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1.
The uptake of water vapor on MgCl2×6H2O and NaCl salt dry solid films was studied over the temperature range 240 to 340 K and at 1 Torr pressure of helium using a flow reactor coupled to a modulated molecular beam mass spectrometer. The H2O to salt uptake data were obtained from the kinetics of H2O loss on salt coated Pyrex rods. The following Arrhenius expression was obtained for the initial uptake coefficient of H2O on MgCl2×6H2O films: γ 0 (MgCl2) = (6.5 ± 1.0) × 10−6 exp[(470 ± 40)/T] (calculated with specific BET surface area, quoted uncertainties are 1σ statistical). The rate of H2O adsorption on NaCl was found to be much lower than on MgCl2×6H2O, and only an upper limit was determined for the corresponding uptake coefficient: γ (NaCl) ≤ 5.6 × 10−6 at T = 300 K. The results show that the rate of H2O adsorption to salt surfaces is drastically dependent on the salt sample composition.  相似文献   

2.
Different flux estimation techniques are compared here in order to evaluate air–sea exchange measurement methods used on moving platforms. Techniques using power spectra and cospectra to estimate fluxes are presented and applied to measurements of wind speed and sensible heat, latent heat and CO2 fluxes. Momentum and scalar fluxes are calculated from the dissipation technique utilizing the inertial subrange of the power spectra and from estimation of the cospectral amplitude, and both flux estimates are compared to covariance derived fluxes. It is shown how even data having a poor signal-to-noise ratio can be used for flux estimations.  相似文献   

3.
The most direct method for flux estimation uses eddy covariance, which is also the most commonly used method for land-based measurements of surface fluxes. Moving platforms are frequently used to make measurements over the sea, in which case motion can disturb the measurements. An alternative method for flux estimation should be considered if the effects of platform motion cannot be properly corrected for. Three methods for estimating CO2 fluxes are studied here: the eddy-covariance, the inertial-dissipation, and the cospectral-peak methods. High-frequency measurements made at the land-based Östergarnsholm marine station in the Baltic Sea and measurements made from a ship during the Galathea 3 expedition are used. The Kolmogorov constant for CO2, used in the inertial-dissipation method, is estimated to be 0.68 and is determined using direct flux measurements made at the Östergarnsholm site. The cospectral-peak method, originally developed for neutral stratification, is modified to be applicable in all stratifications. With these modifications, the CO2 fluxes estimated using the three methods agree well. Using data from the Östergarnsholm site, the mean absolute error between the eddy-covariance and inertial-dissipation methods is 0.25 μmol  m?2 s?1. The corresponding mean absolute error between the eddy-covariance and cospectral-peak methods is 0.26 μmol m?2 s?1, while between the inertial-dissipation and cospectral-peak methods it is 0.14 μmol m?2 s?1.  相似文献   

4.
The interannual variations in the characteristics of the seasonal cycle (annual and seasonal amplitudes, winter emission, dates of annual minimum and maximum, and phase) and in the growth rate of atmospheric carbon dioxide concentration over Central Siberia are analyzed for the period from May 2009 to January 2016. The results are based on the continuous monitoring of CO2 concentration at the Zotino Tall Tower Observatory (ZOTTO, www.zottoproject.org). It is found that the seasonal amplitude of CO2 concentration in the atmo spheric surface layer over Western Siberia is 26.4 ± 0.8 μmol/mol (no long-term trend toward its increase was revealed), the annual mean growth rate of CO2 is 2.34 μmol/mol per year, its variations range from 1 to 4 μmol/mol per year.  相似文献   

5.
Although there is evidence that CO2-efficiency enhancing innovations in one country diffuse into other countries to contribute to the goals of climate change mitigation, very little is known about the conditions under which such international spillovers are most likely to take place. Our contribution in the present article seeks to address this gap by examining whether the strength of cross-border CO2-efficiency spatial dependence working through import ties and inward foreign direct investment (FDI) stocks is greater in (a) countries with lower existing levels of domestic CO2-efficiency and (b) countries with greater social capabilities in terms of a better educated workforce and higher institutional quality. We find that less CO2-efficient countries and countries with higher institutional quality experience stronger FDI-weighted CO2-efficiency spillovers, whereas a higher level of human capital increases receptivity to import-weighted international spillovers.  相似文献   

