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1.
A simple and selective method of flow injection (FI) using a micro-column packed with chelating resin YPA4 as solid phase extractant was developed for the preconcentration and separation of trace amount of noble metals, Au(III), Ag(I), Pd(II) and Pt(IV), followed by ICP-AES determination. In HNO3 media, the chelating resin was selective towards Au(III), Ag(I), Pd(II) and Pt(IV), and the analysed ions were readily desorbed quantitatively with 5 ml of 2.5% m/v thiourea. Effects of acidity, sample flow rate and concentration, elution solution and interfering ions on the recovery of the analytes were systematically investigated. Under optimum conditions, the adsorption capacities of YPA4 for Au(III), Ag(I), Pd(II) and Pt(IV) were 67.2, 43.1, 64.8 and 27.6 mg per gram of resin in HNO3 media, respectively. It was found that YPA4 could be used for more than eight runs in HNO3 media without loss of capacity. The proposed method was used for the determination of trace noble metals in geological and environmental samples, and the analytical results obtained were in good agreement with the recommended values. 相似文献
2.
In order to better identify the mineral phase which controls the rheology of the transition zone (between 410 and 660 km depth) transmission electron microscopy observations were made on several coexisting spinel-garnet assemblies: alkremite xenolith; pyrope-rich – MgO:1.1Al2 O3 spinel assembly deformed at 1173K, 800 MPa in a Griggs apparatus; (Mg,Fe)3 (Al,Mg,Si)2 Si3 O12 majorite – (Mg,Fe)2 SiO4 spinel assembly synthesized in a laser heated diamond anvil cell. It was found that garnet crystals systematically remain undeformed while spinel crystals are plastically deformed. These results are in accord with the assumption that the rheology of majorite is stronger than the rheology of spinel, in the conditions of the transition zone. 相似文献
3.
Abstract. This study examined the effect of CO2 on NaCl solubility in hydrothermal fluid, with the synthetic fluid inclusion technique. Fluid inclusions of 30–40 wt% NaCl and 5 mol % CO2 were synthesized, and their halite dissolution temperatures, Tm (halite), were measured. The solubilities of NaCl in CO2 -bearing aqueous fluid were obtained at 160–320C under vapor-saturated pressures. The Tm (halite) value in aqueous fluid with 5 mol % CO2 obtained in this study agrees with that of Schmidt et al. (1995), showing that 5 mol % CO2 reduces the solubility of NaCl by about 1 wt%.
Calculation of magnetite solubility suggests that 5–10 mol % CO2 decreases magnetite solubility by 4.5–8.9 % relative to the magnetite solubility in CO2-free solution. Therefore, an increase of CO2 content in ore-forming solutions may cause deposition of iron minerals and produce ore deposits. 相似文献
Calculation of magnetite solubility suggests that 5–10 mol % CO2 decreases magnetite solubility by 4.5–8.9 % relative to the magnetite solubility in CO2-free solution. Therefore, an increase of CO2 content in ore-forming solutions may cause deposition of iron minerals and produce ore deposits. 相似文献
4.
A new petrogenetic grid is presented for the system NCKFMASH (Na2 O–CaO–K2 O–FeO–MgO–Al2 O3 –SiO2 –H2 O), in which Ca is incorporated in garnet, and CaAlNa−1 Si−1 solid solution is considered for both the plagioclase and white-mica structures. A compatibility diagram for plagioclase-bearing metapelitic assemblages within the NCKFMASH system also has been derived. A dominant feature of the NCKFMASH grid is the singularities and associated singular reactions which occur along plagioclase+margarite- and plagioclase+paragonite-bearing univariant equilibria. The singularities represent compositional coplanarities which occur in response to the CaAlNa−1 Si−1 substitution occurring at different rates in plagioclase and white-mica. This is controlled by a fundamental difference in the mixing within the two mineral structures. The singularities give rise to a number of intriguing phase diagram features, including azeotropes. From the results presented here, it is predicted that the occurrence of margarite and paragonite in pelitic rocks is controlled by equilibria related to the singularities. The presence of these white-micas is strongly dependent upon bulk composition, and plagioclase-bearing, margarite/paragonite-free assemblages, typical of Barrovian-type terranes, are predicted for bulk compositions of Mg/(Mg+Fe)≈0.4 and Ca/(Ca+Na)≈0.4 at for example 5.5 kbar. 相似文献
5.
