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1.
In order to shed light on upper crustal differentiation of mantle-derived basaltic magmas in a subduction zone setting, we have determined the mineral chemistry and oxygen and hydrogen isotope composition of individual cumulus minerals in plutonic blocks from St. Vincent, Lesser Antilles. Plutonic rock types display great variation in mineralogy, from olivine–gabbros to troctolites and hornblendites, with a corresponding variety of cumulate textures. Mineral compositions differ from those in erupted basaltic lavas from St. Vincent and in published high-pressure (4–10 kb) experimental run products of a St. Vincent high-Mg basalt in having higher An plagioclase coexisting with lower Fo olivine. The oxygen isotope compositions (δ18O) of cumulus olivine (4.89–5.18‰), plagioclase (5.84–6.28‰), clinopyroxene (5.17–5.47‰) and hornblende (5.48–5.61‰) and hydrogen isotope composition of hornblende (δD = −35.5 to −49.9‰) are all consistent with closed system magmatic differentiation of a mantle-derived basaltic melt. We employed a number of modelling exercises to constrain the origin of the chemical and isotopic compositions reported. δ18OOlivine is up to 0.2‰ higher than modelled values for closed system fractional crystallisation of a primary melt. We attribute this to isotopic disequilibria between cumulus minerals crystallising at different temperatures, with equilibration retarded by slow oxygen diffusion in olivine during prolonged crustal storage. We used melt inclusion and plagioclase compositions to determine parental magmatic water contents (water saturated, 4.6 ± 0.5 wt% H2O) and crystallisation pressures (173 ± 50 MPa). Applying these values to previously reported basaltic and basaltic andesite lava compositions, we can reproduce the cumulus plagioclase and olivine compositions and their associated trend. We conclude that differentiation of primitive hydrous basalts on St. Vincent involves crystallisation of olivine and Cr-rich spinel at depth within the crust, lowering MgO and Cr2O3 and raising Al2O3 and CaO of residual melt due to suppression of plagioclase. Low density, hydrous basaltic and basaltic andesite melts then ascend rapidly through the crust, stalling at shallow depth upon water saturation where crystallisation of the chemically distinct cumulus phases observed in this study can occur. Deposited crystals armour the shallow magma chamber where oxygen isotope equilibration between minerals is slowly approached, before remobilisation and entrainment by later injections of magma.  相似文献   

2.
Data from detailed sample traverses in the layered gabbro unit of the North Arm Mauntain massif, Bay of Islands ophiolite, allow meter-scale resolution of magmatic processes in spreading ridge magma chambers. One suite of 46 samples from a 195 m interval near the base of the layered gabbro unit contains cumulus plagioclase (An73.7–87.5; average modal abundance=75%), clinopyroxene (Mg#=80.3–86.0; 18%), and olivine (Fo76.6–82.1; 6%), with intergranular orthopyroxene (Mg#=78.0–83.3; 1%), and accessory Cr-Al spinel (Cr#=32.3–41.4). Ilmenite rims spinel in one sample. Whole rock Zr contents range from <6 to 15 ppm. Plots of stratigraphic height in the traverse versus petrogenetic indicators (e.g. Mg#'s of mafic phases and An in plagioclase) reveal both normal and reverse cryptic variation patterns; the patterns for all indices are generally correlated. The normal portions of the patterns formed during fractional crystallization of basalt batches. Ranges of mineral compositions in the normal trends suggest that 29–38% crystallization of each batch of basalt occurred before magmatic replenishment. The reverse cryptic trends formed by crystallization of hybrid magmas produced during periods of magma mixing. Other evidence for magma mixing is the systematic association of spinel and reversely zoned plagioclase with the reverse trends. Experiments and observations of natural assemblages indicate that 55% modal plagioclase crystallizes from basalts at the olivine+plagioclase+clinopyroxene+liquid piercing point. The average plagioclase content of this suite of leucogabbros from North Arm Mountain is too high to have formed from simple crystallization at the piercing point. Petrologic modeling indicates the leucogabbros may have formed from basalts into which a small amount (<10%) of plagioclase was resorbed during mixing; the initial compositions of these hybrid basalts lie in the plagioclase primary phase volume. Other suites of layered gabbros from North Arm Mountain are not so plagioclase-rich as the leucogabbros described above. Crystallization of basalts in the plagioclase primary phase volume and the consequent formation of plagioclaserich gabbros may occur in restricted portions of zoned magma chambers underlying oceanic spreading centers, or may occur episodically in the overall lifetimes of the magma chambers.  相似文献   

