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1.
A large sediment deposit known as the Meiji Drift, located in the northwestern Pacific Ocean, is thought to have formed from deep water exiting the Bering Sea, although no notable deep water forms there presently. We determine the terrigenous sources since 140 ka to the drift using bulk sediment 40Ar–39Ar and Nd isotopic analyses on the silt-sized (20–63 μm) terrigenous fraction from Ocean Drilling Program (ODP) Site 884 to reconstruct paleo-circulation patterns. There are large changes in both isotopic tracers, varying on glacial–interglacial cycles. During glacial intervals, bulk sediment 40Ar–39Ar ages range between 40 and 80 Ma, while Nd isotopic values range from εNd = ? 1 to + 2. During interglacial intervals, sediments become much younger and more radiogenic, with bulk sediment ages falling to 2–15 Ma and Nd isotopic values ranging between εNd = + 5 and + 9. These data and quantitative comparison to potential source rocks indicate that the young Kamchatkan and Aleutian Arcs, lying NW and NE of the Meiji Drift, contribute the majority of sediment during interglacials. Conversely, older source rocks, such as those drained by the Yukon River and northeast Russia are the dominant origin of sediments during glacials. Mixing model calculations suggest that as much as 35–45% of the sediment deposited in the Meiji Drift during glacials is from the Bering Sea. It remains unclear whether thermohaline-type circulation or focussing of Bering Sea flow lead to the glacial–interglacial sediment source changes observed here.  相似文献   

2.
Understanding the history of Antarctic glaciation is important for interpreting paleoclimatic changes and estimating the changes in climate, sea level, and ice volume in the future. Ice core studies of the East Antarctic Ice Sheet (EAIS) and marine sediment cores from the entire Ross Sea have employed numerous proxies to reconstruct the glacial history of the Antarctic region. However, the ice and marine core records can be biased because of their specific locations, such as the uppermost accumulation zone or the terminus of the ablation zone, thereby introducing significant uncertainties in ice modeling. In this study, we analyzed 34 new 10Be and 26Al samples from four benches that were glaciated in the past by David glacier and incorporate the present ice-free flat surfaces. We suggest that the David glacier experienced monotonic and stepwise vertical lowering along the flanks of Mt. Priestley since the early Pleistocene. The uppermost bedrock benches on Mt. Priestley were exposed at 1.77 ± 0.32 Ma, with no evidence of subsequent overriding by readvancing ice. At Mt. Priestley, the David glacier has been characterized by a cold-based regime since 1.77 Ma, with a denudation rate of only ∼16 cm/Ma, corresponding to the regional transition from warm to cold-based glaciation at 3.5 Ma. Simple exposure ages from two lower benches date to Marine Isotope Stage (MIS) 7 (234.1 ± 13.1 ka; 545 m asl) and MIS 4 (64.8 ± 13.7 ka; 222 m asl), suggesting that, since MIS 8, the overall lowering of glaciers has remained monotonic. The upper bench marks the lower limit of the MIS 8 glacial period and the upper limit of Penultimate Glacial Maximum (MIS 6), while the lower landform defines the upper limit of the last glacial period (MIS 4–2). The magnitude of Quaternary ice thinning at the David glacier was the highest (∼990 m) in the present terminal area (i.e., the most sensitive ablation zone), in contrast to the other outlet glaciers draining into the Terra Nova Bay, which experienced less ice lowering. The combination of the terrestrial (in situ 10Be and 26Al) and previous marine (authigenic 10Be) cosmogenic data used in our study document the history of lowering of the David glacier driven by climatic changes during the Pleistocene. Both deglaciation and glaciation were limited during the mid-Pleistocene transition (MPT) and prior to the mid-Bruhnes event (MBE), due to the prevailing cold and arid climate, whereas deglaciation was dominant during other warm periods.  相似文献   

