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1.
A magnetohydrodynamic model of a steady, transverse C-type shock in a dense molecular cloud is presented. A complete gas–grain chemical network is taken into account: the gas-phase chemistry, the adsorption of gas species on dust grains, various desorption mechanisms, the grain surface chemistry, the ion neutralization on dust grains, the sputtering of grain mantles. The population densities of energy levels of ions CI, CII and OI and molecules H2, CO, H2O are computed in parallel with the dynamical and chemical rate equations. The large velocity gradient approximation is used in the line radiative transfer calculations. The simulations consist of two steps: (i) modelling of the chemical and thermal evolution of a static molecular cloud and (ii) shock simulations. A comparison is made with the results of publicly available models of similar physical systems.The focus of the paper is on the chemical processing of gas material and ice mantles of dust grains by the shock. Sputtering of ice mantles takes place in the shock region close to the temperature peak of the neutral gas. At high shock speeds, molecules ejected from ice mantles are effectively destroyed in hot gas, and their survival time is low—of the order of dozens of years. After a passage of high-speed C-type shock, a zone of high abundance of atomic hydrogen appears in the cooling postshock gas that triggers formation of complex organic species such as methanol. It is shown that abundances of some complex organic molecules (COMs) in the postshock region can be much higher than in the preshock gas. These results are important for interpretation of observations of COMs in protostellar outflows.  相似文献   

2.
Ravit Helled  Morris Podolak 《Icarus》2008,195(2):863-870
We present a calculation of the sedimentation of grains in a giant gaseous protoplanet such as that resulting from a disk instability of the type envisioned by Boss [Boss, A.P., 1998. Earth Moon Planets 81, 19-26]. Boss [Boss, A.P., 1998. Earth Moon Planets 81, 19-26] has suggested that such protoplanets would form cores through the settling of small grains. We have tested this suggestion by following the sedimentation of small silicate grains as the protoplanet contracts and evolves. We find that during the course of the initial contraction of the protoplanet, which lasts some 4×105 years, even very small (>1 μm) silicate grains can sediment to create a core both for convective and non-convective envelopes, although the sedimentation time is substantially longer if the envelope is convective, and grains are allowed to be carried back up into the envelope by convection. Grains composed of organic material will mostly be evaporated before they get to the core region, while water ice grains will be completely evaporated. These results suggest that if giant planets are formed via the gravitational instability mechanism, a small heavy element core can be formed due to sedimentation of grains, but it will be composed almost entirely of refractory material. Including planetesimal capture, we find core masses between 1 and 10 M⊕, and a total high-Z enhancement of ∼40 M⊕. The refractories in the envelope will be mostly water vapor and organic residuals.  相似文献   

3.
The question of grain mantle composition in dense clouds is examined in the light of new observational and theoretical results on atomic and molecular concentrations in the gas phase. It is shown that if grain temperatures are less than about 20K these mantles will be primarily solid CO. Methods of identifying CO coated grains are discussed.  相似文献   

4.
Summary The presence of solid carbon monoxide (CO) on interstellar grains was confirmed observationally in 1984 with the detection of infrared absorption at 4.67m wavelength in several molecular clouds. Subsequent observations suggest that solid CO is ubiquitous in the quiescent molecular cloud environment. In some lines of sight, the degree of frosting on to grains is sufficient to reduce appreciably the abundance of CO remaining in the gas, a result of considerable astrophysical significance: in addition to its importance as a tracer of molecular material, CO is vital to the production of many polyatomic molecules by gas phase reaction schemes, and its depletion could have a dramatic effect on the abundances of more complex carbon-bearing molecules. The infrared spectrum of solid CO provides an important diagnostic of the chemical composition and thermal evolution of grain mantles, leading to the prediction that CO2 is also present in solid form.As it is now some six years since observations of interstellar solid CO were first reported, this is an appropriate time to review the topic and to suggest some directions for future research. The introduction (Sect. 1) attempts to place the subject in its broader astrophysical context. The infrared observations and their implications are discussed in detail in Sect. 2. The question of the degree of CO depletion implied by the observations of both solid state and gas phase CO is re-examined in Sect. 3. We assess the possibility of CO detection by means of solid state absorption or luminescence in the ultraviolet in Sect. 4. Future prospects are summarised in the final section.This article was processed by the author using the Springer-Verlag TEX Theaar macro package 1988.  相似文献   

