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1.
Os–Hf–Sr–Nd isotopes and PGE were determined in peridotite xenoliths carried to the surface by Quaternary alkali basaltic magmas in the Tokinsky Stanovik Range on the Aldan shield. These data constrain the timing and nature of partial melting and metasomatism in the lithospheric mantle beneath SE Siberian craton. The xenoliths range from the rare fertile spinel lherzolites to the more abundant, strongly metasomatised olivine-rich (70–84%) rocks. Hf–Sr–Nd isotope compositions of the xenoliths are mainly within the fields of oceanic basalts. Most metasomatised xenoliths have lower 143Nd / 144Nd and 176Hf / 177Hf and higher 87Sr / 86Sr than the host basalts indicating that the metasomatism is older and has distinct sources. A few xenoliths have elevated 176Hf / 177Hf (up to 0.2838) and plot above the Hf–Nd mantle array defined by oceanic basalts.187Os / 188Os in the poorly metasomatised, fertile to moderately refractory (Al2O3 ≥ 1.6%) Tok peridotites range from 0.1156 to 0.1282, with oldest rhenium depletion ages being about 2 Ga. The 187Os / 188Os in these rocks show good correlations with partial melting indices (e.g. Al2O3, modal cpx); the intercept of the Al–187Os / 188Os correlation with lowest Al2O3 estimates for melting residues (∼0.3–0.5%) has a 187Os / 188Os of ∼0.109 suggesting that these peridotites may have experienced melt extraction as early as 2.8 Gy ago. 187Os / 188Os in the strongly metasomatised, olivine-rich xenoliths (0.6–1.3% Al2O3) ranges from 0.1164 to 0.1275 and shows no apparent links to modal or chemical compositions. Convex-upward REE patterns and high abundances of heavy to middle REE in these refractory rocks indicate equilibration with evolved silicate melts at high melt / rock ratios, which may have also variably elevated their 187Os / 188Os. This inference is supported by enrichments in Pd and Pt on chondrite-normalised PGE abundance patterns in some of the rocks. The melt extraction ages for the Tok suite of 2.0 to 2.8 Ga are younger than oldest Os ages reported for central Siberian craton, but they must be considered minimum estimates because of the extensive metasomatism of the most refractory Tok peridotites. This metasomatism could have occurred in the late Mesozoic to early Cenozoic when the Tok region was close to the subduction-related Pacific margin of Siberia and experienced large-scale tectonic and magmatic activity. This study indicates that metasomatic effects on the Re–Os system in the shallow lithospheric mantle can be dramatic.  相似文献   

2.
In order to better understand the nature and formation of oceanic lithosphere beneath the Early Cretaceous Ontong Java Plateau, Re–Os isotopes have been analysed in a suite of peridotite xenoliths from Malaita, Solomon Islands. Geological, thermobarometric and petrological evidence from previous studies reveal that the xenoliths represent virtually the entire thickness of the southern part of subplateau lithospheric mantle (< 120 km). This study demonstrates that vertical Os isotopic variations correlate with compositional variations in a stratified lithosphere. The shallowest plateau lithosphere (< 85 km) is dominated by fertile lherzolites showing a restricted range of 187Os/188Os (0.1222 to 0.1288), consistent with an origin from ~ 160 Ma Pacific lithosphere. In contrast, the basal section of subplateau lithospheric mantle (~ 95–120 km) is enriched in refractory harzburgites with highly unradiogenic 187Os/188Os ratios ranging from 0.1152 to 0.1196, which yield Proterozoic model ages of 0.9–1.7 Ga. Although the whole range of Os isotope compositions of Malaita peridotites is within the variations seen in modern abyssal peridotites, the contrasting isotopic compositions of shallow and deep plateau lithosphere suggest their derivation from different mantle reservoirs. We propose that the subplateau lithosphere forms a genetically unrelated two-layered structure, comprising shallower, typical oceanic lithosphere underpinned by deeper impinged material, which included a component of recycled Proterozoic lithosphere. The impingement of residual but chemically heterogeneous mantle, mechanically coupled to the recently formed, thin lithosphere, may have a bearing on the anomalous initial uplift and late subsidence history of the seismically anomalous plateau root.  相似文献   

