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1.
Representative subsamples of Pocahontas No. 3 coal obtained at a fresh mining cut in a coal mine in West Virginia, U.S.A., were oxidized in air at 50°C or stored at ambient temperature in argon. Periodically, subsamples were removed from their locations and analyzed both petrographically and through Gieseler plastometry.With increasing oxidation, as indicated by plastometer results, the percentage of vitrinite decreased while the percentage of oxyvitrinite increased. Also, the percentage of slitted pseudovitrinite initially increased, but, subsequently decreased. The same trends occurred for both the 50°C and ambient samples, although at a lower rate for the ambient samples. This has been interpreted as indicating that slitted pseudovitrinite is an oxidation product of vitrinite that is intermediate, in terms of degree of oxidation, between vitrinite and oxyvitrinite.Vitrinite and slitted pseudovitrinite reflectances were found to be approximately the same, however, a shallow trend of decreasing reflectance with degree of oxidation may be indicated. No explanation is submitted for an observed decrease (with oxidation) in percentage of micrinite; however, an explanation of the origin of slitted structures in vitrinite material as it relates to cell structure and geological conditions is offered.  相似文献   

2.
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3.
In order to get detailed information about the facies and genesis of Upper Carboniferous coal seams of Northwest Germany, maceral analyses of complete seam profiles (Westphalian B-D, mainly Westphalian C) were carried out. Four main facies and twelve subfacies could be distinguished. The main facies are:
1. (1) The sapropelic-coal facies, consisting of fine-grained inertinite and liptinite, which forms from organic sediments deposited at the bottom of moor lakes.
2. (2) The densosporinite facies which is high in inertinite and liptinite and low in vitrinite. Syngenetic pyrites, clastic layers, thick vitrains and fusains do not occur. This facies originates from peats of ‘open mires’ with higher groundwater table and herbaceous vegetation. The ‘open mire’ was situated in the centre of extensive swamps. Consequently, clastic sedimentation did not affect this swamp type and nutrient supply and pH values were low.
3. (3) The vitrinite-fusinite facies, which is high in vitrinite. This is the result of abundant vitrains. Under the microscope, fusains were mostly identified as fusinite. The vitrinite-fusinite facies originates from a forest mire. More or less abundant seam splits and clastic layers show that rivers flowed in the neighbourhood of this area.
4. (4) The shaly-coal facies, which represents the most marginal part of the former swamp frequently affected by clastic sedimentation.
Within the Carboniferous of the Ruhr Region it seems unlikely that the thin coal seams of the Namurian C and Westphalian A1 contain a densosporinite facies. The swamps were situated in the lower delta plain where they were often affected by marine influences. Consequently, coals are high in minerals and sulfur and they are thin and discontinous. The best conditions for the formation of extensive swamps, with open mires (densosporinite facies) in their central parts, prevailed during Westphalian A2 and B1 times. Low contents of sulfur and minerals and high content of inertinite are typical for these coals. Sedimentation mainly took place in the transitional zone from the lower to the upper delta plain. During the Westphalian B2 and C fluvial sedimentation dominated. Within the coal seams minerals, sulfur and pseudovitrinite increase while inertinite decreases. This is the consequence of coal of the densosporinite facies occurring with increased rarity. The coal seams of the Westphalian C2 contain no densosporinite facies because peat formation was restricted by increasing fluvial sedimentation and by a better drainage. As a consequence, extensive swamps with ‘open mires’ in the centre were no longer formed after the formation of the “Odin” seams. Above the “Odin” seams coal of the vitrinite-fusinite facies contains thick-walled torisporinites. Variations and lowering of the groundwater table caused mild oxidative influences during peat formation. This is documented by an increase in pseudovitrinite, the occurrence of torisporinites and the absence of spheroidal sideritic concretions. Sulfur content increases in the absence of the low-ash and low-sulfur coal of the densosporinite facies.In Upper Carboniferous coal seams of the Ibbenbüren Region the inertinite and telocollinite contents are higher than in those of the Ruhr Region. Therefore, variations of the groundwater table have been more pronounced and resulting oxidative influences must have been more severe. Seldom occurring marine and brackish horizons and a higher fusinite (fusain) content indicate a slight elevation of this area. From Early Westphalian D times onward, peat formation was no longer possible because of the better drainage. This resulted in severe oxidative conditions which excluded peat formation.  相似文献   

