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1.
《Geofísica Internacional》2014,53(4):385-398
Reflectance spectral curves were analysed by a derivative method. Derivative reflectance spectra revealed concealed peaks of both reflectance and absorption curves of Caribbean seawater and elements contained within it. Reflectance curves showed a predominant blue colour (400–500 nm) characteristic of Caribbean oligotrophic waters, conspicuous peaks result from the optical properties of chlorophyll a and seawater. Reflectance curves had a similar spectral response. This paper analyses reflectance spectra of surface seawater at 31 stations in the Caribbean Sea during the summer of 2001.  相似文献   

2.
《Marine pollution bulletin》2009,58(6-12):295-301
The coastal waters of Bolinao, Pangasinan, Philippines experienced environmental changes over a 10-year period (1995–2005), the most significant effect of which was the major fish kill event in 2002 that coincided with the first reported Philippine bloom of a dinoflagellate Prorocentrum minimum. Days before the bloom, dissolved oxygen was <2.0 mg/l in the waters that were stratified. These conditions may be linked to the uncontrolled proliferation of fish pens and cages to more than double the allowable limit of 544 units for Bolinao waters. Mariculture activities release organic matter from unconsumed feed and fecal material that accumulate in the water and sediments. In over 10 years, water quality conditions have become eutrophic with ammonia increasing by 56%, nitrite by 35%, nitrate by 90%, and phosphate by 67%. The addition of more fish pens and cages placed additional stress to this poorly flushed, shallow area that affected water quality due to changes in the water residence time.  相似文献   

3.
Data on the distribution of fCO2 were obtained during a cruise in the Aegean Sea during February 2006. The fCO2 of surface water (fCO2sw) was lower than the atmospheric fCO2 (fCO2atm) throughout the area surveyed and ΔfCO2 values varied from ?34 to ?61 μatm. The observed under-saturation suggests that surface waters in the Aegean represent a sink for atmospheric CO2 during the winter of 2006. Higher fCO2sw values were recorded in the ‘less warm’ and ‘less saline’ shallow northernmost part of the Aegean Sea implying that the lower seawater temperature and salinity in this area play a crucial role in the spatial distribution of fCO2sw.A first estimate of the magnitude of the air–sea CO2 exchange and the potential role of the Aegean Sea in the transfer of atmospheric CO2 was also obtained. The air–sea CO2 fluxes calculated using different gas transfer formulations showed that during February 2006, the Aegean Sea absorbs atmospheric CO2 at a rate ranging from ?6.2 to ?11.8 mmol m?2 d?1 with the shipboard recorded wind speeds and at almost half rate (?3.5 to ?5.5 mmol m?2 d?1) with the monthly mean model-derived wind speed. Compared to recent observations from other temperate continental shelves during winter period, the Aegean Sea acts as a moderate to rather strong sink for atmospheric CO2.Further investigations, including intensive spatial and temporal high-resolution observations, are necessary to elucidate the role of the Aegean Sea in the process of transfer of atmospheric CO2 into the deep horizons of the Eastern Mediterranean.  相似文献   

4.
《Marine pollution bulletin》2013,77(1-2):116-127
The distribution of Ruppia cirrhosa meadow density and its epiphytic organisms in relation with environmental factors were studied in summer 2011 at five stations in the Ghar El Melh lagoon (GML; southern Mediterranean Sea). Eleven epiphytic groups were recognised among which diatoms and dinoflagellates were the dominant groups and greatest contributors to temporal dissimilarity. An overwhelming concentrations of harmful microalgae was recorded, mainly represented by the toxic dinoflagellate Prorocentrum lima with maximal concentrations attaining 6 × 105 cells 100 g−1 of Ruppia fresh weight. The epifauna community accounted for only 1.4% of total epiphyte abundance and was comprised predominantly of nematodes (47.51%), ciliates (32.59%), fish eggs (7.2%) and larvae (4.95%). PERMANOVA analyses revealed a significant spatio-temporal variation of all epiphytic groups (p < 0.01). In this study, R. cirrhosa and its epiphytes were studied as potential early warning indicators of the health status of GML waters.  相似文献   

