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1.
A screening of natural radioactivity content has been carried out in thermal water samples collected from surrounding of Central Anatolia, Turkey. The concentration levels of gross alpha and beta of 19 different samples has been determined using the low background gas-flow proportional counter. The measured gross alpha and beta activities in waters range from 0.11 to 16 Bq/L and 0.10 to 16.9 Bq/L, respectively. The measured values of gross alpha and beta concentrations are compared to previous studies in the literature and recommend WHO guideline activity concentration. The data resulting from the measurement have been statistically analyzed.  相似文献   

2.
The activities of the most common, naturally occurring radionuclides 238U, 226Ra, 210Pb, 228Ra, 228Th, and 40K were measured by gamma-ray spectrometry in samples from reservoir rocks, geothermal fluids, and mineral precipitates at the geothermal research site Groß Schönebeck (North German Basin). Results demonstrated that the specific activity of the reservoir rock is within the range of the mean concentration in the upper earth crust of <800 Bq/kg for 40K and <60 Bq/kg for radionuclides of the 238U and 232Th series, respectively. The geothermal fluid showed elevated activity concentrations (up to 100 Bq/l) for 226Ra, 210Pb, and 228Ra, as compared to concentrations found in natural groundwater. Their concentration in filter residues even increased up to 100 Bq/g. These residues contain predominantly two different mineral phases: a Sr-rich barite (Sr, BaSO4) and laurionite (PbOHCl), which both precipitate upon cooling from the geothermal fluid. Thereby they presumably enrich the radionuclides of Ra (by substitution of Ba) and Pb. Analysis of these precipitates further showed an increased 226Ra/228Ra ratio from around 1–1.7 during the initial months of fluid production indicating a change in fluid composition over time which can be explained by different contributions of stimulated reservoir rock areas to the overall produced fluid.  相似文献   

3.
A total of 1270 raw-water samples (before treatment) were collected from 15 principal and other major aquifer systems (PAs) used for drinking water in 45 states in all major physiographic provinces of the USA and analyzed for concentrations of the Ra isotopes 224Ra, 226Ra and 228Ra establishing the framework for evaluating Ra occurrence. The US Environmental Protection Agency Maximum Contaminant Level (MCL) of 0.185 Bq/L (5 pCi/L) for combined Ra (226Ra plus 228Ra) for drinking water was exceeded in 4.02% (39 of 971) of samples for which both 226Ra and 228Ra were determined, or in 3.15% (40 of 1266) of the samples in which at least one isotope concentration (226Ra or 228Ra) was determined. The maximum concentration of combined Ra was 0.755 Bq/L (20.4 pCi/L) in water from the North Atlantic Coastal Plain quartzose sand aquifer system. All the exceedences of the MCL for combined Ra occurred in water samples from the following 7 PAs (in order of decreasing relative frequency of occurrence): the Midcontinent and Ozark Plateau Cambro-Ordovician dolomites and sandstones, the North Atlantic Coastal Plain, the Floridan, the crystalline rocks (granitic, metamorphic) of New England, the Mesozoic basins of the Appalachian Piedmont, the Gulf Coastal Plain, and the glacial sands and gravels (highest concentrations in New England).  相似文献   

4.
It is important to know the distribution and transfer of radionuclides such as uranium, thorium, and potassium, which exist naturally in the environment we live in. For this reason, measurements of these natural radionuclides have been carried out for 15 gravel samples collected from Konyaalt? Beach, Antalya. In order to measure the natural activity concentrations of potassium-40, uranium-238, and thorium-232 radionuclides, we performed the measurements by applying a gamma spectrometry method with a “3?×?3” NaI(Tl) detector, which is a multichannel analytical detector in the Suleyman Demirel University gamma spectrometry laboratory. The minimum, maximum, and mean values for the 226Ra activity concentration were measured as 19.74 Bq/kg, 37.03 Bq/kg, and 31.64 Bq/kg, respectively. The minimum, maximum, and mean values for the 232Th activity concentration were measured as 12.76 Bq/kg, 34.32 Bq/kg, and 26.67 Bq/kg, respectively. The minimum, maximum, and mean values for the 40K activity concentration were measured as 196.37 Bq/kg, 421.13 Bq/kg, and 350.42 Bq/kg, respectively. Dose parameters and radiation damage indices were calculated using experimentally measured activity results and the resulting dose and hazard index values were compared with the determined limit values. It can be concluded that no risk may threat in terms of the hazard index values. In addition, all results obtained in terms of calculated dose values except for annual gonadal dose are below the recommended limit values.  相似文献   

