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1.
The Mesozoic lithospheric mantle beneath the North China craton remains poorly constrained relative to its Palaeozoic and Cenozoic counterparts due to a lack of mantle xenoliths in volcanic rocks. Available data show that the Mesozoic lithospheric mantle was distinctive in terms of its major, trace element, and isotopic compositions. The recent discovery of mantle peridotitic xenoliths in Late Cretaceous mafic rocks in the Jiaodong region provides an opportunity to further quantify the nature and secular evolution of the Mesozoic lithospheric mantle beneath the region. These peridotitic xenoliths are all spinel-facies nodules and two groups, high-Mg# and low-Mg# types, can be distinguished based on textural and mineralogical features. High-Mg# peridotites have inequigranular textures, high Mg# (up to 92.2) in olivines, and high Cr# (up to 55) in spinels. Clinopyroxenes in the high-Mg# peridotites are generally LREE-enriched ((La/Yb)N>1) with variable REE concentrations, and have enriched Sr–Nd isotopic compositions (87Sr/86Sr = 0.7046–0.7087; 143Nd/144Nd = 0.5121–0.5126). We suggest that the high-Mg# peridotites are fragments of the Archaean and/or Proterozoic lithospheric mantle that underwent extensive interaction with both carbonatitic and silicate melts prior to or during Mesozoic time. The low-Mg# peridotites are equigranular, are typified by low Mg# ( < 90) in olivines, and by low Cr# ( < 12) in spinels. Clinopyroxenes from low-Mg# peridotites have low REE abundances (ΣREE = 12 ppm), LREE-depleted REE patterns ((La/Yb)N < 1), and depleted Sr–Nd isotopic features, in contrast to the high-Mg# peridotites. These geochemical characteristics suggest that the low-Mg# peridotites represent samples from the newly accreted lithospheric mantle. Combined with the data of mantle xenoliths from the Junan and Daxizhuang areas, a highly heterogeneous, secular evolution of the lithosphere is inferred for the region in Late Cretaceous time.  相似文献   

2.
橄榄石是地幔橄榄岩和辉石岩的主要组成矿物,但也经常以斑晶和捕虏晶的形式出现在玄武质岩石中。结合近年来在地幔橄榄岩的主要元素（如Mg和Fe）组成特征以及Li、Mg和Fe稳定同位素地球化学方面的研究成果,重点对橄榄石的地球化学特征与华北克拉通岩石圈地幔演化过程之间的联系进行了讨论,旨在加深对华北克拉通岩石圈地幔演化过程的理解。现有研究表明：地幔橄榄岩中橄榄石的矿物学特征、元素和同位素地球化学组成能够很好地指示岩石圈地幔的特征及其演化过程,因而具有重要的意义。对于克拉通地区的地幔橄榄岩来说,橄榄石的Mg#通常可以指示岩石圈地幔的属性,古老、难熔的地幔橄榄岩中的橄榄石一般具有较高的Mg#（〉92）,而新生的岩石圈地幔橄榄岩中的橄榄石则具有较低的Mg#（〈91）。因此,地幔橄榄岩中橄榄石的Mg#在一定程度上具有年龄意义。橄榄岩中橄榄石的Li、Mg和Fe同位素组成也可以明确指示岩石圈地幔的属性及其所经历的演化过程,正常地幔的δ7Li、δ26Mg和δ57Fe组成相对均一,如果上述同位素组成偏离正常地幔值,则说明岩石圈地幔经历了熔体/流体的交代作用。华北克拉通地区地幔橄榄岩捕虏体中橄榄石的Li、Mg和Fe同位素组成研究表明：该区的岩石圈地幔经历了多个阶段、不同来源的熔体/流体的改造过程。  相似文献   