3.
The ～ 14 km diameter Jänisjärvi impact structure is located in Svecofennian Proterozoic terrain in the southeastern part of the Baltic shield, Karelia, Russia. Previous radioisotopic dating attempts gave K/Ar and 40Ar/39Ar ages of 700 ± 5 Ma and 698 ± 22 Ma, respectively, with both results being difficult to interpret. Recent paleomagnetic results have challenged these ages and proposed instead ages of either 500 Ma or 850–900 Ma. In order to better constrain the age of the Jänisjärvi impact structure, we present new 40Ar/39Ar data for the Jänisjärvi impact melt rock. We obtained five concordant isochron ages that yield a combined isochron age of 682 ± 4 Ma (2σ) with a MSWD of 1.2, P = 0.14, and 40Ar/36Ar intercept of 475 ± 3. We suggest that this date indicates the age of the impact and therefore can be used in conjunction with existing paleomagnetic results to define the position of the Baltica paleocontinent at that time. Argon isotopic results imply that melt homogenization was achieved at the hundred-micrometer scale certainly, because of the low-silica content of the molten target rock that allows fast 40Ar? diffusion in the melt. However, the large range of F(40Ar?inherited) (4.1% to 11.0%) observed for seven grains shows that complete isotopic homogenization was not reached at the centimeter and perhaps the millimeter scale. The F(40Ar?inherited) results are also in good agreement with previous Rb and Sr isotopic data.  相似文献   

4.
The Adelaide rift complex in South Australia contains the type sections for Sturtian and Marinoan glacial deposits. The litho- and chemo-stratigraphy of these deposits play a central role in evaluating global Neoproterozoic ice age hypotheses and Rodinia supercontinent reconstructions, but reliable depositional age constraints have been extremely limited. We report results of in situ Th–U–total Pb (electron microprobe) dating of detrital and authigenic monazite in two samples from the Umberatana Group (Sturtian Holowilena Ironstone and pre-Marinoan Enorama Shale) in the Central Flinders Ranges. Several texturally and chemically distinct detrital and authigenic populations are recognized. Detrital dates range from 1600 Ma to 760 Ma and most relate to well-known orogenic or igneous events in surrounding cratonic regions. Authigenic monazite grew in three or more pulses ranging from 680 Ma to 500 Ma. The date of 680 ± 23 Ma (2σ) for the earliest generation of authigenic monazite in sandstone from the Enorama Shale (1) provides an estimate for the age of the base of the Trezona carbon isotopic anomaly just beneath the Marinoan glacial deposits, (2) provides an absolute minimum age constraint on the underlying Sturtian glacial deposits, and (3) supports proposed correlations between type Marinoan deposits and precisely dated glacial deposits in Namibia and China, which bracket the presumed Marinoan equivalents between 655 and 635 Ma. This age is inconsistent with a Re–Os isochron age of 643 ± 2.4 Ma (2σ) on shales near the bottom of the Sturtian–Marinoan interglacial succession, stratigraphically > 3000 m below the Enorama Shale sample, and militate against the hypothesis that the type Marinoan is correlative with the 580 Ma Gaskiers glaciation. Monazite growth near 600 Ma and again at about 500 Ma probably represent hydrothermal fluid-flow events, the latter of which also corresponds to the well-known Delamerian Orogeny during which the Adelaide sediments were folded into their present structural pattern.  相似文献   