5.
Submarine groundwater discharge (SGD) is herein recognized as a significant pathway of material transport from land to the coastal SW Atlantic Ocean and thus, it can be a relevant factor affecting the marine biogeochemical cycles in the region. This paper focuses on the initial measurements of 226Ra, 228Ra and 222Rn made in Patagonia’s coastal zone of Chubut and Santa Cruz provinces (42°S–48°S, Argentina). 226Ra activity ranged from 2.9 to 73.5 dpm 100 L?1, and 228Ra activity ranged from 11.9 to 311.0 dpm 100 L?1 in groundwater wells. The radium activities found in Patagonia’s marine coastal regions and adjacent shelf indicate significant enrichment throughout the coastal waters. Groundwater samples presented the largest 222Rn activity and ranged from 2.66 to 1083 dpm L?1. Conversely, in the coastal marine environment, the 222Rn activity ranged from 1.03 to 6.23 dpm L?1. The Patagonian coastal aquifer showed a larger enrichment in 228Ra than in 226Ra, which is a typical feature for sites where SGD is dominant, probably playing a significant role in the biogeochemistry of these coastal waters.  相似文献   

6.
Levels of naturally occurring radioactivity in sediment samples of Beni Haroun dam have been investigated. The activity concentrations of 238U and 232Th decay chains and 40K primordial radionuclide have been measured using high-resolution HPGe detector. Activity concentrations of 226Ra, 232Th, and 40K radionuclides were found in the ranges 9–66, 14–37, and 177–288 Bq/kg with the mean values 24.67, 25.98, and 208.10 Bq/kg, respectively. Radiological hazard parameters were estimated based on the activity concentrations for 226Ra, 232Th, and 40K to find out any radiation hazard associated with the sediments. Correlation studies between pairs of radionuclides were performed and discussed, and the obtained results are compared with international recommended values.  相似文献   

7.
《Applied Geochemistry》1995,10(5):491-503
Gross-beta activity has been used as an indicator of beta-emitting isotopes in water since at least the early 1950s. Originally designed for detection of radioactive releases from nuclear facilities and weapons tests, analysis of gross-beta activity is widely used in studies of naturally occurring radioactivity in ground water. Analyses of about 800 samples from 5 ground-water regions of the United States provide a basis for evaluating the utility of this measurement. The data suggest that measured gross-beta activities are due to (1) long-lived radionuclides in ground water, and (2) ingrowth of beta-emitting radionuclides during holding times between collection of samples and laboratory measurements.Although40K and228Ra appear to be the primary sources of beta activity in ground water, the sum of40K plus228Ra appears to be less than the measured gross-beta activity in most ground-water samples. The difference between the contribution from these radionuclides and gross-beta activity is most pronounced in ground water with gross-beta activities > 10 pCi/L, where these 2 radionuclides account for less than one-half the measured ross-beta activity. One exception is groundwater from the Coastal Plain of New Jersey, where40K plus228Ra generally contribute most of the gross-beta activity. In contrast,40K and228Ra generally contribute most of beta activity in ground water with gross-beta activities < 1 pCi/L.The gross-beta technique does not measure all beta activity in ground water. Although3H contributes beta activity to some ground water, it is driven from the sample before counting and therefore is not detected by gross-beta measurements. Beta-emitting radionuclides with half-lives shorter than a few days can decay to low values between sampling and counting. Although little is known about concentrations of most short-lived beta-emitting radionuclides in environmental ground water (water unaffected by direct releases from nuclear facilities and weapons tests), their activities are expected to be low.Ingrowth of beta-emitting radionuclides during sample holding times can contribute to gross-beta activity, particularly in ground water with gross-beta activities > 10 pCi/L. Ingrowth of beta-emitting progeny of238U, specifically234Pa and234Th, contributes much of the measured gross-beta activity in ground water from 4 of the 5 areas studied. Consequently, gross-beta activity measurements commonly overestimate the abundance of beta-emitting radionuclides actually present in ground water. Differing sample holding times before analysis lead to differing amounts of ingrowth of the two progeny. Therefore, holding times can affect observed gross-beta measurements, particularly in ground water with238U activities that are moderate to high compared with the activity of40K plus228Ra. Uncertainties associated with counting efficiencies for beta particles with different energies further complicate the interpretation of gross-beta measurements.  相似文献   