3.
Despite the occurrence of highly variable lithium (Li) elemental distribution and isotopic fractionation in mantle mineral, the mechanism of Li heterogeneity and fractionation remains a controversial issue. We measured Li contents and isotopic compositions of olivine and clinopyroxene xenocrysts and phenocrysts from kamafugite host lavas, as well as minerals in melt pockets occurring as metasomatic products in peridotite xenoliths from the Western Qinling, central China. The olivine xenocrysts in the kamafugites show compositional zonation. The cores have high Mg# (100 × Mg/(Mg+Fe); 91.0–92.2) and Li abundances (5.63–21.7 ppm), low CaO contents (≤0.12 wt%) and low δ7Li values (−39.6 to −6.76‰), which overlap with the compositional ranges of the olivines in the melt pockets as well as those in peridotite xenoliths. The rims of the olivine xenocrysts display relatively low Mg# (85.9–88.2), high CaO contents (0.19–0.38 wt%) and high δ7Li values (18.3–26.9‰), which are comparable to the olivine phenocrysts (Mg#: 86.4–87.1; CaO: 0.20–0.28 wt%; Li: 12.4–36.8 ppm; δ7Li: 18.1–26.0‰) and the silicate-melt metasomatized olivines. The clinopyroxene phenocrysts and clinopyroxenes in the melt pockets have no distinct characteristics with respect to the Li abundances and δ7Li values, but show higher and lower CaO contents, respectively, than the clinopyroxenes from silicate and carbonatite metasomatized samples. These features indicate that Li concentration and isotopic signatures of the cores of the xenocrysts recorded carbonatite melt-peridotite reaction (carbonatite metasomatism) at mantle depth, and the variations in the rims probably resulted from xenocryst–host magma interaction during ascent. Our results reveal that the interaction with carbonatite and silicate melts gave rise to an increase in Li abundance in minerals of peridotite xenoliths at mantle depth or during transportation. In terms of δ7Li, the carbonatite and silicate melts produced remarkably contrasting δ7Li variations in olivine. Based on the systematic variations of Li abundances and Li isotopes in olivines, we suggest that the δ7Li value of olivine is a more important indicator than that of clinopyroxene in discriminating carbonatite and silicate melt interaction agents with peridotites.  相似文献   

4.
The geochemical characteristics of melt inclusions and their host olivines provide important information on the processes that create magmas and the nature of their mantle and crustal source regions. We report chemical compositions of melt inclusions, their host olivines and bulk rocks of Xindian basalts in Chifeng area, North China Craton. Compositions of both bulk rocks and melt inclusions are tholeiitic. Based on petrographic observations and compositional variation of melt inclusions, the crystallizing sequence of Xindian basalts is as follows: olivine (at MgO > ~5.5 wt%), plagioclase (beginning at MgO = ~5.5 wt%), clinopyroxene and ilmenite (at MgO < 5.0 wt%). High Ni contents and Fe/Mn ratios, and low Ca and Mn contents in olivine phenocrysts, combining with low CaO contents of relatively high MgO melt inclusions (MgO > 6 wt%), indicate that Xindian basalts are possibly derived from a pyroxenite source rather than a peridotite source. In the CS-MS-A diagram, all the high MgO melt inclusions (MgO > 6.0 wt%) project in the field between garnet + clinopyroxene + liquid and garnet + clinopyroxene + orthopyroxene + liquid near 3.0 GPa, further suggesting that residual minerals are mainly garnet and clinopyroxene, with possible presence of orthopyroxene, but without olivine. Modeling calculations using MELTS show that the water content of Xindian basalts is 0.3–0.7 wt% at MgO = 8.13 wt%. Using 20–25 % of partial melting estimated by moderately incompatible element ratios, the water content in the source of Xindian basalts is inferred to be ≥450 ppm, much higher than 6–85 ppm in dry lithospheric mantle. The melting depth is inferred to be ~3.0 GPa, much deeper than that of tholeiitic lavas (<2.0 GPa), assuming a peridotite source with a normal mantle potential temperature. Such melting depth is virtually equal to the thickness of lithosphere beneath Chifeng area (~100 km), suggesting that Xindian basalts are derived from the asthenospheric mantle, if the lithospheric lid effect model is assumed.  相似文献   

5.
A rare composite xenolith and abundant cumulative pyroxenites obtained from the Mesozoic Fangcheng basalts on the eastern North China Craton record a complex history of melt percolation and circulation in the subcontinental lithospheric mantle. The composite xenolith has a dunite core and an olivine clinopyroxenite rim. The dunite is of cumulative origin and has a granular recrystallized texture and extremely low Mg# [100 Mg/(Mg + Fe) = 81–82] contents in olivines. The olivine clinopyroxenite contains larger clinopyroxene and/or orthopyroxene with a few fine-grained olivine and tiny phlogopite, feldspar, and/or carbonate minerals interstitial to clinopyroxene. The clinopyroxene has low Mg# (83–85). Compositional similarity between dunitic olivine and pyroxenitic one indicates a sequential crystallization of dunite and pyroxenite from a precursor melt. Pyroxenite xenoliths include olivine websterites and clinopyroxenites, both are of cumulative origin. Estimation of the melt from major oxides in olivines and REE concentrations in clinopyroxenes in these composite and pyroxenite xenoliths suggests a derivation from subducted crustal materials, consistent with the highly enriched EMII-like Sr and Nd isotopic ratios observed in the pyroxenites. Occurrence of phlogopite, feldspar and carbonate minerals in some xenoliths requires the melt rich in alkalis (K, Na), silica and volatiles (water and CO2) at the latest stage as well, similar to highly silicic and potassic melts. Thus, the occurrence of these composite and pyroxenite xenoliths provides an evidence for voluminous injection of recycled crustal melts into the lithosphere beneath the southeastern North China Craton at the Late Mesozoic, a reason for the rapid lithospheric enrichment in both elemental and isotopic compositions.  相似文献   

