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1.
This is a conducted study of the physicochemical and the bacteriological characteristics of groundwater from 24 wells in the six departments of Algeria: Mostaganem, Mecheria, Naama, Tiaret, Bechar, and Adrar. The six departments and surrounding areas depend heavily on water from wells as a resource for drinking water, as well as domestic, industrial, and agricultural uses. Understanding the groundwater chemistry provides insight into the interactions of water with the environment and contributes to better resource management. In total, 24 water samples from wells have been analyzed for major physical–chemical elements and metals. The results show that the water have pH values ranging between 7.1 and 8.2, salinity between 213 and 1,273 mg/L, and nitrate concentrations between 30 and 48.7 mg/L. The high concentration of nitrates is explained by the utilization of chemical fertilizers in agriculture. Almost all the samples are of type Na–SO4 and Na–HCO3, and the trace metal concentrations are within the admissible standard ranges. The bacteriological analysis of 24 samples analyzed showed that nine samples (nos. 3, 5, 8, 12, 14, 16, 17, 22, and 23) are contaminated. We conclude that the groundwater samples may safely be used for drinking, domestic, agricultural, and industrial purposes with the exception of the following samples: nos. 3, 5, 8, 12, 14, 16, 17, 22, and 23.  相似文献   

2.
Mostaganem City, located in the northwestern part of Algeria, has grown and has been urbanized rapidly. The city and surrounding areas depend heavily on groundwater as a resource for drinking water, as well as domestic, industrial, and agricultural uses. Understanding the groundwater chemistry provides insight into the interactions of water with the environment and contributes to better resource management. In total, 12 groundwater samples from wells in Mostaganem City have been analyzed for major physical–chemical elements and metals. The results show that the waters have pH values ranging between 7.1 and 8.1, salinity between 226 and 1,073 mg/L, and nitrate concentrations between 15 and 47.7 mg/L. The high concentration of nitrates is explained by the utilization of chemical fertilizers in agriculture. Almost all samples are of type Na–SO4 and Na–HCO3, and the trace metal concentrations are within the admissible standard ranges. We conclude that the groundwater in Mostaganem may safely be used for drinking, domestic, agricultural, and industrial purposes.  相似文献   

3.
The groundwater in Wadi Queh exists in two main hydrogeological units; fractured Precambrian basement and sedimentary rocks with high contribution for groundwater recharge. To study the impacts of phosphate mining activities on the groundwater quality in the area, three groundwater samples that represent all water wells in the area were collected and analysed for major ions and some heavy metals. In addition, three bulk samples representing the phosphatic sediments collected from upstream and downstream of the drainage basin were collected and analysed to understand the source of groundwater contamination. The total concentrations of dissolved solids suggest that the groundwater in the area grades from fresh to brackish water (961–1,580 mg/l), and is characterized by sodium–calcium–sulphate–chloride and sodium–magnesium–sulphate–chloride chemical types. The results showed high concentrations of the heavy metals in well nos. 1 and 2 in downstream parts compared to well no. 3 in upstream part reflecting their influence by the mining activities.  相似文献   