Bhaskar Chandra ACHARYA Prasanta Kumar PANIGRAHY Binod Bihari NAYAK Rama Krishna SAHOO 《Resource Geology》1998,48(2):125-136
Abstract: Ilmenite, hematite, garnet, monazite, zircon, rutile, magnetite, sillimanite, pyroxene and amphibole from the beach sands of Ekakula, Gahiramatha coast, Orissa, India are reported here for the first time. Their total concentration varies from 26. 4 to 100%. Ilmenite, monazite and zircon are between 100 and 300 um in size and are well rounded in shape. Ilmenite-hematite intergrowth is common. Ilmenite has 50. 02–54. 73% TiO2 , 42. 42–46. 90% FeO (total Fe) and small amounts of Al, Mn, Mg, Ca, Ba, Si, V, Cr, and Zn. The bulk samples contain 10. 63–41. 42 % TiO2 , 6. 15–26. 07 % FeO, 5. 86–16. 75 % Fe2 O3 , 7. 41–61. 74 % SiO2 , 1. 39–12. 83% A12 O3 , 0. 32–4. 97% CaO, 0. 53–4. 24% P2 O5 , 0. 17–3. 27% MgO, 0. 15–2. 97% Na2 O, 0. 07–2. 34% K2 O, and 0. 05–0. 71% V2 O5 together with appreciable amounts of La, Ce, Pr, Nd, Sm, Eu, Y, U, Th, Zr, and trace amounts of Pb, Zn, Cu, Ni, Co, and Cr. Khondalite, charnockite, calc-silicate granulite, leptynite, migmatite, gneiss, basic granulite and pegmatite of the Eastern Ghats appear to be the major source for the above heavy mineral assemblages. The samples are amenable to gravity and magnetic methods of beneficiation. 相似文献
6.
We present a new method that determines precisely and accurately rare earth elements (REE) at the sub-ng g-1 level in ultramafic rocks based on acid dissolution and quadrupole ICP-MS with systematic interference corrections on each sample. The method is demonstrated by analyses of the international geochemical reference materials, PCC-1 (peridotite), DTS-1 (dunite) and DTS-2 (dunite) provided by the United States Geological Survey (USGS), and JP-1 (peridotite) issued by the Geological Survey of Japan (GSJ). Detection limits, as rock equivalent, were calculated to be 0.01-0.08 ng g-1 for our instrument, which is sufficiently low compared to the REE concentrations of ultramafic rocks. In addition, procedural blanks of the proposed method were 0.2-5 pg, which is negligible even for the ultra-low level REE determinations. Reproducibility obtained from separate dissolutions and measurements of USGS DTS-2 and GSJ JP-1 was 3-6%, which corresponds to the high-precision data obtained by ID-TIMS or magnetic sector field ICP-MS with a desolvating nebuliser. The REE data determined exhibit smooth chondrite-normalised REE patterns for all of the tested geochemical reference materials, and the abundances are in good agreement with recently published data. 相似文献
7.
A calculated petrogenetic grid for the system K2 O-FeO-MgO-Al2 O3 -SiO2 -H2 O, with particular reference to contact-metamorphosed pelites 总被引：1，自引：0，他引：1
A petrogenetic grid is presented for the system KFMASH (K2 O-FeO-MgO-Al2 O3 -SiO2 -H2 O), including biotite, muscovite, K-feldspar, chlorite, chloritoid, staurolite, cordierite, garnet, orthoamphibole, orthopyroxene, spinel, andalusite, sillimanite, kyanite, quartz and corundum with H2 O in excess, which was calculated using the computer program THERMOCALC and the Powell and Holland internally consistent thermodynamic dataset. By removing the normal constraint of having quartz in excess, both quartz-bearing and quartz-absent equilibria are shown. Quartz-absent equilibria are particularly relevant at high- T and low- P conditions, because of their common occurrence at these conditions. The calculated mineral assemblage and mineral compositional variations in terms of FeMg-1 and (Fe, Mg)SiAl-2 exchange vectors are broadly compatible with observations on natural rocks, particularly when non-KFMASH components are taken into account. 相似文献
8.
