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1.
Understanding Neoproterozoic crustal evolution is fundamental to reconstructing the Gondwana supercontinent, which was assembled at this time. Here we report evidence of Cryogenian crustal reworking in the Madurai Block of the Southern Granulite Terrane of India. The study focuses on a garnet-bearing granite–charnockite suite, where the granite shows in situ dehydration into patches and veins of incipient charnockite along the contact with charnockite. The granite also carries dismembered layers of Mg–Al-rich granulite. Micro-textural evidence for dehydration of granite in the presence of CO2-rich fluids includes the formation of orthopyroxene by the breakdown of biotite, neoblastic zircon growth in the dehydration zone, at around 870°C and 8 kbar. The zircon U–Pb ages suggest formation of the granite, charnockite, and incipient charnockite at 836 ± 73, 831 ± 31, and 772 ± 49 Ma, respectively. Negative zircon εHf (t) (?5 to ?20) values suggest that these rocks were derived from a reworked Palaeoproterozoic crustal source. Zircon grains in the Mg–Al-rich granulite record a spectrum of ages from ca. 2300 to ca. 500 Ma, suggesting multiple provenances ranging from Palaeoproterozoic to mid-Neoproterozoic, with neoblastic zircon growth during high-temperature metamorphism in the Cambrian. We propose that the garnet-bearing granite and charnockite reflect the crustal reworking of aluminous crustal material indicated by the presence of biotite + quartz + aluminosilicate inclusions in the garnet within the granite. This crustal source can be the Mg–Al-rich layers carried by the granite itself, which later experienced high-temperature regional metamorphism at ca. 550 Ma. Our model also envisages that the CO2 which dehydrated the garnet-bearing granite generating incipient charnockite was sourced from the proximal massive charnockite through advection. These Cryogenian crustal reworking events are related to prolonged tectonic activities prior to the final assembly of the Gondwana supercontinent.  相似文献   

2.
《International Geology Review》2012,54(13):1688-1704
The Yinshan Block, part of the Neoarchaean basement of the Western Block of the North China Craton, is composed of granite–greenstone and granulite–charnockite complexes. We report research on a suite of charnockites from the granulite–charnockite complex and characterize their geochemistry, zircon U–Pb geochronology, and Hf isotopic composition. The charnockites can be divided into intermediate (SiO2 = 59–63 wt.%) and silicic (SiO2 = 69–71 wt.%) groups. U–Pb zircon data yield protolith formation ages of 2524 ± 4 Ma, 2533 ± 15 Ma, followed by metamorphism at 2498 ± 3 Ma, 2490 ± 11 Ma, respectively, for these groups. Although the intermediate charnockites are characterized by higher Al2O3, TiO2, Fe2O3T, MnO, MgO, CaO, P2O5, K2O, Sr, and ΣREE content than the silicic charnockites, the ages and Hf isotopic composition of zircons and REE patterns of both intermediate and silicic charnockites are remarkably consistent, which indicates that they are genetically related. These charnockites are predominantly metaluminous to slightly peraluminous, calc-alkalic to calcic, and magnesian – characteristics generally related to a subduction setting. High-Sr + Ba granites with low K2O/Na2O characteristics, shown by these charnockites, imply a mixture of mafic and felsic magmas generated from an enriched mantle + lower crust. High MgO, Ni, Cr and Mg#, low K2O/Na2O, and metaluminous to slightly peraluminous natures imply that the source rocks most likely were amphibolites. Coeval calc-alkaline magmatism and high-T granulite-facies metamorphism under low-H2O activity in the area lead us to propose a model involving mid-ocean ridge subduction within a Neoarchaean convergent margin. The arc-related rocks accreted along the continent margin, and became a barrier when the lithospheric mantle ascended through the slab window. Melt derived from the decompressing mantle mixed with melt derived from the overlying, juvenile lower crust melt, which was warmed and metamorphosed by the ascending lithospheric mantle.  相似文献   