3.
We present osmium isotopic results obtained by sequential leaching of the Murchison meteorite, which reveal the existence of very large internal anomalies of nucleosynthetic origin (ε184Os from ? 108 to 460; ε186Os from ? 14.1 to 12.6; ε188Os from ? 2.6 to 1.6; ε190Os from ? 1.7 to 1.1). Despite these large variations, the isotopic composition of the total leachable osmium (weighted average of the leachates) is close to that of bulk chondrites. This is consistent with efficient large-scale mixing of Os isotopic anomalies in the protosolar nebula. The Os isotopic anomalies are correlated, and can be explained by the variable contributions of components derived from the s, r and p-processes of nucleosynthesis. Surprisingly, much of the s-process rich osmium is released by relatively mild leaching, suggesting the existence of an easily leachable s-process rich presolar phase, or alternatively, of a chemically resistant r-process rich phase. Taken together with previous evidence for a highly insoluble s-process rich carrier, such as SiC, these results argue for the presence of several presolar phases with anomalous nucleosynthetic compositions in the Murchison meteorite. The s-process composition of Os released by mild leaching diverges slightly from that released by aggressive digestion techniques, perhaps suggesting that the presolar phases attacked by these differing procedures condensed in different stellar environments. The correlation between ε190Os and ε188Os can be used to constrain the s-process 190Os/188Os ratio to be 1.275 ± 0.043. Such a ratio can be reproduced in a nuclear reaction network for a MACS value for 190Os of ~ 200 ± 22 mbarn at 30 keV. More generally, these results can help refine predictions of the s-process in the Os mass region, which can be used in turn to constrain the amount of cosmoradiogenic 187Os in the solar system and hence the age of the Galaxy.We also present evidence for extensive internal variation of 184Os abundances in the Murchison meteorite. A steep anti-correlation is observed between ε184Os and ε188Os. Since 184Os is formed uniquely by the p-process, this anti-correlation cannot be explained by variable addition or subtraction of s-process Os to average solar system material. Instead, this suggests that p-process rich presolar grains (e.g., supernova condensates) may be present in meteorites in sufficient quantities to influence the Os isotopic compositions of the leachates. Nevertheless, 184Os is a low abundance isotope and we cannot exclude the possibility that the measured anomalies for this isotope reflect unappreciated analytical artifacts.  相似文献   

4.
This study presents major-, trace-element, and rhenium–osmium (Re–Os) isotope and elemental data for basalts and gabbros from the Zermatt-Saas ophiolite, metamorphosed to eclogite-facies conditions during the Alpine orogeny. Igneous crystallisation of the gabbros occurred at 163.5 ± 1.8 Ma and both gabbro and basalt were subject to ‘peak’ pressure–temperature (P–T) conditions of > 2.0 GPa and ~ 600 °C at about 40.6 ± 2.6 Ma.Despite such extreme P–T conditions, Re–Os isotope and abundance data for gabbroic rocks suggest that there has been no significant loss of either of these elements during eclogite-facies metamorphism. Indeed, 187Re–187Os isotope data for both unaltered gabbros and gabbroic eclogites lie on the same best-fit line corresponding to an errorchron age of 160 ± 6 Ma, indistinguishable from the age of igneous crystallisation. In contrast, metamorphosed basalts do not yield age information; rather most possess 187Re/188Os ratios that cannot account for the measured 187Os/188Os ratios, given the time since igneous crystallisation. Taken with their low Re contents these data indicate that the basalts have experienced significant Re loss (∼ 50–60%), probably during high-pressure metamorphism. Barium, Rb and K are depleted in both gabbroic and basaltic eclogites. In contrast, there is no evident depletion of U in either lithology.Many ocean-island basalts (OIB) possess radiogenic Os and Pb isotope compositions that have been attributed to the presence of recycled oceanic crust in the mantle source. Published Re–Os data for high-P metabasaltic rocks alone (consistent with this study) have been taken to suggest that excessive amounts of oceanic crust are required to generate such signatures. However, this study shows that gabbro may exert a strong influence on the composition of recycled oceanic crust. Using both gabbro and basalt (i.e. a complete section of oceanic crust) calculations suggest that the presence of ≥ 40% of 2 Ga oceanic crust can generate the radiogenic Os compositions seen in some OIB. Furthermore, lower U/Pb ratios in gabbro (compared to basalt) serve to limit the 206Pb/204Pb ratios generated, while having a minimal effect on Os ratios. These results suggest that the incorporation of gabbro into recycling models provides a means of producing a range of OIB compositions having lower (and variable) 206Pb/204Pb ratios, but still preserving 187Os/188Os compositions comparable to HIMU-type OIB.  相似文献   

