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1.
Noncondensible gases from hot springs, fumaroles, and deep wells within the Valles caldera geothermal system (210–300°C) consist of roughly 98.5 mol% CO2, 0.5 mol% H2S, and 1 mol% other components. 3He/4He ratios indicate a deep magmatic source (R/Ra up to 6) whereas δ13C–CO2 values (−3 to −5‰) do not discriminate between a mantle/magmatic source and a source from subjacent, hydrothermally altered Paleozoic carbonate rocks. Regional gases from sites within a 50-km radius beyond Valles caldera are relatively enriched in CO2 and He, but depleted in H2S compared to Valles gases. Regional gases have R/Ra values ≤1.2 due to more interaction with the crust and/or less contribution from the mantle. Carbon sources for regional CO2 are varied. During 1982–1998, repeat analyses of gases from intracaldera sites at Sulphur Springs showed relatively constant CH4, H2, and H2S contents. The only exception was gas from Footbath Spring (1987–1993), which experienced increases in these three components during drilling and testing of scientific wells VC-2a and VC-2b. Present-day Valles gases contain substantially less N2 than fluid inclusion gases trapped in deep, early-stage, post-caldera vein minerals. This suggests that the long-lived Valles hydrothermal system (ca. 1 Myr) has depleted subsurface Paleozoic sedimentary rocks of nitrogen. When compared with gases from many other geothermal systems, Valles caldera gases are relatively enriched in He but depleted in CH4, N2 and Ar. In this respect, Valles gases resemble end-member hydrothermal and magmatic gases discharged at hot spots (Galapagos, Kilauea, and Yellowstone).  相似文献   

2.
Analysis of nitrogen and light noble gases in a large sample of glass (lithology C) from the antarctic shergottite EETA 79001 yields a minimumδ15N > +300‰ for the isotopic composition of nitrogen trapped in the glass. The new data fall on the mixing line through the martian atmospheric composition defined byδ15N vs.40Ar/14N for two smaller samples analyzed previously. The results from all three samples are consistent with a two-component nitrogen system in which 84 ppb of trapped martian atmospheric N is mixed in variable proportions with another, more thermally labile N component during stepped heating. This second component, which appears to be indigenous to the glass rather than adsorbed from air and is present in amounts that vary by more than a factor of 3 from sample to sample, may represent volatiles from the martian interior. Data from crystalline phases of several SNC meteorites indicate that the indigenous gas may haveδ15N < −35‰ and36Ar/14N 3 × 10−6, similar to the enstatite chondrites.Neon compositions in EETA 79001 glass samples suggest an earth-like value of 10.1 ± 0.7 for the unknown20Ne/22Ne ratio in the martian atmosphere. The nitrogen-argon correlation systematics yield trapped40Ar/36Ar= 2260 ± 200, within error of the Viking value. There is evidence that36Ar/38Ar in the martian atmosphere is4.1 ± 0.2, strikingly different from terrestrial or typical chondritic ratios near 5.3. Attribution of this low value to excess38Ar generated over martian history by galactic cosmic-ray (GCR) spallation of surface materials would be difficult for a number of reasons, among them the excessive GCR fluences required and the absence of a corresponding21Ne excess.  相似文献   

3.
Intensive gas emanations occur throughout the island of Vulcano, Italy. Sharp fluctuations recorded in the crater gas composition suggest the presence of two separate volcanic reservoirs and continuous mixing with another source, “crustal” waters. This mixing differs between the beach and crater fumaroles. Gas samples from three crater fumaroles with temperatures ranging from 200 to 550 ° C were sampled repeatedly over a one year period. During the same interval of time, six samples from submarine and subaerial beach fumaroles and water well gases were also sampled. Gases from one crater fumarole (F5) showed variations of (3He/4He)fumarole to (3He/4He)air between 5 and 6 correlated with variations of several chemical species. High 3He/4He ratios for the beach fluids, similar to those of crater fluids, suggest the existence of a unique large magmatic reservoir at depth feeding both the crater and beach intermediate reservoirs. However, temporal changes clearly indicate variable degrees of fluids mixing, and the geographic distribution of the 3He/4He ratios as well as the chemical composition of the fluids suggest the existence between the magma reservoir and the surface of two intermediate different reservoirs, independently related to crater and to beach fumaroles.  相似文献   