3.
Extremely U-depleted (<1 ppm) zircons from H8 banded ores in the East Orebody of the Bayan Obo REE–Nb–Fe deposit are presented, with mineral compositions, textures, 232Th–208Pb SHRIMP ages and petrological context. Cores of East Orebody zircon contain up to 7 wt% HfO2 and are zoned, depicting bipyramidal crystal forms. A distinct generation of patchy, epitaxial rim zircon, similarly depleted in U, is intergrown with rare earth ore minerals (bastnäsite, parisite, monazite). Overprinting aegirine textures indicate paragenetically late, reactive Na-rich fluids. Chondrite-normalized REE patterns without Eu anomalies match closely with those from the Mud Tank and Kovdor carbonatitic zircons. Increased HREE in rims ((Lu/Gd)N 43–112) relative to cores ((Lu/Gd)N 6–7.5) and the localized presence of xenotime are attributable to reactive, mineralizing fluid compositions enriched in Y, REE and P. Cathodoluminescence further reveals HREE fractionation in rims, evidenced by a narrow-band Er3+ emission at 405 nm. The extreme depletion of U in core and rim zircon is characteristic for this mineral deposit and is indicative of a persistent common source. U depletion is also a characteristic for zircons from carbonatitic or kimberlitic systems. 232Th–208Pb (SHRIMP II) geochronological data reveal the age of zircon cores as 1,325 ± 60 Ma and a rim-alteration event as 455.6 ± 28.27 Ma. The combined findings are consistent with a protolithic igneous origin for zircon cores, from a period of intrusive, alkaline–carbonatitic magmatism. Fluid processes responsible for the REE–Nb mineralizations affected zircon rim growth and degradation during the widely reported Caledonian events, providing a new example in a localized context of HREE enrichment processes.  相似文献   

4.
The recognition of the coeval growth of zircon, orthopyroxene and garnet domains formed during the same metamorphic cycle has been attempted with detailed microanalyses coupled with textural analyses. A coronitic garnet-bearing granulite from the lower crust of Calabria has been considered. U–Pb zircon data and zircon, garnet and orthopyroxene chemistries, at different textural sites, on a thin section of the considered granulite have been used to test possible equilibrium and better constrain the geological significance of the U–Pb ages related to zircon separates from other rocks of the same structural level. The garnet is very rich in REE and is characterised by a decrease in HREE from core to outer core and an increase in the margin. Zircons show core–overgrowth structures showing different chemistries, likely reflecting episodic metamorphic new growth. Zircon grains in matrix, corona around garnet and within the inner rim of garnet, are decidedly poorer in HREE up to Ho than garnet interior. Orthopyroxene in matrix and corona is homogeneously poor in REE. Thus, the outer core of garnet and the analysed zircon grains grew or equilibrated in a REE depleted system due to the former growth of garnet core. Zircon ages ranging from 357 to 333 Ma have been determined in the matrix, whereas ages 327–320 Ma and around 300 Ma have been determined, respectively, on cores and overgrowths of zircons from matrix, corona and inner rim of garnet. The calculated DREEzrn/grt and DREEopx/grt are largely different from the equilibrium values of literature due to strong depletion up to Ho in zircon and orthopyroxene with respect to garnet. On the other hand, the literature data show large variability. In the case study, (1) the D zrn/grt values define positive and linear trends from Gd to Lu as many examples from literature do and the values from Er to Lu approach the experimental results at about 900 °C in the combination zircon dated from 339 to 305 Ma with garnet outer core, and (2) D opx/grt values define positive trends reaching values considered as suggestive of equilibrium from Er to Lu only with respect to the outer core of garnet. The presence of a zircon core dated 320 Ma in the inner rim of garnet suggests that it, as well as those dated at 325–320 Ma in the other textural sites and, probably, those dated at 339–336 Ma showing depletion of HREE, grew after the garnet core, which sequestered a lot of HREE and earlier than the HREE rich margin of garnet. The quite uniform REE contents in orthopyroxene from matrix and corona and the low and uniform contents of HREE in the zircon overgrowths dated at about 300 Ma allow to think that homogenisation occurred during or after the corona formation around this age. The domains dated around 325–320 Ma would approximate the stages of decompression, whereas the metamorphic peak probably occurred earlier than 339 Ma.  相似文献   

5.
Zircon crystals from a locally charnockitized Paleoproterozoic high-K metagranite from the Kerala Khondalite Belt (KKB) of southern India have been investigated by high-spatial resolution secondary ion mass spectrometry analysis of U–Th–Pb and rare earth elements (REE), together with scanning ion imaging and scanning ion tomography (depth-profiled ion imaging). The spot analyses constrain the magmatic crystallization age of the metagranite to ca. 1,850 Ma, with ultrahigh-temperature (UHT) metamorphism occurring at ca. 570 Ma and superimposed charnockite formation at ca. 520–510 Ma, while the ion imaging reveals a patchy distribution of radiogenic Pb throughout the zircon cores. Middle- to heavy-REE depletion in ca. 570 Ma zircon rims suggests that these grew in equilibrium with garnet and therefore date the UHT metamorphism in the KKB. The maximum apparent 207Pb/206Pb age obtained from the unsupported radiogenic Pb concentrations is also consistent with formation of the Pb patches during this event. The superimposed charnockitization event appears to have caused additional Pb-loss in the cores and recrystallization of the rims. The results of depth-profiling of the scanning ion tomography image stack show that the Pb-rich domains range in size from <5 nm to several 10 nm (diameter if assumed to be spherical). The occurrence of such patchy Pb has previously been documented only from UHT metamorphic zircon, where it likely results from annealing of radiation-damaged zircon. The formation of a discrete, heterogeneously distributed and subsequently immobile Pb phase effectively arrests the normal Pb-loss process seen at lower grades of metamorphism.  相似文献   