3.
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts with similar reverse zonation. The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene) saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite + plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg# of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the shield building stage, but may commonly form in ephemeral magma pockets in the rift zones. The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary. Received: 8 July 1998 / Accepted: 2 January 1999  相似文献   

4.
The Kap Edvard Holm Layered Gabbro Complex is a large layeredgabbro intrusion (>300 km2) situated on the opposite sideof the Kangerdlugssuaq fjord from the Skaergaard Intrusion.It was emplaced in a continental margin ophiolite setting duringearly Tertiary rifting of the North Atlantic. Gabbroic cumulates, covering a total stratigraphic thicknessof >5 km, have a typical four-phase tholeiitic cumulus mineralogy:plagioclase, clinopyroxene, olivine, and Fe–Ti oxides.The cryptic variation is restricted (plagioclase An81–51,olivine Fo85–66, clinopyroxene Wo43–41 En46–37Fs20–11) and there are several reversals in mineral chemistry.Crystallization took place in a low-pressure, continuously fractionatingmagma chamber system which was periodically replenished andtapped. Fine-grained (0•2–0•4 mm) equigranular, thin(0•5–3 m), laterally continuous basaltic zones occurwithin an {small tilde}1000 m thick layered sequence in theTaco Point area. Twelve such zones define the bases of individualmacrorhythmic units with an average thickness of {small tilde}80m. The fine-grained basaltic zones grade upwards, over a fewmetres, into medium-grained (>1 mm) poikilitic, olivine gabbrowith smallscale modal layering. Each fine-grained basaltic zoneis interpreted as an intraplutonic quench zone in which magmachilled against the underlying layered gabbros during influxalong the chamber floor. Supercooling by {small tilde}50C isbelieved to have caused nucleation of plagioclase, olivine,and clinopyroxene in the quench zone. The nucleation rate isbelieved to have been enhanced as the result of in situ crystallizationin a continuously flowing magma. The transition to the overlyingpoikilitic olivine gabbro reflects a decreasing degree of supercooling. Compositional variation in the Taco Point sequence is typicalfor an open magma chamber system: olivine (Fo77–68 5)and plagioclase cores (An80–72) show a zig-zag crypticvariation pattern with no overall systematic trend. Olivinehas the most primitive compositions in the quench zones andmore evolved compositions in the olivine gabbro; plagioclasecores show the opposite trend. Although plagioclase cores arebelieved to retain their original compositions, olivines re-equilibratedby reaction with trapped liquid. Some plagioclase cores containrelatively sodic patches which retain quench compositions. Whole-rock compositions of nine different quench zones varyover a range from 10 to 18% MgO although the mg-number remainsconstant at {small tilde}0•78. The average composition(47•7% SiO2, 13•3%MgO, 1•57% Na2O+K2O) is takenas a best estimate of the parental magma composition, and isequivalent to a high-magnesian olivine tholeiite. The compositionalvariation of the quench zones is believed to reflect burstsof nucleation and growth of olivine and plagioclase during quenching. Magma emplacement is believed to have taken place by separatetranquil influxes which flowed along the interface between alargely consolidated cumulus pile and the residual magma. Theresident magma was elevated with little or no mixing. At certainlevels in the layered sequence the magma drained back into thefeeder system; such a mechanism is referred to as a surge-typemagma chamber system.  相似文献   