5.
In an attempt to quantify the extent of geochemical heterogeneity within a restricted and well dated portion of the upper mantle, 27 chromite separates from the 90 My old chromite deposits in the Mayarí–Baracoa ophiolite belt in eastern Cuba have been investigated for platinum group element (PGE) concentrations and Re–Os isotopic systematics. The samples are characterized by systematically subchondritic initial 187Os/188Os ratios and substantial heterogeneity. The initial 187Os/188Os ratios vary with chromite chemistry and with geographical distribution, reflecting differences in the Os isotopic evolution for the different upper mantle sections represented by the ophiolite. Accordingly, the Os isotope data might be divided into three groups. In the Moa–Baracoa district, where the chromite bodies are located in the mantle–crust transition zone, the calculated initial γOs values average − 0.97 ± 0.69 (n = 13). In the Sagua de Tanamo district, where chromite chemistry is highly variable and their location in relation the mantle sequence is less clear, the initial γOs values are intermediate, with an average of − 1.77 ± 0.80 (n = 7). In the Mayarí district, where the chromite bodies are located in the lower part of the mantle sequence, initial γOs values average − 2.66 ± 0.29 (n = 7). These subchondritic (i.e. negative) initial γOs values are most simply explained by Re depletion during ancient partial melting and/or melt percolation events.The Os isotope heterogeneity documented here indicates a high degree of geochemical complexity on small to intermediate length scales in the upper mantle. Our results, in combination with data on chromites from the literature, show that an “average present-day Os isotopic composition” for the hypothetical depleted MORB mantle (DMM) reservoir cannot be precisely established beyond the statement that it is “broadly chondritic”. Indeed, the upper mantle cannot be considered a sufficiently homogeneous geochemical “reservoir” to serve meaningfully as a baseline against which geochemical “anomalies” are evaluated. On the other hand, our findings are consistent with the “Statistical Upper Mantle Assemblage” or “SUMA”-concept, according to which a high level of geochemical heterogeneity is maintained in the upper mantle at all relevant length scales, as a result of the plate-tectonic cycle and intra-mantle processes such as melt-migration and metasomatism.  相似文献   

6.
Coupled 187Os/188Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ± 0.3 pg g? 1 Os, 1.5 ± 0.6 pg g? 1 Ir, 6.8 ± 2.7 pg g? 1 Ru, 16 ± 15 pg g? 1 Pt, 33 ± 30 pg g? 1 Pd and 0.29 ± 0.10 pg g? 1 Re (～ 0.00002 × CI) and Re/Os ratios that were modestly elevated (187Re/188Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (～ 0.00007 × CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle–crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments.If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust–mantle concentration ratios (D-values) must be ≤ 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust–mantle HSE partitioning for the Earth and Moon are somewhat surprising. Low HSE abundances in the lunar crust, coupled with estimates of HSE concentrations in the lunar mantle implies there may be a ‘missing component’ of late-accreted materials (as much as 95%) to the Moon if the Earth/Moon mass-flux estimates are correct and terrestrial mantle HSE abundances were established by late accretion.  相似文献   

