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1.
松辽盆地白垩系砂岩长石碎屑的钠长石化作用   总被引:12,自引:0,他引:12  
松辽盆地白垩系砂岩以长石岩屑砂岩和岩屑长石砂岩为特征。砂岩中发育长石碎屑、岩屑等不稳定组分,而且随着埋藏深度加深(成岩作用加强)钾长石逐渐减少并最终在2700m以下消失。斜长石碎屑中钠长石组分逐渐增多,钙长石组分逐渐减少,最终形成纯钠端元的钠长石。在成岩过程中长石碎屑的钠长石化主要有3种方式:①由离子交代作用导致长石碎屑的钠长石化;②长石碎屑边缘钠长石次生生长;③与长石碎屑溶解伴生的新生钠长石作用。结合热动力学平衡原理分析,斜长石的钠长石化基本不受成岩温度和压力的制约,而钾长石的钠长石化需要较高的成岩温度和压力作用才能进行。因此,斜长石的钠长石化可见于成岩早期,而钾长石的钠长石化只发生于成岩晚期。  相似文献   

2.
不同温度条件下乙酸对长石溶蚀过程的实验研究   总被引:25,自引:3,他引:25  
本文报道了不同埋藏温压条件下乙酸对条纹长石溶蚀过程的实验研究。结果证明:1)在条纹长石溶蚀过程中,K、Na、Al优先释放,Si是最后释放的元素。2)在相对低温的条件下,长石溶出主要元素的比例远远偏离其化学组成,在相对高温的条件下,则接近其化学组成。3)在条纹长石中.钠长石比钾长石更容易分解。4)温度升高对条纹长石中Si的影响最大,其温度效应分别是K、Al、Na的9.2,8.6和5.4倍。5)不同温度区间Si,Al的温度效应存在显著的差别,Al主要在小于95℃区间释放,而Si主要在大于95℃区间释放,此时将有约2/3的Si不能加入到高岭石中。因而在埋藏成岩过程中,自生SiO矿物沉淀造成的孔隙封堵作用主要发生在地温大于95℃的埋深中。6)相对高温高压的实验中获得了蛋白石等自生SiO矿物的沉淀,进一步证明Si主要是在高温区间释放的。  相似文献   

3.
混合表面活性剂存在下锰的高灵敏显色反应研究   总被引:2,自引:0,他引:2  
尹家元  杨光宇 《岩矿测试》1998,17(4):282-284
研究了碱性介质中,Mn(Ⅱ)被空气氧化生成H2MnO3,然后在H3PO4介质中,Cu(Ⅱ)和阳离子型有机相/水相微乳液(CTMAB/戊醇/正庚烷/水)的存在下,Mn(Ⅳ)与二安替比林对乙氧基苯基甲烷(DApEM)生成橙色产物,λmax为450nm,ε=1.95×105L·mol-1·cm-1。Mn(Ⅱ)的质量浓度在0~320μg/L内符合比尔定律。方法用于合金中锰的测定,结果与标准值符合,5次测定结果的RSD<3%。  相似文献   

4.
二安替比林邻乙氧基苯基甲烷与钒的高灵敏显色反应研究   总被引:7,自引:1,他引:6  
林会松  杨光宇 《岩矿测试》1998,17(3):190-192196
合成了新试剂二安替比林邻乙氧基苯基甲烷(DAoEM),研究了它和V(Ⅴ)的显色反应。在H3PO4介质中,Mn(Ⅱ)和吐温20协同作用下,DAoEM和V(Ⅴ)生成橙色产物,λmax=480nm,ε=1.4×106L·mol-1·cm-1,V(Ⅴ)质量浓度在4~60μg/L符合比尔定律。用于钢样和中草药中V(Ⅴ)的测定,结果与原子吸收法结果一致,5次测定结果的RSD在1.8%~3.1%。  相似文献   