6.
Avoiding dangerous climate change will require a rapid transition away from fossil fuels. By some estimates, global consumption and production of fossil fuels—particularly coal and oil—will need to end almost entirely within 50 years. Given the scale of such a transition, nations may need to consider policies that constrain growth in fossil fuel supplies in addition to those that reduce demand. Here, we examine the emissions implications of a supply-constraining measure that was rapidly gaining momentum in the United States (US) under the Obama administration: ceasing the issuance of new leases for fossil fuel extraction on federal lands and waters. Such a measure could reduce global carbon dioxide emissions by an estimated 280 million tons annually by 2030, comparable to that of other major climate policies adopted or considered by the Obama administration. Our findings suggest that measures to constrain fossil fuel supply—though not currently viable in a US Trump administration—deserve further consideration at subnational levels in the US or by other countries now, and by future US administrations.  相似文献   

7.
The global mean surface temperature (GMST) response of HadCM3 to a 1,000 year 4×CO2 forcing is analysed using a transfer function methodology. We identify a third order transfer function as being an appropriate characterisation of the dynamic relationship between the radiative forcing input and GMST output of this Atmosphere-Ocean General Circulation Model (A-OGCM). From this transfer function the equilibrium climate sensitivity is estimated as 4.62 (3.92–11.88) K which is significantly higher than previously estimated for HadCM3. The response is also characterised by time constants of 4.5 (3.2–6.4), 140 (78–191) and 1,476 (564–11,737) years. The fact that the longest time constant element is significantly longer than the 1,000 year simulation run makes estimation of this element of the response problematic, highlighting the need for significantly longer model runs to express A-OGCM behaviour fully. The transfer function is interpreted in relation to a three box global energy balance model. It was found that this interpretation gave rise to three fractions of ocean heat capacity with effective depths of 63.0 (46.7–85.4), 1291.7 (787.3–2,955.3) and 2,358.0 (661.3–17,283.8) meters of seawater, associated with three discrete time constants of 4.6 (3.2–6.5), 107.7 (68.9–144.3) and 537.1 (196.2–1,243.1) years. Given this accounts for approximately 94% of the ocean heat capacity in HadCM3, it appears HadCM3 could be significantly more well mixed than previously thought when viewed on the millennial timescale.  相似文献   

8.
Several economic reviews demonstrate the substantial costs related to climate change and consequently call for early action. These reviews, however, have been limited to measuring ‘objective’ risks and expected material damage related to climate change. The ‘subjective’ perceived risk of climate change and society’s willingness to pay (WTP) to avoid these risks are expected to provide an important additional motivation for direct action. We investigate whether and why air travel passengers—an increasingly important source of greenhouse gas emissions—are supportive of measures that increase the cost of their travel based on the polluter pays principle and compensate the damage caused by their flight. Compared to the results of the few previous studies that have elicited WTP estimates for climate policy more generally, our results appear to be at the lower end of the scale, while a comparison to estimates of the social cost of carbon shows that the average WTP estimate in this study is close to the estimated marginal damage cost. Although significant differences are found between travellers from Europe, North America, Asia and the rest of the world, we show that there exists a substantial demand for climate change mitigation action. The positive risk premium over and above the expected property damage cost assessments should be accounted for more explicitly in economic reviews as it will add to the burden of proof of direct action. Measurements of passenger WTP will help policy makers to design effective financial instruments aimed at discouraging climate-unfriendly travel activities as well as to generate funds for the measures directed at climate change mitigation and adaptation. Based on stated WTP by travellers to offset their greenhouse gas emissions, funds in the order of magnitude of €23 billion could be generated annually to finance climate change mitigation activities.  相似文献   

