首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 406 毫秒
1.
Most research on long chain methyl ketones has focused on their origins and distributions. Their application in paleoclimate studies is less common than that of other n-alkyl lipids. The goal of this research was to explore this potential by studying n-alkan-2-ones from the Hani peat sequence in northeastern China. They were identified using gas chromatography-mass spectrometry (GC-MS) and showed a distribution ranging from C19 to C31 with a strong odd/even predominance. This type of distribution is considered to derive from Sphagum and microbial oxidation of n-alkanes. Comparison with climate sensitive indicators and macrofossil analysis shows that microbial oxidation of n-alkanes derived from higher plants was enhanced during the warm early Holocene period. This led us to develop three n-alkan-2-one proxies - C27/ΣC23-31 (C27/HMW-KET), carbon preference index (CPIH-KET) and average chain length (ACL(27-31)-KET) - as possible indicators of paleoclimate in the peat-forming environment. These proxies, in combination with C27n-alkane δD values and peat cellulose δ18O records, might allow examination of paleo-ecosystem behavior during climatic evolution in northeastern China over the past 16,000 yr.  相似文献   

2.
The most widely accepted origin of n-alkan-2-ones in peats is the microbial oxidation of the related n-alkanes and/or oxidative decarboxylation of fatty acids derived from plant input. The distributions of n-alkanes and n-alkan-2-ones in 48 samples from the Roñanzas 6000 cal. yr BP peat bog profile (N Spain) do not justify a single source. The n-alkan-2-ones typically dominate the n-alkanes, maximizing at C19 or C25/C27, whereas the n-alkanes maximized either at C23 or at C31/C33. The averaged δ13C values of the n-alkanes ranged from −32.3‰ to −33.1‰, but those of the n-alkan-2-ones were consistently higher (−29.2‰ to −29.9‰), suggesting a different, probably bacterial, source for the ketones.  相似文献   

3.
《Applied Geochemistry》2005,20(3):553-568
Seven coal and carbonaceous mudstone samples were collected from outcropping Jurassic coal beds, on the margin of the Dingxi Basin, Northwestern China. The n-alkane distributions in all of the samples are characterised by high concentrations of the C19–C29 homologues, and very much lower amounts outside of this range. C23 or C24 are usually the most abundant n-alkanes. Straight chain n-alkanes from C23 to C29 show moderate odd-to-even C number predominances (CPI range: 1.26–2.70). Long-chain acyclic n-alkan-2-ones, n-alkan-3-ones and n-alkan-4-ones ranging from C15 to C33 with moderate odd-to-even C number predominances, were detected together with one isoprenoid methyl ketone (6,10,14-trimethylpentadecan-2-one) in all of the samples. The C number distributions of the three series of alkanones show a similar distribution to that of the n-alkanes, but the correspondence is not sufficient to substantiate a product–precursor relationship. It can be concluded that the n-alkan-2-ones are a mixture of the products of microbially-mediated β-oxidation of corresponding n-alkanes in the sediments and from the microbial oxidation of higher plant-derived n-alkanes prior to incorporation in the sediments. The n-alkan-3-ones and n-alkan-4-ones were formed from microbially mediated oxidation of the corresponding n-alkanes in the γ and δ positions, respectively. Generation of the ketones from higher plant n-fatty alcohols and n-alkanoic acids could be a possible way to form some of the ketones observed, but it can only play a minor role in the samples analysed.  相似文献   