8.
An assessment of the groundwater in areas underlain by pegmatite in Ede, southwestern Nigeria was carried out to determine the concentration of Potassium-40 (40K), Uranium-238 (238U) and Thorium-232 (232Th) radionuclides. In the earlier work, it was established that zircons in these pegmatites have suffered a high degree of metamictization that has enhanced continuous loss of some radionuclides since the time of emplacement of the pegmatite host rock to the present. The aim of this work is to determine whether or not there is corresponding increase in the concentration of radionuclides in groundwater in the study area. Fifteen groundwater samples were collected from both hand dug wells and boreholes in the area. Ten samples were from Ede town, two samples each from nearby communities of Iddo and Ekuro and one from Iwoye, where the bedrocks were not pegmatites. All the 15 samples were analyzed with the Sodium Iodide scintillator (NaI [Tl]) detector at the Centre for Energy Research and Development, Obafemi Awolowo University, Ile-Ife, Nigeria. The results showed varying concentrations of the radionuclides in the water samples. Activity concentrations of Potassium-40 (40K) indicated an average value of 17.149 Bq/L for samples from Ede, 9.265 Bq/L for Iddo, 6.6 Bq/L for Ekuro, while Iwoye has a value of 21.21 Bq/L. The Uranium-238 (238U) series had an average value of 13.64 Bq/L for Ede, 13.49 Bq/L for Ekuro, 11.685 Bq/L for Iddo and 12.04 Bq/L for the lone sample from Iwoye. Thorium-232 (232Th) series had an average value of 11.182 Bq/L for Ede, while average values of 7.79 Bq/L and 9.025 Bq/L, respectively, were recorded for Iddo and Ekuro and 12.25 Bq/L for Iwoye. The annual effective dose level of 40K is generally below the World Health Organization (WHO) recommended dosage of 0.1 mSv/y except for three locations, while those of 238U and 232Th are in excess of the standard values. The high radionuclides in the groundwater in the study area were not due to anthropogenic sources but directly due to geological processes which release the radioisotopes from rocks after weathering, continuous loss from metamict minerals and natural lateral mobility from regions of radionuclides’ release to other areas. There is thus the need to carry out systematic studies of the radionuclides concentrations on regional scale in the area which could lead to investigating on both short- and long-term health effects on organic species in these areas, and development of purification systems before utilizing water from the areas for domestic and industrial purposes.  相似文献   

9.
Activity ratios (AR) of radium isotopes have been used with success to constrain estimates of water ages and to approximate residence times in coastal waters. We compared two common radium sampling methods (grab sampling and stationary moorings) to estimate water ages and the residence time of St. Andrew Bay waters in northwest Florida, USA. Both sampling methods utilize manganese dioxide fibers (“Mn fibers”) to adsorb dissolved radium from the water column. Grab samples capture radium activities at a discrete time while moorings integrate radium activities over longer deployments. The two methods yielded similar results in this study and thus both approaches are useful for water age comparisons and residence time approximations. However, since radium often varies as a function of tidal stage, deploying moorings over a complete tidal cycle is the preferred approach. An estimated residence time for North Bay and West Bay of 8–11 days was approximated using ARs for both ex224Ra/223Ra and ex224Ra/228Ra. Some complications were introduced as St. Andrew Bay is a tidally dominated, rather than a river-dominated bay system where this method has previously been applied. The largest freshwater source to this bay system is from a man-made reservoir, with an average freshwater flow of only 20 m3 s?1. The activity concentrations and ARs measured by both sampling methods suggest that while the reservoir is the prominent radium source, it is not the only radium source. Nonetheless, a tidal mixing model applied to the western half of the system yielded an approximate flushing time of 10–12 days, similar to that derived from our radium-based water age approach.  相似文献   