5.
Nucleation is a non-equilibrium process: the products of this process are seldom the most thermodynamically stable condensates but are instead those which form fastest. It should therefore not be surprising that grains formed in a circumstellar outflow will undergo some degree of metamorphism if they are annealed or are exposed to a chemically active reagent. Metamorphism of refractory particles continues in the interstellar medium (ISM) where the driving forces are sputtering by cosmic ray particles, annealing by high energy photons and grain destruction in supernova generated shocks. Studies of the depletion of the elements from the gas phase of the interstellar medium tell us that if grain destruction occurs with high efficiency in the ISM, then there must be some mechanism by which grains can be formed in the ISM. Various workers have shown that refractory mantles could form on refractory cores by radiation processing of organic ices. A similar process may operate to produce refractory inorganic mantles on grain cores which survived the supernova shocks. Most grains in a cloud which collapses to form a star will be destroyed; many of the surviving grains will be severely processed. Grains in the outermost regions of the nebula may survive relatively unchanged by thermal processing or hydration. It is these grains which we hope to find in comets. However, only those grains encased in ice at low temperature can be considered pristine since a considerable degree of hydrous alteration might occur in a cometary regolith if the comet enters the inner solar system. Some discussion of the physical, chemical and isotopic properties of a refractory grain at each stage of its life cycle will be attempted based on the limited laboratory data available to date. Suggestions will be made concerning types of experimental data which are needed in order to better understand the processing history of cosmic dust.  相似文献   

6.
Metal-rich carbonaceous CB chondrites are generally assumed to be materials accreted from the gas–dust plume formed in catastrophic collisions of planetesimals, at least one of which was differentiated into a metal core and silicate shell. Micron-sized inclusions of siliceous alkali-rich glasses associated with sulfides were found in the metal globules of the Sierra Gorda 013 (SG 013), a CBa-like chondrite. These inclusions are unusual carriers of volatile alkalis which are commonly depleted in CB chondrites. The inclusions are presented by two types: (1) Al-bearing Nb-poor glass associated with daubréelite and (2) Nb-bearing Ca,Al,Mg-poor glass associated with an unknown Na-bearing Cr-sulfide. The glass compositions do not correspond to equilibrium condensation, evaporation, or melting. The Nb-bearing glass has a superchondritic Nb/Ta ratio (31) most likely indicating the fractionation of Nb and Ta in the high-temperature gas–dust impact plume due to condensation from vapor or evaporation of precursor Nb-rich particles. The glasses are interpreted as reaction products between refractory plume condensate particles (or possibly planetary or chondritic solids) with relatively low-temperature K-Na-Si-rich gas in oxidized conditions, possibly in a common plume vapor reservoir. Compositional differences indicate that the glasses and sulfides originated from several different sources under different fO2, fS2, and T conditions and were likely combined together and transported to the metal globule formation region by material flows in the heterogeneous impact plume. The glass–sulfide particles were enclosed in the globules aggregated from smaller solid or molten metal grains. The metal globules were further melted during transport to the high-temperature plume region or by plume shockwave heating. Thus, the composition of the glasses, the host metal, and the main mass of SG 013 shows dynamic heterogeneity of physical conditions and impact plume composition after a large-scale planetesimal collision.  相似文献   

7.
Laboratory and theoretical studies have been made of the effects of ultraviolet photolysis of interstellar grain mantles which consist of combinations of hydrogen, oxygen, carbon and nitrogen — dirty ice. It is shown that processes involving photolysis (photoprocessing) of interstellar grains are important during most of their lifetime even including the time they spend in dense clouds. A laboratory designed to simulate the interstellar conditions is described. This is the first time such a laboratory has been able to provide results which may be directly scaled to the astrophysical situations involving interstellar grains and their environment. The evolution of grain analogs is followed by observing the infrared absorption spectra of photolyzed samples of ices deposited at 10 K. The creation and storage of radicals and the production of molecules occur as a result of reactions within the solid. A large number of molecules and radicals observed in the interstellar gas appear in the irradiated ices. Energy released during warm-up is seen from visible luminescence and inferred from vapor pressure enhancement which occurs during warming of photolyzed samples relative to unphotolyzed samples. The evolution of a grain and its role as a source as well as a sink of molecules is pictured as a statistical process within dense clouds. The gradual accretion on and photolysis of an individual grain provides the stored chemical energy the release of which is sporadically triggered by relatively mild events (such as low velocity grain-grain collisions) to produce the impulsive heating needed to eject or evaporate a portion of the grain mantle. An extremely complex and rather refractory substance possessing the infrared signatures of amino groups and carboxylic acid groups and having a maximum mass of 514 amu has been produced at a rate corresponding to a mass conversion rate of interstellar grains of between 2% and 20% in 107 yr. The shape and position of the astronomically observed 3.1 m band is duplicated in the laboratory and is shown to be a natural consequence of the processing of grain mantles.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.  相似文献   