5.
The Kamchatka Peninsula in far eastern Russia represents the most volcanically active arc in the world in terms of magma production and the number of explosive eruptions. We investigate large-scale silicic volcanism in the past several million years and present new geochronologic results from major ignimbrite sheets exposed in Kamchatka. These ignimbrites are found in the vicinity of morphologically-preserved rims of partially eroded source calderas with diameters from ～ 2 to ～ 30 km and with estimated volumes of eruptions ranging from 10 to several hundred cubic kilometers of magma. We also identify and date two of the largest ignimbrites: Golygin Ignimbrite in southern Kamchatka (0.45 Ma), and Karymshina River Ignimbrites (1.78 Ma) in south-central Kamchatka. We present whole-rock geochemical analyses that can be used to correlate ignimbrites laterally. These large-volume ignimbrites sample a significant proportion of remelted Kamchatkan crust as constrained by the oxygen isotopes. Oxygen isotope analyses of minerals and matrix span a 3‰ range with a significant proportion of moderately low-δ18O values. This suggests that the source for these ignimbrites involved a hydrothermally-altered shallow crust, while participation of the Cretaceous siliceous basement is also evidenced by moderately elevated δ18O and Sr isotopes and xenocryst contamination in two volcanoes. The majority of dates obtained for caldera-forming eruptions coincide with glacial stages in accordance with the sediment record in the NW Pacific, suggesting an increase in explosive volcanic activity since the onset of the last glaciation 2.6 Ma. Rapid changes in ice volume during glacial times and the resulting fluctuation of glacial loading/unloading could have caused volatile saturation in shallow magma chambers and, in combination with availability of low-δ18O glacial meltwaters, increased the proportion of explosive vs effusive eruptions. The presented results provide new constraints on Pliocene–Pleistocene volcanic activity in Kamchatka, and thus constrain an important component of the Pacific Ring of Fire.  相似文献   

6.
In the summer of 2005, continuous surface water measurements of fugacity of CO2 (fCO2sw), salinity and temperature were performed onboard the IB Oden along the Northwest Passage from Cape Farwell (South Greenland) to the Chukchi Sea. The aim was to investigate the importance of sea ice and river runoff on the spatial variability of fCO2 and the sea–air CO2 fluxes in the Arctic Ocean. Additional data was obtained from measurements of total alkalinity (AT) by discrete surface water and water column sampling in the Canadian Arctic Archipelago (CAA), on the Mackenzie shelf, and in the Bering Strait. The linear relationship between AT and salinity was used to evaluate and calculate the relative fractions of sea ice melt water and river runoff along the cruise track. High-frequency fCO2sw data showed rapid changes, due to variable sea ice conditions, freshwater addition, physical upwelling and biological processes. The fCO2sw varied between 102 and 678 μatm. Under the sea ice in the CAA and the northern Chukchi Sea, fCO2sw were largely CO2 undersaturated of approximately 100 μatm lower than the atmospheric level. This suggested CO2 uptake by biological production and limited sea–air CO2 gas exchange due to the ice cover. In open areas, such as the relatively fresh water of the Mackenzie shelf and the Bering Strait, the fCO2sw values were close to the atmospheric CO2 level. Upwelling of saline and relatively warm water at the Cape Bathurst caused a dramatic fCO2sw increase of about 100 μatm relative to the values in the CAA. At the southern part of the Chukchi Peninsula we found the highest fCO2sw values and the water was CO2 supersaturated, likely due to upwelling. In the study area, the calculated sea–air CO2 flux varied between an oceanic CO2 sink of 140 mmol m−2 d−1 and an oceanic source of 18 mmol m−2 d−1. However, in the CAA and the northern Chukchi Sea, the sea ice cover prevented gas exchange, and the CO2 fluxes were probably negligible at this time of the year. Assuming that the water was exposed to the atmosphere by total melting and gas exchange would be the only process, the CO2 undersaturated water in the ice-covered areas will not have the time to reach the atmospheric CO2 value, before the formation of new sea ice. This study highlights the value of using high-frequency measurements to gain increased insight into the variable and complex conditions, encountered on the shelves in the Arctic Ocean.  相似文献   

