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A number of archeological features, including in‐filled irrigation canals of uncertain prehistoric age, occur within the Holocene floodplain of the Salt River at Phoenix, Arizona. In the first attempt to date irrigation‐canal sediments using luminescence methods, we obtained age estimates of 1640 ± 190 yr B.P. (1σ) (multi‐aliquot or MA) and 1621 ± 95 yr B.P. (post‐IR single‐aliquot‐regenerative‐dose or SAR) for a single sample from the base of the oldest canal‐infilling deposits (all IR‐PSL ages reported in this article are in calendar years before A.D. 2001). For the remaining canal samples, weighted mean luminescence ages of 819 ± 45 yr (MA) and 826 ± 32 yr (post‐IR SAR) were obtained. Thus from photonic dating we can resolve the first and last phases of canal use at this Phoenix site: initiation at ca. 1600 years ago and final use at ca. 800 years ago. These results demonstrate the power of SAR luminescence sediment dating to enhance our understanding of prehistoric irrigation‐canal development and usage here and elsewhere in the world. © 2004 Wiley Periodicals, Inc.  相似文献   

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 Land subsidence in the form of sinks has occurred on and near farmlands near Tucson, Pima County, Arizona, USA. The sinks occur in alluvial deposits along the flood plain of the Santa Cruz River, and have made farmlands dangerous and unsuitable for farming. More than 1700 sinks are confined to the flood plain of the Santa Cruz River and are grouped along two north-northwestward-trending bands that are approximately parallel to the river and other flood-plain drainages. An estimated 17,000 m3 of sediment have been removed in the formation of the sinks. Thirteen trenches were dug to depths of 4–6 m to characterize near-surface sediments in sink and nonsink areas. Sediments below about 2 m included a large percentage of dispersive clays in sink areas. Sediments in nonsink areas contain a large component of medium- to coarse-grained, moderately to well sorted sand that probably fills a paleochannel. Electromagnetic surveys support the association of silts and clays in sink areas that are highly electrically conductive relative to sand in nonsink areas. Sinks probably are caused by the near-surface process of subsurface erosion of dispersive sediments along pre-existing cracks in predominantly silt and clay sediments. The pre-existing cracks probably result from desiccation or tension that developed during periods of water-table decline and channel incision during the past 100 years or in earlier periods. Submitted, April 1997 · Revised, November 1997 · Accepted, April 1998  相似文献   

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An understanding of the hydrogeology of Grand Canyon National Park (GRCA) in northern Arizona, USA, is critical for future resource protection. The ~750 springs in GRCA provide both perennial and seasonal flow to numerous desert streams, drinking water to wildlife and visitors in an otherwise arid environment, and habitat for rare, endemic and threatened species. Spring behavior and flow patterns represent local and regional patterns in aquifer recharge, reflect the geologic structure and stratigraphy, and are indicators of the overall biotic health of the canyon. These springs, however, are subject to pressures from water supply development, changes in recharge from forest fires and other land management activities, and potential contamination. Roaring Springs is the sole water supply for residents and visitors (>6 million/year), and all springs support valuable riparian habitats with very high species diversity. Most springs flow from the karstic Redwall-Muav aquifer and show seasonal patterns in flow and water chemistry indicative of variable aquifer porosities, including conduit flow. They have Ca/Mg-HCO3 dominated chemistry and trace elements consistent with nearby deep wells drilled into the Redwall-Muav aquifer. Tracer techniques and water-age dating indicate a wide range of residence times for many springs, supporting the concept of multiple porosities. A perched aquifer produces small springs which issue from the contacts between sandstone and shale units, with variable groundwater residence times. Stable isotope data suggest both an elevational and seasonal difference in recharge between North and South Rim springs. This review highlights the complex nature of the groundwater system.  相似文献   