10.
The variation of the natural radionuclide concentrations depends on the chemical composition of each site. In this work, two thermal springs in the east of Algeria have been chosen to assess the activity concentration of natural radionuclide, mainly the three natural radioactive series 238U, 235U and 232Th, and 40K. The high-resolution gamma ray spectroscopy was used to determine these concentrations. In these water samples, 235U, 234Th, 210Pb, 226Ra radionuclides are less than the minimum detectable activity. The activity of 238U is dominant. The 238U activity was determined by taking the mean activity of two separate photo-peaks of daughter nuclides 214Pb at 351.92 (37.2%) keV and 214Bi at 609.31 (45%) keV. The measured activity concentrations of 238U in water samples obtained from the concentrations of 214Bi and 214Pb ranged from 0.56 ± 0.20 to 1.13 ± 0.20 Bq/L. The annual effective dose value due to the ingestion of the measured radionuclide 238U in 1 L of water, for an adult, ranged from 9.20 to 18.56 µSv.  相似文献   

11.
The increasing interest in radioactivity has brought about the need for an assessment of human exposure to radiation. It is, therefore, necessary to examine naturally occurring radioactivity in the environment, especially its occurrence in groundwater. The aim of this work was then to study the levels and behavior of the most significant natural radionuclides, also in order to improve the knowledge of the hydrochemical processes involved in the selected groundwater systems. Natural radioactivity in fifteen Calabrian groundwaters for human use was investigated through high-resolution gamma spectrometry (with a negative-biased Ortec HPGe detector) and liquid scintillation measurements. Particular attention was given on those radionuclides (3H, 238U, 226Ra, and 228Ra), which contribute in a significant way to the overall effective dose received by members of the public due to the intake of drinking water originating from groundwater systems. The activity concentration of 238U varied from 1 to 51 mBq/L, as a result of the geology of the investigated area and of the oxidizing conditions that favored U dissolution. 226Ra presented a broad range of activity concentrations (0.011–0.14 mBq/L), lower than uranium ones because radium occurs in groundwater under reducing conditions. Some heavy metals (Cd, Pb, Be, Hg, Ag, As, Tl, Sb, Se, and Ni) were also investigated through ICP-MS measurements and compared with the limits set by the Italian Legislation. Metals are released into the environment by both natural and anthropogenic sources; they leach into underground waters, moving along water pathways and eventually depositing in the aquifer.  相似文献   

12.
Relatively high activity concentrations of some radionuclides (226Ra, 238U, 232Th, and 40K) have been measured in surface and subsurface soils in areas (southern Iraq) where many warfare actions have taken place during the Iran–Iraq and Gulf wars. Such high activity concentrations might be related to the increase in cancerous injuries and birth defects recently reported. The study was aimed to estimate the activity concentrations of some nuclides and a comparison of results with international health hazard indices. In addition, the excess lifetime cancer risk (ELCR) was assessed. Soil samples were collected at three depths (0, 30, and 60 cm) in three locations in Abu Al Khasib and Ad Dayr in Basrah governorates. The average activity concentrations were estimated employing hyper-pure germanium HPGe gamma-ray detection technology. The values obtained in Abu Al Khasib were: 58.44 Bq/kg (226Ra), 43.56 Bq/kg (238U), 19.38 Bq/kg (232Th), and 321.76 Bq/kg (40K) whereas in Ad Dayr 45.71 Bq/kg (226Ra), 35.53 Bq/kg (238U), 20.33 Bq/kg (232Th), and 337.02 Bq/kg (40K). According to UNSCEAR (Sources and effects of ionizing radiations: a report on the effects of atomic radiation to the general assembly with scientific annexes, Annex B, United Nations, New York, 2000) report, higher levels of 226Ra, 238U concentrations than the world’s average values (35 Bq/kg) were observed in both locations. In addition, some radiation hazard indices were determined for both locations: average outdoor external dose (D out), average indoor external dose (D in), total average value of the external dose (D tot), average annual outdoor effective dose (E out), average annual indoor effective dose (E in), and averaged total annual effective dose (E tot). Values for D tot and E tot were higher than the worldwide median (143 nGy/h and 0.48 mSv/y, respectively) in both regions. The measured values of activity concentrations were also used to estimate the outdoor, indoor, and total ELCR. The ELCR values were higher than the worldwide averages. Further analyses and studies need to assess the real risks for human health and possible soil remediation.  相似文献   