G. S. Xeidakis 《Engineering Geology》1996,44(1-4):93-106
The damage caused to structures and other human endeavours, on or in the ground, by swelling clay soils is considered as a natural hazard. In order to mitigate this hazard an attempt was made to stabilize the swelling clay mineral structure by the addition of Mg(OH)2. This will turn the swelling minerals, like montmorillonite, into non-swelling ones, e.g., chloride. Accordingly, the various factors affecting the precipitation-adsorption of the Mg-hydroxide by clays, was investigated, and the conditions giving the best results were established. The factors examined were: the base used as precipitant (NH4OH and NaOH); the preparation of the precipitate, inside or outside the clay suspension; the sequence and the duration of the reagents addition; the OH/Mg ratio; the time of clay-chemical contact; and the drying time and temperature. The method, was applied to different clay minerals (swelling and non-swelling). The material produced after the Mg-hydroxide precipitation was examined by the methylene blue dye adsorption test, XRD, DTA and DTGA methods; the results were treated statistically by factorial analysis. From the results obtained, it is concluded that the factors affecting the Mg-hydroxide adsorption by clays are: the base used as a precipitant, the preparation of the hydroxide directly inside or outside the clay suspension, the drying temperature, and the rate of titration of the reagents. Therefore, the best conditions for the laboratory preparation of hydroxy-Mg-interlayers are a dilute (1–2%) and well-dispersed clay suspension, pH between 10–12; some 12 meq Mg2+, as Mg-salt (e.g., MgCl2) per gram of clay, added before the base and followed by the dropwise titration of 1–2 N NaOH solution into the clay suspension, to give a molar ratio OH/Mg of about 1.5; vigorous agitation of the suspension during titration of the reagents; centrifugation and decantation of the supernatant liquid, and drying the product at about 250°C. Satisfactory results are also obtained with the fast titration of the base and drying at 105°C to complete dryness. 相似文献
9.
Akiko UCHIDA Takushi YOKOYAMA Yoshinobu MOTOMURA Akane MIYAZAKI Yoshihiro OKAUE Koichiro WATANABE Eiji IZAWA 《Resource Geology》2002,52(3):223-230
Abstract: The adsorption of gold on iron(III) and aluminum hydroxides from solutions containing Au(III) complexes has been studied as a function of pH and chloride concentration at 30C. Iron(III) hydroxide was more effective in adsorbing gold from solution than aluminum hydroxide. However, both hydroxides controlled the behavior of Au(III) complex with very similar manner. The most effective gold adsorption occurred in aqueous solution with near neutral pH and low Cl concentration. In this solution condition, Au(III) complexes were mainly dissolved as AuCl2 (OH)2 - and AuCl(OH)3 - , and the surface charge for both hydroxides was positive. In addition, the adsorbed Au(III) complexes were spontaneously reduced to elemental gold in spite of the absence of a specific reducing agent.
The results of this study suggest that adsorption and spontaneous reduction of gold complexes on the surface of hydrous metal oxides with positive charge play an important role in gold precipitation in subsurface environment. 相似文献
The results of this study suggest that adsorption and spontaneous reduction of gold complexes on the surface of hydrous metal oxides with positive charge play an important role in gold precipitation in subsurface environment. 相似文献
10.
A marble band in the ≈ 2.75 Gyr old Ramagiri schist belt in the Dharwar craton of south India gave a Pb–Pb age of 3.075 ± 0.095 Gyr. The geochemical data, including high Sr and low Ba and Mn indicate seawater origin for the parent rock, and that there was insignificant geochemical exchange between the marble and the surrounding rocks. The calculated initial Nd isotopic composition and μ1 indicate an older continental crustal source for the Nd and Pb. The initial 87 Sr/86 Sr of the marble is 0.70128, which is higher than the calculated mantle value at ≈ 3 Ga. Although pre-3 Gyr old marine carbonate rocks are thought to be buffered by mantle Sr, the Ramagiri marble contains evolved, crustal Sr. Despite this, the marble has the lowest measured 87 Sr/86 Sr among carbonates and represents one of the least radiogenic periods in seawater Sr isotope composition. 相似文献
11.
