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1.
High-grade exotic blocks in the Franciscan Complex at Jenner, California, show evidence for polydeformation/metamorphism, with eight distinct stages. Two parallel sets of mineral assemblages [(E) eclogite, and (BS) laminated blueschist] representing different bulk chemistry were identified. Stage 1, recorded by parallel aligned inclusions (S1) of crossite + omphacite + epidote + ilmenite + titanite + quartz (E), and glaucophane + actinolite + epidote + titanite (BS) in the central parts of zoned garnets, represents the epidote blueschist facies. The onset of a second stage (stage 2) is represented by a weak crenulation of S1 and growth of garnet. This stage develops a well-defined S2 foliation of orientated barroisite + epidote + titanite (E), or subcalcic actinolite + epidote + titanite (BS) at c. 90d? to S1, with syntectonic growth of garnet, defining the (albite-)epidote-amphibolite facies. A third stage, with aligned inclusions of glaucophane + (subcalcic) actinolite + phengite parallel to S2 in the outermost rims of large garnet grains, is assigned to the transitional (albite-)epidote-amphibolite/(garnet-bearing) epidote blueschist facies. The fourth stage represents the peak metamorphism, and was identified by unorientated matrix minerals in the least retrograded samples. In this stage the mineral assemblages garnet + omphacite + glaucophane + phengite (E) and garnet + winchite + phengite + epidote (BS) both represent the eclogite facies. Stage 5 is represented by the retrogression of eclogite facies assemblages to the epidote blueschist facies assemblages crossite/glaucophane + garnet + omphacite + epidote + phengite (E), and glaucophane + actinolite + epidote + phengite (BS), with the development of an S5 foliation subparallel to S2. Stage 6 represents a crenulation of S5, with the development of a well-defined S6 crenulation cleavage wrapping around relics of the eclogite facies assemblages. This crenulation cleavage is further weakly crenulated during a D7 event. Post-D7 (stage 8) is recorded by the growth of lawsonite + chlorite ± actinolite replacing garnet, and by veins of lawsonite + pumpellyite + aragonite and phengite + apatite. The different, yet coeval, mineral parageneses observed in rock types (E) and (BS) are probably due to differences in bulk chemistry. The metamorphic evolution from stage 1 to stage 8 seems to have been broadly continuous, following an anticlockwise P-Tpath: (1) epidote blueschist (garnet-free) to (2) (albite-)epidote-amphibolite to (3) transitional epidote blueschist (garnet-bearing)/(albite-)epidote-amphibolite to (4) eclogite to (5) epidote blueschist (garnet-bearing) to (6-7) epidote blueschist (garnet-free) facies to (8) lawsonite + pumpellyite + aragonite-bearing assemblages. This anticlockwise P-T path may have resulted from a decreasing geothermal gradient with time in the Mesozoic subduction zone of California at early or pre-Franciscan metamorphism.  相似文献   

2.
金红石边缘形成榍石冠状边结构在变质中-基性岩中普遍存在,是金红石与退变质流体携带的SiO_2与CaO作用的结果,反应形成的榍石微量元素特征受到金红石和流体的共同影响。雅鲁藏布江缝合带中角闪岩LZ06-04在抬升过程经历近等温降压退变质作用,石榴子石分解导致同一样品中含石榴子石部分与不含石榴子石部分的退变质流体成分的差异。两种流体分别与金红石反应,对应形成的榍石具有相似的Nb、Ta含量和Nb/Ta比值特征,但截然不同的REE特征。榍石的Nb、Ta来源于金红石,残余金红石与含水流体再平衡Nb、Ta的分配系数增大,且D_(Nb)~(Rt/Fluid)≥D_(Ta)~(Rt/Fluid);虽然Nb和Ta在含水流体中都表现为不活动元素,但相对于Nb,Ta在含水流体中活动性较高。榍石的Zr-Hf体系特征受到锆石、石榴子石等矿物的综合影响,并且Zr-Hf在含水流体中表现出比Nb-Ta更高的活动性。榍石的REE特征受流体中REE特征、榍石与流体配分系数以及共生矿物的影响。在岩浆或变质体系,榍石形成过程中,REE富集矿物(如石榴子石、锆石、褐帘石、独居石、磷灰石等)形成或分解将影响榍石的REE分布特征或形成REE环带结构。含水流体中金红石退变质形成榍石反应的进行受流体中TiO_2、CaO和SiO_2活度的影响。因此榍石常见于钙碱性岩浆岩、富Ca基性变质岩和矽卡岩中。流体中CaO活度的变化影响榍石的形成,进而影响Ti、Nb、Ta在流体中的运移能力。俯冲板片产生流体在交代上覆富Ca地幔楔物质过程中形成榍石残留同样可以造成部分熔融体具有亏损HFSE特征。  相似文献   

