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1.
New marine ΔR values for Arctic Canada   总被引：1，自引：0，他引：1  
For more than four decades, the reporting of 14C dates on marine molluscs from Arctic Canada has been notable for the lack of consistently applied marine reservoir corrections. We propose that the common approach of reporting Canadian Arctic marine 14C dates using presumed time-invariant reservoir corrections be abandoned in favour of calibration of 14C dates, using the current standard protocol. This approach best facilitates inter- and intra-regional correlation, and correlation with other geochronometers. In order to enable the consistent calibration of marine 14C dates from Arctic Canada, we analysed a 14C database of 108 marine mollusc samples collected live between 1894 and 1956, and determined regional reservoir offset values (ΔR) for eight oceanographically distinct regions. The following new ΔR values should be used for 14C calibration: NW Canadian Arctic Archipelago, 335 ± 85 yrs; Foxe Basin, 310 ± 90 yrs; NE Baffin Island, 220 ± 20 yrs; SE Baffin Island, 150 ± 60 yrs; Hudson Strait, 65 ± 60 yrs; Ungava Bay, 145 ± 95 yrs; Hudson Bay, 110 ± 65 yrs; and James Bay, 365 ± 115 yrs.  相似文献   

2.
The calibration of marine 14C dates requires the incorporation of regionally specific marine reservoir offsets known as ΔR, essential for accurate and meaningful inter-archive comparisons. Revised, regional ΔR (‘ΔRR’) values for the Barents Sea are presented for molluscs and cetaceans for the two latest iterations of the marine calibration curve, based on previously published pre-bomb live-collected and radiocarbon-dated samples (‘ΔRL’; molluscs: n = 16; cetaceans: n = 18). Molluscan ΔRR, determined for four broad regional oceanographic settings, are: western Svalbard (including Bjørnøya), −61 ± 37 14C yrs (Marine20), 94 ± 38 14C yrs (Marine13); Franz Josef Land, −277 ± 57 14C yrs (Marine20), −122 ± 38 14C yrs (Marine13); Novaya Zemlya, −156 ± 73 14C yrs (Marine20), 0 ± 76 14C yrs (Marine13); northern Norway, −86 ± 39 14C yrs (Marine20), 74 ± 24 14C yrs (Marine13). Molluscan ΔRR values are considered applicable to other marine carbonate materials (e.g., foraminifera, ostracods). Cetacean ΔRR are determined for toothed (n = 10) and baleen (n = 8) whales, and a combined toothed-baleen group (n = 18): toothed, −161 ± 41 14C yrs (Marine20), 1 ± 41 14C yrs (Marine13); baleen, −158 ± 43 14C yrs (Marine20), 8 ± 41 14C yrs (Marine13); combined baleen-toothed whales, −160 ± 41 14C yrs (Marine20), 4 ± 49 14C yrs (Marine13). Where identification and separation of baleen and toothed whales is impossible the combined ΔRR term may be used. However, we explicitly discourage the application of existing cetacean ΔRR terms to other marine mammals. Our new ΔRR values are applicable for as long as those broad oceanographic conditions (circulation and ventilation) have persisted, i.e., through the Holocene. We recommend using the latest iteration of the marine calibration curve, Marine20, which seems to better capture the time-variant nature of R compared to Marine13. More ΔRL datapoints for both molluscs and cetaceans would improve the accuracy and precision of ΔRR. In the meantime, our new ΔR terms facilitate the calibration of marine 14C dates across the region, paving the way for meaningful and accurate late Quaternary histories and inter-regional comparisons.  相似文献   

3.
This study utilizes a combined stable isotope and 14C dating approach to determine the radiocarbon reservoir age correction, ΔR, for the James River, Virginia estuary from 17th century Crassostrea virginica shells of known collection dates. ΔR, which can vary spatially and temporally, is a locality-specific adjustment applied to the global ocean reservoir, R, to further account for the offset between the atmospheric and marine 14C calibration curves. To assess the temporal variability in ΔR, continuous δ18O sampling along the oyster shell hinge provides a seasonal record throughout the oyster's life. This is then used to identify sampling locations for 14C measurements based on calcite precipitated during the Summer (>19 °C) and Fall through Spring (F-Sp, <15 °C) months. The resulting seasonal ΔR values range from −151 ± 46 to +109 ± 55 14C years (260 years) due to changes in the contribution and age of dissolved inorganic carbon (DIC) from marine and freshwater sources in the James River estuary. The F-Sp samples display a larger ΔR range than the Summer samples, as do the shells precipitated during drought conditions (1606–1612) when compared to shells from the remainder of the 17th century. The largest intrashell ΔR variability, 195 14C years, is similarly found in a drought shell and is attributed to variability caused by the extreme regional 1606–1612 drought. Early land use changes related to European development and farming practices also altered the age of DIC in the James River estuary. We estimate that the soil inorganic carbon (SIC) contributing to freshwater DIC ranged from 0 to ∼1800 years old and reflected both the drought and land use changes that occurred during the 17th century. Using only the Summer samples, which represent the majority of shell calcite, we obtain a mean ΔR = −32 ± 11 14C years (1σ) for 17th century James River estuary ΔR at the very onset of European colonization. Employing a seasonally resolved sampling method will provide the greatest constraint on 14C measurements in an estuarine environment where multiple carbon sources can fluctuate on seasonal timescales and as a result of large scale environmental change.  相似文献   