4.
地质导向技术能有效提高煤层气水平井施工成功率和煤层钻遇率,但由于其具有导向参数多、工艺要求高、易受地质因素影响等特点,使其在实际应用中还存在诸多难点。以柳林区块内某多分支水平井为例,针对该井现场地质导向作业面临的资料缺乏、参数受欠平衡钻进干扰、煤层结构复杂等难点,建立合适的地质导向模型,优选合理的导向参数和导向系统,对地质导向技术在实际应用中的工艺与流程进行了系统论述。实践表明,地质导向技术在该井的应用效果良好:煤层钻遇率达到了93.1%;截至目前,该井的产气量达8600m3/d,且还在进一步提升。  相似文献   

5.
The Gunnedah Basin, NSW, Australia, contains more than 500 Gt of coal, and has been the subject of recent coalbed methane exploration. Large areas of the basin contain igneous intrusions and large areas of coal have been heat-affected as a consequence. A detailed study has been undertaken of coal seams intersected in a cored coalbed methane exploration drillhole in which two sill-form igneous intrusions are present. Comparisons are made between coals that are unaltered and coals that have been heat-affected, using petrographic and chemical data, coal seam gas desorption data, and gas chemical analysis data.Results demonstrate that the two igneous intrusions have had a very positive effect on coalbed methane development. The gas content in a number of heat-affected coal seams within thermal aureoles above and below the sills is substantially higher than in adjacent unaffected coal seams. In addition, the intrusions have had little effect on gas quality. The coals in the heat-affected zone were found to contain gas with approximately 95% methane. The coals in the thermal aureoles were found, under the microscope, to contain characteristic micropores and slits, which collectively may serve to enhance gas adsorption capacity, permeability, and gas desorption. Gas contents below each of the sills is substantially higher than above the sill, confirming earlier results that the sills appear to have acted as a reservoir seal, during and for some time after intrusion. The background coal rank in ACM Yannergee DDH 1 is in the high-volatile bituminous range. The igneous intrusions have resulted in an increase in rank such that large areas of coal have moved into the optimal thermogenic gas generation window. This rank increase has affected a major part of the coal-bearing sequence.  相似文献   

6.
首批煤炭国家规划矿区煤中镓的成矿前景   总被引：2，自引：0，他引：2  
基于煤炭资源勘探中获得的5079件煤样实测数据,对全国首批煤炭国家规划矿区煤中Ga进行了资源调查,建立了煤中Ga成矿前景评价方法,固定了煤中Ga的地球化学异常,预测了煤中Ga的资源状况及其分布规律,初步讨论了煤中Ga“矿床”的规模和成矿前景。结果显示,评价区煤中Ga尽管总体上没有达到边界工业品位,但某些勘查区某些层煤中存在Ga的地球化学异常,某些煤层通过初步“选矿”或提取可使Ga得到相当程度的富集,表明区内煤中Ga有一定的成矿前景。  相似文献   

7.
晋北煅烧高岭土用煤矸石的应用矿物学特征   总被引：1，自引：0，他引：1  
为了给晋北煅烧高岭土用煤矸石的评价和开发利用提供科学依据,采用XRD、XRF、SEM和白度计等现代分析测试技术,研究了晋北煅烧高岭土用煤矸石的应用矿物学特征。结果表明:1)根据造纸和涂料用煅烧高岭土的国家标准,晋北煤矸石主要可分为3种类型:合格原料、基本合格原料和不合格原料。2)与合格和基本合格原料相比,不合格原料煅烧产物的化学成分中SiO2、Al2O3、Fe2O3含量以及碱金属与碱土金属总含量都与前者有较大差异。3)合格和基本合格原料主要由高岭石(85%~94%)组成,不合格煤矸石矿物组合为高岭石(30%~60%)+石英(23%~38%)+伊利石(14%~26%),并含少量黄铁矿和白云石等杂质矿物,石英等杂质矿物和含铁矿物是分别导致煅烧产物化学成分和白度不合格的主要原因。4)合格原料中高岭石结晶度较好,主要为不规则片状、书册状和弯曲片状,片表面光滑,片径大小范围较大,为0.05~51.22μm,平均2.80μm,径厚比41.24。  相似文献   