7.
The exceptionally well-preserved sedimentary rocks of the Taoudeni basin, NW Africa represent one of the world's most widespread (> 1 M km2) Proterozoic successions. Hitherto, the sedimentary rocks were considered to be Mid Tonian based on Rb–Sr illite and glauconite geochronology of the Atar Group. However, new Re–Os organic-rich sediment (ORS) geochronology from two drill cores indicates that the Proterozoic Atar Group is ～ 200 Ma older (1107 ± 12 Ma, 1109 ± 22 Ma and 1105 ± 37 Ma). The Re–Os geochronology suggests that the Rb–Sr geochronology records the age of diagenetic events possibly associated with the Pan African collision.The new Re–Os geochronology data provide absolute age constraints for recent carbon isotope chemostratigraphy which suggests that the Atar Group is Mesoproterozoic and not Neoproterozoic.The new Re–Os ORS geochronology supports previous studies that suggest that rapid hydrocarbon generation (flash pyrolysis) from contact metamorphism of a dolerite sill does not significantly disturb the Re–Os ORS systematics. Modelled contact conditions suggest that the Re–Os ORS systematics remain undisturbed at ～ 650 °C at the sill/shale contact and ≥ 280 °C 20 m from the sill/shale contact.Moreover, the Re–Os geochronology indicates that the West African craton has a depositional history that predates 1100 Ma and that ORS can be correlated on a basin-wide scale. In addition, the Re–Os depositional ages for the ORS of the Taoudeni basin are comparable to those of ORS from the São Francisco craton, suggesting that these cratons are correlatable. This postulate is further supported by identical Osi values for the Atar Group and the Vazante Group of the São Francisco craton.  相似文献   

8.
The possible sources of pre-anthropogenic Pb contributed to the world's oceans have been the focus of considerable study. The role of eolian dust versus riverine inputs has been of particular interest. With better calibration of isotopic records from central Pacific ferromanganese crusts using Os isotope stratigraphy it now appears that deep water Pb isotopic compositions were effectively homogeneous over a distance of 5000 km for the past 80 Myr. The composition shifted slightly from high 206Pb/204Pb ratios in the range of 18.87 ± 0.02 before 65 Ma to lower values of 18.62 ± 0.02 by 45 Ma and then gradually increased again very slightly to the present day ratio of 18.67 ± 0.02. The regional homogeneity provides evidence of a dominant well-mixed atmospheric source the most likely candidate for which is volcanic aerosols contributed either directly or as soluble condensates on eolian dust. The slight shift in Pb isotope composition of deep waters in the central Pacific between 65 and 45 Ma may be the result of a regional- or perhaps global-scale change in the sources of volcanic exhalations and volcanic activity caused by an increase in the importance of melting and assimilation of older continental crustal components over the Cenozoic.  相似文献   

9.
A suite of 23 basaltic to dacitic lavas erupted over the last 350 kyr from the Mount Adams volcanic field has been analyzed for U–Th isotope compositions to evaluate the roles of mantle versus crustal components during magma genesis. All of the lavas have (230Th/238U) > 1 and span a large range in (230Th/232Th) ratios, and most basalts have higher (230Th/232Th) ratios than andesites and dacites. Several of the lavas contain antecrysts (crystals of pre-existing material), yet internal U–Th mineral isochrons from six of seven lavas are indistinguishable from their eruption ages. This indicates a relatively brief period of time between crystal growth and eruption for most of the phenocrysts (olivine, clinopyroxene, plagioclase, magnetite) prior to eruption. One isochron gave a crystallization age that is ~ 20–25 ka older than its corresponding eruptive age, and is interpreted to reflect mixing of older and juvenile crystals or a protracted period of magma storage in the crust. Much of the eruptive volume since 350 ka consists of lavas that have small to moderate 230Th excesses (2–16%), which are likely inherited from melting of a garnet-bearing intraplate (“OIB-like”) mantle source. Following melt generation and subsequent migration through the upper mantle, most Mt. Adams magmas interacted with young, mafic lower crust, as indicated by 187Os/188Os ratios that are substantially more radiogenic than the mantle or those expected via mixing of subducted material and the mantle wedge. Moreover, Os–Th isotope variations suggest that unusually large 230Th excesses (25–48%) and high 187Os/188Os ratios in some peripheral lavas reflect assimilation of small degree partial melts of pre-Quaternary basement that had residual garnet or Al-rich clinopyroxene. Despite the isotopic evidence for lower crustal assimilation, these processes are not generally recorded in the erupted phenocrysts, indicating that the crystal record of the deep-level ‘cryptic’ processes has been decoupled from shallow-level crystallization.  相似文献   