9.
PM10 samples were collected to characterize the seasonal and annual trends of carbonaceous content in PM10 at an urban site of megacity Delhi, India from January 2010 to December 2017. Organic carbon (OC) and elemental carbon (EC) concentrations were quantified by thermal-optical transmission (TOT) method of PM10 samples collected at Delhi. The average concentrations of PM10, OC, EC and TCA (total carbonaceous aerosol) were 222?±?87 (range: 48.2–583.8 μg m?3), 25.6?±?14.0 (range: 4.2–82.5 μg m?3), 8.7?±?5.8 (range: 0.8–35.6 μg m?3) and 54.7?±?30.6 μg m?3 (range: 8.4–175.2 μg m?3), respectively during entire sampling period. The average secondary organic carbon (SOC) concentration ranged from 2.5–9.1 μg m?3 in PM10, accounting from 14 to 28% of total OC mass concentration of PM10. Significant seasonal variations were recorded in concentrations of PM10, OC, EC and TCA with maxima during winter and minima during monsoon seasons. In the present study, the positive linear trend between OC and EC were recorded during winter (R2?=?0.53), summer (R2?=?0.59) and monsoon (R2?=?0.78) seasons. This behaviour suggests the contribution of similar sources and common atmospheric processes in both the fractions. OC/EC weight ratio suggested that vehicular emissions, fossil fuel combustion and biomass burning could be the major sources of carbonaceous aerosols of PM10 at the megacity Delhi, India. Trajectory analysis indicates that the air mass approches to the sampling site is mainly from Indo Gangetic plain (IGP) region (Uttar Pradesh, Haryana and Punjab etc.), Thar desert, Afghanistan, Pakistan and surrounding areas.  相似文献   

10.
The paper presents the importance of the Nocturnal Boundary Layer in driving the diurnal variability of the atmospheric CO2 mixing ratio and the carbon isotope ratio at ground level from an urban station in India. Our observations are the first of their kind from this region. The atmospheric CO2 mixing ratio and the carbon isotopic ratio were measured for both the morning (05:30–07:30 IST) and afternoon time (16:00–18:00 IST) air samples at 5 m above ground level in Bangalore city, Karnataka State (12° 58′ N, 77° 38′ E, masl = 920 m) for a 10 day period during the winter of 2008. We observed a change of ~7% the in CO2 mixing ratio between the morning and afternoon time air samples. A stable isotope analysis of CO2 from morning samples showed a depletion in the carbon isotope ratio by ~2‰ compared to the afternoon samples. Along with the ground-based measurement of air samples, data of radiosonde measurements were also obtained from the Indian Meteorological Department to identify the vertical atmospheric structure at different time in a day. We proposed the presence or absence of the NBL as a controlling factor for the observed variability in the mixing ratio as well as its isotopic composition. Here we used the Keeling model approach to find out the carbon isotope ratio for the local sources. The local sources have further been characterized as anthropogenic and biological respiration (in %) using a two-component mixing model. We also used a vertical mixing model based on the concept of the mixing of isotopically depleted (carbon isotope) “polluted air” (PA) with isotopically enriched “free atmospheric air” (FA) above. Using this modeling approach, the contribution of FA at ground level is being estimated for both the morning and afternoon time air samples.  相似文献   

11.
An hourly quantification of inorganic water-soluble PM10 ions and corresponding trace gases was performed using the Monitor for AeRosols and Gases in ambient Air (MARGA) at the TROPOS research site in Melpitz, Germany. The data availability amounts to over 80% for the five-year measurement period from 2010 to 2014. Comparisons were performed for the evaluation of the MARGA, resulting in coefficients of determinations (slopes) of 0.91 (0.90) for the measurements against the SO2 gas monitor, 0.84 (0.88), 0.79 (1.39), 0.85 (1.20) for the ACSM NO3 ?, SO4 2? and NH4 + measurements, respectively, and 0.85 (0.65), 0.88 (0.68), 0.91 (0.83), 0.86 (0.82) for the filter measurements of Cl?, NO3 ?, SO4 2? and NH4 +, respectively. A HONO comparison with a batch denuder shows large scatter (R2 = 0.41). The MARGA HNO3 is underestimated compared to a batch and coated denuder with shorter inlets (slopes of 0.16 and 0.08, respectively). Less NH3 was observed in coated denuders for high ambient concentrations. Long-time measurements show clear daily and seasonal variabilities. Potential Source Contribution Function (PSCF) analysis indicates the emission area of particulate ions Cl?, NO3 ?, SO4 2?, NH4 +, K+ and gaseous SO2 to lie in eastern European countries, predominantly in wintertime. Coarse mode sea salt particles are transported from the North Sea to Melpitz. The particles at Melpitz are nearly neutralised with a mean molar ratio of 0.90 for the five-year study. A slight increase of the neutralization ratio over the last three years indicates a stronger decrease of the anthropogenically emitted NO3 ? and SO4 2? compared to NH4 +.  相似文献   