5.
The Kap Edvard Holm Layered Series forms part of the East GreenlandTertiary Province, and was emplaced at shallow crustal level(at depths corresponding to a pressure of 1–2 kbar) duringcontinental break-up. It consists of two suites: a gabbro suitecomprising olivine and oxide gabbros, leucocratic olivine gabbrosand anorthosites, and a suite of wehrlites that formed fromthe intrusion of the gabbros during their solidification bya hydrous, high-MgO magma. Ion microprobe analyses of clinopyroxenereveal chemical contrasts between the parental melt of the wehrlitesuite and that of the gabbro suite. Thin sills (1–2 mthick) of the wehrlite suite, however, have clinopyroxene compositionssimilar to the gabbro suite, and were formed by interactionwith interstitial melts from the host layered gabbros. All evolvedmembers of the gabbro suite have elevated Nd, Zr and Sr concentrationsand Nd/Yb ratios, relative to the melt parental to the gabbrosuite. These characteristics are attributed to establishmentof a magma chamber at depths corresponding to a pressure of10 kbar, where melts evolved before injection into the low-pressuremagma chamber. Anorthosites of the gabbro suite are believedto have crystallized from such injections. The melts becamesupersaturated in plagioclase by the pressure release that followedtransportation to the low-pressure magma chamber after initialfractionation at 10 kbar. The most evolved gabbros formed bysubsequent fractionation within the low-pressure magma chamber.Our results indicate that high-pressure fractionation may beimportant in generating some of the lithological variationsin layered intrusions. KEY WORDS: fractionation; ion microprobe; layered intrusions; rift processes; trace elements *Corresponding author.  相似文献   

6.
The Khopoli intrusion, exposed at the base of the Thakurvadi Formation of the Deccan Traps in the Western Ghats, India, is composed of olivine gabbro with 50–55 % modal olivine, 20–25 % plagioclase, 10–15 % clinopyroxene, 5–10 % low-Ca pyroxene, and <5 % Fe-Ti oxides. It represents a cumulate rock from which trapped interstitial liquid was almost completely expelled. The Khopoli olivine gabbros have high MgO (23.5–26.9 wt.%), Ni (733–883 ppm) and Cr (1,432–1,048 ppm), and low concentrations of incompatible elements including the rare earth elements (REE). The compositions of the most primitive cumulus olivine and clinopyroxene indicate that the parental magma of the Khopoli intrusion was an evolved basaltic melt (Mg# 49–58). Calculated parental melt compositions in equilibrium with clinopyroxene are moderately enriched in the light REE and show many similarities with Deccan tholeiitic basalts of the Bushe, Khandala and Thakurvadi Formations. Nd-Sr isotopic compositions of Khopoli olivine gabbros (εNdt?=??9.0 to ?12.7; 87Sr/86Sr?=?0.7088–0.7285) indicate crustal contamination. AFC modelling suggests that the Khopoli olivine gabbros were derived from a Thakurvadi or Khandala-like basaltic melt with variable degrees of crustal contamination. Unlike the commonly alkalic, pre- and post-volcanic intrusions known in the Deccan Traps, the Khopoli intrusion provides a window to the shallow subvolcanic architecture and magmatic processes associated with the main tholeiitic flood basalt sequence. Measured true density values of the Khopoli olivine gabbros are as high as 3.06 g/cm3, and such high-level olivine-rich intrusions in flood basalt provinces can also explain geophysical observations such as high gravity anomalies and high seismic velocity crustal horizons.  相似文献   

7.
Garnet-bearing mantle xenoliths have been recovered from Quaternary alkali basalts, both within and peripheral to the Hangay dome of central Mongolia. Microfabric analysis and thermobaromery, combining empirical thermobarometers and the self-consistent dataset of THERMOCALC, indicate that garnet websterites from the Shavaryn-Tsaram volcanic centre at the dome core were formed in the spinel-lherzolite upper mantle at pressures of 17–18 kbars and temperatures of 1,070–1,090°C, whereas garnet lherzolites were derived from greater depths (18–20 kbars). Garnet lherzolites from the Baga Togo Uul vents near the dome edge were formed at 18–22 kbars under significantly cooler conditions (960–1,000°C). These xenoliths reveal reaction coronas of (1) orthopyroxene, clinopyroxene, plagioclase and spinel mantling garnets; (2) spongy rims of olivine replacing orthopyroxene and (3) low-Na, low-Al clinopyroxene replacing primary clinopyroxene. Trace-element abundances indicate that clinopyroxene from these coronas is in chemical equilibrium with the host magma. The thermobarometric and textural data suggest that lherzolite xenoliths from both sites were derived from depths of 60–70 km and entrained in magma at 1,200–1,300°C. The average rate of ascent, as determined by olivine zoning, lies in the range 0.2–0.3 m s−1. The contrast in thermal profiles of the upper mantle between the two sites is consistent with a mantle plume beneath the Hangay dome with elevated thermal conditions beneath the core of the dome being comparable to estimates of the Pleistocene geotherm beneath the Baikal rift.  相似文献   