10.
Landfill leachates that contain persistent organic pollutants (POPs) are a big threat to groundwater systems and are projected to have hazardous effects in the long term if proper management strategies of the landfills are not put in place by those responsible. Monitoring the levels of POPs in landfill leachates is very crucial. This work presents an amperometric biosensor for determination of selected POPs in landfill leachates. The biosensor is based on kinetic inhibition of horseradish peroxidase (HRP). The enzyme was immobilised by electrostatic attachment on a polyaniline-modified Pt electrode surface. Selected POPs inhibited HRP enzyme activity and the decrease in the enzyme activity was used to determine these environmental pollutants. Selected polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs) and polychlorinated biphenyls (PCBs) were the analytes of choice because they are commonly found in South Africa water systems. Limits of detection for the amperometric biosensor were established as 0.014, 0.018, 0.022, 0.016 and 0.019 μg l−1 for BDE-100, PBB-1, PCB-1, PCB-28 and PCB-101, respectively. The HRP biosensor system gave different linear ranges for; BDE-100 (0.424–25.8 μg l−1), PBB-1 (0.862–13.4 μg l−1), PCB-1 (0.930–18.1 μg l−1), PCB-28 (0.730–15.7 μg l−1) and PCB-101 (0.930–27.1 μg l−1). Inhibition studies on HRP biosensor response toward the reduction of H2O2 in the absence and presence of the selected POPs were carried out to investigate the inhibition kinetics and its mechanism. The results obtained indicated that the inhibition mechanism was competitive for PBDEs and non-competitive for biphenyls (PCBs and PBBs). The application of the biosensor was tested on wastewater samples obtained from landfill leachate for determination of selected POPs. The leachate samples were found to contain PCB-28 (0.28 ± 0.03 μg l−1) and PCB-101 (0.31 ± 0.02 μg l−1). The samples were also analysed by GC–MS as a cross-check method and the two sets of results were in close agreement.  相似文献   

11.
The Toarcian Oceanic Anoxic Event (OAE) in the Early Jurassic (∼ 183 Ma ago) was characterized by widespread near-synchronous deposition of organic-rich shales in marine settings, as well as perturbations to several isotopic systems. Characteristically, two positive carbon-isotope excursions in a range of materials are separated by an abrupt negative shift. Carbon-isotope profiles from Toarcian fossil wood collected in England and Denmark have previously been shown to exhibit this large drop (∼ − 7‰) in δ13C values, interpreted as due to an injection of isotopically light CO2 into the ocean–atmosphere system. However, the global nature of this excursion has been challenged on the basis of carbon-isotope data from nektonic marine molluscs (belemnites), which exhibit heavier than expected carbon-isotope values. Here we present new data, principally from fossil wood and bulk carbonate collected at centimetre scale from a hemipelagic section at Peniche, coastal Portugal. This section is low in organic carbon (average TOC = ∼ 0.5%), and the samples should not have suffered significant diagenetic contamination by organic carbon of marine origin. The carbon-isotope profile based on wood shows two positive excursions separated by a large and abrupt negative excursion, which parallels exactly the profile based on bulk carbonate samples from the same section, albeit with approximately twice the amplitude (∼ − 8‰ in wood versus ∼ − 3.5‰ in carbonate). These data indicate that the negative carbon-isotope excursion affected the atmosphere and, by implication, the global ocean as well. The difference in amplitude between terrestrial organic and marine carbonate curves can be explained by greater water availability in the terrestrial environment during the negative excursion, for which there is independent evidence from marine osmium-isotope records and, plausibly, changes in atmospheric CO2 content, for which independent evidence is also available. The Peniche succession is also notable for the occurrence of re-deposited sediments: their lowest occurrence coincides with the base of the negative excursion and their highest occurrence coincides with its top. Thus, slope instability and sediment supply could have been strongly linked to the global environmental perturbation, an association that may misleadingly simulate the effects of sea-level fall.  相似文献   

