与残积成因高岭石为无序或较无序,古生代煤系高岭石为有序和高度有序,岩浆热液成因的高岭石常为有序或高度有序;北方古生代软质粘土（紫矸）为规模较大、较为均匀稳定的高度有序高岭石,应积极开发。硬水铝石岩溶铝土矿应属于生物有机质成矿作用的沉积型铝土矿。 相似文献