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1.
煤的吸附性能及影响因素 总被引：22，自引：0，他引：22
为了研究煤的储气性能,笔者对124个煤样进行等温吸附试验、煤岩测试、工业分析、压汞试验和低温液氮测试．研究表明：(1)煤变质对煤吸附能力具有控制作用,反射率从0．3％～4．25％,可燃基的Langmuir体积是11．25～47．16cm^2／g;(2)平衡水煤样吸附量与镜质组含量呈正相关、与惰质组含量呈负相关、与孔隙比表面积、微孔比表面积、微孔孔体积呈正相关;(3)水分、温度对煤的吸附能力有负面影响．煤变质程度不同,吸附曲线的变化趋势不同：气煤随着温度和压力增加吸附量一直增大,说明压力的影响起主导作用;无烟煤在温度小于60℃、压力小于15MPa之前,随着温度和压力同时增加吸附量增大,说明压力的影响起主导作用,之后,吸附量减小,说明温度的影响大于压力的影响。 相似文献
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深部煤层含气量变化特征与浅部有所不同,实测数据极少,需要研发新的方法对其进行预测。本文以鄂尔多斯盆地东部主煤层为对象,分析了影响吸附常数的地质因素。基于煤样在不同温度条件下的高压甲烷等温吸附实验,采用主成分分析方法,探讨了深部煤层含气量预测方法。选取温度、镜质组反射率、水分含量、灰分产率、镜质组含量、惰质组含量6个因素进行主成分分析,提取出3个主成分,获得吸附常数与3个主成分之间的多元一次函数关系,根据朗格缪尔方程并结合含气饱和度建立了深部煤层含气量预测模型。采用这一模型,对鄂尔多斯盆地东部深部煤层进行了实例研究。结果表明,煤层含气量随埋深的变化存在一个临界深度,临界深度大致在750~1200m之间,随煤级及地层温度和地层压力而呈规律性变化。在临界深度以浅,煤层含气量随埋深的增大而增高;超过临界深度后,含气量随埋深的增大而减低。 相似文献
3.
现有数据表明我国1 000 m以浅低阶煤层含气量普遍偏低,而深层低阶煤试采效果显示较好。基于Langmuir方程开展了低阶煤高温高压环境下等温吸附模拟实验,结果表明:褐煤吸附量约占长焰煤、气煤吸附量的1/3,吸附能力最弱,随着煤阶的升高,吸附量逐渐增大;实验发现低阶煤在55℃、12 MPa以下吸附量随温度、压力增大而增加较快,并建立了基于煤阶-温度-压力条件下的深层低阶煤饱和吸附模型;煤层随着埋藏深度的增加,吸附量呈现出快速增加-缓慢增加-缓慢递减的过程,即深层煤层吸附量存在吸附临界深度带,为1 400~1 700 m。1 400 m以浅吸附量受压力正效应大于温度负效应,吸附量随埋深增加而增加,临界深度带内吸附量达到极限,不再增加,1 700 m以深温度负效应大于压力正效应,吸附量随深度增加而减小。实验结果为深层低阶煤层气资源评价及开发潜力提供理论依据。 相似文献
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准噶尔盆地南缘(准南)是我国重要的低煤阶煤层气地区。以准南低阶煤储层为研究对象,以压汞法为基础,运用分形维数对煤储层孔隙结构进行了探讨。研究发现,该地区煤储层微小孔较为发育,压汞曲线分为两类,第一类汞饱和度和退汞率较高,利于煤层气的产出,第二类汞饱和度和退汞效率相对较低,不利于煤层气的产出,但有利于煤层气的储集,该区整体储层较好。从分形维数的角度来看,孔径在10~2 100nm具有明显的分段分形特征,并呈现出随孔径增大而增大的趋势。此外,通过分形维数与煤岩特征相关性分析发现,在低阶煤阶段,大孔分形维数与R_(o,max)、惰质组含量呈正相关,但与灰分含量、镜质组含量、挥发分含量呈负相关。而分形维数越高,孔隙结构越复杂,因此,在研究区,高演化程度的富惰质组煤储层孔隙结构较差,而高灰分、挥发分、富镜质组的煤储层孔隙结构较好。 相似文献
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河北南部地区石炭一二叠系煤层煤种丰富,峰峰、邯郸矿区煤层的宏观煤岩类型以半亮煤和半暗煤为主;显微煤岩类型为微镜煤、微镜惰煤及微暗煤;煤的结构以细、中宽条带状结构为主,在半亮煤和半暗煤中最多;有机显微组分以镜质组最高,一般可占50％～91％,惰质组占10％～35％,壳质组含量一般不超过5％,对煤层气来说,这是比较有利的烃源条件：区内大淑村矿2煤的矿物质含量最低,其煤的吸附能力较其它矿区高;主煤层镜质组最大反射率具有北高南低的分布规律,揭示了煤的生烃强度具有由南向北逐渐增高的趋势。该区煤层气源岩不仅影响煤的生烃能力,还影响着煤层对甲烷的吸附能力和煤层气的开采能力。 相似文献
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为揭示深部煤层超临界CO2（ScCO2）吸附特征及其控制机理,以沁水盆地南部余吾矿、寺河矿、成庄矿的3号煤为研究对象,通过自制等温吸附仪进行了不同温度（45℃,62.5℃,80℃）、最高压力达到CO2超临界压力以上时的等温吸附实验。研究结果表明:高温高压条件下ScCO2吸附曲线不同于常温常压下CO2吸附曲线,随压力升高ScCO2过剩吸附量和绝对吸附量分别呈4段式和3段式变化,ScCO2达到过剩吸附量峰值出现的压力点具有随温度升高向高压增高的特征;ScCO2过剩吸附量远低于绝对吸附量,无法采用Langmuir吸附模型进行解释;温度对ScCO2吸附抑制明显,水分对ScCO2吸附没有起到抑制作用,灰分含量较高对ScCO2吸附量有明显抑制作用,煤中高镜质组含量和高Rmax对ScCO2吸附具有较明显的促进作用;超临界状态下煤对ScCO2的吸附量大小由微孔和过渡孔所控制,且与微孔比表面积大小有关,高变质煤对ScCO2的吸附能力降低可能是因微孔中矿物充填所致。 相似文献
8.
煤体性质对煤吸附容量的控制作用探讨 总被引：6，自引：2，他引：4
煤体性质是影响煤吸附容量的重要因素之一。通过对中国华北和西北两个重要煤层气富集区煤的煤岩学、煤化学和等温吸附实验分析,从煤级、显微组分、煤体变形三个方面对煤的吸附容量及其控制因素进行了, 分析探讨。结果表明,水分平衡条件下煤的吸附容量与煤阶的关系为倒U字型,吸附容量随煤阶的变化为跃变式, 基本与四次煤化作用跃变阶段相对应,主要受控于煤化作用过程中煤的亲甲烷能力和孔隙度的变化;煤体中惰质组含量较高时,其对煤体的吸附容量的影响较为明显,主要与惰质组中丝质体的高吸附能力有关;在构造应力作用下,煤体表面物化发生的变化使构造煤吸附容量比同一矿区同一煤层原生结构煤高。 相似文献
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西北地区中侏罗统的煤层多为不粘煤、弱粘煤,其煤岩组分以丝炭居多,也见有镜煤透镜体,以镜煤反射率可将其变质程度分为Ⅰ、Ⅱ、Ⅲ阶段,它与惰质组含量有很大关系。惰质组含量高、煤化程度低是造成二氧化碳分解率高的主要因素之一。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
13.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
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正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
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正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
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正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
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正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献