4.
Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from 210Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y−1 in the inner bay to 2.6 mm y−1 close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y−1 before the 1960s and 0.76 cm y−1 since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m3 s−1 to 160 m3 s−1. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.  相似文献   

5.
Dead stranded sea turtles were recovered and examined to determine the impact of anthropogenic debris and fishery activities on sea turtles on the coast of Rio Grande do Sul State, Brazil. Esophagus/stomach contents of 38 juvenile green Chelonia mydas, 10 adults and sub-adults loggerhead Caretta caretta, and two leatherback Dermochelys coriacea turtles (adult or sub-adult) included plastic bags as the main debris ingested, predominated by white and colorless pieces. The ingestion of anthropogenic debris accounted for the death of 13.2% of the green turtles examined. Signs of damage over the body and carapace indicated that fishing activities caused the death of 13.6% (3/22) of loggerheads and 1.5% (1/56) of green turtles. Therefore, it appears that direct and indirect effects of fishing activities may pose a threat to these species in Brazilian waters. Other sources of plastic debris should be investigated as well as the direct impact of fisheries, especially bottom trawl and gill nets, in order to establish effective conservation action.  相似文献   

6.
Magellanic penguins (Spheniscus magellanicus) are non-breeding winter visitors to the Brazilian coast. In 2008 and 2010, plastic items and other marine debris were found in the stomachs and intestines of 15% of 175 dead penguins collected in the Lagos Region of the state of Rio de Janeiro. One bird had its stomach perforated by a plastic straw, which may have caused its death. There are few records of penguins ingesting plastic litter, but previous studies have found similar levels of debris ingestion among Magellanic penguins stranded on the Brazilian coast (35.8% of 397 birds). The high incidence of marine debris in this species in Brazil may result at least in part from the predominance of juveniles reaching these waters, as juvenile penguins may have a broader diet than adults. It is unclear to what extent plastic ingestion affects the mortality rate in this species and whether the incidence in stranded birds reflects that in the entire population. The present study addresses the increasing impact of plastic debris on marine life.  相似文献   

7.
In an effort to better understand the dynamics of westward velocities of the nocturnal F-region plasma, the climatology of the westward traveling plasma bubbles – WTB – occurring during quiettime is studied here. The climatology of the WTB is analyzed here based on airglow images obtained during 14 quiet days between 2001 and 2006 at the Brazilian station São João do Cariri (Geographic 7.45°S, 36.5°W, dip ～20°S). The frequency of occurrence of the WTB maximizes in the descending phase of the solar cycle. The WTB velocities ranged between ～20 and 40 ms?1. The frequency of occurrence had a peak value of only 3.65% at 2345 LT. The maximum occurrence of the WTB was in July–September. No WTB have been observed from November until April in all years 2001–2006. We show for the first time theoretically that the WTB dominant forcing mechanisms during geomagnetically quiet days are westward thermospheric winds.  相似文献   