4.
This study provides a reconstruction of the environmental evolution since 128 ka recorded by the lipid biomarkers of the C15–C35 n-alkanes, the C13–C33 n-alkan-2-ones and the C12–C30 n-alkanols isolated from the Tawan loess section, Northwest China. Variations in paleoenvironment are reconstructed from the values of the carbon preference index (CPI), the average chain length (ACL), the L/H (ratio of lower-molecular-weight to higher-molecular-weight homologues), the n-alkane C27/C31 ratios, and the n-alkan-2-one C27/C31 ratio. These parameters indicate the dominance of grasses over the west Chinese Loess Plateau (CLP) during the late Pleistocene. Lower values of the CPI and the ACL values, respectively, indicate stronger microbial reworking of organic matter and changes in plant species, which are both indicative of a warmer-wetter environment. Furthermore, the fluctuations of environment recorded in the Tawan section exhibit ten phases that show obvious cycles between warm periods and cold intervals. This study reveals that changes in the biomarker proxies agree well with changes in the magnetic susceptibility and grain size, and it indicates a huge potential for paleoenvironmental reconstructions by using the n-alkan-2-one and n-alkanol proxies.  相似文献   

5.
We determined the distribution of lipids (n-alkanes and n-alkan-2-ones) in present-day peat-forming plants in the Roñanzas Bog in northern Spain. Consistent with the observation of others, most Sphagnum (moss) species alkanes maximized at C23, whereas the other plants maximized at higher molecular weight (C27 to C31). We show for the first time that plants other than seagrass and Sphagnum moss contain n-alkan-2-ones. Almost all the species analysed showed an n-alkan-2-one distribution between C21 and C31 with an odd/even predominance, maximizing at C27 or C29, except ferns, which maximized at lower molecular weight (C21-C23). We also observed that microbial degradation can be a major contributor to the n-alkan-2-one distribution in sediments as opposed to a direct input of ketones from plants.  相似文献   

6.
Peats in a sediment core from Ruoergai bog, which has a cold and moist plateau climate with major source input from herbaceous plants, have been studied by GC–MS in order to understand the composition and diagenetic processes of lipids in this depositional environment. Long chain components (C21–C35) predominate in the n-alkanes, n-alk-1-enes, n-fatty acids, n-alkan-2-ones and n-alkanols with a maximum of C31, C27, C22 or C24, C23 or C25 and C22, respectively. A herbaceous origin for these long chain compounds is suggested, and this is supported by their stable carbon isotopic compositions. Diterpenoid hydrocarbons with abietane, pimarane and kaurane skeletons, some of which have not been reported often in modern sediments, are prominent and are derived from higher plants. Several triterpenoid ketones and alcohols with oleanane or lupane skeletons, and a series of des-A-triterpenoid hydrocarbons which have not been reported often in modern sediments are also present, and are assigned to a higher plant source. Hopanoids, including their alkanes, alkenes, ketones, alcohols and esters, are abundant and of bacterial origin. Steroid ketones and alkanols are dominated by C29 homologues. C28 and C29 steroids are derived mainly from higher plants, whereas the C27 component is assigned to a microbial source. The presence of short-chain n-alkanes with no odd-even carbon predominance, bacterially derived fatty acids (C14, C15, iso- and unsaturated acids), n-alkan-2-ones, des-A-triterpenoid hydrocarbons, hopanoids and some steroid ketones indicate that intense microbial reworking of the organic matter has taken place in this depositional environment. The chemical and biochemical conversions of some cyclic alkenes to alkanes, such as tricyclic diterpenoids, tetracyclic terpenoids and steroid ketones, are also evident with depth. The dominance of C20 components in the diterpenoid hydrocarbons may reflect an oxidizing or reducing depositional condition.  相似文献   