8.
谢燮  杨建国  王小红  王磊  江磊  姜安定 《现代地质》2015,29(6):1259-1270
甘肃北山红柳沟基性-超基性岩体位于塔里木板块北缘北山裂谷带, 岩体侵位于敦煌岩群,主要岩石类型有辉长岩、橄榄辉长岩、橄榄苏长辉长岩、橄榄角闪苏长岩、橄榄辉长苏长岩、二辉橄榄岩、橄榄辉石岩和辉石岩等。橄榄石Fo介于66.97%~82.92%之间,属贵橄榄石,斜方辉石En成分范围为68.49~77.65,属古铜辉石;单斜辉石En成分范围为45.85~48.81,主要为斜顽辉石和透辉石;斜长石An为58.70~72.69,以拉长石为主;角闪石以普通角闪石为主。岩体母岩浆Mg#值为0.59~0.62,属于高镁拉斑玄武质岩浆,岩浆演化过程中主要发生了橄榄石、斜方辉石、单斜辉石和斜长石的分离结晶作用,主要分离结晶矿物受单斜辉石和斜方辉石的控制,岩浆上升侵位过程中遭受到下地壳物质混染。从构造环境、母岩浆、岩体类型、岩浆分异程度、同化混染等方面综合分析认为红柳沟岩体具有形成铜镍硫化物矿床的较大潜力。  相似文献   

9.
Summary Mineral compositions in leucite-bearing and leucite-free rocks from Vico volcano are reported. FeO/MgO partitioning (Kdol/liq) between olivine and latite (0.14–0.22), and between olivine and trachyte (0.06–0.10) indicates a lack of equilibrium between mineral and host rock. This suggests that mingling and/or mixing between magmas was a leading process during magmatic differentiation. In addition, a phono-tephrite olivine population with high (0.84) and equilibrium (0.23–0.29) Kdol/liq values has been produced by the interaction of differently evolved magmas. Zoning in clinopyroxene and plagioclase from these rocks recorded the same processes. In addition, resorbed quartz xenocrysts with coronas of clinopyroxene microlites indicate that digestion of crustal rocks occurred during the residence of magma in a shallow level reservoir. Increasing Fe coupled with decreasing Ca in diopside crystals from some phonolites, together with the petrographic and trace element data, indicate that polybaric fractional crystallisation also may be involved in the genesis of magmas of the second period of Vico activity. Leucite-free trachybasalts erupted in a late stage contain highly forsteritic olivine phenocrysts (forsterite 84–88 mol.%) in-equilibrium (Kdol/liq = 0.24–0.35) with the host rock, which indicate that they did not suffer chemical modification at low pressure. Received November 28, 2000; revised version accepted September 27, 2001  相似文献   