6.
ABSTRACT

Mashhad granitoids and associated mafic microgranular enclaves (MMEs), in NE Iran record late early Mesozoic magmatism, was related to the Palaeo-Tethys closure and Iran-Eurasia collision. These represent ideal rocks to explore magmatic processes associated with Late Triassic closure of the Palaeo-Tethyan ocean and post-collisional magmatism. In this study, new geochronological data, whole-rock geochemistry, and Sr–Nd isotope data are presented for Mashhad granitoids and MMEs. LA–ICP–MS U–Pb dating of zircon yields crystallization ages of 205.0 ± 1.3 Ma for the MMEs, indicating their formation during the Late Triassic. This age is similar to the host granitoids. Our results including the major and trace elements discrimination diagrams, in combination with field and petrographic observations (such as ellipsoidal MMEs with feldspar megacrysts, disequilibrium textures of plagioclase), as well as mineral chemistry, suggest that MMEs formed by mixing of mafic and felsic magmas. The host granodiorite is a felsic, high K calc-alkaline I-type granitoid, with SiO2 = 67.5–69.4 wt%, high K2O (2.4–4.2 wt%), and low Mg# (42.5–50.5). Normalized abundances of LREEs and LILEs are enriched relative to HREEs and HFSEs (e.g. Nb, Ti). Negative values of whole-rock εNd(t) (?3 to ?2.3) from granitoids indicate that the precursor magma was generated by partial melting of enriched lithospheric mantle with some contributions from old lower continental crust. In the MMEs, SiO2 (53.4–58.2 wt%) is lower and Ni (3.9–49.7 ppm), Cr (0.8–93.9 ppm), Mg# (42.81–62.84), and εNd(t) (?2.3 to +1.4) are higher than those in the host granodiorite, suggesting a greater contribution of mantle-derived mafic melts in the genesis of MMEs.  相似文献   

7.

The Miocene lamproites of the West Kimberley region, Western Australia include olivine-leucite lamproites (≤10 wt% MgO) containing olivine and leucite microphenocrysts, and diamondiferous olivine lamproites (20–30 wt% MgO) containing olivine phenocrysts and larger (1–10 mm) olivine as mantle xenocrysts and dunite micro-xenoliths. Olivine phenocrysts and thin (<100 μm) magmatic rims define trends of decreasing Cr and Ni, and increasing Ca and Mn, with decreasing olivine Mg#, consistent with fractional crystallisation of olivine (and minor chromite). Many phenocrysts are zoned, and those with cores of similar Mg# and trace element abundances to the mantle xenocrysts may be xenocrysts overgrown by later olivine crystallised from the lamproite magma. Magmatic olivines Mg#91–92 are estimated to have been in equilibrium with olivine lamproite magma(s) containing ~22–24 wt% MgO. The xenocrystic mantle olivines Mg90–92.5 in the olivine lamproites are inferred from trace element abundances to be mostly derived from garnet peridotite with equilibration temperatures estimated from the Al-in-olivine thermometer (Bussweiler et al. 2017) to be ~1000–1270 °C at depths of 115–190 km. Olivines from the deeper lithosphere are less depleted (lower Mg#, higher Na, Al, P, Ti, Zr etc) than those at shallower depths, a feature suggested to reflect the combined effects of metasomatic re-enrichment of the craton roots (Ti, Fe, Zr etc) and increasing temperature with depth of origin (Na, Al, Ca). The West Kimberley lamproite olivines are not enriched in Li, as might be expected if their source regions contained continental sedimentary material as has been previously inferred from lamproite large-ion-lithophile trace elements, and Sr and Pb isotopes.