3.
Abstract In the Su-Lu ultrahigh- P terrane, eastern China, many coesite-bearing eclogite pods and layers within biotite gneiss occur together with interlayered metasediments now represented by garnet-quartz-jadeite rock and kyanite quartzite. In addition to garnet + omphacite + rutile + coesite, other peak-stage minerals in some eclogites include kyanite, phengite, epidote, zoisite, talc, nyböite and high-Al titanite. The garnet-quartz-jadeite rock and kyanite quartzite contain jadeite + quartz + garnet + rutile ± zoisite ± apatite and quartz + kyanite + garnet + epidote + phengite + rutile ± omphacite assemblages, respectively. Coesite and quartz pseudomorphs after coesite occur as inclusions in garnet, omphacite, jadeite, kyanite and epidote from both eclogites and metasediments. Study of major elements indicates that the protolith of the garnet-quartz jadeite rock and the kyanite quartzite was supracrustal sediments. Most eclogites have basaltic composition; some have experienced variable 'crustal'contamination or metasomatism, and others may have had a basaltic tuff or pyroclastic rock protolith.
The Su-Lu ultrahigh- P rocks have been subjected to multi-stage recrystallization and exhibit a clockwise P-T path. Inclusion assemblages within garnet record a pre-eclogite epidote amphibolite facies metamorphic event. Ultrahigh- P peak metamorphism took place at 700–890° C and P >28 kbar at c . 210–230 Ma. The symplectitic assemblage plagioclase + hornblende ± epidote ± biotite + titanite implies amphibolite facies retrogressive metamorphism during exhumation at c . 180–200 Ma. Metasedimentary and metamafic lithologies have similar P-T paths. Several lines of evidence indicate that the supracrustal rocks were subducted to mantle depths and experienced in-situ ultrahigh- P metamorphism during the Triassic collision between the Sino-Korean and Yangtze cratons.  相似文献   

4.
向华  张利  钟增球  周汉文  曾雯 《地球科学进展》2007,23(12):1258-1267
榍石在各类岩石中普遍存在，其稳定性受全岩成分、氧逸度和水活度以及温度和压力等因素影响。它在岩浆岩中主要存在于高Ca/Al比值的岩石中，在变质岩中常见于绿片岩相、蓝片岩相和角闪岩相岩石，在钙质变质岩中其稳定范围可达榴辉岩相或高压麻粒岩相。一般榍石结构中U含量较高，且具有高达高角闪岩相上限的U Pb同位素体系封闭温度，是理想的U-Pb定年矿物。由于榍石的组成元素均为岩石中的主要元素，很容易与其它矿物、熔体及流体发生反应，所以榍石的U-Pb年龄记录的更可能是结晶年龄，而不是简单的扩散重置年龄；也因为它容易反应，变质榍石复杂的U Pb体系可能记录了岩石的整个变质历史信息。通过与榍石平衡共生的矿物组合或利用榍石Zr温压计可确定岩石的P T条件，结合相关的榍石年龄信息即可建立变质过程的P T t轨迹。利用SHRIMP、LA MC ICP MS以及LA ICP MS方法可对不均一榍石颗粒内部进行原位微区分析得到有意义的U Pb年龄；利用榍石中Zr含量对温度，尤其是对压力比较敏感，可建立榍石Zr含量温压计。  相似文献   