5.
《Marine pollution bulletin》2014,85(1-2):391-400
A comparative study of 23 PAH congeners in sediment of the Caspian Sea coast and Anzali Wetland was conducted in 2010. Surface sediment was analyzed using chromatography and mass spectrometry. Total PAH concentrations ranged between 212 and 9009 ng g−1 dw. Spatial distribution maps revealed that PAH levels were higher in the coastal areas of the Caspian Sea where oil related activities have been common since 1800’s. Diagnostic ratios analysis indicated that PAHs largely originated from petrogenic processes. PAH toxicity level was assessed using sediment quality guidelines and toxic equivalent concentrations to determine toxic effects on marine organism. Based on these investigations, in our study areas, the probability of toxicity for benthic organisms is “low to medium”. The toxic equivalent concentrations of carcinogenic PAHs varied between 11 and 231 ng TEQ/g; higher total toxic equivalent concentrations values were found in the coastal areas of the Caspian Sea.  相似文献   

6.
An annual amplitude of ∼18 cm mass-induced sea level variations (SLV) in the Red Sea is detected from the Gravity Recovery and Climate Experiment (GRACE) satellites and steric-corrected altimetry from 2003 to 2011. The annual mass variations in the region dominate the mean SLV, and generally reach maximum in late January/early February. The annual steric component of the mean SLV is relatively small (<3 cm) and out of phase of the mass-induced SLV. In situ bottom pressure records at the eastern coast of the Red Sea validate the high mass variability observed by steric-corrected altimetry and GRACE. In addition, the horizontal water mass flux of the Red Sea estimated from GRACE and steric-corrected altimetry is validated by hydrographic observations.  相似文献   

7.
《Continental Shelf Research》1999,19(14):1833-1848
A well-defined front in temperature and salinity separates the stratified Clyde Sea water from the vertically well mixed water of the North Channel. The detailed structure of the front was observed in autumn 1990 by a combination of, repeated crossings of the front using a ship-borne ADCP and a towed undulating CTD system, and the deployment of a fixed mooring system with temperature, salinity and velocity sensors for a period of 12 days. The results show that the front was situated on the Great Plateau near a contour of log10(H/U32)=2.7∼3.7 where H is the water depth and U2 the amplitude of M2 tidal velocity. The temperature structure in the Clyde Sea was inverted and the Clyde Sea surface temperature was lower than that of the vertically well mixed water in the North Channel. Since the salinity gradient was stronger than the temperature gradient with fresher water on the surface, the density structure was predominantly controlled by salinity. There were indications of warm and saline bottom water upwelling on the mixed side of the front during spring tides. This upwelling disappeared and the salinity and temperature structure at the front was more diffuse during the neap tide period. A jet-like along-front residual current was observed flowing to the northwest in the surface layer with a counter flow to the southeast in the bottom layer. The vertical difference in velocity was about 9 cm s−1 and was approximately consistent with the shear determined from the thermal wind relation. Both cross- and along-front components of the current observed at the mooring station varied in response to the advection of the front, although both components had large variations with periods of less than one day and several days. The front was advected past the mooring system by a mean flow from the North Channel to the inner basin, while oscillating 3–5 km back and forth with the tidal currents. From the velocity at a current meter mooring and CTD data, the front was estimated to have moved up to 20 km during the observational period and the cross frontal velocity was inferred to be 3–4 cm s−1.  相似文献   

8.
The horizontal and vertical distribution of jellyfish was assessed in the Chiloé Inland sea, in the northern area of the Chilean Patagonia. A total of 41 species of cnidarians (8 siphonophores, 31 hydromedusae, 2 scyphomedusae) were collected. Eleven jellyfish species were recorded for the first time in the area. Species richness was higher in spring than in winter (37 vs. 25 species, respectively). Species such as Muggiaea atlantica, Solmundella bitentaculata, and Clytia simplex were extremely abundant in spring. The total abundance (408,157 ind 1000 m?3) was 18 times higher in spring than in winter (22,406 ind 1000 m?3).The horizontal distribution of the most abundant species (four in winter, five in spring) showed decreasing abundances in the north–south direction in winter and spring. Peak abundances occurred in the northern microbasins (Reloncaví Fjord, Reloncaví and Ancud gulfs), where the water column stability, phytoplankton and zooplankton abundance were higher, compared with the southern microbasins (Corcovado Gulf, Boca del Guafo). During the spring higher jellyfish abundance season, the vertical distribution of the dominant species (except M. atlantica) showed peak values at mid-depth (30–50 m) and in the deepest sampled layer (50–200 m). This vertical distribution pattern reduced seaward transport in the shallowest layer through estuarine circulation and also limited mortality by predation in the more illuminated shallow layers. Thus, jellyfish were able to remain in the interior waters during the season of maximum biological production.  相似文献   