ABSTRACT A cave in granitic rocks was studied in Mezesse, South Cameroon. Coralloid speleothems, draperies and dissolution traces on the cave walls attest to its truly karstic nature. The speleothems consist of microlayers of opal and taranakite (K,NH4 )Al3 (PO4 )3 (OH).9H2 O. They indicate a significant mobilization of silica, Al and K from granite during the formation of the cave. Identification of silicified bacteria in the speleothems layers suggests a possible role of these micro-organisms in silica deposition. The presence of taranakite and of silicified organic remains within the speleothems lead to a better understanding of the genesis of the cave. 相似文献
12.
A new method has been developed for the determination of platinum and palladium based on separation and preconcentration with a microcolumn packed with nanometric TiO2 immobilised on silica gel (immobilised nanometric TiO2 ) prior to their determination by inductively coupled plasma-atomic emission spectrometry. The optimum experimental parameters for the preconcentration of Pt and Pd, such as the pH of the sample solution, its flow rate and volume, the type and concentration of eluent and interfering ions, have been investigated. Platinum and Pd could be quantitatively retained by immobilised nanometric TiO2 in the pH range 6–8, then eluted completely with 2.0 ml of 3% m/v thiourea in 1.0 mol l−1 HNO3 . The detection limits of this method for Pt and Pd were 12 and 7. 6 ng l−1 with an enrichment factor of 100, and the relative standard deviations were 4.7% and 3.3% at the 10 ng ml−1 level. The method has been applied for the determination of Pt and Pd in geological samples with satisfactory results. 相似文献
13.
Determination of Trace Elements in Twenty Six Chinese Geochemistry Reference Materials by Inductively Coupled Plasma-Mass Spectrometry 总被引：20，自引：0，他引：20
We report new data for thirty seven elements determined in twenty six Chinese geochemistry reference materials using inductively coupled plasma-mass spectrometry and a reliable and simple dissolution technique. One hundred milligrams of sample were digested with 1 ml of HF and 0.5 ml of HNO3 in PTFE-lined stainless steel bombs heated to 200 °C for 12 hours. Insoluble residues were dissolved using 6 ml of 40% v/v HNO3 heated to 140 C for 3 hours. Analytical calibration was accomplished using aqueous standard solutions. Rhodium was used as an internal standard to correct for matrix effects and instrument drift. Precisions were typically better than 5% RSD. Most of the data presented here agree well with the published certified values. For the elements Zr, Hf and most other trace elements, the measured values were less than 10% in error when compared to certified values. 相似文献
14.
Mayuri Inoue Masato Nohara Takashi Okai Atsushi Suzuki Hodaka Kawahata 《Geostandards and Geoanalytical Research》2004,28(3):411-416
Trace elements in the Geological Survey of Japan carbonate reference materials Coral JCp-1 and Giant Clam JCt-1 were determined by inductively coupled plasma-mass spectrometry after digestion with 2% v/v HNO3 . A standard addition method was adopted in this determination in order to neutralise the Ca matrix effect. In addition, Sc, Y, In and Bi were used as internal standards to control the matrix effect and correct instrumental drift. Of the eighteen elements measured in JCp-1, precisions for fourteen elements, including Cu, Cd and Ba, were better than 10% RSD and concentrations ranged from 0.002 μg g-1 (Cs) to 8.02 μg g-1 (Ba). The concentrations of measured trace elements in JCt-1, except for Cu, were lower than those in JCp-1. Precisions for all elements with concentrations higher than 0.04 μg g-1 in JCt-1 were also better than 10% RSD and concentrations were found to be between 0.001 μg g-1 (Cs) and 4.84 μg g-1 (Ba). The concentrations of more than fifteen trace elements in the aragonite reference materials are reported here for the first time. Both reference materials are suitable for use in geochemical studies of environmental reconstruction based upon biogenic carbonate materials. 相似文献
15.