5.
本文主要对沂水青龙峪出露的超镁铁质岩石和基性麻粒岩进行了锆石SHRIMP U-Pb定年研究。超镁铁质岩石以捕掳体形式存在于沂水杂岩中,不发育鬣刺结构,氧化物组成具有超镁铁质科马提岩的高MgO、富CaO、低SiO2、TiO2、K2O和Na2O含量特征;矿物组合以单斜辉石+橄榄石±斜方辉石+铬铁矿为主;变质矿物以角闪石+蛇纹石化为特征;该岩石以稀土元素总含量(∑REE)低、LREE/HREE=3.35～4.40及Ce和Eu负异常为特征。微量元素组成以Ba、Nb、Zr负异常和Nd、Sm正异常为特征。根据锆石SHRIMP U-Pb定年法对该超镁铁质岩石中捕获的早期岩浆结晶锆石和新生的变质锆石进行的研究,年龄值分别为2657～2702Ma和2551～2585Ma,表明该超镁铁质岩石形成年龄为2585～2657Ma。基性麻粒岩的氧化物组成特征表明其属高Mg的洋岛拉斑玄武岩,麻粒岩相——高角闪岩相变质作用与新太古代的深熔和岩浆侵入作用有关,矿物组合以紫苏辉石+单斜辉石±角闪石+斜长石±石榴子石为特征;晚期蚀变作用与辉长岩墙、辉绿岩脉及石英闪长岩买的侵入有关,矿物组合以滑石化+绢云母化+绿泥石化为特征;稀土元素组成以轻重稀土元素无分异和无Eu异常为特征;微量元素组成以Nb、Zr、P、Ti负异常和Sr、K正异常为特征;锆石SHRIMP U-Pb定年结果表明麻粒岩相——角闪岩相变质作用年龄为2498.4±7.6Ma,导致麻粒岩相——角闪岩相变质的深熔和岩浆结晶年龄为2551±24Ma,晚期蚀变作用的年龄分别为2231～2235Ma和1850±19Ma。  相似文献   

6.
Calc-silicate boudins from the Rauer Group, East Antarctica, were metamorphosed under granulite facies conditions during late Proterozoic (ca. 1,000 Ma) M3 metamorphism. Boudin cores contain low to moderate aCO 2 assemblages including wollastonite, grossularandradite (grandite) garnet, clinopyroxene, scapolite, plagioclase, quartz±calcite. Petrological and stable isotopic evidence suggests that these core assemblages resulted from pre-peak M3 infiltration of water-rich fluids; there is no evidence for a pervasive fluid phase under peak M3 conditions. The boudins are separated from the surrounding Fe-rich pelites and semi-pelites by a series of concentric, high-variance reaction zones developed under peak M3 conditions. Variations in mineral assemblage, mineral composition and whole rock composition across these zones suggest that they formed by diffusional masstransfer, controlled principally by a chemical potential gradient in Ca across the original calc-silicate-paragneiss lithological boundary. As a consequence of the nearcomplete decarbonation of the calc-silicatesbefore the M3 peak, development of the diffusion-controlled reaction zones did not liberate significant CO2 during granulite facies metamorphism. Similar calcite-poor, low aCO 2 calc-silicate horizons in other granulite facies terrains are unlikely to have been important local fluid sources during deep crustal metamorphism.  相似文献   

7.
U-Pb age and isotope-geochemical features were determined for zircon from kyanite gneisses and amphibolites of the Chupa Sequence of the Belomorian mobile belt (BMB) of the Fennoscandian shield. The cores of the zircon from the gneisses marks the Neoarchean events within 2700–2800 Ma known in the BMB, while those of the amphibolites correspond to the age of magmatic crystallization (2775 ± 12 Ma). The inner rims of zircon from the amphibolites and gneisses likely record two different Neoarchean metamorphic events (2650 ± 8 and 2599 ± 10 Ma, respectively). The outer rims record Paleoproterozoic metamorphism with an age of 1890 Ma, which formed the modern appearance and mineral assemblages of the rock association. The value of δ18O in the zircon from the gneiss is 8.6‰ in cores, slightly decreases to 8.0‰ in inner rims, and sharply decreases to 3.9‰ in outer rims. The value of δ18O in the zircon from the amphibolite is around 6.2‰ in cores, increases up to 8.6 in inner rims, and decreases to 5.2‰ in outer rims. A significant decrease of δ18O is likely related to the anomalous composition of Svecofennian metamorphic fluid restricted to local shear zones. The geochemical features of the zircons in combination with their morphology and anatomy make it possible to distinguish zircon generations of different age and change in metamorphic environments.  相似文献   