4.
This study focuses on the hydrochemical characteristics of 47 water samples collected from thermal and cold springs that emerge from the Hammam Righa geothermal field, located in north-central Algeria. The aquifer that feeds these springs is mainly situated in the deeply fractured Jurassic limestone and dolomite of the Zaccar Mount. Measured discharge temperatures of the cold waters range from 16.0 to 26.5 °C and the hot waters from 32.1 to 68.2 °C. All waters exhibited a near-neutral pH of 6.0–7.6. The thermal waters had a high total dissolved solids (TDS) content of up to 2527 mg/l, while the TDS for cold waters was 659.0–852.0 mg/l. Chemical analyses suggest that two main types of water exist: hot waters in the upflow area of the Ca–Na–SO4 type (Hammam Righa) and cold waters in the recharge zone of the Ca–Na–HCO3 type (Zaccar Mount). Reservoir temperatures were estimated using silica geothermometers and fluid/mineral equilibria at 78, 92, and 95 °C for HR4, HR2, and HR1, respectively. Stable isotopic analyses of the δ18O and δD composition of the waters suggest that the thermal waters of Hammam Righa are of meteoric origin. We conclude that meteoric recharge infiltrates through the fractured dolomitic limestones of the Zaccar Mount and is conductively heated at a depth of 2.1–2.2 km. The hot waters then interact at depth with Triassic evaporites located in the hydrothermal conduit (fault), giving rise to the Ca–Na–SO4 water type. As they ascend to the surface, the thermal waters mix with shallower Mg-rich groundwater, resulting in waters that plot in the immature water field in the Na–K–Mg diagram. The mixing trend between cold groundwaters from the recharge zone area (Zaccar Mount) and hot waters in the upflow area (Hammam Righa) is apparent via a chloride-enthalpy diagram that shows a mixing ratio of 22.6 < R < 29.2 %. We summarize these results with a geothermal conceptual model of the Hammam Righa geothermal field.  相似文献   

5.
This paper reports the results of our studies, the chemical analysis of thermal spring’s waters and their geological settings, the use of different statistical methods to evaluate the origin of the dissolved constituents of spring waters and the estimation of the reservoir temperature of the associated geothermal fields of the Guelma region, Algeria. A major component in 13 spring water samples was analyzed using various techniques. The waters of the thermal springs at Guelma basin vary in temperature between 20 and 94oC. Q-mode hierarchical cluster analysis suggests three groups. The water springs were classified as low, moderate and high salinity. Mineral saturation indices (SI) calculated from major ions indicate the spring waters are supersaturated with the most of the carbonate minerals, and all of the spring water samples are under-saturated with evaporite minerals. The thermal spring waters have a meteoric origin, and all samples are immature with strong mixing between warm and shallow waters, where the temperatures of reservoirs to which the thermal waters are related ranged between 64° and 124°C. The deep circulation of meteoric waters in the study area is supplied by the high geothermal gradient around 4.5°C per 100 m and reaches a high temperature before rising to the surface. The estimated circulation depths ranged from 1425 and 3542 m.  相似文献   

6.
《Applied Geochemistry》2004,19(6):937-946
Analysis of stable isotopes and major ions in groundwater and surface waters in Belize, Central America was carried out to identify processes that may affect drinking water quality. Belize has a subtropical rainforest/savannah climate with a varied landscape composed predominantly of carbonate rocks and clastic sediments. Stable oxygen (δ18O) and hydrogen (δD) isotope ratios for surface and groundwater have a similar range and show high d-excess (10–40.8‰). The high d-excess in water samples suggest secondary continental vapor flux mixing with incoming vapor from the Caribbean Sea. Model calculations indicate that moisture derived from continental evaporation contributes 13% to overhead vapor load. In surface and groundwater, concentrations of dissolved inorganic carbon (DIC) ranged from 5.4 to 112.9 mg C/l and δ13CDIC ranged from −7.4 to −17.4‰. SO42, Ca2+ and Mg2+ in the water samples ranged from 2–163, 2–6593 and 2–90 mg/l, respectively. The DIC and δ13CDIC indicate both open and closed system carbonate evolution. Combined δ13CDIC and Ca2+, Mg2+, and SO42− suggest additional groundwater evolution by gypsum dissolution and calcite precipitation. The high SO42−content of some water samples indicates regional geologic control on water quality. Similarity in the range of δ18O, δD and δ13CDIC for surface waters and groundwater used for drinking water supply is probably due to high hydraulic conductivities of the karstic aquifers. The results of this study indicate rapid recharge of groundwater aquifers, groundwater influence on surface water chemistry and the potential of surface water to impact groundwater quality and vise versa.  相似文献   