10.
The Lengshuiqing area contains several small intrusions made up of peridotite ± quartz diorite ± granite spatially associated with the Gaojiacun pluton (gabbroids + peridotite + diorite). Ni–Cu sulfide ore occur at Lengshuiqing, hosted in peridotite. SHRIMP U–Pb zircon dating produced the ages of 803 ± 4.2 Ma (peridotite), 807 ± 2.6 Ma (oikocrystic hornblende gabbro), 809 ± 4.3 Ma (hornblende gabbronorites) for the Gaojiacun pluton and 807 ± 3.8 Ma (diorite, intrusion I), 817 ± 6.3 Ma (quartz diorite, intrusion II) and 817 ± 5 Ma (peridotite, intrusion 101) for Lengshuiqing. These ages suggest the emplacement of the Gaojiacun pluton later than the intrusions from Lengshuiqing. The olivine from Lengshuiqing does not contain sulfide inclusions and is relatively Ni-rich (1,150–1,550 ppm Ni), suggesting its crystallisation before the sulfide saturation that generated the Ni–Cu deposits. The olivine of the gabbros in the Gaojiacun pluton is Ni-poor (250–800 ppm), which indicates crystallisation from a severely metal-depleted magma after a sulfide saturation event. The olivine in the peridotites from the Gaojiacun pluton has 800–1,150 ppm Ni and contains sulfide inclusions. Moreover, geological evidence suggests the genesis of the peridotites from Gaojiacun in conduits that were ascending through the gabbroids. A sequence of at least three stages of magma emplacement is proposed: (1) Lengshuiqing; (2) gabbroids from Gaojiacun; (3) peridotites from Gaojiacun. Given the age differences, the intrusions at Lengshuiqing and the Gaojiacun pluton might have been produced by different magmatic events.  相似文献   

11.
Gabbro inclusions from Tindfjallajökull are divided into two types: I. Panidiomorphic gabbros of non-cumulative origin composed of plagioclase + olivine ± clinopyroxene and interstitil vesicular glass. They have formed in equilibrium with the host magma and may either represent a marginal facies or a highly solidified magma body. In the latter case the host magma or part of it could be mobilized interstitial liquid. II. Allotriomorphic-hypidiomorphic tholeiitic olivine gabbro and diorite xenoliths with scarce Ti-pargasite which have undergone less than 10% partial melting in the host magma forming melts of alkali basaltic or Hekla andesite-like compositions dependent on the original mineral assemblage. Such liquids, enriched in K2O and possibly other incompatible elements, may contaminate basaltic magmas rising slowly through a gabbroic lower crust. Large scale production of andesites by partial melting of such rocks is not possible but would need more hydrous or differentiated source rocks.  相似文献   

12.
笔架山东基性—超基性岩体位于塔里木板块东北部的新疆北山地区,是笔架山岩带中最东边的一个岩体,岩体形态为椭圆状,出露面积约5 km2.由含长单辉橄榄岩、橄榄辉长岩、含橄辉长岩、辉长岩以及辉绿岩组成.含橄榄石较多的岩石属拉斑玄武岩系列,而辉长岩属钙碱性系列.岩相学、岩石化学和微量元素地球化学特征表明岩浆演化过程中经历了橄榄石、辉石、斜长石的分离结晶作用.Nd、Sr、Pb同位素组成和岩石地球化学特征反映出岩浆与围岩之间存在物质交换.笔架山东岩体的岩浆源区为OIB型地幔源区,原生岩浆为高镁拉斑玄武岩浆[w(MgO)=11.2％],这些性质与塔里木板块东北部其他基性-超基性岩体的特征相似,表明塔里木板块东北部二叠纪基性—超基性岩体的源区主要为OIB型地幔,可能与地幔柱有关.  相似文献   

13.
新疆北山地区罗东镁铁质-超镁铁质层状岩体岩石成因   总被引：4，自引：0，他引：4  
罗东镁铁质-超镁铁质岩体位于塔里木板块东北部的新疆北山地区,岩体平面形态为眼球状,出露面积约2.1 km2.由纯橄岩、单辉橄榄岩、斜长二辉橄榄岩、橄榄二辉岩、方辉辉石岩、橄长岩、橄榄辉长岩、辉长岩、苏长辉长岩和淡色辉长岩组成,堆晶结构和堆晶韵律发育,属于层状岩体.岩浆演化过程中主要分离结晶/堆晶相是橄榄石和单斜辉石,此...  相似文献   