12.
A long-standing question in Paleogene climate concerns the frequency and mechanism of transient greenhouse gas-driven climate shifts (hyperthermals). The discovery of the greenhouse gas-driven Paleocene–Eocene Thermal Maximum (PETM; ～ 55 Ma) has spawned a search for analogous events in other parts of the Paleogene record. On the basis of high-resolution bulk sediment and foraminiferal stable isotope analyses performed on three lower Danian sections of the Atlantic Ocean, we report the discovery of a possible greenhouse gas-driven climatic event in the earliest Paleogene. This event – that we term the Dan-C2 event – is characterized by a conspicuous double negative excursion in δ13C and δ18O, associated with a double spike in increased clay content and decreased carbonate content. This suggests a double period of transient greenhouse gas-driven warming and dissolution of carbonates on the seafloor analogous to the PETM in the early Paleocene at ～ 65.2 Ma. However, the shape of the two negative carbon isotope excursions that make up the Dan-C2 event is different from the PETM carbon isotope profile. In the Dan-C2 event, these excursions are fairly symmetrical and each persisted for about ～ 40 ky and are separated by a short plateau that brings the combined duration to ～ 100 ky, suggesting a possible orbital control on the event. Because of the absence of a long recovery phase, we interpret the Dan-C2 event to have been associated with a redistribution of carbon that was already in the biosphere. The Dan-C2 event and other early Paleogene hyperthermals such as the short-lived early Eocene ELMO event may reflect amplification of a regular cycle in the size and productivity of the marine biosphere and the balance between burial of organic and carbonate carbon.  相似文献   

13.
This study demonstrates that petroleum and source rocks are enriched in Pt and Pd to the ppb level, and that the 187Os/188Os composition coupled with the Pt/Pd value permits the fingerprinting of petroleum to its source. Oils from the United Kingdom Atlantic Margin (sourced from the Upper Jurassic Kimmeridge Clay Fm.) as well as source rock samples have been analysed for Pt and Pd. When the Pt/Pd value is compared with 187Os/188Os (calculated at the time of oil generation; Osg) the values from both the known source and the oils are similar, demonstrating that they can be used as an oil to source fingerprinting tool. This inorganic petroleum fingerprinting tool is particularly important in heavily biodegraded petroleum systems where traditional fingerprinting techniques (e.g. biomarkers) are severely hampered, e.g. the world's largest oil sand deposit, the West Canadian Oil Sands (WCOS). This has caused the source of the WCOS to be hotly debated, with no present day consensus between inputs from potential source units e.g. Exshaw and Gordondale Fms. 187Os/188Os and Pt/Pd fingerprinting of the oil sands shows that the majority of the petroleum have similar 187Os/188Os and Pt/Pd values, supporting the hypothesis of one principal source. Analysis of the potential source rocks establishes that the principal source of the oil sands to be from the Jurassic Gordondale Fm., with a minor Exshaw Fm. input. Thus, the combination of previously pioneered Re–Os petroleum geochronology with 187Os/188Os and Pt/Pd values of petroleum permits both a temporal and spatial understanding of petroleum systems.  相似文献   

14.
《Journal of Geodynamics》2007,43(1):170-186
Stratigraphic and sedimentological studies indicate that Iceland has experienced over 20 glaciations during the last 4–5 Myr, in reasonable agreement with the number of glaciations reconstructed from the ∂18O record in deep-sea sediment. The pattern of glacial erosion was to a large part controlled by constructive volcanic processes resulting in increased topographic relief after 2.5 Myr. Between 2.5 and 0.5 Ma valleys up to 400 m deep were excavated into the Tertiary basalts of eastern and south Iceland with an average erosion rate of 10–20 cm ka−1. During the last 0.5 million years rates of erosion increased to 50–175 cm ka−1, with an additional 200 to over 1000 m of valley excavation. Previous estimates of the rate of landscape erosion during the Holocene vary widely, from 5 to 70,000 cm ka−1. We present new studies that define the rates of landscape denudation during the major part of the Holocene (the last 10,200 years): one based on the Iceland shelf sediment record, the other from the sediment record in the glacier-fed lake, Hvítárvatn. Both studies indicate average Holocene erosion rates of about 5 cm ka−1 similar to our erosion rate estimate for 4–5 Ma old strata that has not been subjected to regional glaciation.  相似文献   

