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1.
Close to 30 deuterated molecules have now been detected in the ISM, including doubly-deuterated species D2H+, ND2H, D2CO, CHD2OH, D2S, and D2CS, as well as triply-deuterated ammonia and methanol. We review the current understanding of depletion and deuteration processes in cold, dense interstellar medium (ISM) and discuss the utility of deuteroammonia as a tracer of the physical conditions and kinematics of cold, dense gas.  相似文献   

2.
给出并解释了星际介质中轻元素D，3He，4He和Li的最新观测数据．星际介质中轻元素的丰度观测结果可以用来检验标准大爆炸核合成理论，因此对这些元素的丰度研究具有重要的天体物理意义．到目前为止，轻元素丰度的观测结果基本上支持开放宇宙的观点．根据最新的观测结果，在本地星际介质中D丰度可能存在小尺度不均匀性，而对类星体吸收云的观测表明不同观测者所获得的原初D丰度结果最大差别可达一个量级．如果观测是可靠的，那么在目前的标准大爆炸核合成理论和星系化学演化模型框架下还不能解释这种结果．另外种种迹象表明太阳系丰度可能不代表45亿年前本地星际介质的丰度．  相似文献   

3.
The redshifted spectral line radiation emitted from both atomic fine-structure and molecular rotational transitions in the interstellar medium (ISM) of high-redshift galaxies can be detected in the centimetre, millimetre and submillimetre wavebands. Here we predict the counts of galaxies detectable in an array of molecular and atomic lines. This calculation requires a reasonable knowledge of both the surface density of these galaxies on the sky, and the physical conditions in their ISM. The surface density is constrained using the results of submillimetre-wave continuum surveys. Follow-up OVRO Millimeter Array observations of two of the galaxies detected in the dust continuum have provided direct measurements of CO rotational line emission at redshifts of 2.56 and 2.81. Based on these direct high-redshift observations and on models of the ISM that are constrained by observations of low-redshift ultraluminous infrared galaxies, we predict the surface density of line-emitting galaxies as a function of line flux density and observing frequency. We incorporate the sensitivities and mapping speeds of existing and future millimetre/submillimetre-wave telescopes and spectrographs, and so assess the prospects for blank-field surveys to detect this line emission from gas-rich high-redshift galaxies.  相似文献   

4.
We present isophot spectrophotometry of three positions within the isolated high-latitude cirrus cloud G 300.2−16.8, spanning from the near- to far-infrared (NIR to FIR). The positions exhibit contrasting emission spectrum contributions from the unidentified infrared bands (UIBs), very small grains (VSGs) and large classical grains, and both semi-empirical and numerical models are presented. At all three positions, the UIB spectrum shapes are found to be similar and the large grain emission may be fitted by an equilibrium temperature of  ∼17.5 K  . The energy requirements of both the observed emission spectrum and optical scattered light are shown to be satisfied by the incident local interstellar radiation field (ISRF). The FIR emissivity of dust in G 300.2−16.8 is found to be lower than in globules or dense clouds and is even lower than model predictions for dust in the diffuse interstellar medium (ISM). The results suggest physical differences in the ISM mixtures between positions within the cloud, possibly arising from grain coagulation processes.  相似文献   

5.
Theoretical predictions by Farebrother et al. and Meijer et al. of rovibrational excitation probabilities in H2 arising from formation by Eley-Rideal processes on a graphite surface are incorporated into a model of the chemistry and excitation of interstellar H2. The model includes the usual radiative and collisional pumping of H2 rotational and vibrational states, in addition to the formation processes. Predictions are made for HH2 rovibrational emission line intensities for representative points in diffuse and in dark interstellar clouds. We find that – if all the interstellar HH2 is formed by this Eley-Rideal process – then the consequences of formation pumping, as distinct from collisional and radiative pumping, should be clearly evident in both cases. In particular, we predict a clear spectral signature of this direct HH2 formation process on graphite, distinct from radiative and collisional pumping; this signature should be evident in both diffuse and dark clouds; but the emissivity for dark clouds is predicted to be some 500 times greater than that in diffuse clouds in which the dense material may be embedded. An observational search for this signature in two dark cloud sources was made, but a preliminary analysis of the data did not yield a detection. The implications of and possible reasons for this preliminary conclusion are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

6.
Transient microstructure in the diffuse interstellar medium (ISM) has been observed towards Galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a molecular component to the transient microstructure. In this paper, we explore the chemistry that may arise in such microstructure. We use a photodissociation region (PDR) code to model the conditions of relatively high density, low temperature, very low visual extinction and very short elapsed time that are appropriate for these objects. We find that there is a well-defined region of parameter space where detectable abundances of molecular species might be found. The best matching models are those where the interstellar microstructure is young (<100 yr), small (∼100 au) and dense  (>104 cm−3)  .  相似文献   