14.
Summary Crust-derived xenoliths hosted by Miocene basaltic diatremes in the Hyblean Plateau (south-eastern Sicily, Italy) provide new information regarding the nature of a portion of the central Mediterranean lower crust. These xenoliths can be divided into three groups: gabbros (plagioclase + clinopyroxene + Fe–Ti oxides ± apatite ± amphibole ± Fe-rich green spinel), diorites (An-poor plagioclase, clinopyroxene ± Fe–Ti oxides ± orthopyroxene) and mafic granulites (plagioclase + clinopyroxene + green spinel ± orthopyroxene ± Fe–Ti oxides). Gabbros form the main subject of this paper. They represent cumulates whose igneous texture has been locally obliterated by metamorphic recrystallization and shearing. They were permeated by Fe–Ti-rich melts related to tholeiitic-type fractional crystallisation. Incompatible element ratios (Zr/Nb = 5–26; Y/Nb = 1.4–11) indicate that these cumulate gabbros derived from MORB liquids. Late-stage and hydrothermal fluids caused diverse, sometimes important, metasomatic trasformations. Petrographic and geochemical comparison with gabbroids from well-known geodynamic settings show that the Hyblean lower crustal xenoliths were probably formed in an oceanic or oceanic-continent transition environment.  相似文献   

15.
M. Lachize  J. P. Lorand  T. Juteau 《Lithos》1996,38(3-4):207-232
The Wadi Haymiliyah section, in the Haylayn block (Semail ophiolite, Oman) displays an unusual plutonic sequence closely similar to those of supra-subduction zone harzburgitic ophiolites (“Troodos sub-type”). It comprizes a bottom, 1000 m-thick, coarse-grained layered gabbro unit (MLGU) overlain by a 1000 m-thick, fine-grained, laminated noritic gabbro unit (MLNGU). Taken as a whole, the mineralogical and bulk-rock trends of the Haymiliah plutonic sequence are those of arc-related calc-alkaline plutons. The MLGU layered gabbros are olivine gabbros and gabbros which differ from low-P cumulates of MORB (oceanic gabbros) by Fe3+-rich cumulus chrome spinel [Fe3+/(Fe3+ + Al + Cr) = 0.2-0.3], diopside (Mg# = 85–91) co-crystallized with highly calcic plagioclase (An96-80) and intercumulus magnesian orthopyroxene (Mg# = 87-80). Plagioclase remains highly calcic at decreasing Fo content, indicating crystallization under high water pressure (> 500 bar). Despite an abrupt decrease in grain size, there exists modal and chemical gradations between MLGU and MLNGU. In the uppermost part of the MLGU, coarse-grained, gabbroic cyclic units culminate with two-pyroxene gabbros containing up to 20 wt.% cumulus Opx. These latter are interbedded over a thickness of ca. 300 m with fine-grained two-pyroxene gabbros and noritic gabbros layers which differ only by slightly higher modal opx and plagioclase contents. The bottom of the MLNGU is marked by norite layers containg up to 80 wt.% plagioclase, cumulus Ti-magnetite and abundant intercumulus Ti-pargasite. Unlike low-pressure differentiates of MORBs, the MLNGU lacks pigeonite and Fe-Ti oxide layers. Cumulus titanomagnetite appears immediately after the orthopyroxene (Mg# = 72–76) in the crystallization order of the norites. The abundance of interstitial Ti-poor pargasite increases at the top of the MLNGU which is brecciated by dioritic differentiates. Both features indicate increasing water pressure and oxygen fugacity (NNO + 2 log units) symptomatic of closed-system magmatic differentiation. Mg#'s of both pyroxenes (70–80) decrease moderately relative to the MLGU coarse-grained gabbros. This and the increase of plagioclase and orthopyroxene modal proportions produce increasing SiO2-Al2O3-Na2O and Sr contents at nearly constant FeO/MgO in bulk-rock chemistry. This feature similar to the calc-alkaline differentiation trend, is due primarily to a parental tholeiitic magma more hydrated and oxidized than MORBs (ƒO2 = NNO instead of NNO-2 to NNO-3 log unit); this trend is fully developed in the Wadi Haymiliah section because closure of the magma reservoir in this region allowed larger extent of magmatic differentiation than in other blocks of the Semail ophiolite. The water-rich and oxidized nature of the parental magmas argues for the evolution of the Semail ophiolite in a marginal basin above a subduction zone rather than at a mature oceanic spreading center.  相似文献   