9.
《Marine pollution bulletin》2014,78(1-2):96-101
The Red Sea is among the world’s top marine biodiversity hotspots. We re-examined coastal ecosystems at sites surveyed during the 1980s using the same methodology. Coral cover increased significantly towards the north, mirroring the reverse pattern for mangroves and other sedimentary ecosystems. Latitudinal patterns are broadly consistent across both surveys and with results from independent studies. Coral cover showed greatest change, declining significantly from a median score of 4 (1000–9999 m2) to 2 (10–99 m2) per quadrat in 2010/11. This may partly reflect impact from coastal construction, which was evident at 40% of sites and has significantly increased in magnitude over 30 years. Beach oil has significantly declined, but shore debris has increased significantly. Although substantial, levels are lower than at some remote ocean atolls. While earlier reports have suggested that the Red Sea is generally healthy, shifting environmental baselines are evident from the current study.  相似文献   

10.
The occidental shore of the southern tip of South America is one of the largest estuarine ecosystems around the world. Although demersal finfish fisheries are currently in full exploitation in the area, the fjords south of 47°S have been poorly investigated. Two bio-oceanographic cruises carried out in austral spring 1996 and 2008 between 47°S and 50°09′S were utilized to investigate the spatial distribution of fish eggs and larvae. Small differences in the environmental conditions were identified in the top 200 m of the water column between years (5.3–10.5 °C and 0.7–33.9 units of salinity in October 1996; 6.3–11.5 °C and 1.2–34.2 units of salinity in November 2008). The low salinity surface layer generated a highly stable water column within the fjords (Brunt–Väisälä frequency, N>0.1 rad/s; wave period <60 s), whereas a well-mixed water column occurred in the gulfs and open channels. For both years, the ichthyoplankton analysis showed that early life stages of lightfish Maurolicus parvipinnis were dominant (>75% total eggs and >70% total larvae) and they were collected throughout the area, irrespective of the water column stratification. However, other components of the ichthyoplankton such as Falkland sprat Sprattus fuegensis, rockfish Sebastes oculatus, and hoki Macruronus magellanicus were more abundant and found in a wider range of larval sizes in less stable waters (N<0.1 rad/s). Oceanic taxa such as myctophids (Lampanyctodes hectoris) and gonostomatids (Cyclothone sp.) were collected exclusively in open waters. The October 1996 observation of Engraulis ringens eggs in plankton samples corresponded to the southernmost record of early stages of this fish in the Pacific Ocean. We found a significant negative relationship between the number of larval species and N, and a significant positive relationship between the number of larval species and wave period. Therefore, only some marine fish species are capable to utilize fjords systems as spawning and nursery grounds in areas having high amounts of freshwater discharges and very high vertical stratification during austral spring season.  相似文献   

11.
《Marine pollution bulletin》2012,64(5-12):523-527
Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06–168.21 mg kg−1 for Zn, 8.91–46.94 mg kg−1 for Cr, 2.69–49.39 mg kg−1 for Cu, 32.46–185.54 mg kg−1 for V, 0.09–0.92 mg kg−1 for Cd, and 0.95–15.25 mg kg−1 for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.  相似文献   

12.
《Continental Shelf Research》2007,27(3-4):296-308
This paper focuses on the delivery of water and sediment to the northern Adriatic to better understand the short-term evolution of continental margin sedimentation under natural and human impact. For that reason, the Po and six Apennine rivers (Metauro, Musone, Potenza, Tronto, Chienti and Pescara) are investigated. The climate-driven hydrological model HydroTrend is used to simulate discharge and sediment loads where observational data are limited. The northern Apennine hinterland has a significant impact on the sediment flux leaving the Po River, contributing 56% of the sediment it delivers to the Adriatic Sea. The Po River experienced a strong decrease in its sediment load (17.2–6.4 Mt/yr) across 1933–1987, in contrast to a small increase in its water discharge. The rivers draining the southern Apennine hinterland contribute more than 50% of the sediment load entering the Adriatic Sea, and this is in spite of human modification of their discharge through numerous small reservoirs that invariably reduce a river's sediment load. As a result, hyperpycnal flows, which historically carried 20–40% of the sediment flux from these Apennine rivers, become rare. Sediment load reduction is also reflected by retreat of the Apennine coastline. Based on the ART model (used in HydroTrend), the total sediment load to the northern Adriatic is 43 MT/yr where the northern Alpine rivers contribute 8 MT/yr, the Po River 13 MT/yr and the Apennine rivers contribute 22 MT/yr.  相似文献   