12.
A network of remote and in-situ sensors was deployed in a Paris suburb in order to evaluate the mesoscale evolution of the daily cycle of CO2 and related tracers in the atmospheric boundary layer (ABL) and its relation to ABL dynamics and nearby natural and anthropogenic sources and sinks. A 2-μm heterodyne Doppler differential absorption lidar, which combines measurements of, (1) structure of the atmosphere, (2) radial velocity, and (3) CO2 differential absorption was a particularly unique element of the observational array. We analyse the differences in the diurnal cycle of CO, CO2, lidar reflectivity (a proxy for aerosol content) and H2O using the lidar, airborne measurements in the free troposphere and ground-based measurements made at two sites located few kilometres apart. We demonstrate that vertical mixing dominates the early morning drawdown of CO and aerosol content trapped in the former nocturnal layer but not the H2O and CO2 mixing ratio variations. Surface fluxes, vertical mixing and advection all contribute to the ABL CO2 mixing ratio decrease during the morning transition, with the relative importance depending on the rate and timing of ABL rise. We also show evidence that when the ABL is stable, small-scale (0.1-km vertical and 1-km horizontal) gradients of CO2 and CO are large. The results illustrate the complexity of inferring surface fluxes of CO2 from atmospheric budgets in the stable boundary layer.  相似文献   

13.
“20110809”石家庄西部大暴雨分析   总被引：2，自引：0，他引：2       下载免费PDF全文
利用雷达、自动站和GPS可降水量等高时空分辨率加密观测资料,对石家庄一次局地大暴雨天气过程进行分析。结果表明：在高温高湿的大气环境下,弱切变线的西摆北伸是此次强对流天气过程出现的触发机制和预报难点,切变线位置是造成石家庄西部大暴雨的主要环流背景;强降水出现前大气水汽含量快速积累,GPS可降水量突升且存在着两个峰值,其中最大值刚好对应降水开始时间,次大值提前于降水出现时间16 h。强降水回波缘于主体回波、阵风锋以及新生回波的合并发展加强,CR、VIL和ET峰值分别达61 dBz、55 kg·m-2和17 km。在高温高湿的大气环境下,新生发展的回波、阵风锋、速度图上辐合、气旋或逆风区等都可以预示强对流天气发展。  相似文献   

14.
“20110730”辽宁大暴雨过程分析   总被引：2，自引：0，他引：2  
利用常规气象资料、卫星云图、雷达回波、自动气象站资料和NCEP(1°×1°)再分析资料,对2011年7月30日辽宁短时大暴雨过程进行分析。结果表明：暴雨期间500 hPa高空槽与850 hPa切变线形成前倾形势,前倾槽为大暴雨的产生提供了有利的不稳定条件。此次暴雨过程的中尺度分析表明,降水时空变率大;TBB等值线密集区和上冲云顶的位置对暴雨落区有较好的指示意义;强降水时雷达回波强度达到65 dBz,且有逆风区和正负速度对出现,中小尺度强对流特征明显;地面等温线密集带与地面切变线（或中尺度低压）的共同作用触发中尺度雨团,降水强度陡增。通过涡度方程诊断切变线形成动力机制得出,当正涡度变率发展加强时,切变线向正涡度变率大值区方向移动,产生辐合动力抬升条件;散度项对低层涡度变率的贡献最大,强辐合是低层切变线生成的动力机制之一。  相似文献   

15.
饱和湿大气Brunt-Väisälä频率及修正的相当位温   总被引：2，自引：0，他引：2  
《气象学报》2003,61(3):379-383
实际大气中受扰动的饱和气块发生凝结后,凝结水会部分脱离气块.以前研究饱和湿大气的Brunt-Väisälä频率(N2m)没有考虑凝结水的部分脱离,相当位温(θe)也忽略了饱和气块的混合比的作用.文中针对这些不足,在假设饱和空气中只存在气液转换条件下,推导出液态水部分脱离气块的、更符合实际情况的N2m表达式和修正的饱和湿大气θe表达式.新的N2m表达式增加了部分脱离气块的液态水的作用项,新的θe表达式中包含有饱和气块的混合比,并对有关的表达式分别作了讨论和比较.  相似文献   