13.
《Chemical Geology》2002,182(2-4):409-421
An improved method was developed to measure 226Ra, 228Ra and 224Ra in freshwaters by gamma spectrometry. Radium was selectively extracted from acidified samples using specific filters (3M EMPORE™ Radium Rad disks). The latter was subsequently analysed by gamma spectrometry. Simultaneous and direct determination of the activities of the three isotopes was performed by comparison of gamma rays of the Radium Rad disks with those of a calibrated standard disk. This efficient and reliable method allowed a reduction of sample processing to a few hours.This technique was applied to analyse the Ra isotope compositions of several CO2-rich hydrothermal springs of the western border of the Limagne graben (French Massif Central). The studied springs emerge from a succession of granitic outcrops lined up along a major fault. Their chemical compositions evolve from calcic and magnesian chloro-bicarbonated to sodic bicarbonated. All the springs display high Ra activities, probably linked to high CO2 content and/or high cation content of these waters, with various Ra isotope ratios. 226Ra activity ranges from 588 to 2287 mBq/l and 228Ra activity from 260 to 1590 mBq/l, whereas 224Ra displays an activity between 245 and 1808 mBq/l. Four of the six analysed springs have (228Ra/226Ra) activity ratios lower than 0.7, thus, significantly lower than the ratio expected from an interaction with a calc-alkaline granitoid (typically having (232Th/238U) activity ratio between 1 and 2). Low (228Ra/226Ra) ratio (0.27) of the northern water (Montpensier) suggests the existence in this area of a zone of U concentration, possibly resulting from U mobilization and accumulation induced by previous hydrothermal events. The (224Ra/228Ra) ratios display smaller variations. They suggest short transit times from the zone of Ra leaching to the surface (a few days) or a very shallow addition of 224Ra (e.g., from a localised zone where 228Th could be preferentially adsorbed on the mineral surfaces). In some cases, these ratios might be used to infer differences in transit times of waters between neighboring springs.  相似文献   

14.
A study of natural radionuclides and radon concentration of Hamirpur District of Himachal Pradesh, India is carried out using various methodologies. The activity concentration of the natural radionuclides viz. 226Ra, 232Th and 40K is measured using high-resolution-based HPGe detector. Indoor radon measurements in the dwellings of Hamirpur district is carried out using LR-115 type II cellulose nitrate films in the bare mode. The average activity concentrations of 226Ra, 232Th and 40K are 35.58, 54.95 and 580.58 Bq kg?1, respectively. The annual average indoor radon value in the study area varies from 173.90 to 198.25 Bq m?3, which is well within the recommended action level given by International Commission on Radiological Protection. The indoor radon values obtained in the present investigation are higher than the world average of 40 Bq m?3. Radon concentration in water samples is measured using RAD7, an active radon detector. The annual effective dose for stomach and lung is determined from the measured value of radon concentration in water. To assess the radiation hazard of the natural radioactivity in all samples to the people, the radium equivalent activity, external hazard index, lifetime fatality risk, absorbed dose rate and total annual effective dose is estimated. The results signify that the studied area does not possess any radiation hazards due to the presence of natural radioactivity concentration.  相似文献   

15.
The recent chemical dynamics of a podzolic forest soil section (from the Strengbach watershed, France) was investigated using U- and Th-series nuclides. Analyses of (238U), (230Th), (226Ra), (232Th), (228Ra) and (228Th) activities in the soil particles, the seepage waters, and the mature leaves of the beech trees growing on this soil were performed by TIMS or gamma spectrometry. The simultaneous analysis of the different soil (sl) compartments allows to demonstrate that a preferential Th leaching over Ra must be assumed to explain the (226Ra/230Th), (228Ra/232Th) and (228Th/228Ra) disequilibria recorded in the soil particles. The overall Ra- and Th- transfer schemes are entirely consistent with the prevailing acido-complexolysis weathering mechanism in podzols. Using a continuous open-system leaching model, the (226Ra/230Th) and (228Ra/232Th) disequilibria measured in the different soil layers enable dating of the contemporary processes occurring in this soil. In this way, we have determined that a preferential Th-leaching from the shallow Ah horizon, due to a strong complexation with organic colloids, began fairly recently (18 years ago at most). The continual increase in pH recorded in precipitations over the last 20 years is assumed to be the cause of this enhanced organic complexation. A lower soil horizon (50-60 cm) is also affected by preferential Th leaching, though lasting over several centuries at least, with a much smaller leaching rate. The migration of Th isotopes through this soil section might hence be used as a tracer for the organic colloids migration and the induced radioactive disequilibria demonstrate to be useful for assessing the colloidal migration kinetics in a forested soil.Ra and Th isotopic ratios also appear to be valuable tracers of some mineral-water-plant interactions occurring in soil. The (228Ra/226Ra) ratio enables discrimination of the Ra flux originating from leaf degradation from that originating from mineral weathering in shallow −10 cm seepage soil waters. It appears that, at least in some cases, the Ra-isotopic ratio measured in forest-soil seepage waters may not be representative of the Ra-isotopic ratio released from mineral weathering, indicating that the different origins of the dissolved 226Ra and 228Ra must be taken into account.  相似文献   