8.
Abstract A metasomatic diopside rock occurs at the top of the dolomitic Connemara Marble Formation of western Ireland and contains titanite and K-feldspar in addition to around 90% diopside ( X Mg= 0.90–0.97). U–Pb isotopic measurements on this mineral assemblage show that the titanite is both unusually uranium-rich and isotopically concordant, with the result that a precise U–Pb age of 478 ± 2.5 Ma can be determined. The age is identical within error to a less precise Rb–Sr age of diopside–K-feldspar of 483 ± 6 Ma. Petrological evidence indicates that the assemblage crystallized at c . 620° C close to or below the closure temperature of titanite. The age thus provides a precise estimate of the time of metamorphism; this age is 11 ± 3 Ma younger than the 490 Ma age for nearby gabbroic plutons which has previously been used to constrain the peak metamorphic age. This difference accords well with geological evidence that the gabbros were emplaced prior to the metamorphic peak. Analysis of minerals with high closure temperature from assemblages whose crystallization is unambiguously associated with a specific episode of fluid infiltration at the peak of metamorphism provides the basis for a new approach to dating metamorphism. The success of this approach is demonstrated by the results from Connemara.  相似文献   

9.
Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800–875 °C and >9–10 kbar) and subsequent decompression in a kilometre‐scale, E‐W striking zone of noncoaxial, high‐grade (c. 700–735 °C and 5.8–6.4 kbar) deformation. However, new SHRIMP U‐Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta‐volcaniclastics) yield 206Pb/238U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield 206Pb/238U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400–300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475–460 Ma & 400–300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300–1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed.  相似文献   

10.
Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.  相似文献   

11.
U-Pb isotope analyses of zircon and titanite extracted from different rocks of the Felbertal scheelite deposit yield the following information: (1) An age of 593±22 Ma (2) is obtained for zircon crystallization in the scheelite-bearing matrix of an eruption breccia in the western ore field. (2) Discordant zircons from an elongated, up to 8 m thick scheelite-rich quartzite body in the eastern ore field give an upper intercept age of 544±5 Ma. This quartzite contains a laminated, fine-grained scheelite mineralization. (3) Zircons from a small granitoid intrusion of the western ore field reveal an age of 336±16 Ma, and concordant titanites document an age of 282±2 Ma for Variscan amphibolite facies metamorphism. Both events, granitoid intrusion and later metamorphism caused ore re-mobilization, including the formation of yellowish fluorescent (molybdo-) scheelite porphyroblasts. (4) For a narrow lamprop-1hyric dike in the western ore field, a concordant titanite age of 283±7 Ma is obtained. This age is identical with the titanites from the amphibolite facies metamorphic intrusion. Tiny scheelite grains were tapped by the dike from pre-existing scheelite mineralizations in the truncated host rocks. (5) Alpine metamorphism at 31±4 Ma did not exceed lowermost amphibolite facies conditions, and it caused scheelite re-mobilization on a minor scale only, producing bluish fluorescent porphyroblasts in quartz veinlets and veins, as well as bluish fluorescent scheelite rims around older scheelite grains. Moreover, crosscutting Alpine fissure fillings show bluish fluorescent, inclusion-free scheelite. (6) The preservation of Variscan titanites, the absence of Alpine titanite growth, and the large degree of Variscan scheelite re-mobilization demonstrate that amphibolite facies metamorphism in the Felbertal area has a Variscan age. This result clearly documents Variscan tectono-metamorphism to be the dominant event, instead of the hitherto surmised Alpine metamorphism. This multi-stage evolution of the Felbertal ore bodies corroborates the view that tungsten deposits are conditioned by several succeeding thermal events, leading to a series of stages that ultimately produce high-grade scheelite concentrations. These high-grade ores predominately occur along shear zones of different age, accompanied by the formation of large volumes of low-grade scheelite mineralizations along host rock foliations and quartz veinlets and veins.  相似文献   

12.
Abstract Concordant U–Pb ages of c. 530–510 Ma and c. 470–420 Ma on titanite from calcsilicate, orthogneiss and amphibolite rocks constrain the age of high‐T metamorphism in the Early Palaeozoic mobile belt at the western margin of Proterozoic Gondwana (Argentina, 26–29°S). The U–Pb ages document the time of titanite formation at high‐T conditions according to the stable mineral paragenesis and occurrence of titanite in the metamorphic fabric. The presence of migmatite at all sample sites indicates temperatures were > c. 650 °C. Titanite formed at similar metamorphic conditions at different times on the regional and on the outcrop scale. The titanite crystals preserved their U–Pb isotopic signatures and chemical composition under ongoing upper amphibolite to granulite facies temperatures. Different thermal peaks or deformations are only detected by the different U–Pb ages and not by changes in the mineral paragenesis or metamorphic fabric of the samples. The range of U–Pb ages, e.g. in the Ordovician and Silurian (c. 470, 460, 440, 430, 420 Ma), is interpreted as the effect polyphase deformation with deformation‐enhanced recrystallization of titanite and/or different thermal peaks during a long‐standing, geographically fixed, high‐T regime in the mid‐crust of a continental magmatic arc. A clear correlation of the different ages with distinct tectonic events, e.g. collision of terranes, is not possible based on the present knowledge of the region.  相似文献   

