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1.
Chemical and Sr, Nd and Pb isotopic compositions of Late Cenozoic to Quaternary small-volume phonolite, trachyte and related mafic rocks from the Darfur volcanic province/NW-Sudan have been investigated. Isotope signatures indicate variable but minor crustal contributions. Some phonolitic and trachytic rocks show the same isotopic composition as their primitive mantle-derived parents, and no crustal contributions are visible in the trace element patterns of these samples. The magmatic evolution of the evolved rocks is dominated by crystal fractionation. The Si-undersaturated strongly alkaline phonolite and the Si-saturated mildly alkaline trachyte can be modelled by fractionation of basanite and basalt, respectively. The suite of basanite–basalt–phonolite–trachyte with characteristic isotope signatures from the Darfur volcanic province fits the compositional features of other Cenozoic intra-plate magmatism scattered in North and Central Africa (e.g., Tibesti, Maghreb, Cameroon line), which evolved on a lithosphere that was reworked or formed during the Neoproterozoic.  相似文献   

2.
Two distinct crustal provinces have been identified in the southern mid-continent based on U–Pb crystallization ages. Both contain large volumes of undeformed granite and rhyolite, with minor amounts of metamorphic rock and mafic intrusions. The Eastern Granite-Rhyolite province is characterized by felsic rocks with crystallization ages of 1,470 ± 30 Ma and exposures are restricted to the St. Francois Mountains in southeastern Missouri. Similarly, the Southern Granite-Rhyolite (SGR) province is characterized by felsic units with ages of 1,370 ± 30 Ma with primary exposures in the eastern Arbuckle Mountains of southern Oklahoma. Within the SGR province three magmatic pulses can be identified starting at 1,400, 1,370, and 1,340 Ma. Although the crystallization ages are different, the Sm–Nd isotopic signatures are similar for the units exposed in these areas as well as the buried basement in between. Depleted mantle model ages for rocks within the Arbuckle Mountains range from 1,530 to 1,430 Ma with ɛNd(t) values of +3.2 to +4.1 while units of the St. Francois Mountains range from 1,550 to 1,430 Ma and +4.5 to +4.7. Comparison of Sm–Nd isotopic data also indicate similarities between the 147Sm/144Nd and 143Nd/144Nd ratios for the rock units in these areas suggesting a common source.  相似文献   

3.
响岩代表了陆内火山岩省钠质碱性岩浆最终端的演化产物,揭示其成因机制对认识陆内火山岩省的岩浆演化过程具有重要意义。文章对出露在我国境内西南天山托云中新生代火山岩盆地的响岩开展了系统的矿物学、岩石学和地球化学研究,以揭示托云火山岩岩浆系列特征和岩浆演化过程。托云响岩以发育碱性长石、单斜辉石、铁橄榄石和角闪石斑晶为特征,在基质中可见霞石。在地球化学组成上,托云响岩以高的Na2O含量(7.9%～8.6%)和K2O含量(5.2%～6.3%)为特征,∑REE变化范围为408×10-6～470×10-6,稀土元素配分曲线具有明显的Eu异常,在原始地幔标准化的微量元素蛛网图上,样品显示出Ba、Sr、P、Ti的负异常和Nb、Ta、Zr、Hf的正异常特征。亏损的Nd同位素组成表明其成因与共生的碧玄岩有紧密的成因联系,经MELTS热力学模拟,响岩可由碧玄岩经碱性长石(36%)、单斜辉石(21%)、尖晶石(10%)、铁橄榄石(6%)和角闪石(5%)的分离结晶作用形成,进一步的EC-AFC模拟表明,响岩在形成过程中受到一定程...  相似文献   

4.
《Gondwana Research》2014,25(3-4):1067-1079
The Mt Painter Province of northern South Australia is a site of exceptional suite of Mesoproterozoic high heat producing (HHP) granites and felsic volcanics. These rocks have very high heat production values of > 5 μW m− 3. The HHP granites, including the Mt Neill, Box Bore, Terrapinna, Wattleowie and Yerila granites, form part of a broadly coeval association of mafic and felsic volcanic rocks that also include the Pepegoona Volcanics, lamprophyres and mafic–intermediate dykes. U–Pb LA-ICPMS zircon dating and Hf-in-zircon isotopic data are used to constrain both the timing and source of these magmatic rocks. U–Pb zircon LA-ICPMS crystallization ages range from ~ 1596 to 1521 Ma and imply a protracted sequence of magmatic events. Initial Hf isotopic compositions of these zircons from both dykes and felsic rocks have overlapping compositional ranges, with εHf values mainly from + 4 to − 2. These Hf values are significantly higher than contemporary crustal values which are likely to have been in the range − 4 to − 20. These data imply that the magmatic suite has both mantle and crustal sources.  相似文献   