8.
Our aim was to quantify the effects of forest plantation and management (clear cut or 30% partial harvest) in relation to pasture, on catchment discharge in southeast Rio Grande do Sul state, Brazil. A paired‐catchment approach was implemented in two regions (Eldorado do Sul and São Gabriel municipalities) where discharge was measured for 4 years at three catchments in each region, two of which were predominantly eucalypt plantation (mainly Eucalyptus saligna, rotation of approximately 7–9 years) with native forest and grass in streamside zones. The third catchment was covered with grazed pasture. Weather, soils, canopy interception, groundwater level, tree growth, and leaf area index were also measured. The 3‐PG process‐based forest productivity model was adapted to predict spatial daily plantation and pasture water balance including precipitation interception, soil evaporation, transpiration, soil moisture, drainage, discharge, and monthly plantation growth. The TOPMODEL framework was used to simulate water pools and fluxes in the catchments. Discharge was higher under pasture than pre‐harvesting plantation and increased for 1–2 years after complete plantation harvest; this change was less pronounced in the catchments under partial harvest. The ratio of discharge to precipitation before harvesting varied from 7% to 13% in the eucalypt catchments and 28% to 29% under pasture. The ratio increases to 23–24% after total harvest, and to 17% after partial harvesting. The ratio under pasture also increases during this period (to 32–44%) owing to increased precipitation. The baseflow, in relation to total discharge, varied from 28% to 62% under Eucalyptus and from 38% to 43% in the pasture catchments. Hence, eucalypt plantations in these regions can be expected to influence discharge regimes when compared with pasture land use, and modelling suggests that partial harvesting would moderate the magnitude of discharge variation compared with a full catchment plantation harvesting. The model efficiency coefficient (Nash–Sutcliffe model efficiency coefficient) varied from 0.665 to 0.799 for the total period of the study. Simulation of alternative harvesting scenarios suggested that at least 20% of the catchment planted area must be harvested to increase discharge. This model could be a useful practical tool in various plantation forestry contexts around the world. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

9.
The climatology of ionospheric plasma bubbles is studied here by means of a comparison of the frequency of occurrence of the spread-F/plasma bubble events over the South American region using the images from two OI 630 nm imager systems located at the subequatorial station São João do Cariri—CA (7.4 S, 36.5 W, 20 S dip) and the low-latitude station Cachoeira Paulista—CP (22.5 S, 45 W, 33 S dip) in Brazil during the years of 2004 and 2005. The results are discussed in the light of current theory and geomagnetic parameters of the two observation stations.  相似文献   

10.
The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.  相似文献   

11.
There is a lack of detailed guidance in the published literature on how to calibrate 14C measurements made on marine or mixed marine/terrestrial (primarily human remains) samples. We describe what we consider to be the best approach towards achieving the most accurate calibrated age ranges, using the most appropriate ΔR and percentage marine diet estimates, and associated, realistic error terms on these values. However, this approach will increase the calibrated age range(s) by fully accounting for the variability in both the model and the material. While the discussion is based on examples from the UK and Iceland, the same fundamental arguments can be applied in any geographic location largely devoid of C4 plants as the high δ13C values from such plants can make identification of marine intake difficult to determine.  相似文献   

12.
Zn and Cd concentrations, stable lead isotopes and 210Pb-derived chronology were determined in a sediment core sampled at Sepetiba Bay (South-eastern Brazil). During the last decades, the bay’s watershed has been modified by the increase of industrial activities and human interventions. In particular, Zn and Cd ore treatment plants were built near the coast in 1960 and 1970, respectively, and water has been diverted from the adjacent Paraíba do Sul River watershed since 1950. The core collected at shallow depth near the industrial area exhibits four successive events: (i) at 50 cm depth, a change in the 206Pb/207Pb ratio from about 1.162 to more than 1.18 might be the result of the São Francisco Channel opening and water diversion from Paraíba do Sul river; (ii) at 40 cm depth, Zn concentration starts to increase (up to 0.8 mg g−1) (iii) above 30 cm depth, relatively high Cd concentrations (up to 1.6 μg g−1) are observed and (iv) at 16 cm depth, change in unsupported 210Pb slope is probably related to a waste dam built to prevent strong metal contamination in the bay. Sediment accumulation rates evaluated by Zn and Cd profiles used as time-markers are higher than those calculated from 210Pb-based chronology models. Using the constant initial concentration (CIC) model both events are supposed to date back to about 1884 and 1902, respectively, while using the constant rate of supply (CRS) model it shifts to about 1925 and 1935. Such discrepancies are probably assigned to the fact that these models do not take into account site-specific local sedimentation dynamics. In the study area, particles deposition seems to be controlled by enrichment with unsupported 210Pb transported by runoff from a mangrove flat bank. Chronology derived from a model that assumes an exponential increase of the initial 210Pb activity fits well with the estimated rates obtained from historical events.  相似文献   