16.
We report petrological, chemical and Os–Nd–Sr isotopic data for the Gaositai ultramafic complex from northern North China craton (NCC) to reveal its petrogenesis. The complex shows features of Alaskan-type intrusions, including (1) the concentric zoning from dunite core, to clinopyroxenite and hornblendite in the rim, and the common cumulative textures; (2) the abundance of olivine, clinopyroxene and hornblende, and the scarcity of orthopyroxene and plagioclase, and (3) the systematic decrease in Mg# of ferromagnesian phases from core to rim, accompanied by the Fe-enrichment trend of accessory spinel. The different rock types show highly varied, radiogenic Os isotopic ratios (0.129–5.2), and unradiogenic Nd isotopic composition (εNd(t) = −8 to −15), but are homogeneous in ISr ratios (0.7054–0.7066). The (187Os/188Os)i ratios are found to be anti-correlated with εNd(t) values and whole-rock Mg# as well. These data suggest significant crustal contamination during magma evolution. The crustal contaminants are dominantly Archean mafic rocks in the lower crust, and subordinate TTG gneisses at shallower crustal levels. The parental magma was hydrous picritic in composition, derived from an enriched lithospheric mantle source above a subduction zone. The zoned pattern of the complex formed probably through “flow differentiation” of a rapidly rising crystal mush along a fracture zone that was developed as a result of lithospheric extension in a back-arc setting in the northern margin of the NCC at ca. 280 Ma.  相似文献   

17.
The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock 87Sr/86Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial 87Sr/86Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetite–ilmenite–apatite)layers and changes up-section from gabbronorite (An72 plagioclase;Mg# 74 clinopyroxene) to magnetite–ilmenite–apatite–fayaliteferrodiorite (An43; Mg# 5 clinopyroxene; Fo1 olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V2O5 of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO2 and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO2 and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation  相似文献   

18.
The well-preserved ?lower Proterozoic McIntosh intrusion consistsof 96 macro-layers with a total stratigraphic thickness of about6 km. The lowermost rocks in this possible cone-shaped intrusionare hidden, and the roof and the upper layers were removed byerosion. The layered sequence is dominated by 40 bimodal cyclicunits of troctolite and olivine gabbro. Minor gabbronorite layersoccur throughout the sequence, and are more abundant and morefractionated higher in the sequence. Six imperfect megacycicunits are developed in the upper 2700 m, each unit consistingof several troctolite-olivine gabbro cyclic units followed bya Fe-Ti oxide-bearing gabbronorite. The overall cumulus crystallizationorder in each megacyclic unit was plagioclase first, closelyfollowed by olivine, then augite, orthopyroxene, and magnetitesuccessively. Cryptic composition data for troctolites and olivine gabbrosshow a slight overall decrease of 10 mol per cent An and Fofrom the base to the top of the layered sequence (approximateranges An80–70 and Fo78–68). Several major fluctuationsoccur however, and are generally associated with the oxide gabbronorites,which are significantly more fractionated than the adjacentlayers (plagioclase An53–60, orthopyroxene Mg52–69Each fluctuation comprises a marked progressive discontinuity(rapid normal fractionation) followed by a gradual to rapidregressive discontinuity (or reversal) in the overlying troctolitesand olivine gabbros. Apparently, such marked progressive discontinuitieshave not been described in layered intrusions. A chilled margin and the overall composition of the intrusionsuggest an olivine tholeiite parent magma, inferred to havecrystallized at P 6 kb, relatively low PH2O and high fO2 (>NNO buffer). The troctolite-olivine gabbro cyclic units areinferred to have formed by fractional crystallization of periodicadditions of new magma. However, the oxide gabbronorites seemtoo fractionated relative to the underlying layers to have formedby conventional crystal fractionation mechanisms, and they couldhave resulted from a ‘liquid fractionation’ processin which fractionated residual magma, instead of rising, periodicallybecame denser and ponded on the temporary floor (a density crossover).Gradual, reversed cryptic trends in the cyclic units above theoxide gabbronorite layers may reflect mixing of this fractionatedmagma with successive magma additions.  相似文献   