High-density CO2 -rich fluid inclusions from a sapphirine-bearing granulite (Hakurutale, Sri Lanka) have been studied by microthermometry, Raman spectrometry and SEM analysis. Based on textural evidence, two groups of inclusions can be identified: primary, negative crystal shaped inclusions (group I) and pseudo-secondary inclusions, which experienced a local, limited post-trapping modification (group II). Both groups contain magnesite as a daughter mineral, occurring in a relatively constant fluid/solid inclusion volume ratio (volsolid =0.15 total volume). CO2 densities for group I and II differ only slightly. Both groups contain a fluid, which was initially trapped at peak metamorphic conditions as a homogeneous (CO2 +MgCO3 ) mixture. Thermodynamic calculations suggest that such a fluid (CO2 +15 vol% MgCO3 ) is stable under granulite facies conditions. After trapping, magnesite separated upon cooling, while the remaining CO2 density suffered minor re-adjustments. A model isochore based on the integration of the magnesite molar volume in the CO2 fluid passes about 1.5–2 kbar below peak metamorphic conditions. This remaining discrepancy can be explained by the possible role of a small quantity of additional water. 相似文献
16.
J. F. A. DIENER R. POWELL R. W. WHITE T. J. B. HOLLAND 《Journal of Metamorphic Geology》2007,25(6):631-656
A recent thermodynamic model for the Na–Ca clinoamphiboles in the system Na2 O–CaO–FeO–MgO–Al2 O3 –SiO2 –H2 O–O (NCFMASHO), is improved, and extended to include cummingtonite–grunerite and the orthoamphiboles, anthophyllite and gedrite. The clinoamphibole model in NCMASH is adopted, but the extension into the FeO- and Fe2 O3 -bearing systems is revised to provide thermodynamic consistency and better agreement with natural assemblage data. The new model involves order–disorder of Fe–Mg between the M2, M13 and M4 sites in the amphibole structure, calibrated using the experimental data on site distributions in cummingtonite–grunerite. In the independent set of end-members used to represent the thermodynamics, grunerite (rather than ferroactinolite) is used for FeO, with two ordered Fe–Mg end-members, and magnesioriebeckite (rather than ferritschermakite) is used for Fe2 O3 . Natural assemblage data for coexisting clinoamphiboles are used to constrain the interaction energies between the various amphibole end-members. For orthamphibole, the assumption is made that the site distributions and the non-ideal formulation is the same as for clinoamphibole. The data set end-members anthophyllite, ferroanthophyllite and gedrite, are used; for the others, they are based on the clinoamphibole end-members, with the necessary adjustments to their enthalpies constrained by natural assemblage data for coexisting clino- and orthoamphiboles. The efficacy of the models is illustrated with P – T grids and various pseudosections, with a particular emphasis on the prediction of mineral assemblages in ferric-bearing systems. 相似文献
17.
A comparison between HBr-HCl and HBr-HNO3 based anion chemistry is presented to test the efficiency of Pb purification in the preparation of samples for isotope ratio measurement by ICP-MS. It was found that the small advantages in yield and blank offered by the HNO3 -based method were more than compensated by the more effective matrix removal of the HCl-based method. Apart from very zinc rich matrices (e.g., sphalerite), a careful single pass purification using HBr and HCl removed more than 99.9% of the matrix. In preparation for the isotope ratio analysis, a small (2–5% m/v) liquid sample aliquot was analysed to determine U, Th and Pb concentrations by solution quadrupole ICP-MS. This allowed accurate prediction of the expected ion signal and permitted optimal spiking with Tl, if desired, for mass bias correction. Long-term results for international rock reference materials showed reproducibilities of better than 1% (Th/U) and 1.5% (U/Pb). For most geological applications, such analyses obviate the need for isotope dilution concentration measurements. 相似文献
18.