6.
The Neoarchean charnockites of North margain of North China Craton(NCC) has become a hot topic into understanding the Early Precambrian basement. Although there is a broad consensus that charnockite is usually related to granulite facies metamorphism, whether its petrogenesis and tectonics characteristics remains controversial. Inclusions within hypersthene and garnet in charnockite are used to identify the peak granulite facies mineral assemblage, with the formation of Magnesian–charnockite attributed to anatexis of the protolith associated with this granulite facies metamorphism. The distribution of major and trace elements in charnockite is very uneven, significant depleted in LILEs(eg. Cs, U, Th) and HFSEs(eg. Nb, Ta, P and Ti), riched in Sr. Raising to the coexistence of Eu–enrichment and Eu–depletion type of REE patterns that influenced by the content of plagioclase and the remnants minerals of zircon and apatite. Comparative the petrography, geochemistry and geochronology data of Magnesian–charnockite indicate that the ratios of mafic pellites and basalts involved in anatectic melting are different by the upwelling of mantle magma, also resulting in the Eu anormals characteristics. The formation of the Magnesian–charnockite is closely connected with the subduction of the NCC oceanic crust(About ～2.5 Ga). However, Ferroan–charnockite may be the formed by the crystallization differentiation of the upwelling of mantle–derived shoshonitic magma(About ～2.45 Ga), with the lower crust material addition.  相似文献   

7.
Exposures in many quarries in southern India exhibit field evidence for incipient charnockitization of tonalitic and granitic gneiss (prograde relationship), or retrogression of charnockite to produce tonalitic gneiss (retrograde relationship). Few systematic geochemical relationships exist between adjacent gneisscharnockite sample pairs during either prograde or retrograde reactions. Most elements and element ratios exhibit inconsistent variations; however, prograde chamockites appear enriched in Ta, Pb, volatiles (chiefly CO2), and in transition metals relative to Mg, and depleted in REE and Y compared to adjacent gneiss protoliths. Retrograde gneisses have higher Rb, Pb, Th, Hf, Zn relative to Co, Nb relative to Ta, Hf relative to Zr, and volatiles (chiefly H2O) compared to parental charnockites. Of those elements (U, Th, Rb, Cs, Pb) significantly depleted in high-pressure charnockites exposed south of the prograde transition zone, only Pb is significantly replenished during retrogression. Evidence suggests that prograde fluids are relatively rich in CO2 and retrograde fluids in H2O and that the typical non-systematic geochemical variations during prograde and retrograde reactions reflect local effects at the wave front.  相似文献   

8.
The microgeochemistry of zircon was studied in three samples: charnockite gneiss (1594), charnockite (1594a), and migmatite leucosome Lc4 (1594c). Prismatic (Zrn I) and oval (Zrn II) zircon morphotypes are distinguished in the first two samples. Most zircon grains consist of two-phase cores and overgrowth rims variable in thickness. The average weighted concordant U–Pb age of Zrn II cores from charnockite gneiss is 2436 ± 10 Ma. The concordant ages of Zrn I and Zrn II cores from charnockite are 2402 ± 16 Ma and 2453 ± 14 Ma, respectively. Some overgrowth rims are 1.9–2.1 Ga in age. In leucosome Lc4, all measured prismatic zircon crystals yielded a discordant age of 1942 ± 11 Ma (the upper intersection of discordia with concordia). These zircons are strongly altered and anomalously enriched in U and Th. Zrn I grains are enriched relative to Zrn II in REE, Li, Ca, Sr, Ba, Hf, Th, and U. Zrn I is considered to be a product of melt crystallization or subsolidus recrystallization in the presence of melt. Zrn II is relict or crystallizing from melt and then partly fused again. Zrn I from charnockite gneiss and especially from charnockite are markedly altered and have a more discordant age than Zrn II. This is probably related to concentration of fluid in the residual melt left after zircon crystallization.  相似文献   