7.
Lipid biomarkers from a peat plateau profile from the Northeast European Russian Arctic were analyzed. The peat originated as a wet fen ca. 9 ka BP and developed into a peat bog after the onset of permafrost ca. 2.5 ka BP. The distributions and abundances of n-alkanols, n-alkanoic acids, n-alkanes, n-alkan-2-ones and sterols were determined to study the effect of degradation on their paleoclimate proxy information. Plant macrofossil analysis was also used in combination with the lipid distributions. The n-alkanol and n-alkanoic acid distributions in the upper part of the sequence generally correspond to compositions expected from plant macrofossil assemblages. Their carbon preference index (CPI) values increase with depth and age, whereas those of the n-alkanes decrease. The different CPI patterns suggest that n-alkanoic acids and n-alkanols deeper in the sequence may be produced during humification through alteration of other lipids. Excursions in the n-alkanoic acid content also suggest an important contribution of invasive roots to the lipid biomarker composition. The CPIs associated with these compounds show that under permafrost conditions organic material from Sphagnum is better preserved than material from vascular plants. Increasing stanol/stenol ratio values and decreasing n-alkane CPI values indicate progressive degradation of organic matter (OM) with depth. The n-alkan-2-one/n-alkane and n-alkan-2-one/n-alkanoic acid ratios were shown to be useful proxies that can reflect the degree of OM preservation and suggest that both microbial oxidation of n-alkanes and decarboxylation of n-alkanoic acids produce n-alkan-2-ones in this peat sequence.  相似文献   

8.
Molecular stratigraphic analyses using gas chromatograph-mass spectrometry have been performed in the upper section (S0, L1, S1) of the Yuanbo loess-paleosol sequences in northwest China, with a record extending from the last interglaciation through the present interglaciation. The CPI (Carbon Preference Index) values of both n-alkanols and n-alkan-2-ones display variations between loess deposits and paleosols, showing a correlation with the magnetic susceptibility record, an indicator of the East Asian summer monsoon. The observed variations in the indexes in relation to changes in lithology/paleoclimate are proposed to result from microbial degradation of higher plant lipids in the paleosols. The CPI values of n-alkanes, n-alkanols, and n-alkan-2-ones are negatively correlated with δ13C of bulk organic matter. The correlations suggest that the observed glacial-interglacial variations of δ13C data in the loess stratigraphy reflect the relative importance of the contribution of paleovegetation compared with microorganisms (including both the degradation and the addition of organic matter) and allochthonous loess/soil parent materials. It is thus necessary to evaluate the contributions of the latter two before the paleovegetation can be reconstructed based on the δ13C analysis of bulk organic matter in some loess-paleosol sequences of the Chinese Loess Plateau.  相似文献   

9.
The molecular distributions of homologous aliphatic lipid compounds (n-alkanes, n-alkanoic acids, n-alkanols, n-alkanals and n-alkan-2-ones) were investigated in sediments of Lake Bera, Malaysia as well as in plant waxes from the vicinity using gas chromatography-mass spectrometry. In addition, triterpenoids of the oleanane, ursane, lupane and friedelane series, and their diagenetic products were also identified. Using the aquatic proxy Paq, it was found that the n-alkanes present in surface sediments S1, S5 and S6 correspond to an input from emergent macrophytes, whereas in sediments collected from open water (S2, S3 and S4) they correspond to input from submerged/floating macrophytes. The presence of n-alkan-2-ols, a commonly found homologous series in the sediments as well as in the plant wax, is novel here. In addition, the presence of 24-methylcycloart-22-enol and 24-ethylcycloart-22-enol in sediments as well as the plant wax of Pandanus helicopus, a dominant reed around the lake, also supports the input of plant biomarkers to the sediments. The occurrence of 5-membered ring triterpenoid derivatives as major diagenetic products of the triterpenoids identified (e.g. friedelan-2,3-dione) shows that the degradation of the organic matter in the sediments occurs mainly under oxic conditions. Also, the presence of ring-A degraded triterpenoids (dihydroputranjivic acid, 3-nor-2,4-seco-friedelane, 4α- and 4β-3-norfriedelanes, A-norfriedel-10-one, and A-norfriedel-8-en-10-one) and the aromatized triterpenoid hydrocarbons (mono- and triaromatic derivatives) as minor diagenetic products indicates photochemical and microorganism-mediated alteration reactions of natural products in the sediments. Additional novel polyfunctional friedelane derivatives, namely friedelane-2,3-dione, friedelane-1,3-diol-2-one and friedel-1(10)-ene-1,3-diol-2-one were identified for the first time in this study. These novel polyfunctional triterpenoids were inferred to derive from the oxidation of the triterpenoids from higher plants in this oxic tropical environment. For future reference purposes, the mass spectra of the identified polar triterpenoids are also presented here. This study provides important data on the biogeochemistry of organic matter in a tropical lake of SE Asia.  相似文献   