5.
Glass Mountain consists of a 1 km3, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H2O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km3) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H2O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H2O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust. Received: 26 March 1996 / Accepted: 14 November 1996  相似文献   

6.
Volcanic rocks in the Middle–Lower Yangtze River Valley (MLYRV) constitute a bimodal magmatic suite, with a significant compositional gap (between 50% and 63% SiO2) between the mafic and felsic members. The suite is characterized by a relatively wide spectrum of rock types, including basalts, trachytes, and rhyolites. The basaltic rocks have low-to-moderate SiO2 contents of 46.00–50.01%, whereas the trachytes and rhyolites possess SiO2 contents in the range of 63.08–77.61%. Rocks of the bimodal suite show moderate enrichment of LILEs, negative Nb, Ta, and Ti anomalies, and are significantly enriched in LREEs. The basalts were most likely generated by parental mafic magmas derived from enriched lithospheric mantle with minor assimilation of crustal materials involving coeval crystal fractionation during magma evolution. The results of energy-constrained assimilation and fractional crystallization simulations demonstrate that the felsic magma was produced by the mixing of 5–20% lower crustal anatectic melts with an evolved mafic magma (～48% SiO2) and accompanied by extensive clinopyroxene, plagioclase, biotite, and Fe–Ti oxide fractionation. Our model for the genesis of felsic rocks in bimodal suites is different from the traditional models of crustal melting and fractional crystallization or assimilation–fractional crystallization of basaltic liquids.  相似文献   

7.
In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc), and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt–mantle interactions or of lower crustal melting, fractional crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb) data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW–SE transect at about 0° latitude and encompassing the frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center, rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes are small and their values are overall rather primitive (e.g., εNd = +1.5 to +6, 87Sr/86Sr = 0.7040–0.70435). Rare earth element patterns are characterized by variably fractionated light to heavy REE (La/YbN = 5.7–34) and by the absence of Eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation. We interpret the petrographic, geochemical, and isotopic data as indicating open-system evolution at all volcanic centers characterized by fractional crystallization and magma mixing processes at different lower- to mid-crustal levels as well as by assimilation of mafic lower crust and/or its partial melts. Thus, we propose that the adakite-like signatures of Ecuadorian rocks (e.g., high Sr/Y and La/Yb values) are primarily the result of lower- to mid-crustal processing of mantle-derived melts, rather than of slab melts and slab melt–mantle interactions. The isotopic signatures of the least evolved adakite-like rocks of the active and recent volcanoes are the same as those of Tertiary ”normal” calc-alkaline magmatic rocks of Ecuador suggesting that the source of the magma did not change through time. What changed was the depth of magmatic evolution, probably as a consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated with subduction of the aseismic Carnegie Ridge.  相似文献   

8.
天山西南部白垩纪-老第三纪发育的托云盆地及其周边出露的岩浆岩是一套完整的碱性岩浆岩系列，包含了苦橄质玄武岩、玄武岩、碧玄岩、碱玄岩（橄榄玄武岩、黑云母辉长二长岩、辉长辉绿岩、辉石橄榄岩）和响岩等多种岩石类型。野外工作显示有火山喷出岩和侵入岩两种不同的产状。年代学结果指示岩浆岩形成于120-50Ma间，为晚白垩世-老第三纪盆地形成演化阶段岩浆活动的产物。分离结晶作用是岩浆演化和岩浆系列形成最主要的因素，托云岩浆岩大致经历了结晶分异过程的两个阶段：早期苦橄质岩浆中橄榄石、尖晶石的结晶分离，表现为MgO和微量元素Cr含量随SiO2含量增加大幅度的降低；晚期主要是单斜辉石、斜长石和钛铁矿等矿物的结晶分异，以CaO、FeO、TiO2等随SiO2含量增加大幅度的降低为特点。苦橄质岩石的出现指示了地幔较高温熔融事件的存在，进而为托云盆地地幔柱的存在提供了有力的证据。无论如何，碱性岩浆的活动表明托云盆地形成的大地构造背景是大陆主动裂谷环境，对应的深部背景为区域性的地幔柱构造。首次发现的响岩是结晶分异作用的最终产物。响岩较极端地指示了岩浆结晶分离过程对岩浆演化的巨大影响。托云岩浆岩的同位素特征指示其源区是一个接近于PREMA地幔，但微量元素特征显示其受地壳流体交代改造的特点。岩浆岩的Nd同位素TDM集中在250～600Ma之间，反映了一个古生代时期形成的新生岩石圈地幔，与新疆北部地区的晚古生代新生岩石圈地幔的事实相符。  相似文献   