7.
The Silver Springs Group, Florida (USA), forms the headwaters of the Silver River and supports a diverse ecosystem. The 30 headwater springs divide into five subgroups based on chemistry. Five selected spring vents were sampled in 2007 to better understand the contaminant sources and groundwater flow system. Elevated nitrate-N concentrations (>0.8 mg/L) in the five spring vents likely originate from inorganic (fertilizers) and organic sources, based on nitrogen and oxygen isotope ratios of nitrate. Evidence for denitrification in the Lost River Boil spring includes enriched δ15N and δ18O, excess N2 gas, and low dissolved O2 concentrations (<0.5 mg/L). Multiple age-tracer data (SF6, 3H, tritiogenic 3He) for the two uppermost springs (Mammoth East and Mammoth West) indicate a binary mixture dominated by recent recharge water (mean age 6–7 years, and 87–97% young water). Tracer data for the three downstream spring vents (Lost River Boil, Catfish Hotel-1, and Catfish Conventional Hall-1) indicate exponential mixtures with mean ages of 26–35 years. Contamination from non-atmospheric sources of CFCs and SF5CF3 precluded their use as age tracers here. Variations in chemistry were consistent with mean groundwater age, as nitrate-N and dissolved O2 concentrations were higher in younger waters, and the Ca/Mg ratio decreased with increasing mean age.  相似文献   

8.
On the basis of isotopic and chemical analyses of 45 spring, well and meteoric water samples from the El Tatio geothermal field in Northern Chile, four main processes giving rise to the formation of a wide range of thermal discharges can be distinguished. (1) Deep dilution of a predominant, primary high chloride (5500 mg/l, 260°) supply water derived from precipitation some 15 km east of El Tatio with local groundwater produces a secondary chloride water. (4750 mg/l, 190°) feeding springs over a limited area. (2) Single step steam separation from these two waters leads to isotopic shifts and increases in chloride contents to 8000 and 6000 mg/l respectively. (3) Absorption of this separated steam and carbon dioxide into local ground water and mixing with chloride waters at shallow levels produces a series of intermediate temperature (160°), low chloride, high bicarbonate waters. (4) Absorption of steam containing H2S into surface waters leads to the formation of zero chloride, high sulfate waters; the isotopic enrichment observed is governed by a kinetic, steady state evaporation process.  相似文献   

9.
Hydrochemical and stable isotopes (18O and 2H) analyses of groundwater samples were employed to establish the origin of major dissolved ions in groundwater within the Lower Pra Basin. Results showed that, the major processes responsible for chemical evolution of groundwater include: silicate (SiO4)4? dissolutions, ion exchange reactions, sea aerosol spray and pyrite (FeS2) and arsenopyrite (FeAsS) oxidations. The groundwater is strongly acidic to neutral, with pH generally range from 3.5 to 7.0 pH units and mean 5.9 (±0.5). Approximately 89 % of boreholes had pH values outside the World Heath Organization (WHO, Guidelines for drinking water quality, 2004) guideline value for drinking water due principally to natural biogeochemical processes and therefore, not suitable for potable purposes. Electrical conductivity (EC) range from 57.6 to 1,201 μS/cm with mean 279.3 (±198.8) μS/cm. Total dissolved solids (TDS) range from 32 to 661 mg/L with mean 151.7 (±106.8) mg/L, with 98.6 % of groundwater as fresh (TDS < 500 mg/L). The chemical constituents generally have low concentrations and are within the WHO (Guidelines for drinking water quality, 2004) guideline value for drinking water. The relative abundance of cations and anions is in the order: Na+ > Ca2+> Mg2+ > K+ and HCO3 ? > Cl? > SO4 2?, respectively. A plot of ?18O ‰ against 2H ‰ showed that, ground and surface waters clustered on or closely along the Global Meteoric Water Line, suggesting that, the waters emanated principally from meteoric source with evaporation playing an insignificant role on the infiltrating water.  相似文献   