13.
ABSTRACT

The city of São Carlos, state of São Paulo, Brazil, has a historical coexistence between society and floods. Unplanned urbanization in this area is a representative feature of how Brazilian cities have developed, undermining the impact of natural hazards. The Gregório Creek catchment is an enigma of complex dynamics concerning the relationship between humans and water in Brazilian cities. Our hypothesis is that social memory of floods can improve future resilience. In this paper we analyse flood risk dynamics in a small urban catchment, identify the impacts of social memory on building resilience and propose measures to reduce the risk of floods. We applied a socio-hydrological model using data collected from newspapers from 1940 to 2018. The model was able to elucidate human–water processes in the catchment and the historical source data proved to be a useful tool to fill gaps in the data in small urban basins.  相似文献   

14.
The epi-benthic dinoflagellate Ostreopsis cf. ovata Fukuyo has an increasingly global distribution. In Brazil there are reports of O. cf. ovata along the coast from 8°S to 27°S latitude and blooms have been registered on the Rio de Janeiro coastline. In the current study, an O. cf. ovata bloom is reported at Saint Paul's Rocks (0°55'10″N; 29°20'33″W), between the southern and northern hemispheres. The Archipelago is not inhabited and not subjected to eutrophication, due to isolation, and sustains a number of endemic species. Therefore, blooms of O. cf. ovata may potentially cause demise to trophic chains by affecting marine invertebrates and vertebrates.  相似文献   

15.
《Marine pollution bulletin》2012,65(12):2834-2838
Polycyclic aromatic hydrocarbons (PAHs) were determined in water samples collected in two streams and a lake located at Niteroi City, Rio de Janeiro State, Brazil between October 2008 and September 2009. Samples were extracted using liquid–liquid extraction and analyzed using high performance liquid chromatography with fluorescence detection. The limits of quantification were sufficiently low to accomplish PAH determination below the maximum concentration levels established by the Brazilian (50 ng/L) and USEPA legislations, with recoveries larger than 81.6%. Phenanthrene, fluoranthene, pyrene and benz[a]anthracene predominated among PAHs. Total concentrations of PAHs were well correlated with rainfall indicating a possible role of runoff to local pollution of water by PAHs and showed a seasonal variation in wet and dry seasons. Our results highlight the contribution of the widespread streams located around Guanabara Bay to the PAH burden found in its waters.  相似文献   

16.
This work investigates the behavior of the sunspot number and Southern Oscillation Index (SOI) signal recorded in the tree ring time series for three different locations in Brazil: Humaitá in Amaz?nia State, Porto Ferreira in S?o Paulo State, and Passo Fundo in Rio Grande do Sul State, using wavelet and cross-wavelet analysis techniques. The wavelet spectra of tree ring time series showed signs of 11 and 22?years, possibly related to the solar activity, and periods of 2–8?years, possibly related to El Ni?o events. The cross-wavelet spectra for all tree ring time series from Brazil present a significant response to the 11-year solar cycle in the time interval between 1921 to after 1981. These tree ring time series still have a response to the second harmonic of the solar cycle (5.5?years), but in different time intervals. The cross-wavelet maps also showed that the relationship between the SOI x tree ring time series is more intense, for oscillation in the range of 4–8?years.  相似文献   

17.
We present a new speleothem record of atmospheric Δ14C between 28 and 44 ka that offers considerable promise for resolving some of the uncertainty associated with existing radiocarbon calibration curves for this time period. The record is based on a comprehensive suite of AMS 14C ages, using new low-blank protocols, and U–Th ages using high precision MC-ICPMS procedures. Atmospheric Δ14C was calculated by correcting 14C ages with a constant dead carbon fraction (DCF) of 22.7 ± 5.9%, based on a comparison of stalagmite 14C ages with the IntCal04 (Reimer et al., 2004) calibration curve between 15 and 11 ka. The new Δ14C speleothem record shows similar structure and amplitude to that derived from Cariaco Basin foraminifera (Hughen et al., 2004, 2006), and the match is further improved if the latter is tied to the most recent Greenland ice core chronology (Svensson et al., 2008). These data are however in conflict with a previously published 14C data set for a stalagmite record from the Bahamas — GB-89-24-1 (Beck et al., 2001), which likely suffered from 14C analytical blank subtraction issues in the older part of the record. The new Bahamas speleothem ?14C data do not show the extreme shifts between 44 and 40 ka reported in the previous study (Beck et al., 2001). Causes for the observed structure in derived atmospheric Δ14C variation based on the new speleothem data are investigated with a suite of simulations using an earth system model of intermediate complexity. Data-model comparison indicates that major fluctuations in atmospheric ?14C during marine isotope stage 3 is primarily a function of changes in geomagnetic field intensity, although ocean–atmosphere system reorganisation also played a supporting role.  相似文献   