16.
Two samples of produced-water collected from a storage tank at US Geological Survey research site B, near Skiatook Lake in northeastern Oklahoma, have activity concentrations of dissolved 226Ra and 228Ra that are about 1500 disintegrations/min/L (dpm/L). Produced-water also contains minor amounts of small (5–50 μm) suspended grains of Ra-bearing BaSO4 (barite). Precipitation of radioactive barite scale in the storage tank is probably hindered by low concentrations of dissolved SO4 (2.5 mg/L) in the produced-water. Sediments in a storage pit used to temporarily collect releases of produced-water have marginally elevated concentrations of “excess” Ra (several dpm/g), that are 15–65% above natural background values. Tank and pit waters are chemically oversaturated with barite, and some small (2–20 μm) barite grains observed in the pit sediments could be transferred from the tank or formed in place. Measurements of the concentrations of Ba and excess Ra isotopes in the pit sediments show variations with depth that are consistent with relatively uniform deposition and progressive burial of an insoluble Ra-bearing host (barite?). The short-lived 228Ra isotope (half-life = 5.76 a) shows greater reductions with depth than 226Ra (half-life = 1600 a), that are likely explained by radioactive decay. The 228Ra/226Ra activity ratio of excess Ra in uppermost pit sediments (1.13–1.17) is close to the ratio measured in the samples of produced-water (0.97, 1.14). Declines in Ra activity ratio (excess) with sediment depth can be used to estimate an average rate of burial of 4 cm/a for the Ra-bearing contaminant. Local shallow ground waters contaminated with NaCl from produced-water have low dissolved Ra (<20 dpm/L) and also are oversaturated with barite. Barite is a highly insoluble Ra host that probably limits the environmental mobility of Ra at site B.  相似文献   

17.
The distribution of radon in ground and surface water samples in Sankey Tank and Mallathahalli Lake areas was determined using Durridge RAD-7 analyzer with RAD H2O accessory. The radiation dose received by an individual falling under different age groups (viz., 3 months; 1, 5, 10, 15 years and adult) depending upon their average annual water consumption rate was attempted. The mean radon activity in surface water of Sankey Tank and Mallathahalli Lake was 7.24 ± 1.48 and 11.43 ± 1.11 Bq/L, respectively. The average radon activities ranged from 11.6 ± 1.7 to 381.2 ± 2.0 Bq/L and 1.50 ± 0.83 to 18.9 ± 1.59 Bq/L, respectively, in 12 groundwater samples each around Sankey Tank and Mallathahalli Lake areas. Majority of the measured groundwater samples (viz., 100 % in Sankey Tank area and 75 % in Mallathahalli Lake area) showed mean radon values above the EPA’s maximum contaminant level of 11.1 Bq/L and only 66.67 % of samples in Sankey Tank area showed radon above the WHO and EU’s reference level of 100 Bq/L. The overall radiation dose due to radon emanating from water in the study area was increasing with increase in age and water consumption rates, but significantly lower than UNSCEAR and WHO recommended limit of 1 mSv/year except for few groundwater samples in Sankey Tank area (i.e., 0.92, 0.99 and 1.39 mSv/year). The radiation dose rate received by bronchial epithelium via inhalation was very high compared to that by stomach walls via ingestion.  相似文献   

18.
Many water-supply systems in South America utilize the waters of the Guarani aquifer at least as part of their networks. However, there is little present knowledge in Brazil of the factors affecting Rn presence in the water supplied for end-users, despite the economic importance of Guarani aquifer. 222Rn analyzes of 162 water samples were performed at 8 municipalities in São Paulo State, Brazil, with the aim of investigating the major factors affecting its presence in solution. The 222Rn activity concentration ranged from 0.04 up to 204.9 Bq/L, with three samples exceeding the World Health Organization maximum limit of 100 Bq/L. Aeration was confirmed as the most important factor for Rn release, as expected due to its gaseous nature. Accumulation in pipes and stratification in the water column were other significant factors explaining the data obtained in some circumstances. The Rn daughters 214Pb and 214Bi were also determined in a set of selected samples and their presence was directly related to the occurrence of Rn dissolved in water.  相似文献   