7.
There are still relatively few hydrochemical studies of glacial runoff and meltwater routing from the high latitudes, where non-temperate glacier ice is frequently encountered. Representative samples of glacier meltwater were obtained from Scott Turnerbreen, a ‘cold-based’ glacier at 78° N in the Norwegian high Arctic archipelago of Svalbard, during the 1993 melt season and analysed for major ion chemistry. Laboratory dissolution experiments were also conducted, using suspended sediment from the runoff. Significant concentrations of crustal weathering derived SO2−4 are present in the runoff, which is characterized by high ratios of SO2−4: (SO2−4+HCO−3) and high p(CO2). Meltwater is not routed subglacially, but flows to the glacier terminus through subaerial, ice marginal channels, and partly flows through a proglacial icing, containing highly concentrated interstitial waters, immediately afront the terminus. The hydrochemistry of the runoff is controlled by: (1) seasonal variations in the input of solutes from snow- and icemelt; (2) proglacial solute acquisition from the icing; and (3) subaerial chemical weathering within saturated, ice-cored lateral moraine adjoining drainage channels at the glacier margins, sediment and concentrated pore water from which is entrained by flowing meltwater. Diurnal variations in solute concentration arise from the net effects of variable sediment pore water entrainment and dilution in the ice marginal streams. Explanation of the hydrochemistry of Scott Turnerbreen requires only one major subaerial flow path, the ice marginal channel system, in which seasonally varying inputs of concentrated snowmelt and dilute icemelt are modified by seepage or entrainment of concentrated pore waters from sediment in lateral moraine, and by concentrated interstitial waters from the proglacial icing, supplied by leaching, slow drainage at grain intersections or simple melting of the icing itself. The ice marginal channels are analogous neither to dilute supra/englacial nor to concentrated subglacial flow components. © 1998 John Wiley & Sons, Ltd.  相似文献   

8.
A new dry gas extraction and analysis method for small (1 cm3) ice samples is presented. The extraction device, cooled to ?20°C, contains two movable steel needle matrices for crushing the ice. During the crushing process the gas escaping from the ice sample is continuously analyzed for CO2 with an infrared laserspectrometer. This method enables a fast measurement (few minutes) of the CO2 concentration in the air bubbles with high spatial resolution in the ice core and a minimum potential contamination. An important CO2 contamination source due to an interaction of water vapour with surfaces is shortly discussed.The reproducibility of extraction and analysis is ±2%. We analyzed CO2 concentrations in the trapped air from different ice cores originating from the Greenland ice sheet and from Antarctica.  相似文献   

9.
We reconstruct the timing of ice flow reconfiguration and deglaciation of the Central Alpine Gotthard Pass, Switzerland, using cosmogenic 10Be and in situ 14C surface exposure dating. Combined with mapping of glacial erosional markers, exposure ages of bedrock surfaces reveal progressive glacier downwasting from the maximum LGM ice volume and a gradual reorganization of the paleoflow pattern with a southward migration of the ice divide. Exposure ages of ∼16–14 ka (snow corrected) give evidence for continuous early Lateglacial ice cover and indicate that the first deglaciation was contemporaneous with the decay of the large Gschnitz glacier system. In agreement with published ages from other Alpine passes, these data support the concept of large transection glaciers that persisted in the high Alps after the breakdown of the LGM ice masses in the foreland and possibly decayed as late as the onset of the Bølling warming. A younger group of ages around ∼12–13 ka records the timing of deglaciation following local glacier readvance during the Egesen stadial. Glacial erosional features and the distribution of exposure ages consistently imply that Egesen glaciers were of comparatively small volume and were following a topographically controlled paleoflow pattern. Dating of a boulder close to the pass elevation gives a minimum age of 11.1 ± 0.4 ka for final deglaciation by the end of the Younger Dryas. In situ 14C data are overall in good agreement with the 10Be ages and confirm continuous exposure throughout the Holocene. However, in situ 14C demonstrates that partial surface shielding, e.g. by snow, has to be incorporated in the exposure age calculations and the model of deglaciation.  相似文献   