9.
The Proterozoic anorthosite–mangerite–charnockite complex dominating the Lindås Nappe in the Scandinavian Caledonides was locally eclogitized in the southwestern part of the nappe during the Caledonian orogeny, whereas only amphibolite facies assemblages are recorded in the rest of the nappe. Sveconorwegian granulites of anorthositic to jotunitic composition in the northernmost eclogite-free exposures of the nappe exhibit large garnet phenoblasts (ca. 900°C) that are fractured and partly replaced by a Caledonian symplectitic amphibolite facies assemblage (ca. 515°C). Metamorphic zircon attributed to this garnet breakdown is dated by ID-TIMS U–Pb at 430 ± 3 Ma, suggesting that the amphibolite facies overprint was coeval with the formation of eclogite 30 km further south, probably implying that the section across the nappe represents a Caledonian pressure gradient. The rocks also preserve a complex Sveconorwegian history including an age of 969 ± 6 Ma, which we interpret as dating magmatic emplacement of jotunitic–anorthositic portions of the complex, 936 ± 12 Ma reflecting the granulite facies metamorphism, and 908 ± 16 Ma, representing a late generation of zircon best explained as having formed by metasomatic processes. Caledonian shearing severely deformed zircon grains in an amphibolite facies shear zone, resetting their U–Pb systems, and forming new ones, hereby also demonstrating a case of resetting and recrystallization of low-U zircon. Our data, gained from diverse lithologies, illustrate several processes involved in making and resetting zircon as well as indicate the contemporaneous evolution and similar origin of the Lindås Nappe and the Jotun Nappe Complex.  相似文献   

10.
Dehydration and anatexis of ultrahigh‐pressure (UHP) metamorphic rocks during continental collision are two key processes that have great bearing on the physicochemical properties of deeply subducted continental crust at mantle depths. Determining the time and P–T conditions at which such events take place is needed to understand subduction‐zone tectonism. A combined petrological and zirconological study of UHP metagranite from the Sulu orogen reveals differential behaviours of dehydration and anatexis between two samples from the same UHP slice. The zircon mantle domains in one sample record eclogite facies dehydration metamorphism at 236 ± 5 Ma during subduction, exhibiting low REE contents, steep MREE–HREE patterns without negative Eu anomalies, low Th, Nb and Ta contents, low temperatures of 651–750 °C and inclusions of quartz, apatite and jadeite. A second mantle domain records high‐T anatexis at 223 ± 3 Ma during exhumation, showing high REE contents, steeper MREE–HREE patterns with marked negative Eu anomalies, high Hf, Nb, Ta, Th and U contents, high temperatures of 698–879 °C and multiphase solid inclusions of albite + muscovite + quartz. In contrast, in a second sample, one zircon mantle domain records limited hydration anatexis at 237 ± 3 Ma during subduction, exhibiting high REE contents, steep MREE–HREE patterns with marked negative Eu anomalies, high Hf, Nb, Ta, Th and U contents, medium temperatures of 601–717 °C and multiphase solid inclusions of albite + muscovite + hydrohalite. A second mantle domain in this sample records a low‐T dehydration metamorphism throughout the whole continental collision in the Triassic, showing low REE contents, steep MREE–HREE patterns with weakly negative Eu anomalies, low Th, Nb and Ta contents, low temperatures of 524–669 °C and anhydrite + gas inclusions. Garnet, phengite and allanite/epidote in these two samples also exhibit different variations in texture and major‐trace element compositions, in accordance with the zircon records. The distinct P–T–t paths for these two samples suggest separate processes of dehydration and anatexis, which are ascribed to the different geothermal gradients at different positions inside the same crustal slice during continental subduction‐zone metamorphism. Therefore, the subducting continental crust underwent variable extents of dehydration and anatexis in response to the change in subduction‐zone P–T conditions.  相似文献   