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8.
The destruction (or reactivation) of the North China Craton (NCC) is one of the important issues related to the Phanerozoic evolution of eastern China, although the processes of destruction remain debated. Two main mechanisms – delamination and thermal/chemical erosion – have been proposed based on the geochemistry of Mesozoic–Cenozoic basalts and entrained deep–seated xenoliths. A key criterion in distinguishing between these mechanisms is the nature of the melt, derived from delaminated crust or the asthenosphere, that modified the lithospheric mantle. Here we investigate the mechanism of destruction of the NCC based on mineral compositions and oxygen isotopic data from olivines, and strontium isotopic data for clinopyroxenes within websterite xenoliths from the Early Cretaceous Feixian basalts in the eastern NCC. Olivines in websterite xenoliths have higher Mg# (86–86.4), Ni content (2187–2468 ppm), and lower Ca (983–1134 ppm), Ti (58.1–76.1 ppm), and Mn (1478–1639 ppm) contents than olivine phenocrysts (Mg# = 71.0–77.3, Ni = 233–1038 ppm, Ca = 1286–2857 ppm, Ti = 120–300 ppm, and Mn = 2092–4106 ppm) from Late Cretaceous basalts. Additionally, olivines in websterite xenolith have δ18O values of 7.10 ± 0.21‰ to 8.40 ± 0.21‰, evidently higher than those of typical mantle-derived olivines. Similarly, orthopyroxenes (Opx) and clinopyroxenes (Cpx) in the websterite xenoliths have much higher Mg# (86.3–89.2 and 87.5–90.3, respectively), and Ni contents (1097–1491 ppm and 581–809 ppm, respectively) than orthopyroxene- and clinopyroxene-phenocrysts (Opx: Mg# = 82.2–83.9, Ni = 730–798 ppm; Cpx: Mg# = 74.2–84.6, Ni = 117–277 ppm) from Late Cretaceous basalts. The 87Sr/86Sr ratios of clinopyroxenes in the websterite xenoliths range from 0.70862 to 0.70979, and are much higher than those of clinopyroxene grains from peridotite xenoliths and basalts. These data indicate that olivines are the residue of ancient lithospheric mantle that was modified intensively by a melt derived from recycled continental crust, and that the silicic and calcic metasomatic melt might have been derived from the partial melting of the subducted Yangtze slab and delaminated lower crust of the NCC. The existence of recycled continental crust in the Mesozoic lithospheric mantle implies that delamination was an important mechanism of destruction of the NCC.  相似文献   

9.
The Denizli region of the Western Anatolia Extensional Province (WAEP) includes a typical example of intra-plate potassic magmatism. Lamproite-like K-rich to shoshonitic alkaline rocks erupted in the Upper Miocene-Pliocene in a tensional tectonic setting. The absence of Nb and Ta depletion, low Th/Zr and high Nb/Zr ratios and distinct isotopic values (i.e. low 87Sr/86Sr, 0.703523–0.703757; high 143Nd/144Nd, 0.512708–0.512784; high 206Pb/204Pb, 19.079–19.227, 207Pb/204Pb, 15.635–15.682, 208Pb/204Pb, 39.144–39.302) mark an anorogenic geochemical signature of the Denizli volcanics. All of the lavas are strongly enriched in large-ion-lithophile elements (e.g. Ba 1,100–2,200 ppm; Sr 1,900–3,100 ppm; Rb 91–295 ppm) and light rare-earth elements (e.g. LaN?=?319–464), with a geochemical affinity to ocean-island basalts and lack of a recognizable subduction signature or any evidence for crustal contamination. The restricted range of isotopic (Sr, Nd, Pb) ratios in both near-primitive (Mg# 66.7–77.2) and more evolved (Mg# 64.6–68.7) members of the Denizli volcanics signify their evolution from an isotopically equilibrated parental mantle source. Their high Dy/Yb and Rb/Sr values also suggest that garnet and phlogopite were present in the mantle source. Their strong EM-II signature, very low Nd model ages (0.44–049 Ga) and isotopic (Sr-Nd-Pb) values analogous to those of the Nyiragongo potassic basanites and kimberlites from the African stable continental settings, suggest that the parental melts that produced the Denizli volcanics are associated with very young and enriched mantle sources, which include both sublithospheric and enriched subcontinental lithospheric mantle melts. Mantle-lithosphere delamination probably played a significant role in the generation of these melts, and could be related to roll-back of the Aegean arc, lithospheric extension and asthenospheric mantle upwelling.  相似文献   