5.
江西岩背含锡斑岩主要造岩矿物标型特征   总被引:2,自引:0,他引:2  
江西会昌岩背J3-K1时期形成的火山穹窿由火山岩,次火山岩和侵入岩组成,大型斑岩型锡矿床赋存于含黄玉花岗斑岩与(次)流纹斑岩内外接触带上,成矿岩体花岗斑岩和花岗岩富Si富F,其钾长石均为Al/Si有序的低微斜长石,黑云母为含Li富F的铁叶云母或黑鳞云母,具低Mg/ΣFe(MF)值,所含岩浆晚期阶段结晶的黄玉,其成分接近于氟黄玉端元,并具有较短的b轴,不同于玻利维亚Sn-B型,本区为Sn-F型,这是  相似文献   

6.
江西雅山花岗岩长石中磷的分布及意义   总被引:6,自引:0,他引:6  
刘昌实  黄小龙 《岩石学报》1999,15(2):291-297
雅山富氟高磷花岗岩具较高的全岩磷含量(0.15%~0.55%),长石是磷的主要赋存矿物,磷以PAlSi-2替换方式进入长石结构中。各种结晶习性的长石的磷含量各不相同。早世代钠长石和雪球结构中钠长石包裹体的结晶较早,平均磷含量分别为0.18%和0.19%,而晚世代钠长石和环带钾长石中钠长石嵌晶的结晶稍晚,具较高的平均磷含量(分别为0.25%和0.23%)。钾长石的磷含量相对于钠长石总体上较低,早期结晶的雪球结构主晶钾长石和环带钾长石的磷含量最低,分别为0.04%和0.02%,晚期细粒钾长石的平均磷含量略高(0.19%)。长石对全岩磷的贡献率还与磷锂铝石等磷酸盐副矿物是否达到饱和有关,当无磷锂铝石结晶时,长石磷的贡献率约为76%,反之则约为31%。  相似文献   

7.
秦岭造山带二台子铜金矿床矿物地球化学研究   总被引:8,自引:3,他引:5  
通过矿物地示化学研究,认为陕西二台子铜金矿床属钠长石碳酸角砾岩型矿床,是大陆热点成矿系统中幔源碱性热流体成岩成矿作用多期叠架所形成。砷黝铜矿富Fe、As,低Sb、Ag;黄铁矿中富As、Se,白云石(内核)有显著的锰铁白云石(外部环带)增生环带;长石类矿物出现富Mg铁长石;这些特征是陕西二台子铜金矿床属钠长石碳酸角砾岩型矿床的典型矿物地球化学特征。矿物地球化学组合类型指标可判断不同矿化类型及分散矿化  相似文献   

8.
长石是一族矿物的名称,从组分说有四种:钾长石、钠长石、钙长石、和钡长石。长石族有三个亚族:钾钠长石亚族,又名正长石亚族,由于阳离子是K、Na故又名碱性长石亚族,斜长石亚族和钡长石亚族。钾长石与钠长石,高温时可以形成完全类质同象,低温是不完全类质同象,它们的类质同象称碱性长石系列;钠长石和钙长石也可以形成类质同象,称斜长石系列,通常仍不正确  相似文献   

9.
李素芝  熊采华 《岩矿测试》2000,19(3):205-208
拟定了电感耦合等离子体原子发射光谱(ICP-AES)测定铅锑合金中As、Bi、Ca、Cd、Co、Fe、Mn、Se和Zn等九个元素的分析方法,考察了Pb、Sb基体对待测元素的干扰情况。样品以HNO3分解,酒石酸抑制Sb水解,ICP-AES同时测定多元素。方法对各元素的测定限在0.07~5.2μg/g,相对标准偏差(n=8)为0.78%~25.5%,加标回收率均大于86%,经与原子吸收光谱法和原子荧光  相似文献   

10.
热液体系中Si的络合作用   总被引:1,自引:0,他引:1  
在不同温度、PH和硅浓度条件下,实验标定了Au-SiO以及Sn-SiO2之间的络合反应:Au^++H3SiO4^-之间的络合反应:Au^++H4SiO=AuH3SiO4 lgK=-1.65436+9611.21/T;Sn^4++4H3SiO4^-=Sn(H3SiO4)4;lgK200c=42.73。通过与Au-Cl、Au-HS以及Sn-OH络合物迁移能力的比较,表明在具地质意义的P睡EH条件下,A  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

15.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

17.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

18.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

19.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

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