10.
Chennai is one of the four major metropolitan cities in India, and is located in the southeastern part of the country. The average rate of population growth of the city is 25 % per decade and this is recurrently reducing the green-covered area in the city. Exceptionally, during the post-economic liberalization period (i.e., between the years 1997 and 2007), the city lost up to 99 % of its green-covered areas at some parts. Subsequently, the Chennai City started to experience wide range of environmental issues, including groundwater pollution and the effects of groundwater depletion. As a consequence of these factors, a study was undertaken to determine the impact of urbanization on the groundwater quality. In the present study, groundwater samples were collected from 54 stations from the study area during the premonsoon and postmonsoon seasons for the year 2011–2012 and were analyzed for physico-chemical parameters and trace elements. The type of water that predominated in the study area was assessed based on hydrochemical facies. The study of the hydrochemical characteristics of the major ions in these waters shows that in premonsoon, the alkalis and the alkaline earth metals are found to be balanced by chlorides and bicarbonates and sulphates, respectively. Reverse ion exchange study illustrates that Ca, Mg and Na concentrations are interrelated through reverse ion exchange. Box and whisker plots illustrate the seasonal effect on the chemical parameters of the groundwater. Gibbs’ diagram reveals that the chemical composition of the groundwater in the study area is predominated by rock–water interaction. Besides, suitability of groundwater for irrigation was evaluated based on sodium adsorption ratio, Kelley’s ratio, magnesium ratio, Wilcox and USSL diagrams.  相似文献   

11.
In this paper, the hydrochemical isotopic characteristics of samples collected from geothermal springs in the Ilica geothermal field, Eastern Anatolia of Turkey, are examined and described. Low-temperature geothermal system of Ilica (Erzurum, Turkey) located along the Eastern Anatolian fault zone was investigated for hydrogeochemical and isotopic characteristics. The study of ionic and isotopic contents shows that the thermal water of Ilica is mainly, locally fed by groundwater, which changes chemically and isotopically during its circulation within the major fault zone reaching depths. The thermal spring has a temperature of 29–39 °C, with electrical conductivity ranging from 4,000 to 7,510 µS/cm and the thermal water is of Na–HCO3–Cl water type. The chemical geothermometers applied in the Ilica geothermal waters yielded a maximum reservoir temperature of 142 °C according to the silica geothermometers. The thermal waters are undersaturated with respect to gypsum, anhydrite and halite, and oversaturated with respect to dolomite. The dolomite mineral possibly caused scaling when obtaining the thermal waters in the study area. According to the enthalpy chloride-mixing model, cold water to the thermal water-mixing ratio is changing between 69.8 and 75 %. The δ18O–δ2H compositions obviously indicate meteoric origin of the waters. Thermal water springs derived from continental precipitation falling on to higher elevations in the study area. The δ13C ratio for dissolved inorganic carbonate in the waters lies between 4.63 and 6.48 ‰. In low-temperature waters carbon is considered as originating from volcanic (mantle) CO2.  相似文献   

12.
Water quality and hydrochemistry of Shariatpur district were evaluated in terms of hydrochemical composition and some important physico-chemical parameters. The groundwater of the study area is good for drinking, domestic as well as for irrigation purposes. Among the major ions, shallow tube well waters give higher concentration of Ca2+ which ranges from 24 to 260 mg/L. The deep tubewell waters show higher concentration of Na+ which varies from 74 to 582 mg/L during dry season. Among the trace elements most of the shallow aquifer samples show higher concentration of Fe2+, Mn2+ and As. Concentration of Fe2+ varies from 0.655 to 18.8 mg/L, and Mn2+ from trace to 0.868 mg/L during dry period. Hydrochemical analyses reveal significant seasonal variation in water quality of shallow aquifer. Both the shallow aquifer and the surface water of the study area are predominantly of Ca–Mg–HCO3 type, while the deep aquifer water is mainly of Na–K–Cl–SO4 type with slight inclination to Ca–Mg–HCO3 type. The study area is suitable for groundwater development if comprehensive and holistic approaches towards water resource management are taken into consideration.  相似文献   

13.
In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems with features including the occurrence of year-round open water and the formation of icings, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Stable isotopes (δ18O, δD, δ13CDIC), and noble gases have proved useful to study groundwater recharge and flow of groundwater which discharges along rivers in Canada’s western Arctic. In these studies of six catchments, groundwater recharge was determined to be a mix of snowmelt and precipitation. All systems investigated show that groundwater has recharged through organic soils with elevated PCO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 5 °C, which when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater circulation times were found to be up to 31 years for non-thermal waters using the 3?H-3He method.  相似文献   