13.
As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.  相似文献   

14.
Trace element distribution in Central Dabie eclogites   总被引：16，自引：0，他引：16  
Coesite-bearing eclogites from Dabieshan (central China) have been studied by ion microprobe to provide information on trace element distributions in meta-basaltic mineral assemblages during high-pressure metamorphism. The primary mineralogy (eclogite facies) appears to have been garnet and omphacite, usually with coesite, phengite and dolomite, together with high-alumina titanite or rutile, or both titanite and rutile; kyanite also occurs occasionally as an apparently primary phase. It is probable that there was some development of quartz, epidote and apatite whilst the rock remained in the eclogite facies. A later amphibolite facies overprint led to partial replacement of some minerals and particularly symplectitic development after omphacite. They vary from very fine-grained dusty-looking to coarser grained Am + Di + Pl symplectites. The eclogite facies minerals show consistent trace element compositions and partition coefficients indicative of mutual equilibrium. Titanite, epidote and apatite all show high concentrations of REE relative to clinopyroxene. The compositions of secondary (amphibolite facies) minerals are clearly controlled by local rather than whole-rock equilibrium, with the composition of amphibole in particular depending on whether it is replacing clinopyroxene or garnet. REE partition coefficients for Cpx/Grt show a dependence on the Ca content of the host phases, with D REE Cpx/Grt decreasing with decreasing D Ca . This behaviour is very similar to that seen in mantle eclogites, despite differences in estimated temperatures of formation of 650–850 °C (Dabieshan) and 1000–1200 °C (mantle eclogites). With the exception of HREE in garnet, trace elements in the eclogites are strongly distributed in favour of minor or accessory phases. In particular, titanite and rutile strongly concentrate Nb and Zr, whilst LREE–MREE go largely into epidote, titanite and apatite. If these minor/accessory minerals behave in a refractory manner during melting or fluid mobilisation events and do not contribute to the melt/fluid, then the resultant melts and fluids will be strongly depleted in LREE–MREE. Received: 11 February 1999 / Accepted: 31 January 2000  相似文献   

15.
The analysis of early stage rodingite from the ultramafic rocks of the Xialu Massif in the Xigaze Ophiolite, Tibet, in China shows that the rodingitization involved continuous changes in fluid composition during different stages of subduction. The early stage prehnite-bearing rodingite was produced at low pressures and temperatures along extensional fractures. Samples of rodingite were collected along a profile from the center to the margin of a rodingitized intrusive igneous rock (~10 m × 30 m), and they record wide variations in bulk composition, mineralogy, and texture. The mineral assemblages, from center to margin, vary from (1) relics of primary clinopyroxene (Cpxr) and primary amphibole (Ampr) + newly formed late amphibole (Act) + primary plagioclase (Plr) + clinozoisite + prehnite + albite + chlorite + titanite + ilmenite (R1 rodingite), through (2) relics of primary clinopyroxene (Cpxr) + newly formed late clinopyroxene (Cpxn) + primary and late amphiboles (Ampr + Act) + clinozoisite + prehnite + albite + chlorite + titanite (R2 rodingite), to (3) newly formed late clinopyroxene (Cpxn) and amphibole (Act) + clinozoisite + prehnite + albite + chlorite + titanite (R3 rodingite). As a result of the metasomatic process of rodingitization, the content of CaO in the whole rock chemical composition from R1 to R3 increases, SiO2 decreases, and Na2O + K2O is almost completely removed. Mass-balance diagrams show enrichments in large ion lithophile elements such as Rb, Cs, Ba, and Pb as well as Ni during rodingitization. The central part of the rodingitized intrusion (R1 rodingite) was only slightly affected by metasomatism. On the other hand, the contents of the rare earth elements (REEs), high field strength elements (HFSEs; e.g. Zr, Nb, Ta, Hf, and Y), and some highly compatible elements such as Cr and Sc decreased slightly during rodingitization. Thermodynamic modeling based on equilibrium mineral assemblages indicates that the rodingite of the Xialu Massif formed in an H2O-saturated, CO2-rich environment. The estimated conditions of metamorphism were ~281–323 °C and 0.4–3.9 kbar, representing the subgreenschist facies. In this environment, REEs and HFSEs were soluble in the fluids and partly removed. Moreover, these prehnite rodingites formed in a progressively reducing and less alkaline environment, as indicated by decreases in f(O2) and bulk-rock Fe3+/Fe2+ ratios, and the records of fluid ΔpH from the center to the margin of the studied rodingitized intrusion.  相似文献   