11.
《Gondwana Research》2009,15(4):663-674
The presence of 1.52–1.50 Ga charnockites from the anorthosite–mangerite–charnockite–granite (AMCG) Mazury complex in southern Lithuania and NE Poland, in the western East European Craton (EEC) is revealed by secondary ion mass-spectrometry (SIMS) and EPMA geochronology. Early 1.85–1.82 Ga charnockites are related to major orogeny in the region whereas the newly studied charnockites intrude the already consolidated crust. The 1.52–1.50 Ga charnockite magmatism (SIMS data on zircon) was followed by high-grade metamorphism (EPMA data on monazite), which strongly affected the surrounding rocks. The 1.85–1.81 Ga zircon cores in Lazdijai and 1.81 Ga monazite domains in the Lanowicze charnockites represent the protolith age of a volcanic island arc. The 1.52–1.50 Ga charnockite magmatism and metamorphism are likely related to the distal, Danopolonian, orogeny further to the west, at the margin of Baltica. The c.1.52–1.50 Ga AMCG magmatism and metamorphism in the western EEC as well as the paired accretionary-rapakivi suites in Amazonia, may be the inboard manifestations of the same early Mesoproterozoic orogeny associated with the juxtaposition of Amazonia and Baltica during the amalgamation of the supercontinent Columbia.  相似文献   

12.
The quarry at Kottavattom in the Trivandrum Block of southern India contains spectacular examples of fluid-assisted alteration of high-grade metamorphic rocks. Garnet-biotite gneiss has undergone a change in mineral assemblage to form submetre scale orthopyroxene-bearing patches, later retrogressed to form an amphibole-bearing lithology. These patches, often referred to as arrested or incipient charnockite, crosscut the original metamorphic foliation and are typically attributed to passage of a low aH2O fluid through the rock. Whilst this conversion is recognised as a late stage process, little detailed chronological work exists to link it temporally to metamorphism in the region. Zircon and monazite analysed from Kottavattom not only record metamorphism in the Trivandrum Block but also show internal, lobate textures crosscutting the original zoning, consistent with fluid-aided coupled dissolution-reprecipitation during formation of the orthopyroxene-bearing patches. High-grade metamorphism at the quarry occurred between the formation of metamorphic monazite at ~585 Ma and the growth of metamorphic zircon at ~523 Ma. The fluid-assisted alteration of the garnet-biotite gneiss is poorly recorded by altered zircon with only minimal resetting of the U–Pb system, whereas monazite has in some cases undergone complete U–Pb resetting and records an age for fluid infiltration at ~495 Ma. The fluid event therefore places the formation of the altered patches at least 25 Myr after the zircon crystallisation in the garnet-biotite gneiss. The most likely fluid composition causing the modification and U–Pb resetting of zircon and monazite is locally derived hypersaline brine.  相似文献   

13.
Laser ablation inductively coupled plasma mass spectrometry analyses of U–Pb isotopes and trace elements in zircon and titanite were carried out on epoxy mounts and thin sections for ultrahigh‐pressure (UHP) eclogite in association with paragneiss in the Dabie orogen. The results provide a direct link between metamorphic ages and temperatures during continental subduction‐zone metamorphism. Zircon U–Pb dating gives two groups of concordant ages at 242 ± 2 to 239 ± 5 Ma and 226 ± 2 to 224 ± 6 Ma, respectively. The Triassic zircon U–Pb ages are characterized by flat heavy rare earth element (HREE) patterns typical of metamorphic growth. Ti‐in‐zircon thermometry for the two generations of metamorphic zircon yields temperatures of 697 ± 27 to 721 ± 8 °C and 742 ± 19 to 778 ± 34 °C, respectively. We interpret that the first episode of zircon growth took place during subduction prior to the onset of UHP metamorphism, whereas the second episode in the stage of exhumation from UHP to HP eclogite facies regime. Thus, the continental subduction‐zone metamorphism of sedimentary protolith is temporally associated with two episodes of fluid activity, respectively, predating and postdating the UHP metamorphic phase. The significantly high Ti‐in‐zircon temperatures for the younger zircon at lower pressures indicate the initial ‘hot’ exhumation after the peak UHP metamorphism. There are two types of titanite. One exhibits light rare earth element (LREE) enrichment, steep MREE–HREE patterns and no Eu anomalies, and yields Zr‐in‐titanite temperatures of 551 to 605 °C at 0.5 GPa, and the other shows LREE depletion and flat MREE–HREE patterns, and gives Zr‐in‐titanite temperatures of 782–788 °C at 2.0 GPa. The former is amenable for U–Pb dating, yielding a discordia lower intercept age of 252 ± 3 Ma. Thus, the first type of titanite is interpreted to have grown in the absence of garnet and plagioclase and thus in the early stage of subduction. In contrast, the second one occurs as rims surrounding rutile cores and thus grew in the presence of garnet during the ‘hot’ exhumation. Therefore, there is multistage growth of zircon and titanite during the continental subduction‐zone metamorphism. The combined studies of chronometry and thermobarometry provide tight constraints on the P–T–t path of eclogites during the continental collision. It appears that the mid‐T/UHP eclogite facies zone would not only form by subduction of the continental crust in a P–T path slightly below the wet granite solidus, but also experience decompression heating during the initial exhumation.  相似文献   