9.
More than ca 100 km3 of nearly homogeneous crystal-poor phonolite and ca 100 km3 of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199°C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (102 years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.  相似文献   

10.
Mount Erebus, Ross Island, Antarctica, is an active, intraplate,alkaline volcano. The strongly undersaturated sodic lavas rangefrom basanite to anorthoclase phonolite, and are termed theErebus lineage (EL). The lavas are porphyritic with olivine(Fo88–51), clinopyroxene (Wo45–53En36–41Fs8–30),opaque oxides (Usp31–76), feldspar (An72–11), andapatite. Rare earth element (REE) contents increase only slightlywith increasing differentiation compared with other incompatibleelements. The light REE are enriched (LaN/YbN= 14–20)and there are no significant Eu anomalies. 87Sr/86Sr is uniformand low ({small tilde} 0.7030) throughout the EL, suggestingderivation of the basanites from a depleted asthenospheric mantlesource, and lack of significant crustal contamination duringfractionation of the basanite. Regular geochemical trends indicatethat the EL evolved from the basanites by fractional crystallization.Major element mass balance calculations and trace element modelsshow that fractionation of 16% olivine, 52% clinopyroxene, 14%Fe-Ti oxides, 11% feldspar, 3% nepheline, and 3% apatite froma basanite parent leaves 23.5% anorthoclase phonolite. Minor volumes of less undersaturated, more iron-rich benmoreite,phonolite, and trachyte are termed the enriched iron series(EFS). The trachytes have 87Sr/86Sr of 0.704, higher than otherEFS and EL rocks, and they probably evolved by a combined assimilation-fractionalcrystallization process. The large volume of phonolite at Mt. Erebus requires significantbasanite production. This occurs by low degrees of partial meltingin a mantle plume (here termed the Erebus plume) rising at arate of about 6 cm/yr.  相似文献   

11.
Experimental melting studies were conducted on a nepheline mugearitecomposition to pressures of 31 kbar in the presence of 0–30%added water. A temperature maximum in the near-liquidus stabilityof amphibole (with olivine) was found for a water content of3·5 wt % at a pressure of 14 kbar. This is interpretedto have petrogenetic significance for the derivation of nephelinemugearite magmas from nepheline hawaiite by amphibole-dominatedfractional crystallization at depth within the lithosphericmantle. Synthetic liquids at progressively lower temperaturesrange to nepheline benmoreite compositions very similar to thoseof natural xenolith-bearing high-pressure lavas elsewhere, andsupport the hypothesis that continued fractional crystallizationcould lead to high-pressure phonolite liquids. Independent experimentaldata for a basanite composition modeled on a lava from the sameigneous province (the Newer Basalts of Victoria) permit theinference that primary asthenospheric basanite magmas undergopolybaric fractional crystallization during ascent, and mayevolve to liquids ranging from nepheline hawaiite to phonoliteupon encountering cooler lithospheric mantle at depths of 42–50km. Such a model is consistent with the presence in some evolvedalkalic lavas of both lithospheric peridotite xenoliths indicativeof similar depths and of megacryst suites that probably representdisrupted pegmatitic segregations precipitated from precursoralkalic magmas in conduit systems within lithospheric mantle. KEY WORDS: experiment; high pressure; alkalic magmas; amphibole; nepheline mugearite; basanite; lithosphere  相似文献   