10.
We present elemental concentrations and magnetic susceptibility data from a new 270‐cm‐long sediment core collected from the western part of palaeolake Babicora and infer millennial‐scale hydrological variations over the last 27 cal. ka in the western Chihuahua Desert. Variations in the available water content at the sediment–air interface of the watershed, lake salinity and lake productivity are inferred from values of the chemical index of alteration (CIA), CaCO 3 and Corg, respectively. An abrupt increase in runoff at c. 24 cal. ka BP appears correlative with the Heinrich 2 (H2) event. Except for this event, diminished runoff between c. 27 and 19 cal. ka BP indicates lower annual precipitation (weak summer rainfall) during the Last Glacial Maximum. The deposition of chemically altered sediments between c. 25 and 22 cal. ka BP results from the higher sediment–water interaction in the watershed owing to lower evaporation, cooler conditions and higher precipitation during the H2 event. Since 19 cal. ka BP the runoff has been characterized by high‐amplitude fluctuations with intervals of reduced precipitation identified at c. 19, 18, 17.5, 13–14, 11.5, 10, 7.5 and 3 cal. ka BP.  相似文献   

11.
Lipid extracts from a 61.7-cm-long subtropical stalagmite in southern China, spanning the period of ca. 10,000–21,000 yr ago as constrained by U–Th dating, were analyzed using gas chromatography–mass spectrometry. The higher plants and microorganisms in the overlying soils contribute a proportion of n-alkanes identified in the stalagmite. The occurrence of LMW (lower molecular weight) n-alkanols and n-alkan-2-ones in the stalagmite was mainly related to the soil microorganisms. We suggest that HMW (higher molecular weight) n-alkanols and n-alkan-2-ones identified in the stalagmite originate from soil organics and reflect input from contemporary vegetation. Shifts in the ratio of LMW to HMW n-alkanols or n-alkan-2-ones indicative of the variation of soil ecosystems (e.g., microbial degradation of organic matter and/or the relative abundance of soil microorganisms to higher plants) are comparable with the subtropical alkenone-SST (sea surface temperature) record of the same period. The similar trends seen in the δ13C data and the lipid parameters in this stalagmite imply that the overlying soil ecosystem response to climate might be responsible for the variation of δ13C values.  相似文献   

12.
The δ13C values of higher plant wax C27–33 n-alkanes were determined in three, time-equivalent Pliocene (2.943 Ma) sapropels and homogeneous calcareous ooze from three different sites forming an east-west transect in the eastern Mediterranean Basin in order to study the composition of the vegetation on the continents surrounding the Mediterranean Sea. A two-end member mixing model transformed the measured δ13C values into the contribution of C4 plants to the terrestrial vegetation. These calculations indicated a high C4 plant contribution (i.e. 40–50%) in the periods just before and just after sapropel formation. During sapropel deposition the C4 plant contribution increased by up to 20% at all sites. This is interpreted to record the increased overall plant coverage of the Mediterranean borderlands resulting from the change in formerly barren desert areas into C4 grass-dominated savannahs as a response to the wetter climate during sapropel deposition. Enhanced accumulation rates (ARs) of long-chain n-alkanes (C27–33) and n-alkan-1-ols (C26–30) towards the middle of the sapropel in concert with a decrease in the Ti/Al ratio confirm an increased delivery of terrigenous organic matter at all sites. These biomarkers were probably predominantly fluvially transported to the Mediterranean Sea, not only by the Nile but by fossil wadi river systems on the northern African continent.  相似文献   