14.
We present new zircon U–Pb and Hf isotopic as well as whole-rock geochemical data for volcanic rocks from the eastern margin of the Xing’an Massif, Northeast China, in order to further our understanding of the suture location between the Xing’an and Songnen–Zhangguangcai Range massifs. Zircon secondary ion mass spectrometry U–Pb dating indicates that the volcanic rocks formed during the Early–Middle Ordovician (473–463 Ma). Compared with the coeval Moguqi basalts (rare earth element [REE] = 171–183 ppm; εHf(t) = +0.3 to +2.7; TDM1 = 1074–977 Ma), the Duobaoshan andesites exhibit lower overall REE abundances (109–131 ppm) with relatively high heavy REE contents, stronger high-field-strength element depletion, higher εHf(t) values (+13.0 to +14.8), and much younger TDM1 ages (559–484 Ma). This suggests that the primary magma for the andesites was generated by the partial melting of a relatively depleted mantle wedge that was metasomatized by subduction-related fluids. The primary magma for the basalts in the Moguqi area was probably derived from the partial melting of a relatively enriched lithospheric mantle that was also modified by fluids sourced from a subducted slab. These interpretations suggest that the andesites in Duobaoshan formed in a newly accreted island arc setting, whereas the coeval basalts in Moguqi formed along an active continental margin. We therefore attribute the Early–Middle Ordovician volcanism along the eastern margin of the Xing’an Massif to the northwestward subduction of the Nenjiang–Heihe oceanic plate beneath the Xing’an Massif. Furthermore, considering coeval igneous activity in the southern parts of the Xing’an Massif, we suggest that a magmatic arc existed along the margin of the Xing’an Massif in the early Palaeozoic (490–420 Ma). We conclude that the location of the suture between the Xing’an and Songnen–Zhangguangcai Range massifs runs from Airgin Sum, via south of Xilinhot, to Ulanhot, Moguqi, Nenjiang, and finally Heihe.  相似文献   

15.
对北秦岭西段黄牛铺岩体进行了LA ICP MS锆石U Pb年代学与岩石地球化学分析。结果显示,黄牛铺岩体的锆石U Pb年龄为(4493±49) Ma,表明其形成时代为晚奥陶世。黄牛铺岩体属于准铝质高钾钙碱性系列,在成因类型上具有I型花岗岩的岩石矿物学与地球化学特征,其稀土元素配分曲线呈轻稀土元素富集、重稀土元素亏损(LREE/HREE=983~1155)、铕弱负异常(δEu=082~095)的右倾型,微量元素Rb、Th、U、Sm等富集,Ta、Nb、Ti、Hf等明显亏损,表现为岛弧岩浆岩的地球化学特征。结合区域地质资料,认为黄牛铺岩体形成于晚奥陶世商丹洋俯冲过程中的岛弧环境,是壳幔岩浆混合作用的产物,这为进一步研究北秦岭的构造演化过程提供了更加充分准确的岩浆活动证据。  相似文献   

16.
The Lakange porphyry Cu–Mo deposit within the Gangdese metallogenic belt of Tibet is located in the southern–central part of the eastern Lhasa block, in the Tibetan Tethyan tectonic domain. This deposit is one of the largest identified by a joint Qinghai–Tibetan Plateau geological survey project undertaken in recent years. Here, we present the results of the systematic logging of drillholes and provide new petrological, zircon U–Pb age, and molybdenite Re–Os age data for the deposit. The ore‐bearing porphyritic granodiorite contains elevated concentrations of silica and alkali elements but low concentrations of MgO and CaO. It is metaluminous to weakly peraluminous and has A/CNK values of 0.90–1.01. The samples contain low total REE concentrations and show light REE/heavy REE (LREE/HREE) ratios of 17.51–19.77 and (La/Yb)N values of 29.65–41.05. The intrusion is enriched in the large‐ion lithophile elements (LILE) and depleted in the HREE and high field‐strength elements (HFSE). The ore‐bearing porphyritic granodiorite yielded a Miocene zircon U–Pb crystallization age of 13.58 ± 0.42 Ma, whereas the mineralization within the Lakange deposit yielded Miocene molybdenite Re–Os ages of 13.20 ± 0.20 and 13.64 ± 0.21, with a weighted mean of 13.38 ± 0.15 Ma and an isochron age of 13.12 ± 0.44 Ma. This indicates that the crystallization and mineralization of the Lakange porphyry were contemporaneous. The ore‐bearing porphyritic granodiorite yielded zircon εHf(t) values between ?3.99 and 4.49 (mean, ?0.14) and two‐stage model ages between 1349 and 808 Myr (mean, 1103 Myr). The molybdenite within the deposit contains 343.6–835.7 ppm Re (mean, 557.8 ppm). These data indicate that the mineralized porphyritic granodiorite within the Lakange deposit is adakitic and formed from parental magmas derived mainly from juvenile crustal material that partly mixed with older continental crust during the evolution of the magmas. The Lakange porphyry Cu–Mo deposit and numerous associated porphyry–skarn deposits in the eastern Gangdese porphyry copper belt (17–13 Ma) formed in an extensional tectonic setting during the India–Asia continental collision.  相似文献   