4.
Physical, chemical and isotopic parameters were measured in fumaroles at the Vulcano crater and in drowned fumaroles near the beach. The data were used to define boundary conditions for possible conceptual models of the system.Crater fumaroles: time variations of CO2 and SO2 concentrations indicate mixing of saline gas-rich water with local fresh water. Cl/Br ratios of 300– 400 favour sea-water as a major source for Cl, Brand part of the water in the fumaroles. Cl concentrations and D values revealed, independently, amixing of 0.75 sea-water with 0.25 local freshwaterin furmarole F-5 during September 1982.Patterns of parameter correlation and mass balances reveal that CO2, S, NH3 and B originate from sources other than sea water. The CO2 value of 13C = – 2%o favours, at least partial, origin from decomposition of sedimentary rocks rather than mantle-derived material. Radiogenic4He(1.3 × lO–3 ccSTP/g water) and radiogenic40Ar(10.6 × 10–4 ccSTP/g water) are observed, (4He/40Ar)radiogenic = 1.2, well in the range of values observed in geothermal systems.Drowned fumaroles: strongly bubbling gas at a pond and at the beachappears to have the same origin and initial compositionas the crater fumaroles (2 km away). The fumarolic gas is modified by depletion of the reactive gases, caused by dissolution in shallow-water. Atmospheric Ne, Ar, Kr and Xe are addeden route, some radiogenic He and Ar are maintained. The Vulcano system seems to be strongly influenced by the contribution of sea-water and decomposition of sedimentary rocks. Evidence of magmatic contributions is mainly derived from heat.  相似文献   

5.
The isotopic composition and abundances of He, Ne and Ar have been measured in a sequence of vertically stacked gas reservoirs at Hajduszoboszlo and Ebes, in the Pannonian Basin of Hungary. The gas reservoirs occur at depths ranging from 727 to 1331 m, are CH4 dominated and occupy a total rock volume of approximately 1.5 km3. There are systematic variations in both major species abundances and rare gas isotopic composition with depth: CO2 and N2 both increase from 0.47 and 1.76% to 14.1 and 30.5%, respectively, and 40Ar/36Ar and 21Ne/22Ne increase systematically from 340 and 0.02990 at 727 m to 1680 and 0.04290 at 1331 m. A mantle-derived He component between 2 and 5% is present in all samples, the remainder is crustal-radiogenic He. The Ar and Ne isotope variations arise from mixing between atmosphere-derived components in groundwater, and crustally produced radiogenic Ar and Ne. The atmosphere-derived 40Ar and 21Ne decreases from 85 and 97% of the total 40Ar and 21Ne at 727 m to 18 and 68% at 1331 m. The deepest samples are shown to have both atmosphere-derived and radiogenic components close to the air-saturated water and radiogenic production ratios. The shallowest samples show significant fractionation of He/Ar and Ne/Ar ratios in atmosphere-derived and radiogenic rare gas components, but little or no fractionation of He/Ne ratios. This suggests that diffusive fractionation of rare gases is relatively unimportant and that rare gas solubility partitioning between CH4 and H2O phases controls the observed rare gas elemental abundances.The total abundance of atmosphere-derived and radiogenic rare gas components in the Hajduszoboszlo gas field place limits on the minimum volume of groundwater that has interacted with the natural gas, and the amount of crust that has degassed and supplied radiogenic rare gases. The radiogenic mass balance cannot be accounted for by steady state production either within the basin sediments or the basement complex since basin formation. The results require that radiogenic rare gases are stored at their production ratios on a regional scale and transported to the near surface with minimal fractionation. The minimum volume of groundwater required to supply the atmosphere-derived rare gases would occupy a rock volume of some 1000 km3 (assuming an average basin porosity of 5%), a factor of 670 greater than the reservoir volume. Interactions between groundwater and the Hajduszoboszlo hydrocarbons has been on a greater scale than often envisaged in models of hydrocarbon formation and migration.  相似文献   