12.
An early Cretaceous (135 ± 2 Ma) felsic volcanic suite of dacite and rhyolite from Huolinhe, NE China is characterized by large ion lithophile element and light REE enrichment and high field strength element (HFSE, e.g., Nb and Ta) and Ti–P depletion, and bulk silicate earth-like Sr [87Sr/86Sr(i) = 0.70409–0.70481], quite radiogenic Nd [ε Nd(t) = +3.98 to +5.88], Pb [e.g., 206Pb/204Pb(i) = 18.46–18.55] and Hf [ε Hf(t) ~+9.2] isotope compositions. Compared with contemporaneous mafic rocks in the region, these felsic rocks have even higher Nd and Hf isotopic ratios, precluding an origin through differentiation of coeval mantle-derived magmas. Isotope calculation results suggest that these magmas were derived from a preexistent mixture composed of mainly juvenile crust (70–80%), and a subordinate recycled crustal component (20–30%) having highly radiogenic Sr and Pb and unradiogenic Nd and Hf. About 25–30% melting of such a mixed source produced the primary dacitic magma. The rhyolites, which have relatively low MgO, FeO*, Al2O3, CaO, TiO2, P2O5, Na2O, Ba, Sr, REE, HFSE and Y, were differentiates of the dacites after removal of a fractional assemblage of hornblende + plagioclase + K-feldspar + apatite + zircon. Considering the prolonged events (from 262 to 130 Ma) that produced such highly positive ε Nd felsic igneous rocks in the region, we prefer a pre-Mesozoic crustal growth model related to arc accretion associated with the Paleo-Asian Ocean subduction.  相似文献   

13.
张超  吴新伟  张渝金  郭威  权京玉 《地质通报》2017,36(9):1531-1541
对大兴安岭北段龙江盆地光华组碱流岩进行了岩石地球化学及锆石U-Pb年龄研究,并对其岩石成因及构造意义进行了讨论。结果表明,龙江盆地碱流岩的锆石具有典型的岩浆振荡生长环带和较高的Th/U值(0.71~2.12),反映了岩浆成因特征,LAICP-MS锆石U-Pb年龄为122.4±1.7Ma(n=19,MSWD=0.77)。岩石富硅、富碱,贫Mg、Ca;稀土元素配分曲线呈现右倾"V"字形特征,显示强烈的负Eu异常;微量元素显示具有较低的Sr和Ba丰度,以及较高的Rb、Th、U、Zr等特点。以上特征表明,龙江盆地碱流岩类似于铝质A1型花岗岩,为长英质地壳部分熔融及其后斜长石和Ti、Fe氧化物分离结晶作用的产物,代表了伸展的构造环境。  相似文献   

14.
A new Rb−Sr age of 779±10 Ma has been obtained for a suite of andesite-daciterhyolite from the Malani Igneous Province of southwestern Rajasthan, dated earlier at 745±10 Ma by Crawford and Compston (1970). The associated basalts may be slightly younger than the felsic volcanics and have a mantle source. The felsic volcanics on the other hand were most probably derived by fractional crystallization of a crustal magma (Srivastavaet al 1989a, b).40Ar−39Ar systematics of three samples viz., a basalt, a dacite and a rhyolite show disturbed age spectra indicating a thermal event around 500–550 Ma ago. This secondary thermal event is quite wide-spread and possibly related to the Pan-African thermo-tectonic episode observed in the Himalayas and south India.  相似文献   

15.
This paper is devoted to detailed study of picritic rocks (olivine melanogabbronorites) and comagmatic gabbrodolerites from sills and dikes in the central part of the Bashkirian meganticlinorium. These rocks are ascribed to the Kama-Belsk magmatic province (KBP) that was formed in the eastern East European Platform (EEP) in the Mesoproterozoic time. The study of minerals (EMPA, SIMS), rocks, and their oxygen isotope compositions showed the contribution of crustal contamination, fractional crystallization and cumulus processes in their formation. The geochemical indicators of crustal contamination (Nb/Nb*, (Nb/La) n , δ18O, and others) show strong variations, which indicates uneven crustal contribution in the parental melts during rock formation (10–25%). The study of weakly contaminated (δ18O = 5.3‰) olivine melanogabbronorites (MgO = 22.55 wt %) from the small Ishlya-1 subvolcanic body, which contain subordinate amount of cumulus (24%), high-magnesian olivine (Fo91.3), and high-Cr spinel (cr# 0.67), as well as HREE depleted clinopyroxenes, allowed us to retrieve the composition of parental melt. The latter contained about 20 wt % MgO and was formed by 19–26% melting of mantle source (potential mantle temperature T m of 1530–1545°C). Geochemical characteristics of KBP reflect the formation of primary melts by melting of mantle column at different depths, mixing of the melts, and significant contamination by crustal material. The dominant role in the formation of the rocks of the Ishlya area and Mashak Complex was played by derivatives of spinel peridotites, while the rocks of the Bakal-Satka area were derived from garnet peridotites.  相似文献   