17.
Integrated petrographic and chemical analysis of zircon, garnet and rutile from ultrahigh‐temperature (UHT) granulites in the Anápolis–Itauçu Complex, Brazil, is used to constrain the significance of zircon ID‐TIMS U–Pb geochronological data. Chondrite‐normalized rare earth element (REE) profiles of zircon cores have positive‐sloping heavy‐REE patterns, commonly inferred to be magmatic, whereas unambiguous metamorphic grains and overgrowths have flat to slightly negatively sloping heavy‐REE patterns. However, in one sample, a core of zircon interpreted as having formed prior to garnet crystallization and a metamorphic zircon formed within microstructures involving garnet breakdown both display elevated heavy‐REE (and Y) with positive‐sloping patterns. DREE(zrc/grt) partition coefficients suggest an approximation to equilibrium between zircon and garnet cores, although progressive enrichment in heavy REE towards garnet rims occurs in two of the samples investigated. Titanium‐in‐zircon thermometry indicates zircon growth during both the prograde and post‐peak evolution, but not at peak temperatures of the UHT metamorphism. By contrast, zirconium‐in‐rutile thermometry of inclusions armoured by garnet records crystallization temperatures, based on the upper end of the interquartile range of the data, of ～890 to 870 °C and maximum temperature around 980 °C, indicating prograde and retrograde growth close to and after peak conditions. Rutile located in retrograde microstructures records crystallization temperatures of 850 to 820 °C. Rutile intergrown with ilmenite and included within orthopyroxene, which is associated with exsolved zircon, records temperatures ～760 °C, consistent with Ti‐in‐zircon crystallization temperatures. ID‐TIMS U–Pb geochronological data from two of the four samples investigated define upper intercept ages of 641.3 ± 8.4 Ma (MSWD 0.91) and 638.8 ± 2.5 Ma (MSWD 1.03) that correlate with periods of zircon growth along the prograde segment of the P–T path. Individual zircon U–Pb dates retrieved from all samples range from 649 to 634 Ma, indicating a maximum duration of c. 15 Myr for the UHT event. This period is interpreted as recording modest thickening of hot backarc lithosphere located behind the Arenópolis Arc at the edge of the São Francisco Craton consequent upon terminal collision of the Parána Block with the arc during the amalgamation of West Gondwana.  相似文献   

18.
跃进山小型矽卡岩型铜金矿床位于完达山地体西南部,矿体主要赋存于矽卡岩、花岗斑岩及其构造裂隙中,呈扁豆状或脉状。本文对矿区花岗闪长岩和花岗斑岩进行锆石U-Pb年代学和岩石地球化学研究,以了解矿床形成时代、成岩（矿）构造背景及矿床成因。测年结果表明,花岗斑岩和花岗闪长岩成岩年龄分别为（115.8±1.0）Ma和（126.9±1.7）Ma,铜金矿化时代与花岗斑岩成岩时代基本一致,为早白垩世晚期。岩石地球化学研究表明,花岗闪长岩属过铝质钙碱性系列岩石,稀土配分模式图为轻稀土富集,重稀土亏损,具较强的铕负异常,无铈异常,岩浆主要来源于壳源物质;花岗斑岩属过铝质钙碱性系列岩石,轻稀土富集,重稀土亏损,具弱铕负异常,无铈异常,相对富集大离子亲石元素（Rb、Ba、K、Sr）和不相容元素（U、Th）,亏损高场强元素（Ta、Nb、P、Ti）和HREE,岩浆来源于壳幔物质混合源区,形成于碰撞后构造环境,成岩成矿作用与太平洋板块强烈俯冲作用后的伸展体制密切相关。  相似文献   