7.
The effects of the production on dust grain surfaces of molecular hydrogen in excited states have been investigated. On the assumption that all of the H2 formed on the surface of grains has a sufficient level of excitation too vercome the energy barriers in the formation reactions for the important OH and CH+ radicals, we consider the likely abundances of excited H2 (H2 *), OH and CH+ in various situations. Two different models are employed; the first links the H2 * abundance directly to that of H2 using a steady-state approximation, whilst the second considers the time-dependence of H2 *. The second model is applied to gas that has been subjected to a strong isothermal shock (specifically, the shock-induced collapse of a diffuse cloud), which results in an extreme (high density, high atomic hydrogen abundance) environment. In general, it is found that the presence of the excited H2 has only marginal effects on the chemistry of interstellar clouds. However, in the isothermal shock model, the abundances of CH+ are significantly enhanced, but only on short timescales, whilst the effects on the OH abundances are smaller, but last longer. We conclude that other than in such exceptional environments there are no obvious chemical signatures of the formation of H2 *. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

8.
Charge‐transfer is the main process linking neutrals and charged particles in the interaction regions of neutral (or partly ionized) gas with a plasma. In this paper we illustrate the importance of charge‐transfer with respect to the dynamics and the structure of neutral gas‐plasma interfaces. We consider the following phenomena: (1) the heliospheric interface ‐ region where the solar wind plasma interacts with the partly‐ionized local interstellar medium (LISM) and (2) neutral interstellar clouds embedded in a hot, tenuous plasma such as the million degree gas that fills the so‐called “Local Bubble”. In (1), we discuss several effects in the outer heliosphere caused by charge exchange of interstellar neutral atoms and plasma protons. In (2) we describe the role of charge exchange in the formation of a transition region between the cloud and the surrounding plasma based on a two‐component model of the cloud‐plasma interaction. In the model the cloud consists of relatively cold and dense atomic hydrogen gas, surrounded by hot, low density, fully ionized plasma. We discuss the structure of the cloud‐plasma interface and the effect of charge exchange on the lifetime of interstellar clouds. Charge transfer between neutral atoms and minor ions in the plasma produces X‐ray emission. Assuming standard abundances of minor ions in the hot gas surrounding the cold interstellar cloud, we estimate the X‐ray emissivity consecutive to the charge transfer reactions. Our model shows that the charge‐transfer X‐ray emission from the neutral cloud‐plasma interface may be comparable to the diffuse thermal X‐ray emission from the million degree gas cavity itself (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

9.
A full radiative transfer model is presented for the ultraviolet (UV) radiation impinging on an interstellar cloud of spherical or finite plane-parallel slab geometry containing gas and dust. The penetration of the UV photons is coupled to detailed chemical processes. Photodestruction rates of atomic and molecular species are calculated from the corresponding cross-sections. We show that CO line intensities are quite sensitive to geometrical effects and to the extinction curve in the far-UV.  相似文献   

10.
The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 106–7 yr). The abundances of those surface species, such as H2O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH3OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1.  相似文献   

11.
We have constructed a chemical reaction model in a contracting interstellar cloud including 104 species which are involved in a network of 557 reactions. The chemical kinetic equations were integrated as a function of time by using gear package. The evolution of the system was followed in the density range 10–107 particles cm-3.The calculated fractional abundances of the charged species are in good agreement with those given by other investigators. The charge density has been followed in diffuse, intermediate and dense regions. The most dominant ionic species are metallic ions, HCO+ and H 3 + in the shielded regions and atomic ions H+, C+, Si+, He+, S+ and metal ions in the diffuse and intermediate regions. The abundances of negatively charged ions were found to be negligible. The results of the calculations on the different metallic ions are interpreted.  相似文献   

12.
The pure rotational spectrum of homonuclear diatomic molecules in the interstellar medium is strongly forbidden, and no such spectrum has been detected. In regions of high excitation, vibrational emission may occur, as is widely detected in the case of H2 in interstellar shocks and photon-dominated regions. However, it is of considerable interest to know the abundance of homonuclear diatomics in quiescent regions. We propose that vibrational emission from homonuclear diatomic molecules in cold clouds may be detectable, where the excitation is mainly through collisions with non-thermal electrons arising from the cosmic-ray ionization of H2. As an example, we estimate the intensity of emission from N2 in cold, dark interstellar clouds. We show that such emission is at the limit of detectability with current technology. Other excitation mechanisms may also contribute and enhance this emission.  相似文献   

13.
Hadronic cosmic rays of energies below about 100 MeV nucleon–1 are thought to be an important component of the Galactic ecosystem. However, since these particles cannot be detected near Earth due to the solar modulation effect, their composition and flux in the interstellar medium are very uncertain. Atomic interactions of low‐energy cosmic rays with interstellar gas can produce a characteristic nonthermal X‐ray emission comprising very broad lines from de‐excitations in fast ions following charge exchange. We suggest that broad lines at ∼0.57 and ∼0.65 keV could be detected from a dark molecular cloud in the local interstellar medium. These lines would be produced by fast oxygen ions of kinetic energies around 1 MeV nucleon–1 (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