10.
To improve the French Plio-Pleistocene biostratigraphy scheme based on mammal biozone boundaries or “Mammal Neogene/Quaternary Zones” (MNQ) we collected volcanic material that could be dated using the 40Ar/39Ar method in five exceptional mammalian paleofauna sites located in the Massif Central (France). We present 40Ar/39Ar ages that we obtained for Perrier-Les Etouaires, Roca-Neyra, Chilhac, Senèze and le Creux de Peyrolles. We show that the overall stratigraphic position of these sites based on faunal assemblages is valid from the relative point of view. However, we greatly improve both the accuracy and precision of the age of these mammalian paleofaunas. We obtained 40Ar/39Ar ages varying between 2.78 ± 0.01 Ma (1σ external) for Les Etouaires (Lower MNQ 16b) and 1.47 ± 0.01 Ma for the Creux de Peyrolles site (MNQ 19). Based on these new dates we estimate the duration of several biozones including MNQ 16b, 17a and 17b. We suggest that the first Late Villafranchian biozone (MNQ 18) starts as early as the Reunion subchron or just after. The first occurrence of Equus stenonis in Roca-Neyra (i.e. 2.60 ± 0.02 Ma) is close to or synchronous with the Gauss–Matuyama transition (i.e. 2.59 Ma) and the Pliocene/Pleistocene boundary. The chronological framework we build shows the very rapid increase of the large grazers community in French faunal assemblages at the beginning of MNQ 17 (i.e. 2.6 to 2.4 Ma). This rapid faunal turnover is probably associated with a general decrease of woodland habitat in the Massif Central contemporaneous with the onset of the Northern Hemisphere glaciations. The faunal assemblages in France, Spain, and Italy covering the period between 2.1 and 2.0 Ma suggest that favorable conditions for early hominin settlement (mainly savannah prairies, grassland with open forest patches) existed in southwestern Europe at least 200 ka before the first traces of Homo in Eurasia. This period also shows the arrival of taxa originating in Asia and Africa, suggesting dispersal events within southwestern Europe well before the Olduvai subchron and with no indication (as yet) of Homo as a “fellow traveler”.  相似文献   

11.
To date, studies of the stability of subsurface ice in the McMurdo Dry Valleys of Antarctica have been mainly based on climate-based vapor diffusion models. In University Valley (1800 m), a small glacier is found at the base of the head of the valley, and adjacent to the glacier, a buried body of massive ice was uncovered beneath 20–40 cm of loose cryotic sediments and sandstone boulders. This study assesses the origin and stability of the buried body of massive ice by measuring the geochemistry and stable O–H isotope composition of the ice and applies a sublimation and molecular diffusion model that accounts for the observed trends. The results indicate that the buried massive ice body represents an extension of the adjacent glacier that was buried by a rock avalanche during a cold climate period. The contrasting δ18O profiles and regression slope values between the uppermost 6 cm of the buried massive ice (upward convex δ18O profile and SD-18O = 5.1) and that below it (progressive increase in δ18O and SD-18O = 6.4) suggest independent post-depositional processes affected the isotope composition of the ice. The upward convex δ18O profile in the uppermost 6 cm is consistent with the ice undergoing sublimation. Using a sublimation and molecular diffusion model, and assuming that diffusion occurred through solid ice, the sublimation rate needed to fit the measured δ18O profile is 0.2 ? 10? 3 mm yr? 1, a value that is more similar to net ice removal rates derived from 3He data from cobbles in Beacon Valley till (7.0 ? 10? 3 mm yr? 1) than sublimation rates computed based on current climate (0.1–0.2 mm yr?1). We suggest that the climate-based sublimation rates are offset due to potential ice recharge mechanisms or to missing parameters, particularly the nature and thermo-physical properties of the overlying sediments (i.e., temperature, humidity, pore structure and ice content, grain size).  相似文献   