8.
尚洪田 《中国煤田地质》2006,18(4):25-26,52
分析了洪山预测区西部洪山岩体地质特征及其向外围扩散的范围和程度，研究了北掌勘查区和焦窑煤矿两邻区煤层受岩浆岩影响的程度，认为洪山岩体对预测区煤系及煤层赋存的影响较小，岩体外围仍有煤系赋存。为下一步找煤指明了方向。  相似文献   

9.
This paper describes the influence of volcanic ash on the concentrations and occurrences of associated elements in coal in the Zhijin Coalfield in western Guizhou Province, China. Our studies reveal that the No. 9 coal seam in the Zhijin Coalfield has very high content of Fe (4.34%), Cu (369.90 μg/g), U (49.6 μg/g), Mo (63.10 μg/g), Zn (33.97 μg/g), and Zr (841.80 μg/g). The studies have also found that elements, such as Fe and Cu, do not occur as sulfides in this coal seam, in sharp contrast to many other coal seams in China. The geochemical and mineralogical anomalies of the coal seam are attributed to synsedimentary volcanic ash. In addition to normal macerals and minerals in coal, a volcanic-influenced material (VIM) derived from volcanic ash, detrital material of terrigenous origin and organic matter was identified under polarized-light reflectance microscopy and scanning electron microscopy equipped with energy-dispersive X-ray (EDX) analyzer. The volcanic-influenced material is the main carrier of the above elements in this coal. Six types of the volcanic-influenced material (VIM-1, VIM-2, VIM-3, VIM-4, VIM-5, and VIM-6) are further distinguished on the basis of their structures and compositions. To the best of our knowledge, this is the first report that presents a detailed classification of coal components with a high content of volcanic ash.  相似文献   

10.
The study focuses on the mineralogy of the upper coal seam accumulated at the top of the Çoraklar Formation (Miocene), Beypazari, Turkey. This coal seam is laterally extensive and averages 3.0 m thick, varying from 1.0 to 4.9 m. Analcime and clinoptiolite comprise up to 80% of the mineral matter (which also includes feldspars, quartz and pyrite and traces of dolomite, clay minerals and apatite) in the coal from the Cayirhan mine. Zeolites were formed when sodium-rich solutions altered aluminosilicate epiclastic material derived from contemporaneous volcanic activity. The allocthonous organic matter accumulated as a result of detrital plant and epiclastic material from an adjacent fresh-water environment being washed into a saline lake in sufficient quantities to form peat with a high mineral matter content (29.7% mean mineral matter content in raw coal). Subsequent syngenetic alteration of the volcanic glass incorporated into the peat resulted in zeolite formation. Alteration of sodium-rich epiclastic material by sodium-rich solutions resulted in the formation of analcime, whilst alteration of calcium-rich epiclastic material by sodium-rich solutions resulted in the formation of clinoptilolite.  相似文献   

