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1.
Bulk compositions of igneous and microbreccia lithic fragments, glasses, and chondrules from Luna 16 fines as well as compositions of minerals in basaltic lithic fragments were determined with the electron microprobe. Igneous lithic fragments and glasses are divided into two groups, the anorthositic-noritic-troctolitic (hereafter referred to as ANT) and basaltic groups. Chondrules are always of ANT composition and microbreccia lithic fragments are divided into groups 1 and 2. The conclusions reached may be summarized as follows: (1) Luna 16 fines are more similar in composition to Apollo 11 than to Apollo 12 and 14 materials (e.g. Apollo 11 igneous lithic fragments and glasses fall into similar ANT and basaltic groups; abundant norites in Luna 16 and Apollo 11 are not KREEP as in Apollo 12 and 14; Luna 16 basaltic lithic fragments may represent high-K and low-K suites as is the case for Apollo 11; rare colorless to greenish, FeO-rich and TiO2-poor glasses were found in both Apollo 11 and Luna 16; Luna 16 spinels are similar to Apollo 11 spinels but unlike those from Apollo 12). (2) No difference was noted in the composition of lithic fragments, glasses and chondrules from Luna 16 core tube layers A and D. (3) Microbreccia lithic fragments of group 1 originated locally by mixing of high proportions of basaltic with small proportions of ANT materials. (4) Glasses are the compositional analogs to the lithic fragments and not to the microbreccias; most glasses were produced directly from igneous rocks. (5) Glasses show partial loss of Na and K due to vaporization in the vitrification process. (6) Luna 16 chondrules have ANT but not basaltic composition. It is suggested that either liquid droplets of ANT composition are more apt to nucleate from the supercooled state; or basaltic droplets have largely been formed in small and ANT droplets in large impact events (in the latter case, probability for homogeneous and inhomogeneous nucleation is larger. (7) No evidence for ferric iron and water-bearing minerals was found. (8) Occurrence of a great variety of igneous rocks in Luna 16 samples (anorthosite, noritic anorthosite, anorthositic norite, olivine norite, troctolite, and basalt) confirm our earlier conclusion that large-scale melting or partial melting to considerable depth and extensive igneous differentiation must have occurred on the moon.  相似文献   

2.
Abundances and isotopic compositions of all the stable noble gases have been measured in 19 different depths of the Apollo 15 deep drill core, 7 different depths of the Apollo 16 deep drill core, and in several surface fines and breccias. All samples analyzed from both drill cores contain large concentrations of solar wind implanted gases, which demonstrates that even the deepest layers of both cores have experienced a lunar surface history. For the Apollo 15 core samples, trapped4He concentrations are constant to within a factor of two; elemental ratios show even greater similarities with mean values of4He/22Ne= 683±44,22Ne/36Ar= 0.439±0.057,36Ar/84Kr= 1.60±0.11·103, and84Kr/132Xe= 5.92±0.74. Apollo 16 core samples show distinctly lower4He contents,4He/22Ne(567±74), and22Ne/36Ar(0.229±0.024), but their heavy-element ratios are essentially identical to Apollo 15 core samples. Apollo 16 surface fines also show lower values of4He/22Ne and22Ne/36Ar. This phenomenon is attributed to greater fractionation during gas loss because of the higher plagioclase contents of Apollo 16 fines. Of these four elemental ratios as measured in both cores, only the22Ne/36Ar for the Apollo 15 core shows an apparent depth dependance. No unambiguous evidence was seen in these core materials of appreciable variations in the composition of the solar wind. Calculated concentrations of cosmic ray-produced21Ne,80Kr, and126Xe for the Apollo 15 core showed nearly flat (within a factor of two) depth profiles, but with smaller random concentration variations over depths of a few cm. These data are not consistent with a short-term core accretion model from non-irradiated regolith. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. The lack of large variations in solar wind gas contents across core layers is also consistent with appreciable pre-accretion irradiation. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmogenic gases below ～65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper ～70 cm of the core. Cosmogenic gas concentrations of several Apollo 16 fines and breccias are consistent with ages of North Ray Crater and South Ray Crater of ～50·106 and ～2·106 yr, respectively.  相似文献   