12.
We have applied the unspiked K-Ar and the 40Ar/39Ar methods to samples precisely collected and localised, on both Central Indian Ridge flanks, to test their effectiveness and reliability when applied to the dating of recent (i.e. less than 1 Ma) MORBs. Twenty six samples) from the sixty five samples collected every ∼500 m up to the Brunhes-Matuyama boundary on both ridge flanks, were selected based on their distance from the ridge axis. Therefore, we can evaluate whether the isotopic ages are a good indicator of the crystallisation age by considering their geographic position with respect to the ridge axis (zero age) and the B/M magnetic boundary. Direct comparison of the isotopic and model ages shows that only 9 out of 26 samples were successfully dated. The GIMNAUT – MORB's test case amply demonstrates that the unspiked K-Ar technique, when applied to submerged volcanic samples, is subject to potentially defective assumptions of trapped atmospheric argon, excess/fractionated argon and extremely sensitive to alteration. Although the unspiked K-Ar technique is theoretically capable to produce high precision ages, the comparison with the 40Ar/39Ar techniques reveals that only 15% (i.e. 4 samples out of 26) of the ages obtained here are geologically meaningful. Five of the seven 40Ar/39Ar incremental heating experiments provide meaningful ages. Because potential sources of systematic errors such as excess 40Ar*, recoil of 39ArK and 37ArCa can be identified and because effects of alteration are significantly reduced by the pre-heating of the samples up to 500–600°c, the 40Ar/39Ar incremental heating method appears to be the method of choice to date MORBs.  相似文献   

13.
Data on the distribution of fCO2 were obtained during a cruise in the Aegean Sea during February 2006. The fCO2 of surface water (fCO2sw) was lower than the atmospheric fCO2 (fCO2atm) throughout the area surveyed and ΔfCO2 values varied from ?34 to ?61 μatm. The observed under-saturation suggests that surface waters in the Aegean represent a sink for atmospheric CO2 during the winter of 2006. Higher fCO2sw values were recorded in the ‘less warm’ and ‘less saline’ shallow northernmost part of the Aegean Sea implying that the lower seawater temperature and salinity in this area play a crucial role in the spatial distribution of fCO2sw.A first estimate of the magnitude of the air–sea CO2 exchange and the potential role of the Aegean Sea in the transfer of atmospheric CO2 was also obtained. The air–sea CO2 fluxes calculated using different gas transfer formulations showed that during February 2006, the Aegean Sea absorbs atmospheric CO2 at a rate ranging from ?6.2 to ?11.8 mmol m?2 d?1 with the shipboard recorded wind speeds and at almost half rate (?3.5 to ?5.5 mmol m?2 d?1) with the monthly mean model-derived wind speed. Compared to recent observations from other temperate continental shelves during winter period, the Aegean Sea acts as a moderate to rather strong sink for atmospheric CO2.Further investigations, including intensive spatial and temporal high-resolution observations, are necessary to elucidate the role of the Aegean Sea in the process of transfer of atmospheric CO2 into the deep horizons of the Eastern Mediterranean.  相似文献   

14.
Meltwaters collected from boreholes drilled to the base of the Haut Glacier d'Arolla, Switzerland have chemical compositions that can be classified into three main groups. The first group is dilute, whereas the second group is similar to, though generally less concentrated in major ions, than contemporaneous bulk glacial runoff. The third group is more concentrated than any observed bulk runoff, including periods of flow recession. Waters of the first group are believed to represent supraglacial meltwater and ice melted during drilling. Limited solutes may be derived from interactions with debris in the borehole. The spatial pattern of borehole water levels and borehole water column stratification, combined with the chemical composition of the different groups, suggest that the second group represent samples of subglacial waters that exchange with channel water on a diurnal basis, and that the third group represent samples of water draining through a ‘distributed’ subglacial hydraulic system. High NO−3 concentrations in the third group suggest that snowmelt may provide a significant proportion of the waters and that the residence time of the waters at the bed in this particular section of the distributed system is of the order of a few months. The high NO−3 concentrations also suggest that some snowmelt is routed along different subglacial flowpaths to those used by icemelt. The average SO2−4: (HCO−3 + SO2−4) ratio of the third group of meltwaters is 0.3, suggesting that sulphide oxidation and carbonate dissolution (which gives rise to a ratio of 0.5) cannot provide all the HCO−3 to solution. Hence, carbonate hydrolysis may be occurring before sulphide oxidation, or there may be subglacial sources of CO2, perhaps arising from microbial oxidation of organic C in bedrock, air bubbles in glacier ice or pockets of air trapped in subglacial cavities. The channel marginal zone is identified as an area that may influence the composition of bulk meltwater during periods of recession flow and low diurnal discharge regimes. © 1997 by John Wiley & Sons, Ltd.  相似文献   