8.
Silicon carbide (SiC), a refractory material, condenses near the photospheres of C-rich asymptotic giant branch stars, giving rise to a conspicuous emission feature at 11.3 μm. In the presence of a stellar wind, the SiC grains are carried outwards to colder regions, where less-refractory carbonaceous material can condense, either by itself or in mantles upon SiC grains. Enough carbon can condense on the latter that their specific feature is completely veiled. Thus the following may be explained: (i) the coexistence of the SiC feature protruding above a carbonaceous continuum, with a range of contrasts, corresponding to various volume ratios of mantle to core; or (ii) the ultimate disappearance of the 11.3-μm feature from the interstellar medium, where the mantle has become completely opaque due to the much higher cosmic abundance of carbon.  相似文献   

9.
Interstellar shock waves can erode and destroy grains present in the shocked gas, primarily as the result of sputtering and grain-grain collisions. Uncertainties in current estimates of sputtering yields are reviewed. Results are presented for the simple case of sputtering of fast grains being stopped in cold gas. An upper limit is derived for sputtering of refractory grains in C-type MHD shocks: shock speedsv s 50 km s–1 are required for return of more than 30% of the silicate to the gas phase. Sputtering can also be important for removing molecular ice mantles from grains in two-fluid MHD shock waves in molecular gas. Recent estimates of refractory grain lifetimes against destruction in shock waves are summarized, and the implications of these short lifetimes are discussed.  相似文献   

10.
This paper presents a semi-empirical model for variations of interstellar polarization curves based upon the Serkowski-Wilking law for optical and near-infrared wavebands. The model assumes that nonspherical dust grains producing interstellar polarization are core-mantle particles shaped like oblate spheroids. The physical picture is one in which large (a 0 0.1µm) particles in the dense cloud phase are deposited into the diffuse cloud medium and thereafter undergo mantle processing by galactic shocks and UV starlight. It is shown that polarization curves vary their widths mainly as a consequence of the nonthermal sputtering of mantles by low-velocity shocks. Mantle sputtering by shocks in low density clouds tends to broaden the curves, whereas mantle sputtering by shocks in denser clouds produce narrow curves. Hence, shock processing of grain mantles can explain the observed correlation between the width of polarization curves and the dust grain environment.  相似文献   

11.
Three consequences of the existence of grains with metal-rich ice mantles are considered: (i) The production of metal-poor stars by expulsion of protostellar grains by radiation pressure during star formation. (ii) The effects of these expelled grains in reddening massive stars in an OB association. (iii) The production of the icy mantles on grains in OB associations.  相似文献   

12.
The chemical desorption of an adsorbed CO molecule in the vicinity of H2-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H2. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H2 formation energy in the vicinity of H2-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H2-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (1013 s) and that for H2 forming in the vicinity of an adsorbed CO molecule (more than 2×1013 s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.  相似文献   

13.
The physical adsorption energy,E, of hydrogen molecules on various substrates at temperatures between 5 and 30 K and at the lowest practicable gas densities has been measured. Values ofE/k are for condensed CO 340 K, CO2 800 K, H2O 850 K and for ‘dirty’ graphite 980 K and ‘dirty’ copper 800 K. From these measurements temperature ranges in which H atoms might combine on the surface to form H2 molecules are estimated. Duley has discussed the formation and composition of condensed gas mantles on interstellar grains. The effects of such mantles in promoting and poisoning hydrogen molecule formation are discussed.  相似文献   