6.
This study compares the Isis II satellite measurements of the electron density and temperature, the integral airglow intensity and volume emission rate at 630 nm in the SAR arc region, observed at dusk on 4 August, 1972, in the Southern Hemisphere, during the main phase of the geomagnetic storm. The model results were obtained using the time dependent one-dimensional mathematical model of the Earth’s ionosphere and plasmasphere (the IZMIRAN model). The major enhancement to the IZMIRAN model developed in this study to explain the two component 630 nm emission observed is the analytical yield spectrum approach to calculate the fluxes of precipitating electrons and the additional production rates of N+2, O+2, O+(4S), O+(2D), O−(2P), and O+(2P) ions, and O(1D) in the SAR arc regions in the Northern and Southern Hemispheres. In order to bring the measured and modelled electron temperatures into agreement, the additional heating electron rate of 1.05 eV cm−3 s−1 was added in the energy balance equation of electrons at altitudes above 5000 km during the main phase of the geomagnetic storm. This additional heating electron rate determines the thermally excited 630 nm emission observed. The IZMIRAN model calculates a 630 nm integral intensity above 350 km of 4.1 kR and a total 630 nm integral intensity of 8.1 kR, values which are slightly lower compared to the observed 4.7 kR and 10.6 kR. We conclude that the 630 nm emission observed can be explained considering both the soft energy electron excited component and the thermally excited component. It is found that the inclusion of N2(v > 0) and O2(v > 0) in the calculations of the O+(4S) loss rate improves the agreement between the calculated Ne and the data on 4 August, 1972. The N2(v > 0) and O2(v > 0) effects are enough to explain the electron density depression in the SAR arc F-region and above F2 peak altitude. Our calculations show that the increase in the O+ + N2 rate factor due to the vibrationally excited nitrogen produces the 5–19% reductions in the calculated quiet daytime peak density and the 16–24% decrease in NmF2 in the SAR arc region. The increase in the O+ + N2 loss rate due to vibrationally excited O2 produces the 7–26% decrease in the calculated quiet daytime peak density and the 12–26% decrease in NmF2 in the SAR arc region. We evaluated the role of the electron cooling rates by low-lying electronic excitation of O2(a1δg) and O2(b1σg+), and rotational excitation of O2, and found that the effect of these cooling rates on Te can be considered negligible during the quiet and geomagnetic storm period 3–4 August, 1972. The energy exchange between electron and ion gases, the cooling rate in collisions of O(3P) with thermal electrons with excitation of O(1D), and the electron cooling rates by vibrational excitation of O2 and N2 are the largest cooling rates above 200 km in the SAR arc region on 4 August, 1972. The enhanced IZMIRAN model calculates also number densities of N2(B3πg+), N2(C3πu), and N2(A3σu+) at several vibrational levels, O(1S), and the volume emission rate and integral intensity at 557.7 nm in the region between 120 and 1000 km. We found from the model that the integral integral intensity at 557.7 nm is much less than the integral intensity at 630 nm.  相似文献   

7.
Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in3He/4He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.  相似文献   

8.
Results are presented on scubadiving investigations carried out on thermal manifestations in the area of Panarea (Aeolian Islands). The area investigated falls inside a caldera which extends from the main island to the group of islets located to the northeast. The distribution of the gaseous manifestations is regulated by the NE-SW, NW-SE and N-S regional tectonic directrices, through which the more recent basic magma intruded, giving rise to dikes and pillow lavas. fO2-temperature relation of the gases sampled in the investigated area was calculated to be: logfO2 = 11−24,593/T which indicates that a buffering mechanism acted on the gases as they cooled down during their ascent. The high 3He/4He ratio (6 × 10−6) and the δ13C = −3.2%. (PDB), suggest the presence of a magmatic component in the gas feeding the investigated manifestations. The above relations and the almost constant high He/N2 ratio suggest that all the fumaroles are fed by the same deep hot fluids. On the basis of both the chemical characters of the fluids and the geothermo-barometric data, a deep geothermal body, having a temperature of about 240°C, is recognized. Two other shallower thermal aquifers, with a temperature of 170–210°C, are identified. A circulation pattern of the geothermal fluids is also proposed. On the basis of calculations regarding the convective energy released by the geothermal system of Panarea, and the magmatic mass responsible for the positive gravimetric anomaly of the area, it was estimated that the last volcanic activity took place less then 10,000 years ago.  相似文献   