19.
The Aral Sea has been shrinking since 1963 due to extensive irrigation and the corresponding decline in the river water inflow. Understanding of the current hydrological situation demands an improved understanding of the surface water/groundwater dynamics in the region. 222Rn and 226Ra measurements can be used to trace groundwater discharge into surface waters. Data of these radiometric parameters were not previously available for the study region. We determined 222Rn activities after liquid phase extraction using Liquid Scintillation Counting (LSC) with peak-length discrimination and analyzed 226Ra concentrations in different water compartments of the Amu Darya Delta (surface waters, unconfined groundwater, artesian water, and water profiles from the closed Large Aral Sea (western basin).The water samples comprise a salinity range between 1 and 263 g/l. The seasonal dynamics of solid/water interaction under an arid climate regime force the hydrochemical evolution of the unconfined groundwater in the Amu Darya Delta to high-salinity Na(Mg)Cl(SO4) water types. The dissolved radium concentrations in the waters were mostly very low due to mineral over-saturation, extensive co-precipitation of radium and adsorption of radium on coexisting solid substrates.The analysis of very low 226Ra concentrations (<10 ppq) at remote study sites is a challenge. We used the water samples to test and improve different analytical methods. In particular, we modified a procedure developed for the α-spectrometric determination of 226Ra after solid phase extraction of radium using 3M Empore™ High Performance Extraction Disks (Purkl, 2002) for the analysis of the radionuclide using an ICP sector field mass spectrometer. The 226Ra concentration of 17 unconfined groundwater samples ranged between 0.2 and 5 ppq, and that of 28 artesian waters between <0.2 and 13 ppq. The ICP-MS results conformed satisfactorily to analytical results based on γ-measurements of the 222Rn ingrowth after purging and trapping on super-cooled charcoal. The 226Ra concentrations were positively correlated with the salinity and the dissolved NaCl concentrations. The occurrence of unusually high 226Ra activities is explained by radium release from adsorption sites with increasing salinity. The inferred spatial variability of 222Rn in the Aral Sea and of 222Rn and 226Ra in the groundwater of the Amu Darya Delta is discussed in the context of our own previous hydrochemical studies in the study sites. Relatively low 222Rn activities in the unconfined GW (1–9.5 Bq/l) indicate the alluvial sediments hosting the GW to be a low-238U(226Ra) substrate. Positive correlations between U and 226Ra, and U and 222Rn are likely related to locally deposited Fe(Mn)OOH precipitates. The 222Rn activity of the GW, however, distinctly exceeds the 222Rn concentration in the Aral Sea (10 mBq/l), in principle, making 222Rn a sensitive tracer for the inflow of GW. The high water volume of the Large Aral Sea and wind induced mixing of its water body, however, hamper the detection of local groundwater inflow.  相似文献   

20.
This study focuses on the water and gas chemistry of the northeastern Algerian thermal waters. The helium gas was used to detect the origin of the geothermal fluid. In the Guelma Basin, the heat flow map shows an anomaly of 120 ± 20 mW/m2 linked to the highly conductive Triassic extrusion. The chemical database reveals the existence of three water types, Ca-SO4/Na-Cl, which are related to evaporites and rich in halite and gypsum minerals. The third type is Ca (Na)-HCO3, which mostly characterizes the carbonated Tellian sector. The origin of thermal waters using a gas-mixing model indicates a meteoric origin, except for the El Biban hot spring (W10), which shows a He/Ar ratio of 0.213, thus suggesting the presence of batholith. The helium distribution map indicates a lower 3He/4He ratio between 0 Ra and 0.04 Ra in the W10 and W15 samples, which is compatible with the crustal ratio. Reservoir temperatures estimated by silica geothermometers give temperatures less than 133 °C. The geothermal conceptual model suggests that a geothermal system was developed by the deep penetration of infiltrated cold waters to a depth of 2.5 km and then heated by a conductive heat source (batholith for El Biban case). The thermal waters rise up to the surface through the deep-seated fractures. During their ascension, they are mixed with shallow cold groundwater, which increase the Mg content and cause the immature classification of the water samples.  相似文献   

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