10.
The paper presents data on the composition of olivine macrocrysts from two Devonian kimberlite pipes in the Arkhangelsk diamond province: the Grib pipe (whose kimberlite belongs to type I) and Pionerskaya pipe (whose kimberlite is of type II, i.e., orangeite). The dominant olivine macrocrysts in kimberlites from the two pipes significantly differ in geochemical and isotopic parameters. Olivine macrocrysts in kimberlite from the Grib pipe are dominated by magnesian (Mg# = 0.92–0.93), Ti-poor (Ti < 70 ppm) olivine possessing low Ti/Na (0.05–0.23), Zr/Nb (0.28–0.80), and Zn/Cu (3–20) ratios and low Li concentrations (1.2–2.0 ppm), and the oxygen isotopic composition of this olivine δ18O = 5.64‰ is higher than that of olivine in mantle peridotites (δ18O = 5.18 ± 0.28‰). Olivine macrocrysts in kimberlite from the Pionerskaya pipe are dominated by varieties with broadly varying Mg# = 0.90–0.93, high Ti concentrations (100–300 ppm), high ratios Ti/Na (0.90–2.39), Zr/Nb (0.31–1.96), and Zn/Cu (12–56), elevated Li concentrations (1.9–3.4 ppm), and oxygen isotopic composition δ18O = 5.34‰ corresponding to that of olivine in mantle peridotites. The geochemical and isotopic traits of low-Ti olivine macrocrysts from the Grib pipe are interpreted as evidence that the olivine interacted with carbonate-rich melts/fluids. This conclusion is consistent with the geochemical parameters of model melt in equilibrium with the low-Ti olivine that are similar to those of deep carbonatite melts. Our calculations indicate that the variations in the δ18O of the olivine relative the “mantle range” (toward both higher and lower values) can be fairly significant: from 4 to 7‰ depending on the composition of the carbonate fluid. These variations were formed at interaction with carbonate fluid, whose δ18O values do not extend outside the range typical of mantle carbonates. The geochemical parameters of high-Ti olivine macrocrysts from the Grib pipe suggest that their origin was controlled by the silicate (water–silicate) component. This olivine is characterized by a zoned Ti distribution, with the configuration of this distribution between the cores of the crystals and their outer zones showing that the zoning of the cores and outer zones is independent and was produced during two episodes of reaction interaction between the olivine and melt/fluid. The younger episode (when the outer zone was formed) likely involved interaction with kimberlite melt. The transformation of the composition of the cores during the older episode may have been of metasomatic nature, as follows from the fact that the composition varies from grain to grain. The metasomatic episode most likely occurred shortly before the kimberlite melt was emplaced and was related to the partial melting of pyroxenite source material.  相似文献   

11.
The results of geochronological, mineralogical, petrographical, and geochemical study of the Ilbokich ultramafic lamprophyre are reported. The specific features in the mineral and chemical compositions of the studied ultramafic lamprophyre indicate that it can be regarded as a variety similar to aillikite, while other differences dominated by K-feldspar can be referred to damtjernite. According to Rb–Sr analysis, ultramafic lamprophyre dikes intruded at the turn of the Early and Middle Devonian, about 392 Ma ago. This directly proves the existence of Early Paleozoic alkali–ultramafic magmatism in the northern part of the southwest Siberian Platform. A finding of Devonian alkali–ultramafic lamprophyre is of dual predictive importance. On the one hand, it is indicative of the low probability of finding large diamond-bearing deposits in close association with aillikite. On the other hand, it can be indicative of a possible large Devonian diamond province in the studied territory, where diamondiferous kimberlite is structurally separated from aillikite.  相似文献   

12.
A classification suggested for alkaline ultramafic rocks of the Ary-Mastakh and Staraya Rechka fields, Northern Anabar Shield, is based on the modal mineralogical composition of the rocks and the chemical compositions of their rock-forming and accessory minerals. Within the framework of this classification, the rocks are indentified as orangeite and alkaline ultramafic lamprophyres: aillikite and damtjernite. To estimate how much contamination with the host rocks has modified their composition when the diatremes were formed, the pyroclastic rocks were studied that abound in xenogenic material (which is rich in SiO2, Al2O3, K2O, Rb, Pb, and occasionally also Ba) at relatively low (La/Yb)PM, (La/Sm)PM, and not as much also (Sm/Zr)PM and (La/Nb)PM ratios. The isotopic composition of the rocks suggests that the very first melt portions were of asthenospheric nature. The distribution of trace elements and REE indicates that one of the leading factors that controlled the diversity of the mineralogical composition of the rocks and the broad variations in their isotopic–geochemical and geochemical characteristics was asthenosphere–lithosphere interaction when the melts of the alkaline ultramafic rocks were derived. The melting processes involved metasomatic vein-hosted assemblages of carbonate and potassic hydrous composition (of the MARID type). The alkaline ultramafic rocks whose geochemistry reflects the contributions of enriched vein assemblages to the lithospheric source material, occur in the northern Anabar Shield closer to the boundary between the Khapchan and Daldyn terranes. The evolution of the aillikite melts during their ascent through the lithospheric mantle could give rise to damtjernite generation and was associated with the separation of a C–H–O fluid phase. Our data allowed us to distinguish the evolutionary episodes of the magma-generating zone during the origin of the Triassic alkaline ultramafic rocks in the northern Anabar Shield.  相似文献   

13.

New results of Rb–Sr and Sm–Nd isotope analyses have been obtained on samples of deformed peridotite xenoliths collected from the Udachnaya kimberlite pipe (Yakutia). The data obtained imply two main stages of metasomatic alteration of the lithospheric mantle base matter in the central part of the Siberian Craton. Elevated ratios of Sr isotopes may be considered as evidence of an ancient stage of metasomatic enrichment by a carbonatite melt. The acquired Nd isotope composition together with the geochemistry of the deformed peridotite xenoliths suggests that the second stage of metasomatic alteration took place shortly before formation of the kimberlite melt. The metasomatic agent of this stage had a silicate character and arrived from an asthenosphere source, common for the normal OIB type (PREMA) and the Group-I kimberlite.