15.
The widely accepted age estimate for the onset of glaciation in the Northern Hemisphere ranges between 2 and 15 million years ago (Ma). However, recent studies indicate the date for glacial onset may be significantly older. We report the presence of ice-rafted debris (IRD) in ～ 44 to 30 Ma sediments from the Greenland Sea, evidence for glaciation in the North Atlantic during the Middle Eocene to Early Oligocene. Detailed sedimentological evidence indicates that glaciers extended to sea level in the region, allowing icebergs to be produced. IRD may have been sourced from tidewater glaciers, small ice caps, and/or a continental ice sheet.  相似文献   

16.
The Kamchatka Peninsula in far eastern Russia represents the most volcanically active arc in the world in terms of magma production and the number of explosive eruptions. We investigate large-scale silicic volcanism in the past several million years and present new geochronologic results from major ignimbrite sheets exposed in Kamchatka. These ignimbrites are found in the vicinity of morphologically-preserved rims of partially eroded source calderas with diameters from ～ 2 to ～ 30 km and with estimated volumes of eruptions ranging from 10 to several hundred cubic kilometers of magma. We also identify and date two of the largest ignimbrites: Golygin Ignimbrite in southern Kamchatka (0.45 Ma), and Karymshina River Ignimbrites (1.78 Ma) in south-central Kamchatka. We present whole-rock geochemical analyses that can be used to correlate ignimbrites laterally. These large-volume ignimbrites sample a significant proportion of remelted Kamchatkan crust as constrained by the oxygen isotopes. Oxygen isotope analyses of minerals and matrix span a 3‰ range with a significant proportion of moderately low-δ18O values. This suggests that the source for these ignimbrites involved a hydrothermally-altered shallow crust, while participation of the Cretaceous siliceous basement is also evidenced by moderately elevated δ18O and Sr isotopes and xenocryst contamination in two volcanoes. The majority of dates obtained for caldera-forming eruptions coincide with glacial stages in accordance with the sediment record in the NW Pacific, suggesting an increase in explosive volcanic activity since the onset of the last glaciation 2.6 Ma. Rapid changes in ice volume during glacial times and the resulting fluctuation of glacial loading/unloading could have caused volatile saturation in shallow magma chambers and, in combination with availability of low-δ18O glacial meltwaters, increased the proportion of explosive vs effusive eruptions. The presented results provide new constraints on Pliocene–Pleistocene volcanic activity in Kamchatka, and thus constrain an important component of the Pacific Ring of Fire.  相似文献   

17.
The Chinkuashih district at northern Taiwan hosts one of the largest Au deposits in the western Pacific gold province. Gold were precipitated from hydrothermal solutions as native gold or incorporated into sulfides at a temperature range of 200-350 °C. The sulfides in ore mines have 187Os/188Os ratios varying from 0.139 to 0.249. The positive 187Os/188Os-1/Os correlation is consistent with derivation from the hybrid fluids containing various proportions of mantle and crustal components. The crustal component was the meteoric water that had acquired its Sr and Os isotopic signatures from the local sedimentary formations and dacitic intrusions. The mantle component was the magmatic fluid segregated from the dacitic magma by fractional crystallization. Based on the 187Os/188Os-1/Os correlation, the hybrid fluids forming the Chinkuashih sulfides contained less than 30% magmatic fluid, except for one sulfide sample from Hsumei, which required >40% magmatic fluid. Compared to meteoric water, the magmatic fluid contained a higher Os content (130 times higher) and was enriched in Os relative to Sr with an Os/Sr ratio two orders higher than that of the crustal fluid. Consequently, the Os budget in the hybrid fluids was controlled by the magmatic fluid, although the meteoric water was volumetrically dominated. If gold and Os behave similarly in chemistry, the Chinkuashih gold deposits are of mantle origin and the area where sulfides with the greatest mantle Os signature may host undiscovered gold deposits. Finally, the 187Os/188Os ratios of sulfides show no relationship with the mineral assemblages of sulfides, implying that the sulfide mineral assemblages reflect local surfacial redox conditions rather than the chemical characteristics of parental fluids.  相似文献   