15.
Stable isotope variability and fractionation associated with transformation of precipitation/accumulation to firn to glacial river water is critical in a variety of climatic, hydrological and paleoenvironmental studies. This paper documents the modification of stable isotopes in water from precipitation to glacier runoff in an alpine catchment located in the central Tibetan Plateau. Isotopic changes are observed by sampling firnpack profiles, glacier surface snow/ice, meltwater on the glacier surface and catchment river water at different times during a melt season. Results show the isotopic fractionation effects associated with glacier melt processes. The slope of the δD‐δ18O regression line and the deuterium excess values decreased from the initial precipitation to the melt‐impacted firnpack (slope from 9.3 to 8.5 and average d‐excess from 13.4‰ to 7.4‰). The slope of the δD‐δ18O line further decreased to 7.6 for the glacier runoff water. The glacier surface snow/ice from different locations, which produces the main runoff, had the same δD‐δ18O line slope but lower deuterium excess (by 3.9‰) compared to values observed in the firnpack profile during the melt season. The δD‐δ18O regression line for the river water exhibited a lower slope compared to the surface snow/ice samples, although they were closely located on the δD‐δ18O plot. Isotope values for the river and glacier surface meltwater showed little scatter around the δD‐δ18O regression line, although the samples were from different glaciers and were collected on different days. Results indicate a high consistency of isotopic fractionation in the δD‐δ18O relationships, as well as a general consistency and temporal covariation of meltwater isotope values at the catchment scale. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
Cosmogenic nuclide exposure dating of glacial clasts is becoming a common and robust method for reconstructing the history of glaciers and ice sheets. In Antarctica, however, many samples exhibit cosmogenic nuclide ‘inheritance’ as a result of sediment recycling and exposure to cosmic radiation during previous ice free periods. In-situ cosmogenic 14C, in combination with longer lived nuclides such as 10Be, can be used to detect inheritance because the relatively short half-life of 14C means that in-situ 14C acquired in exposure during previous interglacials decays away while the sample locality is covered by ice during the subsequent glacial. Measurements of in-situ 14C in clasts from the last deglaciation of the Framnes Mountains in East Antarctica provide deglaciation ages that are concordant with existing 26Al and 10Be ages, suggesting that in this area, the younger population of erratics contain limited inheritance.  相似文献   

17.
New high-precision single crystal sanidine 40Ar/39Ar ages for the Huckleberry Ridge Tuff (HRT), Yellowstone volcanic field, show that the three HRT members (A, B, and C) represent at least two different eruptions. The new 40Ar/39Ar ages (all ages calculated relative to the optimisation model of Renne et al., 2011) are: 2.135 ± 0.006 Ma, 2.131 ± 0.008 Ma, and 2.113 ± 0.004 Ma (2σ, full uncertainty propagation), for members A, B and C, respectively. Members A and B are within uncertainty of one another and both are more precise than, but in agreement with, previously published ages. Member C was erupted later than members A and B. HRT members A and B were deposited during the Reunion Normal Polarity Subchron (C2r.1n). Member C was deposited during Subchron C2r.1r. Previously published radiogenic and stable isotope data show that member C was sourced from an isotopically discrete magma with a higher fraction of crustal material than members A and B. The volume of the first HRT eruption is reduced by c. 12% from previous estimates and explosive eruptions from the Yellowstone volcanic field occurred more frequently, producing more homogeneous magma than was previously believed. High-precision 40Ar/39Ar dating is key for resolving the eruptive history of Yellowstone, temporal dissection of voluminous ignimbrites, and rigorous investigation of what constitutes a ‘super-eruption’.  相似文献   