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14.
The Shanwang and Qixia basalts lie within the North China block and were erupted in Miocene to Pliocene time (18.1 to 4.3 Ma) and Pliocene time (6.4 to 5.9 Ma), respectively. The Shanwang area lies astride the Tancheng-Lujiang (Tanlu) fault zone, a major lithospheric fault, whereas the Qixia area lies east of the fault zone. The basaltic rocks (alkali olivine basalts, basanites, nephelinites) carry abundant deep-seated xenoliths including spinel lherzolite (dominant), dunite, and pyroxenite, and a megacryst suite including augite, anorthoclase, phlogopite, ilmenite, and garnet. Xenoliths with coarse-grained microstructures are common in the Qixia xenolith suite, but are absent in Shanwang. Reconstructed bulk compositions of the lherzolites range from relatively depleted (<3% modal diopside) to fertile (>12% modal diopside). Equilibration temperatures of 850° to 1020°C indicate entrainment of these lherzolites from depths ≤45 km, within the lithosphere; the geotherm may have been higher beneath Shanwang. The Shanwang suite contains less-depleted lherzolites, and more pyroxenites, than the Qixia suite. The chondrite-normalized REE patterns in clinopyroxenes of the Shandong xenoliths vary from LREE depleted, through concave shaped, to LREE enriched; spidergrams for the clinopyroxenes can be divided into depleted, fertile, and metasomatic types. Progressive depletion in Na and Al is accompanied by depletion in moderately incompatible elements such as Y, Yb, and Zr, and an increase in Mg#. Ti and Zr in clinopyroxenes have not been affected by the metasomatic process, and MREE have been little disturbed, whereas the light rare-earth elements, Nb, and Sr have been strongly enriched during metasomatism; this suggests that carbonate-rich fluids/melts were the metasomatic agent. The mantle beneath the Shandong Peninsula sampled by these basalts is dominantly Phanerozoic in character rather than Archean or Proterozoic lithospheric mantle. This mantle probably represents a mixture of older lithospheric mantle and newly accreted material that replaced the Archean lithospheric keel through extension, thermal erosion, and fluid/melt metasomatism. The differences in micro-structures, chemistry, temperature, and fluid/melt activity between Shanwang and Qixia are ascribed to their spatial relationships to the Tanlu fault, which is a major translithospheric suture that hasplayed an important role in the Cenozoic replacement of the pre-existing Archean lithospheric mantle.  相似文献   

15.
The collision between the North and South China cratons in Middle Triassic time (240–225 Ma) created the world’s largest belt of ultrahigh-pressure (UHP) metamorphism. U–Pb ages, Hf isotope systematics and trace element compositions of zircons from the Xugou, Yangkou and Hujialing peridotites in the Sulu UHP terrane mainly record a ~470 Ma tectonothermal event, coeval with the Early Paleozoic kimberlite eruptions within the North China craton. This event is interpreted as the result of metasomatism by fluids/melts derived from multiple sources including a subducting continental slab. The peridotites also contain zircons with ages of ~3.1 Ga, and Hf isotope data imply a component ≥3.2 Ga old. Most zircon Hf depleted mantle model ages are ~1.3 Ga, suggesting that the deep subcontinental lithospheric mantle beneath the southeastern margin of the North China craton experienced a intense mid-Mesoproterozoic metasomatism by asthenospheric components, similar to the case for the eastern part of this craton. Integrating data from peridotites along the southern margin of the craton, we argue that the deep lithosphere of the cratonic margin (≥3.2 Ga old), from which the Xugou, Yangkou and Hujialing peridotites were derived, experienced Proterozoic metasomatic modification, followed by a strong Early Paleozoic (~470 Ma) tectonothermal event and the Early Mesozoic (~230 Ma) collision and northward subduction of the Yangtze craton. The Phanerozoic decratonization of the eastern North China craton, especially along its southern margin, was not earlier than the Triassic continental collision. This work also demonstrates that although zircons are rare in peridotitic rocks, they can be used to unravel the history of specific lithospheric domains and thus contribute to our understanding of the evolution of continental cratons and their margins.  相似文献   