16.
Lower ocean crust is primarily gabbroic, although 1–2% felsic igneous rocks that are referred to collectively as plagiogranites occur locally. Recent experimental evidence suggests that plagiogranite magmas can form by hydrous partial melting of gabbro triggered by seawater-derived fluids, and thus they may indicate early, high-temperature hydrothermal fluid circulation. To explore seawater–rock interaction prior to and during the genesis of plagiogranite and other late-stage magmas, oxygen-isotope ratios preserved in igneous zircon have been measured by ion microprobe. A total of 197 zircons from 43 plagiogranite, evolved gabbro, and hydrothermally altered fault rock samples have been analyzed. Samples originate primarily from drill core acquired during Ocean Drilling Program and Integrated Ocean Drilling Program operations near the Mid-Atlantic and Southwest Indian Ridges. With the exception of rare, distinctively luminescent rims, all zircons from ocean crust record remarkably uniform δ18O with an average value of 5.2 ± 0.5‰ (2SD). The average δ18O(Zrc) would be in magmatic equilibrium with unaltered MORB [δ18O(WR) ~ 5.6–5.7‰], and is consistent with the previously determined value for equilibrium with the mantle. The narrow range of measured δ18O values is predicted for zircon crystallization from variable parent melt compositions and temperatures in a closed system, and provides no indication of any interactions between altered rocks or seawater and the evolved parent melts. If plagiogranite forms by hydrous partial melting, the uniform mantle-like δ18O(Zrc) requires melting and zircon crystallization prior to significant amounts of water–rock interactions that alter the protolith δ18O. Zircons from ocean crust have been proposed as a tectonic analog for >3.9 Ga detrital zircons from the earliest (Hadean) Earth by multiple workers. However, zircons from ocean crust are readily distinguished geochemically from zircons formed in continental crustal environments. Many of the >3.9 Ga zircons have mildly elevated δ18O (6.0–7.5‰), but such values have not been identified in any zircons from the large sample suite examined here. The difference in δ18O, in combination with newly acquired lithium concentrations and published trace element data, clearly shows that the >3.9 Ga detrital zircons did not originate by processes analogous to those in modern mid-ocean ridge settings.  相似文献   

17.
The South Mountain Batholith (SMB) of southwestern Nova Scotia (Canada) is a Late Devonian (~375 Ma) composite intrusion, which crops over an area of about 7,300 km2. This peraluminous granitoid body consists of rocks ranging from granodiorite through monzogranite and leucomonzogranite to leucogranite that locally host greisen tin-base metal mineralization. K-feldspar displays large compositional variations of trace elements and Pb isotopic ratios, particularly in the highly fractionated rocks. Many variations are consistent with processes of fractional crystallization, but a distinct enrichment of Rb, Li and Cs accompanied by low K/Rb, Ba/Rb, Eu/Eu* and K/Cs ratios point to the role of fluids during the late stages of magmatic evolution. The correlation of Pb isotopic ratios with the enriched elements and their ratios implies that the isotopic variations are an integral part of the evolution of the SMB. Together with well-defined isochronal relationships of Pb systems in the feldspars, the correlation suggests that fractional crystallization accompanied in the late stages by fluid fractionation led to the formation of Li–F-rich leucogranites. Internally derived U-rich fluids fractionated U/Pb ratios, which in turn produced distinct variations of 206Pb/204Pb and 238U/204Pb ratios in K-feldspars. This implies that the Pb isotopic values of K-feldspar, which have traditionally been used for tectonic reconstructions, might have been modified in many granitic rocks. Thus, only early magmatic K-feldspars, which show no discernible effects of fluid fractionation yield the initial Pb isotopic compositions of the parental granitic magmas and their sources. The data also show that the geochemical characteristics of the leucogranites are the results of magmatic evolution rather than a distinctive source.  相似文献   