16.
羌塘中部高压变质带的形成过程   总被引：1，自引：1，他引：0  
羌塘中部高压变质带由榴辉岩、石榴石白云母片岩和蓝片岩等组成,与蛇绿混杂岩、晚古生代浅变质地层岩片等共同构成了龙木错-双湖板块缝合带这一构造混杂岩带,是伴随古特提斯洋闭合的深俯冲作用及后期构造作用的产物。通过对其野外地质特征、不同岩石类型岩石学、矿物学以及同位素年代学等的研究,确认榴辉岩和石榴石白云母片岩在早期分别经历了各自的形成过程,在榴辉岩形成之后的折返过程中二者共同构成了高压变质带,并且在折返过程中榴辉岩发生蓝片岩相退变质作用,同时导致了带内蓝片岩的形成。同位素年代学研究结果表明,龙木错-双湖板块缝合带闭合过程中的榴辉岩相变质作用发生于240Ma左右,折返过程中的蓝片岩相退变质作用及蓝片岩的形成应在220～200Ma,高压变质带最终在214Ma之前抬升出露地表。  相似文献   

17.
The mineralogical, petrological, geochemical and geochronological data on the Garevka metamorphic complex (GMC) of the Yenisey Ridge were used to evaluate the age, nature, and provenance of their protoliths. The evolution of the GMC occurred in two stages with different ages, thermodynamic regimes, and metamorphic field gradients. The final emplacement of granitoids was marked by high-pressure (HP) amphibolite facies regional metamorphism (970 Ma). At the second stage, these rocks experienced Late Riphean (900–870 Ma) retrograde epidote-amphibolite facies metamorphism accompanied by the formation of blastomylonitic complexes within narrow zones of brittle-ductile deformation. The metamorphism of migmatites (850 Ma) is coeval with the collisional medium-pressure metamorphism of the kyanite-sillimanite type. The GMC is different from the other rock complexes of the Yenisey Ridge in the presence of rapakivi-type granites. The geochemistry of these rocks, which is characterized by stronger enrichment in K2O, FeO, Y, Th, U, Zr, Hf, Nb, Ta, and REE relative to the other mineral assemblages of the GMC, is typical of anorogenic (A-type) within-plate granites. Among other distinctive features of these rocks are the strong iron enrichment of the melanocratic minerals, the presence of ilmenite as the sole Fe-Ti oxide, and crystallization from higher temperature (T = 825°C vs. T = 750°C) water-poor magmas under reducing conditions below the FMQ buffer. Significant variations in the geochemical and petrological characteristics of the GMC rocks suggest that they could not be derived from a single source. The main volume of the high-K rocks varying in composition from A-type to S-type granites was generated by melting of mixed mantlecrustal sources. The products of melting of the Late Archean-Early Proterozoic infracrustal gneisses of the Siberian Craton could be a possible source for the least oxidized rocks.  相似文献   

18.
Three successive metamorphic stages M1, M2 and M3 have been distinguished in polymetamorphic granulite facies quartz-feldspathic gneisses from the Seiland Igneous Province, Caledonides of northern Norway. An early period of contact metamorphism (M1; 750–950°C, ca. 5 kbar) was followed by cooling, accompanied by strong shearing and recrystallization at intermediate-P granulite facies conditions (M2; 700–750°C, 5–6kbar). High-P granulite facies (M3; ca. 700°C, 7–8 kbar) is related to recrystallization in narrow ductile shear zones and secondary growth on M2 minerals. On the basis of composition, fluid inclusions in cordierite, quartz and garnet can be divided into three major types: (1) CO2 inclusions; (2) mixed CO2–N2 inclusions; (3) N2 inclusions. Fluid chronology and mineral assemblages suggest that the earliest inclusions consist of pure CO2 and were trapped at the M1 contact metamorphic episode. A carbonic fluid was also present during the intermediate-P granulite facies M2 metamorphism. The CO2-rich inclusions in M2 garnet can be divided into two generations, an early lower-density and a late higher-density, with isochores crosscutting the P-T box of M2 and M3, respectively. The nitrogen-rich fluids were introduced at a late stage in the fluid evolution during the high-P M3 event. The mixed CO2–N2 inclusions, with density characteristics compatible with M3 conditions, are probably produced from intersection between pre-existing pure CO2 inclusions and N2 fluids introduced during M3. The fluid inclusion data agree with the P-T evolution established from mineral assemblages and mineral chemistry.  相似文献   