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The Tertiary sedimentary sequence of the Date Creek basin area of Arizona is composed principally of intertonguing alluvial-fan and lacustrine deposits. The lacustrine rocks contain large intermediate- to, locally, high-grade uranium deposits that form one of the largest uranium resources in the United States (an estimated 670,000 tons of U3O8 at an average grade of 0.023% is indicated by drilling to date). At the Anderson mine, about 50,000 tons of U3O8 occurs in lacustrine carbonaceous siltstones and mudstones (using a cutoff grade of 0.01%). The Anderson mine constitutes a new class of ore deposit, a lacustrine carbonaceous uranium deposit.Floral and faunal remains at the Anderson mine played a critical role in creating and documenting conditions necessary for uranium mineralization. Organic-rich, uraniferous rocks at the Anderson mine contain plant remains and ostracodes having remarkably detailed preservation of internal features because of infilling by opaline silica. This preservation suggests that the alkaline lake waters in the mine area contained high concentrations of dissolved silica and that silicification occurred rapidly, before compaction or cementation of the enclosing sediment. Uranium coprecipitated with the silica. Thinly laminated, dark-colored, siliceous beds contain centric diatoms preserved with carbonaceous material suggesting that lake waters at the mine were locally deep and anoxic. These alkaline, silica-charged waters and a stagnant, anoxic environment in parts of the lake were necessary conditions for the precipitation of large amounts of uranium in the lake-bottom sediments.Sediments at the Anderson mine contain plant remains and pollen that were derived from diverse vegetative zones suggesting about 1500 m of relief in the area at the time of deposition. The pollen suggests that the valley floor was semiarid and subtropical, whereas nearby mountains supported temperate deciduous forests.  相似文献   

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W. Chen  R. J. Arculus 《Lithos》1995,36(3-4):203-225
A wide variety of xenoliths has been entrained in Miocene-to-Recent alkali olivine and hypersthene-normative basalts in the San Francisco Volcanic Field (SFVF), northern Arizona, U.S.A. Based on petrography, mineralogy, bulk rock chemistry and Sr-Nd isotopic characteristics, SFVF xenoliths can be divided into two major groups: cumulates and granulites. The cumulates are genetically related to the Cenozoic volcanic rocks and represent under- and/or intraplated additions to the crust of the Colorado Plateau. Assemblages are mafic to ultramafic and are dominated by clinopyroxene-orthopyroxene-plagioclase-spinel-amphibole-olivine. The granulites are probably Proterozoic in age, mafic-to-intermediate/felsic in bulk composition, either two pyroxene-plagioclase-spinel or plagioclase-alkali feldspar-quartz-magnetite-amphibole-biotite assemblages. Many of the granulites show evidence of partial melting. Some high SiO2, very high Rb/Sr glasses are close in composition to erupted rhyolites, and probably represent end-member melts that have interacted with basalt to produce a variety of hybrid intermediate lavas. The major element, trace element and Sr-Nd isotope geochemistry is highly variable in the SFVF xenoliths. Extremely high Ba contents and Ba/Nb of a number of the granulites are equivalent to values characteristics of modern supra-subduction zone magmas. The considerable variation of chemical and isotopic composition depends upon mineral proportions, assemblages and chemistry. Isotopically, three end-members can be identified within the granulites: (i) lowest 87Sr/86Sr (0.702870) with low 143Nd/144Nd (0.511541, εNd-21.4); (ii) high 87Sr/86Sr (0.711069) with the lowest 143Nd/144Nd (0.511434, εNd-23.5); (iii) highest 87Sr/{86}Sr (0.715306) with low 143Nd/144Nd (0.511793, εNd-16.5). Two important age ranges deduced from the isotopic data probably relate to episodes of crustal-growth beneath the SFVF (1.88 ± 0.33 Ga and Cenozoic). Thermobarometric calculations assuming equilibrium show that the xenoliths are derived from the lower crust (0.6–1.3 GPa, 850–1050 °C). The average SFVF lower crust is mafic in composition. In the absence of partial lithospheric delamination, the lower crust may become mafic with time due to under- and intraplating of continental crust by mafic magmas derived from the mantle.  相似文献   