14.
Aromatic hydrocarbons account for a significant portion of the organic matter in carbonaceous chondrite meteorites, as a component of both the low molecular weight, solvent-extractable compounds and the insoluble organic macromolecular material. Previous work has suggested that the aromatic compounds in carbonaceous chondrites may have originated in the radiation-processed icy mantles of interstellar dust grains. Here we report new studies of the organic residue made from benzene irradiated at 19 K by 0.8 MeV protons. Polyphenyls with up to four rings were unambiguously identified in the residue by gas chromatography–mass spectrometry. Atmospheric pressure photoionization Fourier transform mass spectrometry was used to determine molecular composition, and accurate mass measurements suggested the presence of polyphenyls, partially hydrogenated polyphenyls, and other complex aromatic compounds. The profile of low molecular weight compounds in the residue compared well with extracts from the Murchison and Orgueil meteorites. These results are consistent with the possibility that solid phase radiation chemistry of benzene produced some of the complex aromatics found in meteorites.  相似文献   

15.
Abstract— Fischer‐Tropsch catalysis, by which CO and H2 are converted to CH4 on the surface of transition metals, has been considered to be one of the most important chemical reactions in many planetary processes, such as the formation of the solar and circumplanetary nebulae, the expansion of vapor clouds induced by cometary impacts, and the atmospheric re‐entry of vapor condensate due to asteroidal impacts. However, few quantitative experimental studies have been conducted for the catalytic reaction under conditions relevant to these planetary processes. In this study, we conduct Fischer‐Tropsch catalytic experiments at low pressures (1.3 times 10?4 bar ≤ P ≤ 5.3 times 10?1 bar) over a wide range of H2/CO ratios (0.25–1000) using pure iron, pure nickel, and iron‐nickel alloys. We analyze what gas species are produced and measure the CH4 formation rate. Our results indicate that the CH4 formation rate for iron catalysts strongly depends on both pressure and the H2/CO ratio, and that nickel is a more efficient catalyst at lower pressures and lower H2/CO ratios. This difference in catalytic properties between iron and nickel may come from the reaction steps concerning disproportionation of CO, hydrogenation of surface carbon, and the poisoning of the catalyst. These results suggest that nickel is important in the atmospheric re‐entry of impact condensate, while iron is efficient in circumplanetary subnebulae. Our results also indicate that previous numerical models of iron catalysis based on experimental data at 1 bar considerably overestimate CH4 formation efficiency at lower pressures, such as the solar nebula and the atmospheric re‐entry of impact condensate.  相似文献   

16.
Measurements of the strengths of the diffuse interstellar bands at 4430, 5780 and 5797 Å show that the bands tend to be week with respect to extinction in dense interstellar clouds. Data on 10 stars in the ? Ophiuchi cloud complex show further that the diffuse band-producing efficiency of the grains decreases systematically with increasing grain size. It is concluded that the diffuse bands are not formed in the mantles which accrete on the grains in interstellar clouds, but that they could be produced in the cores of grains or in some molecular species.  相似文献   

17.
To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H2O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H2O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H2O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H2O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.  相似文献   

18.
S.A. Stern  L. Trafton 《Icarus》1984,57(2):231-240
Cosmic abundance, vapor pressure, and molecular weight considerations restrict the likely gas candidates for Pluto's atmosphere to Ne, N2, CO, O2, and Ar, in addition to the already detected CH4. The vapor pressures and cosmic abundances of these gases indicate that all except Ne should be saturated in Pluto's atmosphere. The vapor pressure of Ne is so high that the existence of solid or liquid Ne on Pluto's surface is very unlikely; cosmic abundance arguments imply that Ne cannot attain saturation in Pluto's atmosphere. At both perihelion, N2 should dominate the saturated gases. CO2 should have the next highest mixing ratio, followed by O2 and Ar. CH4 should have the smallest mixing ratio. Because vapor pressures of these gases vary with temperature at diverse rates, the bulk and constituent mixing ratios of Pluto's atmosphere should vary with season. Between perihelion and aphelion, the column abundance of CH4 may change by a factor of 260 while that of N2 changes by only a factor of 52. The potential seasonal variation of Pluto's atmosphere was investigated by considering the behavior of these gases when individually mixed with CH4. The effects of diurnal and latitudinal variation of insolation and eclipses on the atmosphere also were investigated. Seasonal effects are shown to dominate. It was shown that the atmospheric bulk may not be a minimum near aphelion but rather at intermediate distances from the Sun during summer/winter inadequate ice deposits may allow the atmosphere to collapse by freezing out over winter latitudes. If the atmosphere does not collapse, its weight is sufficient to keep it distributed uniformly around Pluto's surface. In this case, the atmosphere tends to regulate the surface temperature to a seasonally dependent value which is uniform over the globe.Finally, the likely global circulation regimes for each model atmosphere as a function of temperature were investigated and it was concluded that if CH4, O2, or CO dominates the atmosphere, Pluto will exhibit cyclic variations between an axially symmetric circulation system at perihelion and a baroclinic wave regime at aphelion. However, if N2 dominates, as is likely, the wave regime should hold continuously. If the atmosphere collapses to a thin halo during summer/winter seasons, only a weak, symmetric circulation should occur.  相似文献   