16.
台风“达维”不对称结构特征分析   总被引：1，自引：0，他引：1  
利用地面加密观测资料、FY-2E卫星TBB和水汽图像资料、NCEP1°×1°再分析资料综合分析了2012 年第10 号台风“达维”的不对称结构特征及成因。结果表明：台风“达维”登陆后在云系结构、降水落区、高低层风场等都表现出不对称分布,其中暴雨主要分布在台风中心北到东北侧;通过FY-2E水汽图像分析清晰地揭示了这种不对称结构的演变,台风西侧干下沉暗区切断了西南侧水汽输送,使得台风中心西侧和南侧对流云系减弱消失,而东南侧一直存在一水汽羽伸入台风环流为其提供水汽和能量。同时,强高空辐散、弱垂直风切变以及明显的上升运动,有利于台风“达维”北到东北侧对流云系的发展维持,引发强降水;高空槽带来的冷空气侵入台风环流内部,破坏了它的暖心结构,使得台风“达维”在渤海海面填塞消失。  相似文献   

17.
农业作为响应气候变化最敏感的领域之一,未来作物产量可能受到深刻影响。量化气候变化冲击作物产量导致的最终经济影响,需要综合“气候变化—作物产量—经济影响”开展链式研究。文中采用系统回顾和Meta回归分析方法整合了55篇文献的667项研究结果,推导出我国七大地区主要作物（水稻、玉米、小麦）产量与地区内未来温度和降水变化的定量关系,并将其作为农业部门的损失量代入改进的多区域投入产出模型,量化七大地区内与地区间遭受的经济波及影响（ERE)。结果显示：(1)气候变化对我国作物产量的影响主要体现在温度升高上,每升温1℃减产2.6%~12.7%,东北和西北地区作物受升温影响最显著;(2) 气候变化导致的作物减产将对经济产生更严重的波及影响,GDP因作物减产每下降1%将额外产生17.8%的波及影响;(3) 21世纪末,若不考虑CO2肥效作用,作物减产导致的ERE将占GDP的-0.1%~13.6%（负值表示收益),最悲观情况下ERE与当前我国农业总产值相当（2012年为基准年);(4)不同地区受ERE影响程度的差异较大,因各区之间产业结构、贸易联系及经济发展程度存在差异,西南地区遭受本区及来自其他地区的ERE比华东地区高2.8~8.5倍。  相似文献   

18.
The yields of carbonyl-containing reaction products from the ozonolysis of α-pinene have been investigated using concentrations of ozone found in the indoor environment ([O3] ≤ 100 ppb). An impinger was used to collect gas-phase oxidation products in water, where the derivatization agent O-tert-butylhydroxylamine hydrochloride (TBOX) and gas chromatography-mass spectrometry were used to identify carbonyl-containing species. Seven carbonyl-containing products were observed. The yield of the primary product, pinonaldehyde was measured to be 76 %. Using cyclohexane as a hydroxyl radical (?OH) scavenger, the yield of pinonaldehyde decreased to 46 %, indicating the influence secondary OH radicals have on α-pinene ozonolysis products. Furthermore, the use of TBOX, a small molecular weight derivatization agent, allowed for the acquisition of the first mass spectral data of oxopinonaldehyde, a tricarbonyl reaction product of α-pinene ozonolysis. The techniques described herein allow for an effective method for the collection and identification of terpene oxidation products in the indoor environment.  相似文献   

19.
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20.
利用两步变分反演方法,研究2006年第4号台风“碧利斯”,对照单部雷达资料和两部雷达资料的反演结果。结果表明：利用单部雷达资料不能很好的反演出台风的风场结构特征,而两部雷达资料在第一步反演背景场时,可以看出台风的涡旋特征。通过检验发现,此次台风过程的水平切向风在最大风速半径内部与Rankine模型相近,外部与Chen 3模型接近。为了更有效地利用单部雷达的观测信息准确定位台风的移动路径,故在单部雷达资料第一步反演背景场时加入模型弱约束。反演结果表明,加入模型弱约束后,反演的背景风场就能看出台风的涡旋特征,通过第二步反演后与两部雷达资料结果相近;加模型弱约束的单部雷达反演结果与两部雷达反演结果间u、v分量的相关系数均在0.8或以上,2-7 km高度层u、v分量的均方根误差明显减小。  相似文献   

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