18.
Southeastern Brazil is characterized by seasonal rainfall variability. This can have a great social, economic, and environmental impact due to both excessive and deficient water availability. During 2014 and 2015, the region experienced one of the most severe droughts since 1960. The resulting water crisis has seriously affected water supply to the metropolitan region of São Paulo and hydroelectric power generation throughout the entire country. This research considered the upstream basins of the southeastern Brazilian reservoirs Cantareira (2,279 km2; water supply) and Emborcação (29,076 km2), Três Marias (51,576 km2), Furnas (52,197 km2), and Mascarenhas (71,649 km2; hydropower) for hydrological modelling. It made the first attempt at configuring a season‐based probability‐distributed model (PDM‐CEMADEN) for simulating different hydrological processes during wet and dry seasons. The model successfully reproduced the intra‐annual and interannual variability of the upstream inflows during 1985–2015. The performance of the model was very satisfactory not only during the wet, dry, and transitional seasons separately but also during the whole period. The best performance was obtained for the upstream basin of Furnas, as it had the highest quality daily precipitation and potential evapotranspiration data. The Nash–Sutcliffe efficiency and logarithmic Nash–Sutcliffe efficiency were 0.92 and 0.93 for the calibration period 1984–2001, 0.87 and 0.88 for the validation period 2001–2010, and 0.93 and 0.90 for the validation period 2010–2015, respectively. Results indicated that during the wet season, the upstream basins have a larger capacity and variation of soil water storage, a larger soil water conductivity, and quicker surface water flow than during the dry season. The added complexity of configuring a season‐based PDM‐CEMADEN relative to the traditional model is well justified by its capacity to better reproduce initial conditions for hydrological forecasting and prediction. The PDM‐CEMADEN is a simple, efficient, and easy‐to‐use model, and it will facilitate early decision making and implement adaptation measures relating to disaster prevention for reservoirs with large‐sized upstream basins.  相似文献   

19.
Rapid deposition of mud on the beach along the shoreface of Rio Grande do Sul, Brazil dramatically influences the normal operations in the littoral zone. In the surf zone, fluid and suspended mud opposes water-wave movement and dissipates water-wave energy; on the beach, mud limits trafficability. As part of a multinational, multidisciplinary program to evaluate the influence of mud strength, density and viscosity on water-wave attenuation, sediments were evaluated in situ or collected for evaluation from an area offshore of Cassino Beach, slightly south of the Patos Lagoon mouth. Shear strength of deposited sediments ranged from 0.6 kPa at the seafloor to 3.4 kPa at ∼1 m below the seafloor. Mud sediments were also collected to simulate the in situ response of fluid mud to shear stresses. For this determination, rheological evaluations were made using a strain-controlled Couette viscometer on numerous remixed samples that ranged in density from 1.05 to 1.30 g/cm3. It was determined that this mud is a non-ideal Bingham material in that it has a true initial yield stress as well as a upper Bingham yield stress. Initial yield stress ranged from 0.59 to 2.62 Pa, upper Bingham yield stress ranged from 1.05 to 7.6 Pa. Apparent viscosity ranged from 0.02 to 4.7 Pa s with the highest viscosities occurring between the two yield stresses. Sediment strength in the remixed samples is 2 to 3 orders of magnitude lower than the horizontal shear strength of the sediment bed as determined by shear vane or predicted from penetrometer measurements. This difference is partially due to the fact that rheological evaluations are made on fully remixed sediments, whereas horizontal shear strength is determined within relatively undisturbed sediments. Similar values of viscosity and shear strength are comparable to those determined for mud in other coastal areas where fluid mud deposits occur.  相似文献   

20.
A set of 24 AMS 14C measurements were performed on different sediment fractions from short gravity cores taken from the Gulf of Cariaco (northeastern Venezuela) in order to construct a detailed sedimentary archive for recent centuries. A local reservoir effect was expected because of i) strong upwelling from the neighboring Cariaco Trough and anoxia and ii) the specific geomorphological setting related to active faults with seeps and diapirism. Measurements were thus performed on different components: sediment bulk organic fraction (SBOF), pteropods shells (surface water), bivalve shells (bottom), and plant fragments. Based on comparisons of the different results, we discuss different age corrections and calibrations, which lead us to consider a negligible local reservoir correction (ΔR) for the bivalve and pteropod shells, which show no reservoir age for carbonate and an absence of water stratification. However, a local 633 ± 64 yr ΔR appears in the organic fraction of the sediment, and its origin is primary related to the upwelling mechanism.  相似文献   

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