19.
J.E. Chambers 《Icarus》2010,208(2):505-19170
The formation of 1-1000 km diameter planetesimals from dust grains in a protoplanetary disk is a key step in planet formation. Conventional models for planetesimal formation involve pairwise sticking of dust grains, or the sedimentation of dust grains to a thin layer at the disk midplane followed by gravitational instability. Each of these mechanisms is likely to be frustrated if the disk is turbulent. Particles with stopping times comparable to the turnover time of the smallest eddies in a turbulent disk can become concentrated into dense clumps that may be the precursors of planetesimals. Such particles are roughly millimeter-sized for a typical protoplanetary disk. To survive to become planetesimals, clumps need to form in regions of low vorticity to avoid rotational breakup. In addition, clumps must have sufficient self gravity to avoid break up due to the ram pressure of the surrounding gas. Given these constraints, the rate of planetesimal formation can be estimated using a cascade model for the distribution of particle concentration and vorticity within eddies of various sizes in a turbulent disk. We estimate planetesimal formation rates and planetesimal diameters as a function of distance from a star for a range of protoplanetary disk parameters. For material with a solar composition, the dust-to-gas ratio is too low to allow efficient planetesimal formation, and most solid material will remain in small particles. Enhancement of the dust-to-gas ratio by 1-2 orders of magnitude, either vertically or radially, allows most solid material to be converted into planetesimals within the typical lifetime of a disk. Such dust-to-gas ratios may occur near the disk midplane as a result of vertical settling of short-lived clumps prior to clump breakup. Planetesimal formation rates are sensitive to the assumed size and rotational speed of the largest eddies in the disk, and formation rates increase substantially if the largest eddies rotate more slowly than the disk itself. Planetesimal formation becomes more efficient with increasing distance from the star unless the disk surface density profile has a slope of −1.5 or steeper as a function of distance. Planetesimal formation rates typically increase by an order-of-magnitude or more moving outward across the snow line for a solid surface density increase of a factor of 2. In all cases considered, the modal planetesimal size increases with roughly the square root of distance from the star. Typical modal diameters are 100 km and 400 km in the regions corresponding to the asteroid belt and Kuiper belt in the Solar System, respectively.  相似文献   

20.
Abstract— We demonstrate a new formation route for TiC core‐graphitic mantle spherules that does not require carbon‐atom addition and the very long time scales associated with such growth (Bernatowicz et al. 1996). Carbonaceous materials can be formed from C2H2 and its derivatives, as well as from CO gas. In this paper, we will demonstrate that large‐cage‐structure carbon particles can be produced from CO gas by the Boudouard reaction. Since the sublimation temperature for such fullerenes is low, the large cages can be deposited onto previously nucleated TiC and produce TiC core‐graphitic mantle spherules. New constraints for the formation conditions and the time scale for the formation of TiC core‐graphitic mantle spherules are suggested by the results of this study. In particular, TiC core‐graphitic mantle grains that are found in primitive meteorites that have never experienced hydration could be mantled by fullerenes or carbon nanotubes rather than by graphite. In situ observations of these grains in primitive anhydrous meteoritic matrix could confirm or refute this prediction and would demonstrate that the graphitic mantle on such grains is a metamorphic feature due to interaction of the presolar fullerenes with water within the meteorite matrix.  相似文献   

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