16.
Although the diamond potential of cratons is linked mainly to thick and depleted Archean lithospheric keels, there are examples of craton-edge locations and circum-cratonic Proterozoic terranes underlain by diamondiferous mantle. Here, we use the results of comprehensive major and trace-element studies of detrital garnets from diamond-rich Late Triassic (Carnian) sedimentary rocks in the northeastern Siberia to constrain the thermal and chemical state of the pre-Triassic mantle and its ability to sustain the diamond storage. The studied detrital mantle-derived garnets are dominated by low- to medium-Cr lherzolitic (～45%) and low-Cr megacrystic (～39%) chemistries, with a significant proportion of eclogitic garnets (～11%), and only subordinate contribution from harzburgitic garnets (～5%) with variable Cr2O3 contents (1.2–8.4 wt.%). Low-Cr megacrysts display uniform, “normal” rare-earth element (REE) patterns with no Eu/Eu* anomalies, systematic Zr and Ti enrichment (mainly within 2.5–5), which are evidence of their crystallization from deep metasomatic melts. Lherzolitic (G9) garnets exhibit normal or humped to MREE-depleted sinusoidal REE patterns and elevated Nd/Y (up to 0.33–0.41) and Zr/Y ratios (up to 7.62). Rare low- to high-Cr harzburgitic (G10) garnets have primarily “depleted”, sinusoidal REE-patterns, low Ti, Y and HREE, but vary significantly in Zr-Hf, Ti and MREE-HREE contents, Nd/Y (within 0.1–2.4) and Zr/Y (1.53–19.9) ratios. The observed trends of chemical enrichment from the most depleted, harzburgitic garnets towards lherzolitic (including high-Ti high-Cr G11-type) garnets and megacrysts result from either voluminous high-temperature metasomatism by plume-derived silicate melts or recurrent mobilization of less voluminous kimberlitic or related carbonated mantle melts, rather than the initially primitive, fertile nature of the Proterozoic SCLM. Calculated Ni-in-garnet temperatures (primarily within ～1150–1250 °C) indicate their derivation from at least ～220 km thick Cr-undersaturated lithosphere at the relevant Devonian to Triassic thermal flow of ～45 mW/m2 or cooler. We suggest the existence of rare harzburgitic domains in the primarily lherzolitic diamond-facies SCLM beneath the northeastern Siberian craton at least by Triassic, whereas the abundance of eclogitic garnets, predominance of E-type inclusions in placer diamonds and specific morphologies argue for diamondiferous eclogites occurring within a ～50–65 kbar diamond window of the Olenek province by the same time.  相似文献   

17.
The Cenozoic Haoti kamafugite field (23 Ma) is situated at the western Qinling Orogen, Gansu Province in China, which is a conjunction region of the North China Craton, the Yangtze Craton and the Tibetan Plateau. Fresh peridotitic xenoliths entrained in these volcanic rocks provide an opportunity to study the nature and processes of the lithospheric mantle beneath the western Qinling. These xenoliths can be divided into two groups based on the petrological features and mineral compositions, type 1 and type 2. Type 1 xenoliths with strongly deformed texture have higher Fo (90–92.5) contents in olivines, Mg# (91–94) and Cr# (15–35) of clinopyroxenes, and Cr# (36–67) of spinels than the weakly deformed type 2 xenoliths, which have the corresponding values of 89–90, 89–91.5, 10–15 and 5–15 in minerals, respectively. CaO contents in fine-grained olivines are slightly higher than 0.10 wt% compared with coarse-grained ones (less than 0.10 wt%). Fine-grained clinopyroxenes have low Al2O3 + CaO contents (generally <23 wt%) relative to coarse-grained ones (>23 wt%). Fo contents in fine-grained olivines mainly in the melt pocket of the type 1 xenoliths are higher than those in coarse-grained ones, which is somewhat contrary to the type 2 xenoliths without melt pocket. Clinopyroxenes of the type 2 display higher Na2O contents (1.7–1.9 wt%) than those of the type 1 (<1.4 wt%). P–T estimations reveal that the type 1 xenoliths give temperature in range of 1106–1187 °C and pressure of 21–26 kbar and that relatively low temperature (907 and 1022 °C) and pressure (19.0 and 18.5 kbar) for the type 2 xenoliths. The type 1 xenoliths are characterized by depletion due to high degree of partial melting (>10%), modal metasomatic and deformed characteristics, and may represent the old refractory lithospheric mantle. In contrast, the type 2 peridotites show fertile features with low degree of partial melting (<5%) and may represent the newly-accreted lithospheric mantle. The lithospheric mantle beneath the western Qinling underwent partial melting, recrystallization, deformation and metasomatism due to asthenospheric upwelling and the latest decompression responding to the Cenozoic extensive tectonic environment. These processes perhaps are closely related to the evolution of Tibetan Plateau caused by the India-Asian collision.  相似文献   