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Sand temper compositions of regionally distinct Hohokam pottery sherds were determined by detailed point counts using sedimentary petrographic methods. Different temper compositions from different sites were compared with maps of sand composition zones within the geographic range of the pottery in order to establish the probable provenance of each sherd. A number of probable instances of intraregional pottery exchange were identified. The larger number of sand sources in undecorated vs. decorated pottery at each site suggests that undecorated pottery was made in more places than decorated vessels, and may have been traded differently as well. Petrographic analysis of temper is a useful method for studying exchange of homogeneous pottery in geologically diverse areas, and for investigating prehistoric Hohokam interaction in the Tucson and Red Rock Basins on a scale not possible with traditional archaeological techniques.  相似文献   

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This study examines the groundwater characteristics in the Silver Bell Mountains, Arizona, USA, using a numerical model. Groundwater modeling is developed to describe the flow pattern in the study area and subsequently explores the possible interaction with regional porphyry copper deposits. A conceptual model is developed for the study area and regional hydrogeological conditions are simulated using the finite-difference groundwater flow model, MODFLOW-2005. The model results show that groundwater flow in the Silver Bell Mountains is strongly influenced by topography and its velocity varies with depth. In addition, the numerical model supports the idea of a continuous sustained interaction between groundwater flow and porphyry copper deposits in the Silver Bell Mountains. This interaction may result in continuing leaching of trace elements from the ore deposit, an important implication for continuing supergene alteration and enrichment of the porphyry copper deposit.  相似文献   

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《Applied Geochemistry》1997,12(1):83-95
In a column experiment, acidic groundwater from Pinal Creek Arizona, a Cu mining area, was eluted through a composited alluvial sample obtained from a core that had been removed from a well downgradient of the acidic groundwater. The minerals present in typical grains and flakes in the alluvium before and after the elution were determined by X-ray diffraction (XRD), scanning electron microscopy, and energy dispersive multichannel analyses (EDX). The concentrations of Fe, Ti, Mn, Si, Al, Na, Ca, K, Mg and S in these grains and flakes and in their microcrystalline surface coatings were measured by EDX.In addition to magnetite, hematite, and Fe-Ti oxides, Fe was most concentrated in micas (especially biotite-like flakes) and in the microcrystalline coatings. The measured elements in these microcrystalline coatings were primarily K, Fe, Al, and Si. The microcrystalline coatings on the mica flakes also contained Mg. The approximate l:3 Mg:Si atomic ratios (ARs)_of the biotite-life flake both before and after the elution would suggest that the Fe deposited during the elution had not substituted for Mg in these flakes. As a result of the elution, assuming no loss of Si, the averaged recorded Fe:Si AR of the microcrystalline coatings increased from (0.46 to 0.58):3.00.Iron deposition on the typical grains and flakes may relate to the presence of Fe in the particle on which it is deposited or to the presence of Fe in the microcrystalline surface coatings before elution. The data here are not sufficient for a statistical evaluation, but elution caused the following trends: (l) The Fe:Si AR increased in the (K,Fe,Al,Si)-microcrystalline surface coatings; (2) For the mica flakes, there was more than a 2-fold increase in the Fe:Si AR for the microcrystalline surface coatings of the Fe-rich biotite-like flakes but no measurable increase of the Fe:Si AR for the microcrystalline surface coatings of the muscovite-like flakes that contained 3–5 times less Fe; (3) Also for the biotite-like flakes, the increase in Fe:Si AR was greater in the flakes that had a higher Fe:Si AR; (4) The Fe deposition on the Fe-rich microcrystalline surface coatings of the feldspar was much greater than on the Fe-poor, beige quartz and feldspar grains that, prior to elution, had only CaS04 microcrystalline coatings; and (5) No Fe was deposited on Fe-poor grains with no microcrystalline surface coating.  相似文献   