19.
The Gede Volcanic Complex (GVC) of the Sunda island arc (West Java, Indonesia) consists of multiple volcanic centres and eruptive groups with complex magmatic histories. We present new petrological, mineralogical, whole-rock major and trace element and Sr–O isotopic data to provide constraints on the relative importance of fractional crystallisation and magma mixing in petrogenesis, as well as on the role and nature of the arc crust. Banded juvenile scoria from Young and Old Gede provide unequivocal evidence for the (late-stage) interaction of distinct magmas at Gede volcano. However, the relatively small-degree compositional zoning observed in plagioclase phenocrysts of all eruptive groups (up to ~20 mol% An) may be attributed to physical changes in magma properties (e.g. P, T, and PH2O) rather than changes in melt composition. Major element and trace element variations within each eruptive series are inconsistent with magmatic evolution through simple mixing processes. Instead, mixing of variably fractionated magma batches is suggested to account for the significant scatter in some element variation diagrams. No correlation is observed between textural complexity and/or mineral disequilibrium and whole-rock geochemistry. REE data and geochemical modelling indicate that fractional crystallisation involving amphibole in the mid- to lower crust, and fractionation of plagioclase, clinopyroxene, Fe–Ti oxide ± olivine ± orthopyroxene provide strong control on the geochemical evolution of GVC rocks. Two-pyroxene geothermobarometry provides pre-eruption crystallisation temperatures of 891–1,046°C and pressures of 3.4–6.5 kbar, equivalent to ~13–24 km depth beneath the volcanoes (mid- to lower crust). Low, mantle-like clinopyroxene δ18O values of GVC lavas and poor correlation of Sr isotope ratios with indices of differentiation precludes significant assimilation of isotopically distinct crust during magmatic differentiation. Therefore, we suggest that the geochemical character of the moderately thick West Javan arc crust is relatively immature compared to typical continental crust. Trace element ratios and strontium isotopes show that the magmatic source composition of the older geographical units, Gegerbentang and Older Quaternary, is distinct from the other GVC groups.  相似文献   

20.
Gabbro xenoliths reported in this paper were collected in northern Fuerteventura, the Canary Island located closest to the coast of Africa. The xenoliths are very fresh and consist of Ti–Al-poor clinopyroxene + plagioclase (An87–67) + olivine (Fo72–86) ± orthopyroxene. Clinopyroxene and orthopyroxene are constantly and markedly depleted in light rare earth elements (LREE) relative to heavy REE (HREE), as expected for cumulus minerals formed from highly refractory N-MORB-type melts. In contrast, whole-rock Primordial Mantle-normalized trace element patterns range from mildly S-shaped (mildly depleted in Pr–Sm relative to both the strongly incompatible elements Rb–La and the HREE) to enriched. Estimates show that the trace element compositions of the rocks and their minerals are compatible with formation as N-MORB gabbro cumulates, which have been infiltrated at various extents (≤1% to >5%) by enriched alkali basaltic melts. The enriched material is mainly concentrated along grain boundaries and cracks through mineral grains, suggesting that the infiltration is relatively recent, and is thus associated with the Canary Islands magmatism. Our data contradict the hypothesis that a mantle plume was present in this area during the opening of the Atlantic Ocean. No evidence of continental material that might reflect attenuated continental crust in the area has been found. Gabbro xenoliths with REE and trace element compositions similar to those exhibited by the Fuerteventura gabbros are also found among gabbro xenoliths from the islands of La Palma (western Canary Islands) and Lanzarote. The compositions of the most depleted samples from these islands are closely similar, implying that there was no significant change in chemistry during the early stages of formation of the Atlantic oceanic crust in this area. Strongly depleted gabbros similar to those collected in Fuerteventura have also been retrieved in the MARK area along the central Mid-Atlantic Ridge. The presence of N-MORB oceanic crust beneath Fuerteventura implies that the continent–ocean transition in the Canary Islands area must be relatively sharp, in contrast to the situation both further north along the coast of Morocco, and along the Iberian peninsula.  相似文献   

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