19.
The Meliata unit represents a mélange-like accretionary wedge, containing blueschist facies tectonic blocks and slices in a Triassic and Jurassic sedimentary matrix. The blueschist facies rocks are tectonic remnants of the subducted parts of the Meliata-Hallstatt branch of the Tethys. The phyllosilicate assemblages in very low-grade metapelites represent metastable disequilibrium stages which the assemblages have reached during reaction progress. Therefore, temperature and pressure values of low-T metamorphism of the sedimentary series and the late stages of decompressional cooling of blueschist facies rocks, obtained by phyllosilicate "crystallinity", chlorite thermometric and white K-mica geobarometric methods, can be regarded as semiquantitative estimates. However, results of chlorite–white mica thermobarometry suggest that local equilibrium was approached at a microscopic scale. For deciphering the age relations of prograde and retrograde events, K–Ar isotope geochronological methods were applied. The sedimentary series and related basalts of the Meliata unit experienced high-T anchizonal prograde regional metamorphism, the temperature and pressure of which can vary between ca. 280 and 350 °C and ca. 2.5 and 5 kbar. White K-mica b geobarometry suggests possible minimal pressures of ca. 1.5 to 3 kbar. The mylonitic retrogression of blueschist facies phyllites is characterised by 340 °C and 4 kbar (minimal P). The low-T prograde metamorphism was synchronous with the retrograde metamorphism of the blueschists. The ages of these two events may be between ca. 150 and 120 Ma, culminating most probably at around 140–145 Ma. Thus, the Upper Jurassic (lowermost Cretaceous) very low-grade metamorphism of the Meliata unit is younger than the subduction-related, 160–155 Ma blueschist facies event, and definitely older than the Cretaceous (100–90 Ma) metamorphism of the footwall Gemer Palaeozoic.  相似文献   

20.
The evolution of the mineral assemblages and P–T conditions during partial melting of upper‐amphibolite facies paragneisses in the Orue Unit, Epupa Complex, NW Namibia, is modelled with calculated P–T–X phase diagrams in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O system. The close concordance of predictions from the phase diagrams to petrographic observations and thermobarometric results documents that quantitative phase diagrams are suitable to explain the phase relationships in migmatitic upper‐amphibolite facies low‐ and medium‐pressure metapelites, which occur in many high‐grade metamorphic terranes worldwide. Different mineral assemblages in the migmatitic metapelites of the Orue Unit reflect regional discrepancies in the metamorphic grade: in a Northern Zone, early biotite–sillimanite–quartz assemblages were replaced via melt‐producing reactions by cordierite‐bearing assemblages. In a Southern Zone, they were replaced via melt‐producing reactions by garnet‐bearing assemblages while cordierite is restricted to rare metapelitic granofelses, which preserve Grt–Sil–Crd–Bt peak assemblages. Peak‐metamorphic conditions of 700–750 °C at 5.5–6.7 kbar in the Southern Zone and of ～750 °C at 4.5 kbar in the Northern Zone are estimated by integrating thermobarometric calculations with data from calculated mineral composition isopleths. Retrograde back‐reactions between restite and crystallizing melt are recorded by the replacement of garnet by biotite–sillimanite and/or biotite–muscovite intergrowths. Upper‐amphibolite facies metamorphism and partial melting (c. 1340–1320 Ma) in the rocks of the Southern Zone of the Orue Unit, which underwent probably near‐isobaric heating–cooling paths, are attributed to contact metamorphism induced by the coeval (c. 1385–1319 Ma) emplacement of the Kunene Intrusive Complex, a huge massif‐type anorthosite body. The lower‐pressure metapelites of the Northern Zone are interpreted to record contact metamorphism at an upper crustal level.  相似文献   

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