18.
This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO2 drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq+ m−2 a−1 for Svalbard (range: 160–560 Σmeq+ m−2 a−1), which lies within the global range of 94–4200 Σmeq+ m−2 a−1 for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq+ m−2 a−1. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO2 drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO2 drawdown lies in the range 110–3000 kg C km−2 a−1, whilst the range is 110–13000 kg C km−2 a−1 for the northern hemisphere glacial data set. Transient CO2 drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO2 drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

19.
Non-dispersive infrared(NDIR) and cavity ring-down spectroscopy(CRDS) CO_2 analyzers use 12CO_2 isotopologue absorption lines and are insensitive to all or part of other CO_2-related isotopologues. This may produce biases in CO_2 mole fraction measurements of a sample if its carbon isotopic composition deviates from that of the standard gases being used. To evaluate and compare the effects of carbon isotopic composition on NDIR and CRDS CO_2 analyzers, we prepared three test sample air cylinders with varying carbon isotopic abundances and calibrated them against five standard cylinders with ambient carbon isotopic composition using CRDS and NDIR systems. We found that the CO_2 mole fractions of the sample cylinders measured by G1301(CRDS) were in good agreement with those measured by Lo Flo(NDIR). The CO_2 values measured by both instruments were higher than that of a CO_2 isotope measured by G2201i(CRDS) analyzer for a test cylinder with depleted carbon isotopic composition δ~(13)C =-36.828‰, whereas no obvious difference was found for other two test cylinders with δ~(13)C=-8.630‰ and δ~(13)C=-15.380‰, respectively. According to the theoretical and experimental results, we concluded that the total CO_2 mole fractions of samples with depleted isotopic compositions can be corrected on the basis of their 12CO_2 values calibrated by standard gases using Lo Flo and G1301 if the δ~(13)C and δ18O values are known.  相似文献   

20.
Petrological, volcanological and geochronological data collected at Mathews Tuya together provide constraints on paleoclimate conditions during formation of the edifice. The basaltic tuya was produced via Pleistocene glaciovolcanism in northern British Columbia, Canada, and is located within the Tuya volcanic field (59.195°N/130.434°W), which is part of the northern Cordilleran volcanic province (NCVP). The edifice comprises a variety of lithofacies, including columnar-jointed lava, pillow lava, massive dikes, and volcaniclastic rocks. Collectively these deposits record the transition from an explosive subaqueous to an effusive subaerial eruption environment dominated by Pleistocene ice. As is typical for tuyas, the volcaniclastic facies record multiple fragmentation processes including explosive, quench and mechanical fragmentation. All samples from Mathews Tuya are olivine-plagioclase porphyritic alkali olivine basalts. They are mineralogically and geochemically similar to nearby glaciovolcanic centers from the southeastern part of the Tuya volcanic field (e.g., Ash Mountain, South Tuya, Tuya Butte) as well as the dominant NCVP rock type. Crystallization scenarios calculated with MELTS account for variations between whole rock and glass compositions via low pressure fractionation. The presence of olivine microphenocrysts and the absence of pyroxene phenocrysts constrain initial crystallization pressures to less than 0.6 GPa. The eruption of Mathews Tuya occurred between 0.718 ± 0.054 Ma and 0.742 ± 0.081 Ma based on 40Ar/39Ar geochronology (weighted mean age of 0.730 Ma). The age determinations provide the first firm documentation for large (>700 m thick), pre-Fraser/Wisconsin glaciers in north-central British Columbia ~0.730 Ma, and correlate in age with glaciovolcanic deposits in Russia (e.g., Komatsu et al. Geomorph 88: 352-366, 2007) and with marine isotopic evidence for large global ice volumes ~0.730 Ma.  相似文献   

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