18.
The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat–Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz–sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na2O, CaO, P2O5, and Sr and enrichment in K2O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U–Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant 206Pb/238U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean 206Pb/238U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant 206Pb/238U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. 176Hf/177Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the Chelopech area and the about 92-Ma-old Elatsite porphyry–Cu deposit, suggest two different magma sources in the Chelopech–Elatsite magmatic area. Magmatic rocks associated with the Elatsite porphyry–Cu deposit and the dacitic dome-like body north of Chelopech are characterized by zircons with ɛHfT90 values of ∼5, which suggest an important input of mantle-derived magma. Some zircons display lower ɛHfT90 values, as low as −6, and correlate with increasing 206Pb/238U ages up to about 350 Ma, suggesting assimilation of basement rocks during magmatism. In contrast, zircon grains in andesitic rocks from Chelopech are characterized by homogeneous 176Hf/177Hf isotope ratios with ɛHfT90 values of ∼1 and suggest a homogeneous mixed crust–mantle magma source. We conclude that the Elatsite porphyry–Cu and the Chelopech high-sulfidation epithermal deposits were formed within a very short time span and could be partly contemporaneous. However, they are related to two distinct upper crustal magmatic reservoirs, and they cannot be considered as a genetically paired porphyry–Cu and high-sulfidation epithermal related to a single magmatic–hydrothermal system centered on the same intrusion.  相似文献   

19.
Tenerife is the largest of the seven Tertiary to Recent volcanic islands that make up the Canary Archipelago. The island is composed of volcanics belonging to the basanitetrachyte-phonolite assemblage that characterises many Atlantic islands. The most voluminous development of intermediate and salic volcanics has been in the centre of the island where the Las Canadas volcanoes arose upon a basement shield composed mainly of basanite and ankaramite flows, tuffs and agglomerates. The initial post-shield activity built the Vilaflor volcanic complex (Lower and Upper Canadas Series) that originally covered much of the underlying shield volcanics. A vast collapse of the complex, probably during post-Pleistocene times, in the centre of the island has left a large semi-circular wall, and provides an excellent vertical section through the complex. Quaternary volcanism within the collapsed area has built the twin, central-type volcanoes, Viejo and Teide, both of which have attendant satellite vents. That part of the Vilaflor Complex exposed in Las Canadas, together with the Viejo and Teide volcanoes, comprise the Las Canadas volcanoes.Four distinct rock types can be recognised in these volcanoes, basanite, trachybasanite, plagioclase phonolite, and phonolite. Each rock type can be recognised chemically and mineralogically, but there is essentially a gradational series from basanite to phonolite that includes both aphyric and glomerophyric rocks. The volcanics are strongly undersaturated and sodic, and some of the phonolites are mildly peralkaline. Variations in degree of undersaturation, and trace element abundances indicate a number of cycles of activity which would be consistent with the known field relations.Forsteritic olivine occurs in the basanites and trachybasanites but is not a stable phase in the more salic volcanics. Clinopyroxene is ubiquitous, varying in composition from titanaugite in the basanites to slightly sodic augite in the phonolites. Strongly sodic pyroxene is restricted to the groundmass of the microcrystalline phonolites along with aenigmatite and a kataphoritic amphibole. Plagioclase is found only in the groundmass of the basanites, but andesine and potash-oligoclase are common phenocryst minerals in the trachybasanites and plagioclase phonolites respectively, whereas the characteristic feldspar of the phonolites is anorthoclase.The relatively smooth curves of major and trace element variation, the presence of accumulative volcanics at all stages of differentiation, zoning of the mineral phases, and the clustering of the phonolites around the low temperature trough in Petrogeny's Residua System, all indicate that the descent from basanite to phonolite has resulted from fractional crystallisation of a basanite parent magma. The trend of pyroxene crystallisation, and the fairly constant FeO/Fe2O3 ratio during fractionation indicate crystallisation under low PO2 conditions.  相似文献   

20.
Zircon U–Pb geochronology results indicate that the John Muir Intrusive Suite of the central Sierra Nevada batholith, California, was assembled over a period of at least 12 Ma between 96 and 84 Ma. Bulk mineral thermochronology (U–Pb zircon and titanite, 40Ar/39Ar hornblende and biotite) of rocks from multiple plutons comprising the Muir suite indicates rapid cooling through titanite and hornblende closure following intrusion and subsequent slow cooling through biotite closure. Assembly of intrusive suites in the Sierra Nevada and elsewhere over millions of years favors growth by incremental intrusion. Estimated long-term pluton assembly rates for the John Muir Intrusive Suite are on the order of 0.001 km3 a−1 which is inconsistent with the rapid magma fluxes that are necessary to form large-volume magma chambers capable of producing caldera-forming eruptions. If large shallow crustal magma chambers do not typically develop during assembly of large zoned intrusive suites, it is doubtful that the intrusive suites represent cumulates left behind following caldera-forming eruptions.  相似文献   

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