13.
High resolution records of long chain n-alkanol biomarkers were obtained from a peat-lacustrine core from the Dingnan profile in southern China. The n-alkanol distributions are characterized by the predominance of even-over-odd carbon number and maximize at C24 or C26. On the basis of the reported n-alkanol records in the literature and the n-alkane record in our samples, we concluded that the n-alkanol ratio of C26/C30 varying from 1.25 to 6.48, together with the n-alkanol ratio C22/C24 less than unity, is indicative of the presence of a dominant forest paleovegetation. A 2000-year cycling in the variation of the n-alkanol ratio C26/C30 is identifiable in our profile, and probably results from the change in the abundance of the grass relative to trees induced by a cyclic paleoclimate. The n-alkanol ratio C24/C26 appears to be more sensitive to change in precipitation than in temperature, and may be a potential indicator of precipitation/humidity, with increased values being associated with relatively dry conditions. The paleovegetation and the paleoclimate reconstructed on the basis of the n-alkanol records for the recent 18000 cal a BP in general accord with the pollen data and other lipid evidence recorded in the Dingnan region in southern China. In particular, both the n-alkanol records and the pollen data infer the different paleoclimate conditions for the two peat sequences, with a cool and wet climate dominating in the lower peat deposition formed during the latest Pleistocene and a change to a drier and cooler climate occurring in the upper peat sequence in mid-Holocene.  相似文献   

14.
The compositions of sterol, alcohol and ketone fractions from an oxic intertidal surface sediment from Corner Inlet. Victoria, Australia, have been examined by capillary gas chromatographymass spectrometry and related to the lipids of diatoms cultured from the sediment and to lipids of the sea-grass Zostera muelleri. Of the more than thirty sterols in the sediment most appear to derive from diatoms, including the major sterol 24-methylcholesta-5.22E-dien-3β-ol. Small amounts of 24-ethylcholesterol probably derive from Zostera, with a minor diatom contribution. 5α-stanols, both fully saturated and with a side-chain double bond, represented ca. 14% of the total sterols: a significant proportion of these are probably derived from marine invertebrates. These organisms also contribute C26 sterols. most of the cholesterol and possibly small amounts of Δ-sterols. The data suggest that in situ biohydrogenation of stenols was not a major process in sterol transformation in the surface oxic sediment. Alcohols ranged from C12 to C30 and showed an unusual abundance of unsaturated components with Δ9-16:1 being the major constituent. The long-chain alcohols probably originate largely from Zostera but the shorter-chain. C12-C20. alcohols are at least partly derived from wax esters of unknown origin. Diatoms do not contribute significant amounts of alcohols. Ketones were not major constituents of the sediment and consisted mainly of 6.10.14-trimethylpentadecan-2-one and a series of n-alkan-2-ones ranging from C16 to C33. The latter showed a similar distribution to that of the n-alkanes but the correspondence was not sufficient to substantiate a product-precursor relationship. Very long-chain C3- C39 unsaturated methyl and ethyl ketones, which may originate from the marine unicellular alga Emiliania huxleyi. were present in low concentration.  相似文献   

15.
利用GC－MS对西北干旱区-半干旱区兰州兴隆山森林区典型植被与现代土壤样品中可抽提的类脂物进行了系统分析,检测出包括正构烷烃和α正构脂肪酮等一系列类脂物分子化石。在未进行族分离的情况下,检出兴隆山现代森林木本植物的正构烷烃以C27或C29为主峰,草本植物则以C31为主峰;  土壤样品中均保留有很强的、几乎均势的C27,C29和C31信号; α正构脂肪酮具有明显的奇碳优势,植物中以C23,C25或C29为主峰,土壤样品以C27或C29为主峰;  其反映的信息是植被与微生物共同作用的结果。本研究为理解现代土壤和古土壤中类脂物所指示的植被信息、进一步探讨类脂物分子在植被(有机质)-微生物-土壤-湖泊沉积体系中存在与相互转换关系这一基础理论问题提供了科学资料。同时,为分子化石分析方法的改进和不同处理过程所得数据之间的对比和科学解释提供资料。  相似文献   