14.
The southwestern Chad basin is a semi-arid region with annual rainfall that is generally less than 500 mm and over 2,000 mm of evapotranspiration. Surface water in rivers is seasonal, and therefore groundwater is the perennial source of water supply for domestic and other purposes. Stable isotope has been measured for rainwater, surface water and groundwater samples in this region. The stable isotope data have been used to understand the inter-relationships between the rainwater, surface water, shallow and deep groundwater of this region. This is being used in a qualitative sense to demonstrate present day recharge to the groundwater. Stable isotope in rainwater for the region has an average value of –4‰ δ18O and –20‰ δ2H. Surface water samples from rivers and Lake Chad fall on the evaporation line of this average value. The Upper Zone aquifer water samples show stable isotope signal with a wide range of values indicating the complex character of the aquifer Zone with three distinguishable units. The wide range of values is attributable to waters from individual unit and/or mixture of waters of different units. The Middle and Lower aquifers Zones’ waters show similar stable isotopes values, probably indicating similarity in timing and/or mechanism of recharge. These are palaeowaters probably recharged under a climate that is different from today. The Upper Zone aquifer is presently being recharged as some of its waters show stable isotope compositions similar to those of average rainfall waters of the region.  相似文献   

15.
Bio-concentration of elements such as Mo, As, Se, Fe, Cu, Zn, Ni and Pb was analyzed in spring onion (Allium fistulosum L.) in three different locations of central Punjab, Pakistan. At location GW, relatively low level of hazardous elements was found in spring onion, suggesting that groundwater is a safe source of water for irrigating food crops. The pH of soil at wastewater irrigation was found less acidic (pH 7.4) than the other sites. The range of concentration in the different samples of spring onion was as follows: 6.15–8.16 mg kg?1 for Mo, 2.77–4.28 mg kg?1 for As, 0.395–0.705 mg kg?1 for Se, 36.73–48.17 mg kg?1 for Fe, 10.58–16.26 mg kg?1 for Cu, 28.87–39.79 mg kg?1 for Zn, 6.66–8.75 mg kg?1 for Ni and 4.33–6.09 mg kg?1 for Pb, respectively. High bio-concentration of Zn (15.37) from soil to spring onion was found at canal water irrigated location. The estimated daily intake of metal for spring onion was less, but the health risk index was higher than 1 for Mo, As, Cu, Pb and Ni, respectively. This was due to higher proportion of spring onion in diet, which consequently increased the health risk index for metals. Therefore, it is recommended to avoid growing vegetables in untreated urban and rural wastewater containing elevated amounts of metals.  相似文献   

16.
The groundwater of major karst systems and submarine springs in the coastal limestone aquifer of Syria has been investigated using chemical and isotopic techniques. The δ18O values of groundwater range from ?6.8 to ?5.05‰, while those for submarine springs vary from ?6.34 to +1.08‰ (eastern Mediterranean seawater samples have a mean of +1.7‰). Groundwater originates from the direct infiltration of atmospheric water. Stable isotopes show that the elevation of the recharge zones feeding the Banyas area (400–600 m a.s.l.) is higher than that feeding the Amrit area (100–300 m a.s.l.). The 18Oextracted (18O content of the seawater contribution) for the major submarine springs suggests a mean recharge area elevation of 600–700 m a.s.l., and lower than 400 m a.s.l. for the spring close to Amrit. Based on the measured velocity and the percentage of fresh water at the submarine springs outlet, the estimated discharge rate is 350 million m3/year. The tritium concentrations in groundwater (1.6–5.9 TU) are low and very close to the current rainfall values (2.9–5.6 TU). Adopting a model with exponential time distribution, the mean turnover time of groundwater in the Al-sen spring was evaluated to be 60 years. A value of about 3.7 billion m3 was obtained for the maximum groundwater reservoir size.  相似文献   