9.
Isotopic and elemental compositions of rare gases in various types of gas samples collected in the Japanese Islands were investigated. Excess3He was found in most samples. Many samples showed a regionally uniform high3He/4He ratio of about 7 times the atmospheric ratio. The He concentrations varied from 0.6 to 1800 ppm, and they were low in CO2-rich gases and high in N2-rich gases. Ne isotopic deviations from the atmospheric Ne were detected in most volcanic gases. The deviations and the elemental abundance patterns in volcanic gases can be explained by a mixing between two components, one is mass fractionated rare gases and the other is isotopically atmospheric and is enriched in heavy rare gas elements. Ar was a mixture of mass fractionated Ar, atmospheric Ar and radiogenic Ar, and the contribution of radiogenic40Ar was small in all samples. Except for He, elemental abundance patterns were progressively enriched in the heavier rare gases relative to the atmosphere. Several samples were highly enriched in Kr and Xe relative to the abundance pattern of dissolution equilibrium of atmospheric rare gases in water. The component which is highly enriched in heavy rare gases may be released from sedimentary materials in the crust.  相似文献   

10.
A detailed analysis of published data on the N2, Ar, and He content and Ar and He isotopic composition of fumarolic fluids from Vulcano crater (south Italy) supports a model with two endmembers comprising magmatic and hydrothermal fluids with correspondingly low and high H2O content. The magmatic component with the highest 3He/4He and highest absolute concentrations of N2, Ar, and He also has the lowest N2/Ar and N2/He ratios (∼300 and ∼500, respectively). In contrast, the hydrothermal endmember, with the lower 3He/4He and lower absolute N2, Ar, and He abundances, has high N2/Ar (∼1,000) and high N2/He (>3,000) ratios. The hydrothermal component is also characterized by the highest 40Ar/36Ar ratios (>1,000) and is proposed to be the main carrier of metamorphic gases from the arc crust.  相似文献   

11.
The groundwaters of the Great Artesian Basin (Australia) have been previously shown to be accumulating in-situ production helium for groundwaters ages < 50 kyr and an external helium flux equivalent to whole crustal production for groundwater ages > 100 kyr [1,2]. New helium isotope measurements show that the observed in-situ production helium (3He/4He 1.6 × 10−8) is isotopically distinct from the crustal degassing helium flux (3He/4He 6.6 × 10−8). Furthermore, the crustal degassing helium isotope ratio is marginally in excess of the whole crustal production ratio (3He/4He= 3.5 × 10−8) and the production ratio in a variety of continental rock types. This suggests that the upper limit on volatile transport across the mantle-crust boundary beneath the (relatively) stable and “complacent” Australian continent can be characterized by a “conductive-diffusive” helium/heat flux ratio of 2.6 × 1064He atoms mW−1 s−1 which is two orders of magnitude less than the “intrusive-volcanic” ratio of 2.9 × 1084He atoms mW−1 s−1 measured at the Galapagos [16]. These results constrain the transcrustal mantle degassing fluxes of4He and40Ar to be much less than the mid-ocean ridge degassing fluxes; which are much less than the degassing of4He and40Ar from continental crust. Thus, the degassing of the Earth's interior is dominated by magmatic processes but the dominant fluxes of4He and40Ar to the atmosphere must come from the continental crust.  相似文献   

12.
Detailed geochemistry supported by geologic mapping has been used to investigate Sulphur Springs, an acid-sulfate hot spring system that issues from the western flank of the resurgent dome inside Valles Caldera. The most intense activity occurs at the intersection of faults offsetting caldera-fill deposits and post-caldera rhyolites. Three geothermal wells in the area have encountered pressures <1 MPa and temperatures of 200°C at depths of 600 to 1000 m. Hot spring and fumarole fluids may discharge at boiling temperatures with pH 1.0 and SO4 8000 mg/l. These conditions cause argillic alterations throughout a large area.Non-condensible gases consist of roughly 99% CO2 with minor amounts of H2S, H2, and CH4. Empirical gas geothermometry suggests a deep reservoir temperature of 215 to 280°C. Comparison of 13C and 18O between CaCO3 from well cuttings and CO2 from fumarole steam indicates a fractionation temperature between 200 and 300°C by decarbonation of hydrothermally altered Paleozoic limestone and vein calcite in the reservoir rocks. Tritium concentrations obtained from steam condensed in a mudpot and deep reservoir fluids (Baca #13, 278°C) are 2.1 and 1.0 T.U. respectively, suggesting the steam originates from a reservoir whose water is mostly >50 yrs old. Deuterium contents of fumarole steam, deep reservoir fluid, and local meteoric water are practically identical even though 18O contents range through 4‰, thus, precipitation on the resurgent dome of the caldera could recharge the hydrothermal system by slow percolation. From analysis of D and 18O values between fumarol steam and deep reservoir fluid, steam reaches the surface either (1) by vaporizing relatively shallow groundwater at 200°C or (2) by means of a two-stage boiling process through an intermediate level reservoir at roughly 200°C.Although many characteristics of known vapor-dominated geothermal systems are found at Sulphur Springs, fundamental differences exist in temperature and pressure of our postulated vapor-zone. We propose that the reservoir beneath Sulphur Springs is too small or too poorly confined to sustain a “true” vapor-dominated system and that the Sulphur Springs system may be a “dying” vapor-dominated system that has practically boiled itself dry.  相似文献   