18.
The Pacific margin of Canada has been subjected to tectonism, dramatic sea level change and vigorous storm and tidal energy since glacial times resulting in a complex seafloor. Extensive multibeam mapping of this shelf has provided an opportunity to understand how these processes have impacted sedimentology and morphology. Bathymetric restriction of the tidally dominated flow between the inland seas and the open Pacific has resulted in the development of very large subaqueous dune fields and terrace moats. For example, in the southern Strait of Georgia nearly symmetrical dunes with wavelengths between 100 and 300 m, dune heights up to 28 m, cover the seafloor in 170–210 m water depth. In northern Hecate Strait a 72 km2 area of large 2D dunes occurs at the transition with Dixon Entrance which opens to the Pacific Ocean and steep (>10°) wave-cut terraces and drowned spits, a result of sea level changes during the Holocene, are now being undercut to generate moats 7 m deep, in a narrowing shelf trough. Currents, with velocities ranging between 0.2 and 2.2 m s?1, are dominated by semi-diurnal tidal streams that are continually modified by wind and estuarine circulation. There appears to be a clear association of grain size, water depth and flow velocity controlling the size of the subaqueous dunes.  相似文献   

19.
The transition from the early Pliocene “Warmhouse” towards the present “Icehouse” climate and the role of Gateway dynamics are intensively debated. Both, the constrictions of the Central American Seaway and the Indonesian Gateway affected ocean circulation and climate during the Pliocene epoch. Here, we use combined δ18O and Mg/Ca ratios of planktonic foraminifera (marine protozoa) from surface and subsurface levels to reconstruct the thermal structure and changes in salinities from the Southwest Pacific Deep Sea Drilling Project (DSDP) Site 590B from 6.5 to 2.5 Ma. Our data suggest a gradual cooling of ~ 2 °C and freshening of the sea surface during ~ 4.6–4 Ma with an increased meridional temperature gradient between the West Pacific Warm Pool and the Southwest Pacific when the closing of the Central American Seaway reached a critical threshold. After ~ 3.5 Ma, the restricted Indonesian Gateway might have amplified the East Australian Current, allowing enhanced heat transport towards the Southwest Pacific with reduced meridional temperature gradients when the global climate gradually cooled. At the same time our data suggest a cooling and freshening of Subantarctic Mode Water (SAMW) or/and an increased northward flow of SAMW towards Site 590B, possibly a first step towards the present Antarctic Frontal System.  相似文献   

20.
Paleoelevation constraints from fossil leaf physiognomy and stable isotopes of sedimentary carbonate suggest that significant surface uplift of the northern Andean plateau, on the order of 2.5 ± 1 km, occurred between ～ 10.3 and 6.4 Ma. Independent spatial and temporal constraints on paleoelevation and paleoclimate of both the northern and southern plateau are important for understanding the distribution of rapid surface uplift and its relation to climate evolution across the plateau. This study focuses on teeth from modern and extinct mammal taxa (including notoungulates, pyrotheres, and litopterns) spanning ～ 29 Ma to present, collected from the Altiplano and Eastern Cordillera of Bolivia (16.2°S to 21.4°S), and lowland Brazil. Tooth enamel of large, water-dependent mammals preserves a record of surface water isotopes and the type of plants that animals ingested while their teeth were mineralizing. Previous studies have shown that the δ18O of modern precipitation and surface waters decrease systematically with increasing elevations across the central Andes. Our results from high elevation sites between 3600 and 4100 m show substantially more positive δ18O values for late Oligocene tooth samples compared to < 10 Ma tooth δ18O values. Late Oligocene teeth collected from low elevation sites in southeast Brazil show δ18O values similar (within 2‰) to contemporaneous teeth collected at high elevation in the Eastern Cordillera. This affirms that the Andean plateau was at a very low elevation during the late Oligocene. Late Oligocene teeth from the northern Eastern Cordillera also yield consistent δ13C values of about ? 9‰, indicating that the environment was semi-arid at that time. Latitudinal gradients in δ18O values of late Miocene to Pliocene fossil teeth are similar to modern values for large mammals, suggesting that by ～ 8 Ma in the northern Altiplano and by ～ 3.6 Ma in the southern Altiplano, both regions had reached high elevation and established a latitudinal rainfall gradient similar to modern.  相似文献   

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