13.
We elucidate the ecology of Recent Ostracoda from a deep brackish lake, Tangra Yumco (30°45′—31°22′N and 86°23′—86°49′E, 4595 m a.s.l.) and adjacent waters on the southern Tibetan Plateau. Ostracod associations (living and empty valves) in sixty-six sediment samples collected from diverse aquatic habitats (lakes, estuary-like water and lagoon-like water waters, rivers, ponds and springs) were quantitatively assessed.Eleven Recent Ostracoda were found (nine living and two as empty valves only). Cluster analysis established two significant (p < 0.05) habitat specific associations; (i) Leucocytherella sinensis, Limnocythere inopinata, Leucocythere? dorsotuberosa, Fabaeformiscandona gyirongensis and Candona xizangensis are lacustrine fauna. (ii) Tonnacypris gyirongensis, Candona candida, Ilyocypris sp., Heterocypris incongruens and Heterocypris salina are temporary water species.Ostracod distribution and abundance are significantly (p < 0.05) correlated to physico-chemical variables. The first two axes of a canonical correspondence analysis (CCA) explain 30.9% of the variation in the species abundance data. Conductivity and habitat types are the most influential ecological factors explaining the presence and abundance of ostracods. Spearman correlation analysis reveals that: (i) Two species, L.? dorsotuberosa (r = 0.25) and L. inopinata (r = 0.36) have a significant positive correlation with conductivity while one species, T. gyirongensis (r = −0.68) displays a significant negative correlation with conductivity. Limnocythere inopinata correlates significantly positive (r = 0.37) with alkalinity. Fabaeformiscandona gyirongensis correlates significantly positive (r = 0.28) with water depth.Key indicator living assemblages are: (i) L. sinensis dominates Ca-depleted brackish waters although ubiquitously distributed; (ii) L.? dorsotuberosa dwells in fresh to brackish waters; (iii) L. inopinata predominates in mesohaline to polyhaline waters; (iv) F. gyirongensis inhabits exclusively brackish-lacustrine deeper waters; (v) C. candida populates freshwaters; (vi) T. gyirongensis and Ilyocypris sp. are restricted to shallow temporary waters; (vii) H. incongruens occurs in ponds.Water depth indicators are F. gyirongensis and L.? dorsotuberosa, useful in ostracod assemblages for palaeo-water depth reconstruction.Our results expand the knowledge of the ecological significance of Recent Tibetan Ostracoda ecology. This is a new insight on habitat chacteristics of both living assemblages and sub-Recent associations of ostracods in mountain aquatic ecosystems. The new modern ostracod dataset can be used for the quantitative reconstruction of past environmental variables (e.g., conductivity) and types of water environment. The key indicator ostracods are relevant in palaeolimnological and climate research on the Tibetan Plateau.  相似文献   

14.
Spatial distribution, source apportionment, and potential ecological risks of sixteen polycyclic aromatic hydrocarbons (PAHs) and seven endocrine disrupting compounds (EDCs) in the intertidal sediment at the Shuangtaizi Estuary, Bohai Sea of China were analyzed. Results showed that the total PAH concentrations ranged from 28.79 ng g? 1 dw to 281.97 ng g? 1 dw (mean: 115.92 ng g? 1 dw) and the total EDC concentrations from 0.52 ng g? 1 dw to 126.73 ng g? 1 dw (mean: 37.49 ng g? 1 dw). The distribution pattern for the PAHs was generally different from that of the EDCs possibly due to their distinct sources and n-octanol-/water partition coefficients (KOW). Qualitative and quantitative analytical results showed that PAH sources were mainly from a mixture of pyrogenic and petrogenic contributions. The higher levels at the southeast of Geligang indicated that the EDC pollutants may have mainly originated from the plastic industry and other chemical plants located along the Liao River. Ecological risk assessment revealed that PAHs exhibited low ecotoxicological effects, whereas EDCs, especially 4-tert-octylphenol and bisphenol A, had high ecological hazard to the estuarine biota.  相似文献   