13.
We have analysed volatiles (H2O, He, Ar, CO2) in differentiated (basaltic andesite, dacite) volcanic glasses dredged at a depth of ca. 2000 m in the eastern part of the Manus Basin between 151°20′ and 152°10′ E. These samples have Sr–O–B isotopic ratios that show that they most likely represent lavas evolved from a common magma source. Since these glasses are very fresh, they provide a unique opportunity to study the behaviour of magmatic volatiles during assimilation–fractional crystallisation–degassing (AFCD). The samples are highly vesicular (up to 18%) and the volatiles trapped in vesicles consist predominantly of H2O with minor amounts of CO2, and the concentration of water in the glasses indicates that H2O saturation was attained. Rare gases except helium are atmospheric in origin, and the 3He/4He ratios and the CO2/3He ratios are respectively lower and higher than those typical of Mid-Ocean Ridge Basalt (MORB), and appear to correlate with the degree of differentiation. AFCD allows efficient degassing of mantle-derived volatiles and contribution of crust-derived and atmosphere-derived volatiles. Given the widespread occurrence of differentiated magmatism at arcs, we suggest that AFCD is responsible for large-scale occurrence of 3He-rich crustal fluids and of atmospheric-like rare gases in arc emanations, and that most of the volatiles are lost continuously during fractional crystallisation, rather than catastrophically during eruptions.  相似文献   

14.
The vesicle size distribution (VSD) and rare gas abundances in popping rocks from 14°N on the Mid-Atlantic Ridge provide constraints on the behavior of volatiles during ridge crest volcanism. These popping rocks, which contain 16–18 volume percent vesicles, are rare mid-ocean ridge basalt (MORB) magmas which appear to have retained much of their volatile inventory. The logarithm of vesicle population density displays the same linear correlation with decreasing size in two of the samples studied. This implies that continuous and simultaneous nucleation and bubble growth have occurred during magma ascent, with no significant perturbations due to accumulation, coalescence or loss of bubbles. In contrast, most MORB magmas display low vesicularities and we suggest that they have suffered some degree of pre-eruptive vesicle loss. We tentatively propose that large vesicles are produced by coalescence when MORB melt is at rest in chambers and conduits, and may be lost during early gas-rich episodes. Most MORB would represent residual liquids which erupt after vesicle loss has occurred, whereas popping rocks would represent a rare case where physical sorting of vesicles from melt did not occur, because storage in a magma chamber did not occur.The rare gas concentrations in the studied popping rocks are the highest yet measured in glassy ridge basalts ([He] > 50 μccSTP/g). The rare gas abundance pattern of these popping rocks probably resembles the pattern for non-vesiculated MORB magma and potentially reflects that of the depleted mantle source. This pattern is similar to the “mean MORB” pattern (computed from MORB glasses with40Ar/36Ar > 10,000) although a higher enrichment in He (and possibly Ne) compared to the heavier rare gases is observed in MORB. The overall similarity in abundance patterns for MORB and popping rocks indicates that vesiculation and vesicle loss do not fractionate the ArKrXe relative abundances from those in non-vesiculated magma, and that the modern flux ratios of these gases at ridges are similar to their elemental ratios in the depleted mantle. The degassing flux of He at ridge crests estimated from the MORB He deficit relative to popping rocks is comparable to the flux derived from the3He budget for the abyssal ocean. This suggests that degassing at ridges may be strongly influenced by the dynamics and style of submarine volcanism.  相似文献   