18.
《Gondwana Research》2016,29(4):1344-1360
Using free-board modeling, we examine a vertically-averaged mantle density beneath the Archean–Proterozoic Siberian Craton in the layer from the Moho down to base of the chemical boundary layer (CBL). Two models are tested: in Model 1 the base of the CBL coincides with the LAB, whereas in Model 2 the base of the CBL is at a 180 km depth. The uncertainty of density model is < 0.02 t/m3 or < 0.6% with respect to primitive mantle. The results, calculated at in situ and at room temperature (SPT) conditions, indicate a heterogeneous density structure of the Siberian lithospheric mantle with a strong correlation between mantle density variations and the tectonic setting. Three types of cratonic mantle are recognized from mantle density anomalies. ‘Pristine’ cratonic regions not sampled by kimberlites have the strongest depletion with density deficit of 1.8–3.0% (and SPT density of 3.29–3.33 t/m3 as compared to 3.39 t/m3 of primitive mantle). Cratonic mantle affected by magmatism (including the kimberlite provinces) has a typical density deficit of 1.0–1.5%, indicative of a metasomatic melt-enrichment. Intracratonic sedimentary basins have a high density mantle (3.38–3.40 t/m3 at SPT) which suggests, at least partial, eclogitization. Moderate density anomalies beneath the Tunguska Basin imply that the source of the Siberian LIP lies outside of the Craton. In situ mantle density is used to test the isopycnic condition of the Siberian Craton. Both CBL thickness models indicate significant lateral variations in the isopycnic state, correlated with mantle depletion and best achieved for the Anabar Shield region and other intracratonic domains with a strongly depleted mantle. A comparison of synthetic Mg# for the bulk lithospheric mantle calculated from density with Mg# from petrological studies of peridotite xenoliths from the Siberian kimberlites suggests that melt migration may produce local patches of metasomatic material in the overall depleted mantle.  相似文献   

19.
We present data on volatile (S, F and Cl) and major element contents in olivine-hosted melt inclusions (MIs) from alkaline basaltic tephras along the Quaternary Payenia backarc volcanic province (~34°S–38°S) of the Andean Southern Volcanic Zone (SVZ). The composition of Cr-spinel inclusions and host olivines in Payenia are also included to constrain any variations in oxygen fugacity. The variation of potassium, fluorine and chlorine in MIs in Payenia can be modelled by partial melting (1–10%) of a variously metasomatised mantle. The high chlorine contents in MIs (up to 3200 ppm) from Northern Payenia require addition of subduction-related fluids to a mantle wedge, whereas volatile signatures in the southern Payenia are consistent with derivation from an enriched OIB source. Cl and Cl/K ratios define positive correlations with host olivine fosterite content (Fo80-90) that cannot be explained by olivine fractionation, degassing and/or degree of mantle melting. Neither can the correlation between SiO2 and TiO2 in the MIs and host olivine Fo-content be explained by magmatic differentiation processes. Instead these correlations essentially require a south to north mantle source transition from a low Mg# pyroxenite (from recycled eclogite) to a high Mg# fluid metasomatised peridotite. The Cl/K and S/K ratios in Payenia MIs extend from enriched OIB-like signatures (south) to Andean SVZ arc like signatures (north). We show that the northward increase in S, Cl and S/K is coupled to a northward increase in melt oxidation states and thus in Fe3+/Fetot ratios in the magmas. The increase in oxidation state also correlates with an increase of Mn/Fe (olivine) ratios. We calculate that 25% of the apparent north–south pyroxenite–peridotite source variation in Payenia (based on olivine Mn/Fe ratios) can be explained by the south to north variation in melt oxidation states.  相似文献   

20.
Interaction between basaltic melts and peridotites has played an important role in modifying the lithospheric and asthenospheric mantle during magma genesis in a number of tectonic settings. Compositions of basaltic melts vary considerably and may play an important role in controlling the kinetics of melt–peridotite interaction. To better understand the effect of melt composition on melt–peridotite interaction, we conducted spinel lherzolite dissolution experiments at 2 GPa and 1,425 °C using the dissolution couple method. The reacting melts include a basaltic andesite, a ferro-basalt, and an alkali basalt. Dissolution of lherzolite in the basaltic andesite and the ferro-basalt produced harzburgite–lherzolite sequences with a thin orthopyroxenite layer at the melt–harzburgite interface, whereas dissolution of lherzolite in the alkali basalt produced a dunite–harzburgite–lherzolite sequence. Systematic variations in mineral compositions across the lithological units are observed. These mineral compositional variations are attributed to grain-scale processes that involve dissolution, precipitation, and reprecipitation and depend strongly on reacting melt composition. Comparison of mineral compositional variations across the dissolution couples with those observed in mantle xenoliths from the North China Craton (NCC) helps to assess the spatial and temporal variations in the extent of siliceous melt and peridotite interaction in modifying the lithospheric mantle beneath the NCC. We found that such melt–rock interaction mainly took place in Early Cretaceous, and is responsible for the enrichment of pyroxene in the lithospheric mantle. Spatially, siliceous melt–peridotite interaction took place in the ancient orogens with thickened lower crust.  相似文献   

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