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Spinel lherzolite and pyroxenite inclusions from the Geronimovolcanic field, Arizona (and Dish Hill, California) record,in their constituent minerals, a chronology of diverse mantledepletion and enrichment events. Certain portions of the lithosphericmantle have remained relatively isolated for considerable periodsof time(1–4 b.y.) while wall rock adjacent to conduitsof basanite has been recently (< 0-2 b.y.) modified. Evidenceexists for a widespread ancient (1–4 b.y.) partial meltingresidue, now recognizable as MORB-like mantle below the southwesternU.S.A. Trace element enrichment (0?9 b.y.) has increased thelight rare earth element (LREE) and Sr content of many refractoryperidotites without any mineralogical changes to the host rock.The fluids/melt responsible for this enrichment have a complexhistory involving heterogeneous mantle sources. In contrast,modal metasomatism of the mantle (< 0.2 b.y.) in aureolesaround evolved derivatives of basanite has petrographicallyand chemically transformed this ancient partial melting residue.The metasomatic fluids responsible for such metasomatism havean asthenospheric mantle source identical to the host magma.It is proposed that modal metasomatism occurs in contact metamorphicaureoles that surround apophyses of basanitic silicate meltin the lithospheric mantle. The gradient in CO2/(CO2 ? H2O)ratio that must surround such veins in the upper mantle (<20 kb) may encourage the development of enrichment fronts. Immediatelyadjacent to the vein, a wet zone with a relatively low CO2/(CO2? H2O) ratio would allow a precipitation of mica ? amphibole.Beyond this a dry zone with a higher CO2/(CO2 ? H2O) ratio wouldhasten chemical but not petrographic transformation of the wallrock.  相似文献   

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The development of irrigation agriculture on valley floors in the southwestern United States has substantially altered natural drainage systems. This study discusses five anthropogenic factors that have altered the hydrologic function of a dryland basin floor in south-central Arizona. These factors are: (1) upstream urbanization and channel entrenchment, (2) dam construction, (3) artificial diversion of drainage, (4) obstruction of flow by transportation routes, and (5) stream channelization. The first two factors have altered hydrologic inputs to the basin floor, the third and fourth factors have changed regional and local patterns of flooding, and the fifth factor has resulted in channel instability and reduced flood attenuation. These five factors, along with a recent increase in the frequency of incursions of tropical moisture into southern Arizona, have enhanced flow variability and the potential for devastating flooding on the basin floor. This research demonstrates the need for basin-wide approaches to stream management in drylands and illustrates the importance of basing management decisions on geomorphic information concerning fluvial forms and processes.  相似文献   

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Lignin derivatives have been isolated for the first time from carbonaceous sections of the silicified (~90% SiO2) conifer Araucarioxylon arizonicum. The products released by sequential high vacuum pyrolysis and identified by combined gas chromatography-mass spectrometry (GC-MS) include a wide variety of alkyl-substituted, phenolic and condensed aromatic compounds.Brauns spruce lignin was pyrolized and analyzed by GC-MS as a comparison for the fossil wood data. The primary pyrolyzates at the 300°C step were CO2, H2O, ethanol and propanol. The main product at 450°C was 4-methyl-2-methoxyphenol (methyl guaiacol), but at 600°C the pyrolyzates were similar both in product composition and in relative abundance to those from silicified wood. The results suggest that the fossil wood experienced a mild thermal event during which the ether bonds were ruptured and loss of oxygen occurred along with the rearrangement of the original wood into a highly stable polymer.  相似文献   

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A reconnaissance geochemical survey of stream drainages within 21,000 km2 of southeastern Arizona and southwestern New Mexico shows broad zones of low-level to moderate contrast anomalies, many associated with mid-Tertiary eruptive centers and Tertiary fault zones. Of these eruptive centers, few are known to contain metallic deposits, and most of those known are minor. This, however, may be more a function of shallow erosion level than an indication of the absence of mineralization, since hydrothermal alteration and Fe-Mn-oxide staining are widespread, and geochemical anomalies are pervasive over a larger part of the region than outcrop observations would predict. Accordingly, interpretations of the geochemical data use considerations of relative erosion levels, and inferred element zonalities, to focus on possible undiscovered deposits in the subsurface of base-, precious-, and rare-metal deposits of plutonic-volcanic association. In order to enhance the identification of specific deep targets, we use the empirically determined ratio: This ratio is based on reported metal contents of nonmagnetic heavy-mineral samples from the drainage sediment, determined by emission spectrographic analysis. Before the ratio was computed for each sample site, the data were normalized to a previously estimated regional threshold value. A regional isopleth map was then prepared, using a cell-averaging computer routine, with contours drawn at the 25th, 50th, 75th, 80th, 90th, 95th and 99th percentiles of the computed data.  相似文献   

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