15.
《Marine pollution bulletin》2009,58(6-12):313-324
This study investigated the seasonal and spatial dynamics of nutrients and phytoplankton biomass at 12 stations in Hong Kong (HK) waters during a three year period from 2004 to 2006 after upgraded sewage treatment and compared these results to observations before sewage treatment. Pearl River estuary (PRE) discharge significantly increased NO3 and SiO4 concentrations, particularly in western and southern waters when rainfall and river discharge was maximal in summer. Continuous year round discharge of sewage effluent resulted in high NH4 and PO4 in Victoria Harbour (VH) and its vicinity. In winter, spring and fall, the water column at all stations was moderately mixed by winds and tidal currents, and phytoplankton biomass was relatively low compared to summer. In summer, the mean surface phytoplankton chl biomass was generally >9 μg L−1 in most areas as a result of thermohaline stratification, and high nutrients, light, and water temperature. In summer, the potential limiting nutrient is PO4 in the most productive southern waters and it seldom decreased to limiting levels (∼0.1 μM), suggesting that phytoplankton growth may be only episodically limiting. The mean bottom dissolved oxygen (DO) remained >3.5 mg L−1 at most stations, indicating that the eutrophication impact in HK waters was not as severe as expected for such a eutrophic area. After the implementation of chemically enhanced primary sewage treatment in 2001, water quality in VH improved as indicated by a significant decrease in NH4 and PO4 and an increase in bottom DO. In contrast, there were an increase in chl a and NO3, and a significant decrease in bottom DO in southern waters in summer, suggesting that hypoxic events are most likely to occur in this region if phytoplankton biomass and oxygen consumption keep increasing and exceed the buffering capacity of HK waters maintained by monsoon winds, tidal mixing and zooplankton grazing. Therefore, future studies on the long-term changes in nutrient loading from PRE and HK sewage discharge will be crucial for developing future strategies of sewage management in HK waters.  相似文献   

16.
The subsidence rates of the Aegean margins during the Middle-Upper Pleistocene were evaluated based on new and historical seismic profiling data. High-resolution seismic profiling (AirGun, Sparker and 3.5 kHz) have shown that (at least) four major oblique prograding sequences can be traced below the Aegean marginal slopes at increasing subbottom depths. These palaeo-shelf break glacial delta sediments have been developed during successive low sea-level stands (LST prograding sequences), suggesting continuous and gradual subsidence of the Aegean margins during the last 400 ka. Subsidence rates of the Aegean margins were calculated from the vertical displacement of successive topset-to-foreset transitions (palaeo-shelf break) of the LST prograding sediment sequences.The estimated subsidence rates that were calculated in the active boundaries of the Aegean microplate (North Aegean margins, Gulfs of Patras and Corinth) are high and range from 0.7 to 1.88 m ka?1, while the lowest values (0.34–0.60 m ka?1) are related to the low tectonic and seismic activity margins like the margin of Cyclades plateau. Lower subsidence rates (0.34–0.90 m ka?1) were estimated for the period 146–18 ka BP (oxygen isotopic stages 6–2) and higher (1.46–1.88 m ka?1) for the period from 425 to 250 ka BP (oxygen isotopic stages 12/10–8). A decrease of about 50% of the subduction rates in the Aegean margins was observed during the last 400 ka.During the isotopic stages 8, 10, 11 and 12, almost the 50–60% of the present Aegean Sea was land with extensive drainage systems and delta plains and large lakes in the central and North Aegean. Marine transgression in the North Aegean was rather occurred during the isotopic 9 interglacial period. The estimated palaeomorphology should imply fan delta development and sediment failures in the steep escarpments of the North Aegean margins and high sedimentation rates and turbidite sediment accumulation in the basins. It is deduced that the Black Sea was isolated from the Mediterranean during the Pleistocene prior oxygen isotopic stage 5.  相似文献   