11.
Petrographic investigations of serial ply samples from five high- to medium-volatile bituminous coal seams from Australia (4) and Canada (1) reveal substantial in-seam variations in the reflectance and monochromatic microfluorescence intensities of the maceral subgroup telovitrinite. The variations consist of one case of reflectance enhancement and fluorescence suppression, and four cases of reflectance suppression and fluorescence enhancement. The single case of reflectance enhancement and fluorescence suppression is due to the oxidation of the vitrinite nuclei at the sequence boundary between the Bayswater and Upper Wynn seams in New South Wales. The four cases of reflectance suppression and fluorescence enhancement result from the syn- and epigenetic absorption by the vitrinite nuclei of hydrogen donated by, presumably, anaerobic bacteria-generated lipids. Two of the coals are marine-influenced: the Liskeard Seam from the Bowen Basin by combined syngenetic and epigenetic effects, and the Greta Seam from the Sydney Basin mainly by epigenetic contact with sea water. For both coals, the results are strong vitrinite reflectance suppression and fluorescence enhancement. The remaining two coals, the Bulli Seam from the Sydney Basin and a coal seam from the Gates Formation in British Columbia, show moderate epigenetic effects on the optical properties of telovitrinite by fresh-water. In the Bulli Seam which was studied in two adjacent localities, the reflectance suppression and fluorescence enhancement of telovitrinite are stronger under sandstone roof than under shale roof. In some cases, the epigenetic effects are superimposed on syngenetic telovitrinite reflectance and fluorescence variations resulting from the cogeneration and mixing of different telovitrinite precursors, for example, autochthonous roots and hypautochthonous or allochthonous shoots. A measure of the degree of dispersal and mixing is the coefficient of variation of telovitrinite reflectance and/or fluorescence. This coefficient correlates well with detrital minerals and dispersed macerals, e.g., inertodetrinite and, to a lesser extent, sporinite. Some comments are made on slitted so-called pseudovitrinite which is regarded as a telovitrinite that was subjected to very weak post-coalification desiccation and possibly oxidation without losing much of its thermoplastic properties.  相似文献   

12.
Cleat orientation, cleat frequency and cleat angle distribution of deep coal seams are only available by the use of drilling cores and from coal mine samples. Coal drilling cuttings are a cheap and fast alternative to measure cleat angle distributions with the use of image analysis techniques. In this study oriented coal samples and drilling cuttings of the RECOPOL field experiment are compared and used to explain and validate the proposed method. In other words, cleat angle distributions from drilling cuttings are measured by image analysis. The geological framework of the polish coals is described. The image analysis methodologies for the measurement of fracture faces of cuttings and from CT-scan images, derived from these coals, are explained. The results of the methods on the cuttings are compared with cleat orientation distributions from CT-scans and artificial fragments from coal blocks of the same seams. These evaluations show high agreements between the methods. The cleat angle distributions of drilling cuttings of four seams are compared with the cleat orientation distributions of a regional structural geological study. The high correlation in this study shows that cleat angle distributions of coal seams can be used as input parameters for reservoir modelling.  相似文献   

13.
Floral character in mires has changed progressively through time. In the Carboniferous, pteridophytes, sphenophytes and lycophytes were dominant but by the Permian gymnosperms were an important component of mire flora. During the early Mesozoic gymnosperms remained the characteristic mire vegetation, together with pteridophytes, and conifers became dominant during the Jurassic. Cretaceous and Paleocene vegetation are similar, with taxodiaceous flora being important in mire vegetation. From the Eocene onwards, however, angiosperms were increasingly dominant in mire communities and in the Miocene herbaceous vegetation began to play a significant role. Together with these changes in floral character at least three aspects of coal character also appear to vary sequentially with time and are distinctive in the Tertiary: (1) proportions and thickness of vitrain banding, (2) coal bed thickness and (3) proportions of carbonised material. A compilation has been made of data from the coal literature comparing older coals with those of the Tertiary, in order to give a perspective in which to examine Tertiary coals. It was found that only Tertiary coals contain significant proportions of coal devoid of vitrain bands. In addition, Tertiary coals are the thickest recorded coal beds and generally contain low percentages of carbonised material (many less than 5%) as compared to older coals. It is interesting to note that Paleocene coal beds are similar to Cretaceous coals in that they tend to be thinner and contain higher proportions of carbonised material than do younger Tertiary coals.The absence of vitrain bands in some Tertiary coal beds is thought to result from the floras dominated by angiosperms, which are relatively easily degraded as compared to gymnosperms. The thickness of Tertiary coals may be related to an increase in biomass production from the Carboniferous through to the Tertiary, as plants made less investment in producing lignin, an energy-intensive process. In addition, with less lignin in plants, easier degradation of biomass may have facilitated nutrient recycling which, in turn, led to greater biomass production. Increased biomass production may have also ‘diluted’ the carbonised material present in some Tertiary peats, leading to lower proportions in the coal. Another possible cause of decreased carbonised components in Tertiary coal is that decreasing lignin content resulted in decreased charring during fires, as lignin is particularly prone to charring. A third possibility is that the carbonised component of peat may be concentrated during coalification so that Tertiary coals, generally of lower rank than Mesozoic or Paleozoic coals, contain a smaller fraction of carbonised plant material. It is not at present clear which of these mechanisms may have affected carbonised material in peat and coal but it is clear that lignin type and content has had an important role in determining peat and coal character since the Paleozoic.  相似文献   