16.
A 40 cm deep Sphagnum-dominated peat monolith from Bolton Fell Moss in Northern England was systematically investigated by lipid molecular stratigraphy and compound-specific δ13C and δD analysis using gas chromatography (GC), GC-mass spectrometry (GC-MS), GC-combustion-isotope ratio-MS (GC-C-IRMS) and GC-thermal conversion-IRMS (GC-TC-IRMS) techniques. 210Pb dating showed the monolith accumulated during the last ca. 220 yr, a period encompassing the second part of Little Ice Age. While the distributions of lipids, including n-alkan-1-ols, n-alkan-2-ones, wax esters, sterols, n-alkanoic acids, α,ω-alkandioic acids and ω-hydroxy acids, display relatively minor changes with depth, the cooler climate event was recorded in the concentrations of n-alkanes and organic carbon, CPI values of n-alkanes and n-alkanoic acids, and the ratio of 5-n-alkylresorcinols/sterols. Superimposed on the fossil fuel effect, the relatively cooler climate event was also recorded by δ13C values of individual hydrocarbons, especially the C23n-alkane, a major compound in certain Sphagnum spp. The δD values of the C29 and C33n-alkanes correlated mainly with plant composition and were relatively insensitive to climatic change. In contrast the C23n-alkane displayed variation that correlated strongly with recorded temperature for the period represented by the monolith, agreeing with previously reported deuterium records in tree ring cellulose spanning the same period in Scotland, Germany and the USA, with more negative values occurring during the second part of Little Ice Age. These biomarker characteristics, including the compound-specific δ13C and δD records, provide a new set of proxies of climatic change, potentially independent of preserved macrofossils which will be of value in deeper sections of the bog where the documentary records of climate are unavailable and humification is well advanced.  相似文献   

17.
Small mountain lakes are natural archives for understanding long-term natural and anthropogenic impact on the environment. This study focused on long-term (last ca. 13 000 years) vegetation changes and sedimentary processes in the catchment area of Lake Planina pri jezeru (1430 m a.s.l.) by using mineralogical, geochemical and palynological methods. Palynological results suggest that regional vegetation between 12 900 and 11 700 cal a bp was a herbaceous–forest tundra (Pinus, Artemisia, Poaceae ). Climate warming at the beginning of the Holocene (ca. 11 700 cal a bp ) caused the transition from a wetland (Cyperaceae) to an eutrophic lake with alternating anoxic (pyrite) and oxic conditions (gypsum). In addition, the surrounding area became forested (Picea, Larix, Ulmus). Fagus expanded at 10 200 cal a bp and Abies at 8200 cal a bp. Between 7500 and 4300 cal a bp , human impact on the environment was barely noticeable and mostly limited to grazing. During 4300–430 cal a bp human impact became more evident and gradually increased. The greatest influence was observed from 430 cal a bp onwards, when excessive exploitation of the surrounding area (logging and grazing) severely eutrophicated the lake.  相似文献   

18.
In response to the lack of studies focussing on the residence time of molecular biomarkers in soils, the lipid content of three soil profiles from the French Massif Central with different land use history were examined. The free neutral lipid content of two reference soil profiles developed under grassland and forest vegetation, and of a former grassland soil converted to forest about 60 years ago, was analysed using gas chromatography–mass spectrometry (GC–MS). Wax esters as well as the ratio of major homologues of n-alkanes and n-alkan-2-ones could be used to characterise the overlying vegetation in the reference forest and grassland soil profiles, but failed to distinguish the respective grassland and forest contributions to the profile of the soil that had changed use. For n-alkanes and n-alkan-2-ones, the failure might be attributed either to mixing of the molecular patterns inherited from the former and current plant cover, whereas for compounds such as wax esters simple degradation is likely to be involved. Conversely, iso- and anteiso-C15:0 fatty acid methyl esters (FAMEs; of bacterial origin), steroids (tracing cattle faecal contamination), tricyclic diterpenoids and their oxygenated derivatives, as well as methoxyserratenes (inherited from Pinaceae) and triterpenyl acetates (specific to the Asteraceae), proved to be effective in distinguishing current land use for the reference soil profiles and for the converted soil. The persistence of these compounds in the changed use soil allowed us to estimate their residence time in soil.  相似文献   