17.
《Marine pollution bulletin》2014,78(1-2):110-117
Sea microlayer (SML) and subsurface water (SSW) samples were collected around Xiamen Island to study the enrichment and partitioning of polycyclic aromatic hydrocarbons (PAHs). Total PAH concentrations ranged from 93.43 to 411.05 ng L−1 in the SML and 49.29–279.42 ng L−1 in the SSW. Compared with the results of previous studies before pollution control measurements, PAHs levels decreased significantly. The enrichment factors (EFs) of dissolved and particulate PAHs varied from 0.68 to 2.71 and 0.43–3.56. EFs showed the consistent enrichment trends with sites and exhibited different enrichment characteristics between 2 and 3 ring PAHs and 4 ring PAHs. Furthermore, the much higher concentrations of BaP (strong carcinogenicity) were accompanied by higher EFs in the SML samples from the Western Xiamen Harbour, which together indicated the risk of impacts to the fish eggs that usually float on the SML water after exposure to oil spills and combustion, contributed directly by the port and shipping activities.  相似文献   

18.
《Continental Shelf Research》2008,28(18):2574-2583
Horizontal distribution patterns of jack mackerel Trachurus japonicus larvae were investigated extensively in the East China Sea (ECS) along the shelf-break region between 26° and 30°N during February–March based on fine-scale larval sampling in 2002 and 2003. A total of 2363 T. japonicus ranging from 1.2 to 12.4 mm body length (BL) were collected at 310 bongo net sampling stations, of which larvae <10 mm BL accounted for 99.1%. In both years, newly hatched larvae (<3 mm BL) were concentrated in the shelf-break region mainly in the southern part of ECS between 26° and 27°N in warm water of 21–23 °C, suggesting that their primary spawning ground existed in and around this area. With growth, larvae were transported in two different directions, i.e., northward and northeastward, corresponding closely with the direction of the Kuroshio Branch Current north of Taiwan (KBCNT) and the Kuroshio, respectively. Replicate sampling cruises at 2 week intervals were conducted in 2003, and the larval distribution pattern changed significantly between the sampling cruises, suggesting that the transport process fluctuates over relatively short periods in relation to oceanographic processes. The transport speed by the KBCNT was estimated to be 0.13–0.28 knots based on the larval distribution, which is one order of magnitude slower than that by the Kuroshio (1.5–3 knots). Habitat temperature gradually declined with growth in both the Kuroshio and KBCNT, but in the KBCNT it was 1–2 °C lower than in the Kuroshio. Our results suggest that the two different larval transport processes lead to a significant difference in the transport route, habitat conditions (such as temperature and food), and site where young fish recruit to the demersal habitat, which will result in different survival and recruitment processes.  相似文献   

19.
《Marine pollution bulletin》2009,58(6-12):801-806
The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify 137Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured 137Cs levels were found to be very low (usually <1 Bq kg−1 wet wt) 137Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.  相似文献   

20.
《Continental Shelf Research》1999,19(9):1113-1141
Relationships among primary production, chlorophyll, nutrients, irradiance and mixing processes were examined along the salinity gradient in the Mississippi River outflow region. A series of six cruises were conducted during 1988–1992 at various times of year and stages of river discharge. Maximum values of biomass and primary production were typically observed at intermediate salinities and coincided with non-conservative decreases in nutrients along the salinity gradient. Highest values of productivity (>10 gC m−2 d−1) and biomass (>30 mg chlorophyll a m−3) were observed in April 1988, July–August 1990 and April–May 1992; values were lower in March and September 1991. Rates of primary production were apparently constrained by low irradiance and mixing in the more turbid, low salinity regions of the plume, and by nutrient limitation outside the plume. Highest values of primary production occurred at stations where surface nutrient concentrations exhibited large deviations from conservative mixing relationships, indicating that depletion of nutrients was related to phytoplankton uptake. Mixing and advection were important in determining the location and magnitude of primary production maxima and nutrient depletion. In addition to growth within plume surface waters, enhanced growth and/or retention of biomass may have occurred in longer residence time waters at the plume edge and/or beneath the surface plume. Vertical structure of some plume stations revealed the presence of subsurface biomass maxima in intermediate salinity water that was depleted in nutrients presumably by uptake processes. Exchange between subsurface water and the surface plume apparently contributed to the reduction in nutrients at intermediate salinities in the surface layer. DIN (=nitrate+nitrite+ammonium) : PO4 (=phosphate) ratios in river water varied seasonally, with high values in winter and spring and low values in late summer and fall. Periods of high DIN : PO4 ratios in river nutrients coincided with cruises when surface nutrient concentrations and their ratios indicated a high probability for P limitation. N limitation was more likely to occur at high salinities and during late summer and fall. Evidence for Si limitation was also found, particularly in spring.  相似文献   

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