14.
The bituminous coals of the Mecsek Mountains were formed during the Early Lias and are of paralic origin. The limnic complex of the layers consists of sandstone, aleurite and coal, and the upper layer contains marl of marine origin. The 9–15 minable coal seams have a thickness of 1.2–14.0 m. The Mecsek Coal Field and the coal complex within it show a folded and fractured structure, and with regard to their mechanical behaviour, are strongly stressed.75–90% of the coal material is vitrinite, and 1–14% is inertinite. The quantity of liptinite is smaller than 9%. The coal rank is that of gas coal and fat coal with a reflectivity of 0.85–1.5%, respectively. The coal rank differences and variations according to zones are the consequence of forces of various magnitude that occurred in the course of orogenic movements.During the Early Cretaceous, there was some under-sea-bed volcanic activity in this field, the diabasic material of which appeared in the form of a bed vein along the coal seams, and this has exerted a strong metamorphic influence on the coal. It has resulted in thermo-contact alteration, i.e. in the appearance of natural coke and semicoke of various degrees of metamorphism. This alteration badly affected the quality and technological characteristics, especially the cokability of the coal.  相似文献   

15.
贵州省含煤渣建材的放射性污染调查   总被引：6，自引：0，他引：6  
调查研究了贵州省主要煤田及贵阳地区部分小煤矿中天然放射性核素含量水平，叙述了利用煤渣作建筑材料所产生的巨大社会效益和经济效益。阐明了根据煤灰（渣）的天然放射性核素含量水平进行分类管理的重要性，分析煤灰（渣）作建筑材料存在的一些问题，对可能产生的放射性污染提出防治对策。  相似文献   

16.
煤粉问题是制约煤层气连续稳定排采的关键因素之一。以韩城煤层气区块为研究区,采用煤层气井现场监测、实验测试分析、物理模拟实验、现场工程应用相结合的方法,从煤粉产出的影响因素及成因、煤粉产出规律及管控措施方面,开展了煤粉产出机理及管控措施的系统研究。研究结果表明:影响煤粉产出的因素分为煤储层物性静态地质因素与煤层气开发动态工程因素两类。指出了不同煤体结构煤产出煤粉的倾向性及特征不同。碎粒煤和糜棱煤产出的煤粉体积分数高,产出煤粉量大。产出煤粉的成分以无机矿物和镜质组为主。在煤层气不同排采阶段,产出煤粉的体积分数和粒度特征具有明显的阶段性变化。在煤粉产出机理研究的基础上,结合煤层气井生产实践,从地质预防、储层改造、设备优选、生产预警、排采控制和工艺治理方面,提出了一套煤粉管控措施体系。应用于韩城区块煤层气井的煤粉管控,取得了良好效果。   相似文献   

17.
目前,我国对煤的定义似乎很明确,但在实际应用中会遇到煤与非煤的界定问题,其势必影响到煤炭的合理划分及应用。为此从煤的沉积及变质演化入手,明确煤与炭质泥岩、天然焦、石墨等演化关系,进而从其相互间的物质成分差异、变质程度及宏观与显微特征差异加以界定,初步总结出划分煤及其相邻非煤类别的灰分、水分、变质程度、宏观和显微的差异特征,为后续煤和邻近非煤划分提供理论参考。  相似文献   