19.
The paper presents new U–Pb zircon ages and geochemical data from early Carboniferous volcanic rocks of the Wuerkashier Mountains in the northern West Junggar region, NW China, and of the Char suture–shear zone in East Kazakhstan. The study included analysis of geological setting, major and trace elements, and rock petrogenesis. Both localities host early Carboniferous volcanic units dominated by plagioclase-porphyry andesites and dacites. A West Junggar dacite yielded a 206Pb/238U age of 331 ± 3 Ma. The Junggar volcanic rocks are tholeiitic, and the Char samples are intermediate between tholeiitic and calc-alkaline. Both the Junggar and Char volcanic units are characterized by LREE enriched rare-earth spectra (La/Smn = 1.1–2.4) with Eu negative anomalies (Eu/Eu* = 0.12–1.0) and Nb-Ta minimums (Nb/Thpm = 0.15–0.35; Nb/Lapm = 0.3–0.7) on multi-element spectra. The Junggar andesites and dacites have higher REE and HFSE (Ti, Nb, Zr, Y, and Th) compared with the Char rocks, suggesting their derivation from a different mantle source. The melting modelling in the Nb-Yb system showed that the Junggar volcanic rocks formed by low- to medium- (2–5%) degree melting of depleted mantle harzburgite and spinel lherzolite. The Char volcanic rocks formed by high-degree melting (15–20%) of spinel lherzolite and garnet-bearing peridotite. The regional geology of West Junggar and East Kazakhstan and the geochemical features of the rocks under study (i.e. depletion in Nb, Ta, and Ti and enrichment in Th, and combination of LREE enrichment and HFSE depletion) all suggest a subduction-related origin of both Junggar and Char volcanic rocks. The early Carboniferous volcanic rocks of West Junggar possibly formed by subduction of the Junggar-Balkhash ocean beneath an active margin of the Kazakhstan continent, whereas those of East Kazakhstan formed by subduction of the Irtysh-Zaisan Ocean beneath an intra-oceanic arc at the active margin of the Siberian continent.  相似文献   

20.
We present results of study of mineral assemblages and PT-conditions of metamorphism of mafic garnet–two-pyroxene and two-pyroxene granulites in the Early Precambrian metamorphic complex of the Angara–Kan terrane as well as the U–Pb age and trace-element and Lu–Hf isotope compositions of zircon from these rocks and the zircon/garnet REE distribution coefficients. The temperatures of metamorphism of two-pyroxene granulites are estimated as 800–870 to ~ 900 °C. Mafic garnet–two-pyroxene granulites contain garnet coronas formed at 750–860 °C and 8–9.5 kbar. The formation of the garnet coronas proceeded probably at the retrograde stage during cooling and was controlled by the rock composition. The age (1.92–1.94 Ga) of zircon cores, which retain the REE pattern typical of magmatic zircon, can be taken as the minimum age of protolith for the mafic granulites. The metamorphic zircon generation in the mafic granulites is represented by multifaceted or soccerball crystals and rims depleted in Y, MREE, and HREE compared to the cores. The age of metamorphic zircon in the garnet–two-pyroxene (~ 1.77 Ga) and two-pyroxene granulites (~ 1.85 and 1.78 Ga) indicates two episodes of high-temperature metamorphism. The presence of one generation (1.77 Ga) of metamorphic zircon in the garnet–two-pyroxene granulites and, on the contrary, the predominance of 1.85 Ga zircon in the two-pyroxene granulites with single garnet grains suggest that the formation of the garnet coronas proceeded at the second stage of metamorphism. The agreement between the zircon/garnet HREE distribution coefficients and the experimentally determined values at 800 °C suggests the simultaneous formation of ~ 1.77 Ga metamorphic zircon and garnet. Zircon formation by dissolution/reprecipitation or recrystallization in a closed system without exchange with the rock matrix is confirmed by the close ranges of 176Hf/177Hf values for the core and rims. The positive εHf values (up to + 6.2) for the zircon cores suggest that the protolith of mafic granulites are derived from depleted-mantle source. The first stage of metamorphism of the mafic granulites and paragneisses of the Kan complex (1.85–1.89 Ga) ended with the formation of collisional granitoids (1.84 Ga). The second stage (~ 1.77 Ga) corresponds to the intrusion of the second phase of subalkalic leucogranites of the Taraka pluton and charnockites (1.73–1.75 Ga).  相似文献   

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