15.
The nitrogen isotope geochemistry of 15 basaltic glasses has been investigated using stepped heating and high sensitivity static vacuum mass spectrometry. At low temperature (< 600°C) the glasses release small amounts of nitrogen with δ15NAIR, averaging −0.3‰, suggesting surficial adsorption of atmospheric nitrogen. At high temperature, usually with a maximum at 1000°C, indigenous nitrogen with a concentration ranging from 0.2 to 2.1 ppm is released. The δ15N values of this high temperature release show a wide range from −4.5‰ to +15.5‰. There is no correlation between N ppm and δ15N, and the samples apparently form 3 groups with distinctive δ15N. Six MORB glasses from the Mid-Atlantic Ridge, East Pacific Rise and Juan de Fuca Ridge define a group with δ15N = +7.5 ± 1.3‰. In contrast two Indian Ocean MORB glasses (Carlsberg Ridge and Gulf of Aden) gave negative δ15N averaging −3.2‰. Glasses from Loihi Seamount have high δ15N averaging +14.0 ± 1.0‰. Comparison of the δ15N data with the mantle models derived from helium and argon isotope studies suggests that the wide range in δ15N may reflect in part heterogeneities in the mantle related to its degassing history. It is possible, however, that magmatic degassing processes have also affected nitrogen isotopic compositions, and the data cannot yet be unambiguously interpreted in terms of source variations.  相似文献   

16.
The submarine counterparts of late Quaternary subaerial pyroclastic flow deposits off the western flanks of Dominica, Lesser Antilles, have been investigated by 3.5 kHz seismic profiling and dredging (cruise EN20 of R/V “Endeavor”). Block-and-ash flow deposits formed by dome collapse and a welded ignimbrite from a prominent fan at Grande Savanne, Dominica. This fan can be traced underwater as a major constructional ridge (2–4 km wide and 200–400 m thick) to over 13 km offshore at a water depth of 1800 m. The submarine ridge has a volume of 14 km3 and has the characteristic morphology of a debris flow apron composed of several individual units. The evidence suggests that pyroclastic flows can move underwater without losing their essential character.  相似文献   

17.
Secular variations in 13C/12C ratios and chemical compositions of gas samples from October 1986 to July 1992 are reported from a 92–95 °C steam well located about 3 km north of Mt. Mihara, an active volcano on Izu-Oshima Island, Japan. The δ13C value steeply increased from −2.97‰ (relative to PDB carbonate) in December 1986 to −1.15‰ in March 1988 and then gradually decreased to −1.75‰ in July 1992. Over the same period, the CO2 content changed similarly with time, even though the experimental error is relatively large. These variations are consistent with helium isotope changes. Initially rapid and then slow enhancements of 3He/4He ratio, δ13C value and CO2 content are invoked by violent eruptions of Izu-Oshima volcano from 15 November to 18 December 1986. After the eruptive activity, depletion of magmatic gas emission and subsequent mixing with crustal fluids in the hydrothermal system may produce the gradual decreases of 3He/4He ratio, δ13C value and CO2 content. Taking into account the rates of these decreases, we suggest that helium and carbon isotope ratios will return to the situation of before the magmatic eruption within 15 years.  相似文献   

18.
Mantle-derived volatiles in continental crust: the Massif Central of France   总被引：1，自引：0，他引：1  
CO2-rich gases and groundwaters from springs and boreholes originating within the basement of the Massif Central have variable3He/4He ratios with correspondingR/Ra values ranging from 0.8 to 5.5 and 0.3 to 2.8 respectively, indicating the presence of a significant component of mantle helium. Molar concentrations of rare gases in the CO2-rich gases are approximately 5 orders of magnitude greater than in the waters and suggest that a near-surface Henry's Law fractionation has occurred between exsolving CO2 and water.δ13C values of the CO2-rich gases are in the range −4.2 to −6.1‰, i.e. in that range normally attributed to mantle carbon, but which could also represent an average crustal composition and therefore do not discriminate between mantle and crustal sources.C/3He ratios show 4 orders of magnitude variation from 1.4 × 1012 to 5 × 108 and, compared to a mantleC/3He ratio of 109, indicate that either a complex fractionation has occurred between mantle helium and mantle CO2 or more likely that mantle rare gases have been diluted by large quantities of CO2 with an average crustal carbon isotope composition. The regional distribution of3He and C does not show any obvious relationship to age or proximity of volcanic centres or major faults, suggesting that mantle-derived C and He components decoupled from their silicate melt sources at some depth.The results from this area of active fluid circulation suggest that C-isotope data derived from metamorphic terrains should be interpreted with great caution, but that input of some mantle-derived carbon is expected to accompany crustal extension.  相似文献   