18.
超无烟煤（也称变质无烟煤）中广泛发育石墨微晶,为深入分析煤中石墨微晶产出特征及成因,以福建省永安煤田典型样品为例,采用光学显微镜、扫描电镜和透射电镜等测试方法,识别并分析煤中石墨微晶的光学性质、物质组成、晶体结构等特征,并探讨其成因。结果显示:石墨微晶主要产出于煤中微裂缝和空腔内,多数具有类似于石油焦的纤维状显微结构,可见气泡膜状结构;石墨微晶最大反射率为9.29%~10.83%,远远高于煤中原有显微组分;正交偏光加石膏试板观测条件下,石墨微晶呈现一级黄、二级蓝干涉色以及镶嵌状、区域状、纤维状等显微结构,局部定向性明显。扫描电镜加电子探针探测显示,石墨微晶多呈鳞片状并见流动状结构和气孔构造,同时显示出纯碳特点。高分辨率透射电镜观测到石墨微晶晶格条纹呈平直定向排列,选区电子衍射呈现典型的石墨晶格环斑模式。初步分析认为,煤中石墨微晶的碳质来源于高度熔融的（变）壳质组和富氢（变）镜质体,热源为侵入煤田周边及盆地底部的燕山期花岗岩,熔融含碳物质在孔缝空间内汇聚流动并在高温下脱除杂质元素,然后在强大岩浆侵位压力下结晶形成秩理性显著的石墨微晶;同时,也不排除渗出沥青质体再次活化形成研究区煤中石墨微晶的可能性。移动阅读   相似文献   

19.
Accurate prediction of in-situ stress directions plays a key role in any Coal Bed Methane (CBM) exploration and exploitation project in order to estimate the production potential of the CBM reservoirs. Permeability is one of the most important factors for determination of CBM productivity. The coal seams in Jharia coalfield generally show low permeability in the range of 0.5 md to 3 md. To estimate the in-situ stress direction in the study area, an attempt has been made to undertake the cleat orientation mapping of four regional coal seams of two underground coal mines located at south-eastern part of Jharia coalfield, India. Cleat orientation mapping is critical to determine the maximum principal compressive horizontal stress (SH) direction for CBM exploration and exploitation, which in turn controls the direction of maximum gas or water flow though coal beds. From the field study it is found that the average face and butt cleat azimuths are towards N15°W and N75°E respectively. Average permeability of the four above-mentioned major coal seams has been calculated from well logs of nine CBM wells distributing over an area of 7.5 km2, adjacent to the underground mines. The cleat orientations are congruous with the regional lineament pattern and fits well with the average permeability contour map of the study area to infer the orientation of in-situ maximum horizontal stress. Goodness of fit for the exponential regressions between vertical stress and permeability for individual coal seams varies between 0.6 and 0.84. The cleat orientation is further validated from the previous fracture analysis using FMI well log in Parbatpur area located southern part of the Jharia coalfield. The major coal seams under the study area exhibit directional permeability, with the maximum permeability, oriented parallel to the direction of face cleat orientation.  相似文献   

20.
This article examines the social and material politics of coal, focusing on mobilizations against opencast mining in the United Kingdom and Indonesia. Contested spaces and practices elicited by coal extraction provide important openings through which to understand how ‘hydrocarbon modernity’ is experienced and entangled with different processes of neoliberal capitalism. We investigate resistance against coal at Ffos-y-Fran in South Wales and the IndoMet project in the Indonesian province of Central Kalimantan, exploring how assemblages of protest have challenged the material effects, discursive practices and regimes of accumulation attendant within the coal industry. In both countries, campaigns seeking to ‘end coal’ have built dynamic geographical alliances, and as collective challenges to mining activities have unfolded, we consider how movements targeting specific sites of extraction have sought to disrupt the industry’s 'dis-embedding' of coal from the landscape. Drawing on accounts of how hydrocarbon politics shape societies, the approach we present draws attention to changing linkages between economic, environmental and social advocacy while illuminating the varied ways in which coal mining can compound and perpetuate inequality.  相似文献   

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