17.
The functioning of karst systems in the Tlemcen Mountains, Algeria, was studied using environmental isotopic and chemical parameters. The weakly enriched values of 18O suggest a fast infiltration of water through the karst systems. The deuterium (2H) excess in groundwater and tritium (3H) in precipitation show that the region is subjected to Mediterranean and Atlantic influences with a predominance of the former. The isotopic gradient, in combination with topographic and geologic criteria, allows the recharge areas of the main karst systems to be estimated. The results of 13C, 14C and 3H analysis show that the majority of present waters come from perched systems and mixture waters influenced by three clusters (“ante-thermonuclear” waters, “thermonuclear” waters, and present waters) that generally emerge from semi-confined systems. The oldest waters are relatively rare and are stored in deeply confined systems. These results are consistent with the hydrochemical and the hydrogeological findings. The results have important implications in groundwater protection.  相似文献   

18.
The inorganic chemistry of 85 samples of bottled natural mineral waters and spring waters has been investigated from 67 sources across the British Isles (England, Wales, Scotland, Northern Ireland, Republic of Ireland). Sources include boreholes, springs and wells. Waters are from a diverse range of aquifer lithologies and are disproportionately derived from comparatively minor aquifers, the most represented being Lower Palaeozoic (10 sources), Devonian Sandstone (10 sources) and Carboniferous Limestone (9 sources). The waters show correspondingly variable major-ion compositions, ranging from Ca–HCO3, through mixed-cation–mixed-anion to Na–HCO3 types. Concentrations of total dissolved solids are mostly low to very low (range 58–800 mg/L). All samples analysed in the study had concentrations of inorganic constituents well within the limits for compliance with European and national standards for bottled waters. Concentrations of NO3–N reached up to half the limit of 11.3 mg/L, although 62% of samples had concentrations <1 mg/L. Concentrations of Ba were high (up to 1010 μg/L) in two spring water samples. Such concentrations would have been non-compliant had they been classed as natural mineral waters, although no limit exists for Ba in European bottled spring water. In addition, though no European limit exists for U in bottled water, should a limit commensurate with the current WHO provisional guideline value for U in drinking water (15 μg/L) be introduced in the future, a small number of groundwater sources would have concentrations close to this value. Two sources had groundwater U concentrations > 10 μg/L, both being from the Welsh Devonian Sandstone. The highest observed U concentration was 13.6 μg/L.  相似文献   

19.
The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234U/238U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.  相似文献   

20.
The present work focuses on the evaluation of the groundwater quality by chemical and bacteriological analyses to ensure its suitability for drinking and irrigation. Twenty groundwater samples were collected and analyzed from Manfalut district, Assiut, Egypt. Several water quality parameters were determined; the results show higher concentration of total dissolved solids (50 %), electrical conductivity (55 %), chloride (20 %), total hardness (20 %), and bicarbonate (55 %). This indicates signs of deterioration regarding drinking and domestic uses. Salinity hazard, sodium absorption ratio, sodium (Na) percentage, and residual Na carbonate were used to evaluate groundwater quality for irrigation. The values of electrical conductivity and SAR of groundwater samples were estimated illustrating that the most dominant classes are C2S1 (45 %; medium-salinity-low SAR), C3S1 (50 %; high-salinity-low SAR), and C4S1 (5 %; very high-salinity-low SAR). Bacteriological analysis was also conducted for 20 groundwater wells from December 2011 to May 2012. Seven samples (35 %) are contaminated by bacteria (total and fecal coliforms); these wells are not suitable for drinking. The analysis exhibits that bacterial contamination was the maximum in wells located at the center of the study area; this may be due to using the residential septic tanks. It was also discovered that the quality of groundwater is suitable for irrigation in the target aquifer except in a few locations. As for drinking, about 55 % of the samples are not suitable. However, the groundwater wells which are located in the center of the study area are suitable for drinking according to the hydochemical analysis. It was found that some of these wells are not suitable based on bacteriological analysis.  相似文献   

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