19.
Geochemical (element analysis, molecular analysis of organic compounds), physical, palynological, mineralogical and sedimentary facies analysis were performed to characterise the sedimentary record in Fuentillejo maar‐lake in the Central Spanish Volcanic Field of Campo de Calatrava, in order to reconstruct the palaeoenvironmental and palaeoclimatic processes which controlled vegetation patterns and deposition of different sedimentary facies. The upper 20 m of core FUENT‐1 show variations in clastic input, water chemistry, vegetation and organic fraction sources in the lake throughout the Late Pleistocene and Holocene. The temporal framework provided by 14C accelerator mass spectrometry dating allows assigning the sequence to the last 50 cal. ka BP. Arid phases identified in the FUENT‐1 sequence are correlated to Heinrich events (HE) and to stadials of the Dansgaard/Oeschger (D/O) cycles. Siliciclastic facies with high magnetic susceptibility values, high Juniperus pollen content, a low Paq index (aquatic macrophysics proxy index), a decrease in the relative percentage of the n‐C27 and an increase in the n‐C31 alkanes are indicative of arid and colder climatic events related to HE 2, HE 1 and the Younger Dryas (YD). Similar short cold and arid phases during the Holocene were identified at 9.2–8.6, 7.5–7 and 5.5–5 cal. ka BP. In dolomite–mud facies, the pollen data show an increase in the herbs component, mainly – Chenopodiaceae, Artemisia and Ephedra – steppe taxa; a low Paq index, a decrease in the relative percentage of the n‐C27 alkane and an increase in the n‐C31 alkane are also observed. This facies was probably the result of lower lake levels and more saline–alkaline conditions, which can be interpreted as linked to arid–warm periods. These warm and arid phases were more frequent during Marine Isotope Stage (MIS) 3 and the interstadials of MIS 2. HE 4, HE 2, HE 1 and the YD in core FUENT‐1 were immediately followed by increases of warm steppe pollen assemblages that document rapid warming similar to the D/O cycles but do not imply increasing humidity in the area. Fuentillejo hydrology is controlled by changes in the atmospheric and oceanic systems that operated on the North Atlantic region at millennial scale during the last 50 cal. ka BP. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

20.
With a production of 208.2 m3/d, heavy oil was produced by drill stem test (DST) from three shallow reservoirs in Sand Group Nos. Ⅰ and Ⅲ of the Neogene Guantao Formation (NgⅠ and NgⅢ) and the Eogene Dongying Formation (Ed) in an exploratory well Ban-14-1 within the Qianmiqiao region, Bohai Bay Basin, northern China. Based on the GC and GC-MS data of the NgⅠ and NgⅢ heavy oil samples, all n-alkanes and most isoprenoid hydrocarbons are lost and the GC baseline appears as an evident "hump", implying a large quantity of unresolved complex mixture (UCM), which typically revealed a result of heavy biodegradation. However, there still is a complete series of C14-C73 n-alkanes in the high-temperature gas chromatograms (HTGC) of the heavy oil, among which, the abundance of C30- n-alkanes are drastically reduced. The C35-C55 high molecular weight (HMW) n-alkanes are at high abundance and show a normal distribution pattern with major peak at C43 and an obvious odd-carbon-number predominance with CPI37-55 and  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号