14.
The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH2→HNC+H, and N+CH2→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.  相似文献   

15.
We have computed cross-sections and rate coefficients for rovibrational transitions in HD, induced by collisions with atomic and molecular hydrogen. We employed fully quantum-mechanical methods and the potential of Boothroyd et al. for H–HD, and that of Schwenke for H2–HD. The rate coefficients for vibrational relaxation v =1→0 of HD are compared with the corresponding values for H2. The influence of vibrationally excited channels on the rate coefficients for rotational transitions within the v =0 vibrational ground state of HD is shown to be small at T =500 K, where T is the kinetic temperature. The rate coefficients, for 100 T 2000 K, are available from http://ccp7.dur.ac.uk/.  相似文献   

16.
We have computed the time dependence of the H2 rovibrational emission spectrum from molecular outflows. This emission arises in shock waves generated by the impact of jets, associated with low-mass star formation, on molecular gas. The shocks are unlikely to have attained a state of equilibrium, and so their structure will exhibit both C- and J-type characteristics. The rotational excitation diagram is found to provide a measure of the age of the shock; in the case of the outflow observed in Cepheus A West by the ISO satellite, the shock age is found to be approximately 1.5×103 yr. Emission by other species, such as NH3 and SiO, is also considered, as are the intensities of the fine-structure transitions of atoms and ions.  相似文献   

17.
The evolution of the interstellar medium (ISM) is driven by a variety of phenomena, including turbulence, shearing flows, magnetic fields and the thermal properties of the gas. Among the most important forces at work is self-gravity, which ultimately drives protostellar collapse. As part of an ongoing study of instabilities in the ISM, Hunter, Whitaker & Lovelace have discovered another process driven by self-gravity: the instability of an interface of discontinuous density. Theory predicts that this self-gravity driven interfacial instability persists in the static limit and in the absence of a constant background acceleration. Disturbances to a density interface are found to grow on a time-scale of the order of the free-fall time, even when the perturbation wavelength is much less than the Jeans length. Here we present the first numerical simulations of this instability. The theoretical growth rate is confirmed and the non-linear morphology displayed. The self-gravity interfacial instability is shown to be fundamentally different from the Rayleigh–Taylor instability, although both exhibit similar morphologies under the condition of a high density contrast, such as is commonly found in the ISM. Such instabilities are a possible mechanism by which observed features, such as the pillars of gas seen near the boundaries of interstellar clouds, are formed.  相似文献   

18.
The effects of the hyperfine structure (HFS) that is present in some interstellar absorption lines are investigated in the case of a single absorbing cloud. If the respective total equivalent widths of two or more unresolved HFS multiplets measured in relatively low-resolution spectra are analysed specifically by means of a curve of growth, the column density N (X) and the linewidth parameter b (X) inferred for absorbing species X in the cloud will generally be in error if the HFS is ignored. The fundamental physical effect is the reduced line saturation that arises because the total column density is divided among the HFS levels of the ground atomic level, each of which generally gives rise to an HFS line at a different wavelength. For nuclear spins   I = 3/2  and   I = 5/2  , theoretical curves of growth are calculated for some of the resonance lines of some alkali atoms, for each of four illustrative choices of the parameter  α=Δ/ b   , the ratio of the HFS splitting in the ground atomic level to the linewidth. Applications of the results to interstellar absorption by Na  i , K  i and Al  iii are emphasized. HFS is, fortunately, unimportant for most interstellar lines, however. Among the 35 elements that have been detected in diffuse clouds via interstellar absorption in the ultraviolet/optical spectral region, the most abundant isotope of each of 25 of these shows no HFS, because   I = 0  or, in the relevant ground atomic level,   J = 0  .  相似文献   

19.
We have computed optical absorption-line profiles of CH+ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C+(H2, H)CH+. Whilst CH+ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH+3(e−, H2)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH+ and CH line profiles is found to be no more than approximately 2 km s−1, which is smaller than has previously been assumed. We also investigate OH and HCO+, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.  相似文献   

20.
The molecular phase of the ISM constitutes the main source of fuel for the activity in starburst and AGNs. The physical conditions and chemical constitution of the molecular gas will change with, and respond to, the evolution of the activity. This paper includes a short discussion of the 12CO/13CO 1–0 line intensity ratio as a diagnostic tool of the molecular gas properties of luminous galaxies – paired with examples of high-resolution studies of how the line ratio varies within galaxies. A possible connection between the OH megamasers and galaxies with unusually high 12CO/13CO 1–0 line intensity ratios are also briefly discussed.The relative intensities of the dense gas tracers HNC, HCN, HCO+ and CN are a result of both chemistry and starburst evolution. The discussion on the interpretation of HNC 1–0 emission includes the importance of ion-neutral chemistry in a luminous starburst region. Finally, simple cartoon ISM models and how they can be applied to LIRGs and ULIRGs, are presented.  相似文献   

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