19.
Geomorphologic analysis of submarine and subaerial surface features using a combined topographic/bathymetric digital elevation model coupled with onshore geological and geophysical data constrain the age and geometry of giant landslides affecting the north flank of Tenerife. Shaded relief and contour maps, and topographic profiles of the submarine north flank, permit the identification of two generations of post-shield landslides. Older landslide materials accumulated near the shore (<40-km) and comprise 700 km3 of debris. Thickening towards a prominent axis suggests one major landslide deposit. Younger landslide materials accumulated 40–70 km offshore and comprise the products of three major landslides: the La Orotava landslide complex, the Icod landslide and the East Dorsal landslide complex, each with an onshore scar, a proximal submarine trough, and a distal deposit lobe. Estimated lobe volumes are 80, 80 and 100 km3, respectively. The old post-shield landslide scar is an amphitheatre, 20–25 km wide, partly submarine, now completely filled with younger materials. Age–width relationships for Tenerife's coastal platform plus onshore geological constraints suggest an age of ca. 3 Ma for the old collapse. Young landslides are all less than 560 ka old. The La Orotava and Icod slides involved failures of slabs of subaerial flank to form the subaerial La Orotava and Icod valleys. Offshore, they excavated troughs by sudden loading and basal erosion of older slide debris. The onshore East Dorsal slide also triggered secondary failure of older debris offshore. The slab-like geometry of young failures was controlled by weak layers, deep drainage channels and flank truncation by marine erosion. The (partly) submarine geometry of the older amphitheatre reflects the absence of these features. Relatively low H/L ratios for the young slides are attributed to filling of the slope break at the base of the submarine edifice by old landslide materials, low aspect ratios of the failed slabs and channelling within troughs. Post-shield landslides on Tenerife correlate with major falls in sea level, reflecting increased rates of volcanism and coastal erosion, and reduced support for the flank. Landslide head zones have strongly influenced the pattern of volcanism on Tenerife, providing sites for major volcanic centres.  相似文献   

20.
It has long been recognized that the Kii Peninsula in the southwest Japan arc is peculiar in a non-volcanic region, indicated by the presence of high temperature hot springs, high terrestrial heat flow and high 3He content in hot spring gases. Geophysical and geochemical studies were carried out to understand the geotectonic environment in the southern part of the Kii Peninsula. Most of the measured 3He / 4He ratios are similar or higher than air, indicating wide spread incorporation of mantle-derived helium into meteoric water. A region with rather high 3He / 4He ratios (> 4 RA) on the west side of the Omine Mountains coincides with the occurrence of high temperature hot springs. A deep crustal resistivity structure across the Omine Mountains was imaged by wide-band magnetotelluric soundings. A 2-D inversion with N–S strike using both TM and TE modes reveals two conductors, one in the upper (3–7 km depth) and the other in lower crust (25–35 km depth) to the west of the Omine Mountains. The distribution of microearthquakes and low-frequency tremors, and the existence of seismic reflectors indicate that the large conductor in the lower crust is related to aqueous fluids derived from the Philippine Sea plate. The upper-crustal conductive zone may also reflect the aqueous fluids trapped in the upper crust, which are presumably derived from the subducting slab. Considering the occurrence of seismic events in the subducting slab beneath the southern Kii Peninsula, the aqueous fluids generated by dehydration of the slab mantle could plausibly include MORB-type helium derived from the residual lithospheric mantle. Therefore, the high temperature hot springs and high 3He emanations in hot spring gases and other geotectonic events in the southern Kii Peninsula may be due to heat flux and mantle-derived helium discharged from aqueous fluid in the upper crust.  相似文献   

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