Abstract. The Cerro Colorado intrusive stock in the northeastern Chilean Precordillera is a plutonic complex formed during Late Cretaceous (64–72 Ma), and consists predominantly of pyroxene-bearing biotite monzogabbro (Colorado Unit), with lesser amounts of pyroxene-bearing hornblende biotite diorite (Pucaquisca Unit) and biotite hornblende monzonite (Pabellón Unit). Compositional variations of major and trace elements suggest that the Cerro Colorado complex is composed of shoshonitic alkali granitoids generated at the active continental margin. The basic to intermediate rocks of the Colorado Unit are characterized by high contents of A12 O3 (>20 wt%), CaO and LIL elements (K, Sr, Ba), high Fe/Mg ratio and fairly low contents of Cr, Ni and Y. These characteristics suggest that the Colorado Unit was formed by plagioclase-free source magma originated from asthenospheric mantle or mafic lower crust. All the Cerro Colorado rocks generally display linear compositional trends, and the latest Pabellón Unit rocks are richer in SiO2 than the Colorado Unit and Pucaquisca Unit rocks. These indicate that the Pabellón Unit rocks were produced by assimilation-fractional crystallization process of the basic to intermediate magma genetically related to the voluminous Colorado Unit. 相似文献
19.
Results of electron microprobe and microthermometric studies of samples collected from the Bouvet Triple Junction Region (BTJR) during a joint Russian-Italian geological expedition on the R/V Academician Nikolaj Strakhov (1994) have revealed new data on the composition of basaltic magmas and oceanic hydrothermal fluids connected with magmatic processes. Detailed analysis of basaltic glasses shows that the modem Mid-Atlantic Ridge (MAR) rift valley is composed of normal mid-ocean ridge basalts with low concentrations of K2 O and TiOz (N-MORB), while its flanks are more enriched with these components approaching E-MORB. A marked influence of the Bouvet hot spot volcanism on magma generation on the South-West Indian Ridge (SWIR) near Bouvet Island is observed. Basaltic melts in this area belong to alkalic and transitional series and have maximum contents of K2 O, TiO2 , H2 O.
Microthermometric analyses of fluid inclusions in the samples from the BTJR have revealed major differences in the oceanic hydrothermal fluid systems on the MAR and near SWIR, which depends on the peculiarities of magma. In the area of the MAR (with dry melts) only H2 O solution inclusions in quartz were found; thus, seawater is probably the only primary source of hydrothermal fluids (NaCl + MgCl2 + H2 O; T = 170–200°C). In the SWIR area (with the high content of water in melts) syngenetic liquid CO2 and H2 O solution inclusions in quartz indicate the influence of the magmatic fluid component on the ore-forming water/carbon dioxide solutions (NaCl + CaC12 + H2 O + CO2 ; T = 200–310 °C; P = 900–1700 bar). 相似文献
Microthermometric analyses of fluid inclusions in the samples from the BTJR have revealed major differences in the oceanic hydrothermal fluid systems on the MAR and near SWIR, which depends on the peculiarities of magma. In the area of the MAR (with dry melts) only H
20.
The solid-solid reaction magnesiocarpholite = sudoite + quartz has been bracketed between 350 and 500°C, 6.3 and 7.8 kbar. Because it is impossible to synthesize end-member sudoite, all experiments were carried out using natural minerals as starting materials. Although mineral compositions were very close to those of the end-members, the effect of the fluorine content in carpholite was significant. Particularly in those experiments where sudoite grows at the expense of carpholite, electron microprobe analysis of the run products shows that a more stable F-rich carpholite crystallizes too, and consumes the fluorine released in solution by the breakdown of the original carpholite.
Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)-1 substitutions in phyllosilicates. This allows us to constrain the feasible thermodynamic parameters (H°f , sud; S ° sud) and (H°f,car ; S °car ) for the Mg end-members. Using the partition coefficients calculated from natural parageneses, we have computed a petrogenetic grid for the system FeO–MgO–Al2 O3 –SiO2 –H2 O. It demonstrates that parageneses involving sudoite and carpholite can be used as indicators of P–T conditions, up to 600° C, 8 kbar for sudoite, and at higher pressure for carpholite. 相似文献
Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)