3.
A technique employing the resonant nuclear reaction 1H(19F, αγ) 16O has been used to measure hydrogen concentration versus depth in selected coarse fine fragments from the Apollo 11 and Apollo 15 missions, and in glass coated surface chips from two Apollo 15 rocks. The highly variable hydrogen content in the coarse fine fragments is concentrated mainly in a layer extending from the surface to a depth of 2000 ± 500A?. The hydrogen content of the surface region of the Apollo 15 rock chips is comparable to that of the coarse fine samples, but is concentrated mainly within a few hundred angstroms of the surface. The hydrogen depth distribution in a piece of platinum foil from the Apollo 16 Lunar surface Cosmic Ray Experiment was also measured in an attempt to place a limit on the flux of 10–40 keV protons associated with a solar flare event.  相似文献   

4.
Evidence from Apollo 11 and Apollo 12 lunar samples indicates that particle radiation is not important for the production of grains in the lunar soil greater than 22 microns in size even though sufficiently prolonged irradiations by protons, heavy ions and electrons fracture minerals and glasses like those found on the lunar surface.  相似文献   

5.
Plagioclase ultraphyric basalts in Iceland: the mush of the rift   总被引：1，自引：0，他引：1  
Glassy, plagioclase ultraphyric basalts from six locations in Iceland have bimodal phenocryst size distributions where microphenocrysts (ol+plg±cpx±mt) are in equilibrium with the matrix glass, but macrophenocrysts (ol+plg±cpx) are too primitive to be so. Matrix glass compositions are similar to those of other rift zone glasses from Iceland, and oxygen isotope variations suggest they interacted with the Icelandic crust. A lack of negative Eu-anomalies in matrix glasses precludes large amounts of plagioclase crystallisation from their parental liquids. Compositions of glass inclusions in plagioclase and olivine macrophenocrysts indicate that parental magma compositions of the macrophenocryst assemblage are similar to those of primitive, Icelandic rift zone glasses. Temperatures for plagioclase macrophenocryst crystallisation obtained from Linkam® heating stage experiments, and from glass inclusion compositions corrected for post-entrapment crystallisation, give temperatures up to 1260°C, corresponding to crystallisation at middle to deep crustal levels. Temperature differences of less than 100°C between plagioclase-hosted glass inclusions before and after post-entrapment plagioclase crystallisation show that the macrophenocrysts must have been kept at elevated temperatures prior to incorporation in their present host magmas. We suggest that the macrophenocrysts of the plagioclase ultraphyric basalts accumulated in crystal mush bodies underneath the rift zone and were picked up by their present hosts during a rifting event with increased magma supply from the mantle.  相似文献   

6.
Data on the variation of temperature with time and in space are essential to a complete understanding of the crystallization history of basaltic magma in Kilauea Iki lava lake. Methods used to determine temperatures in the lake have included direct, downhole thermocouple measurements and Fe-Ti oxide geothermometry. In addition, the temperature variations of MgO and CaO contents of glasses, as determined in melting experiments on appropriate Kilauean samples, have been calibrated for use as purely empirical geothermometers and are directly applicable to interstitial glasses in olivine-bearing core from Kilauea Iki. The uncertainty in inferred quenching temperatures is ±8–10° C. Comparison of the three methods shows that (1) oxide and glass geothermometry give results that are consistent with each other and consistent with the petrography and relative position of samples, (2) downhole thermo-couple measurements are low in all but the earliest, shallowest holes because the deeper holes never completely recover to predrilling temperatures, (3) glass geothermometry provides the greatest detail on temperature profiles in the partially molten zone, much of which is otherwise inaccessible, and (4) all three methods are necessary to construct a complete temperature profile for any given drill hole. Application of glass-based geothermometry to partially molten drill core recovered in 1975–1981 reveals in great detail the variation of temperature, in both time and space, within the partially molten zone of Kilauea Iki lava lake. The geothermometers developed here are also potentially applicable to glassy samples from other Kilauea lava lakes and to rapidly quenched lava samples from eruptions of Kilauea and Mauna Loa.  相似文献   

7.
Polymict samples can be used to establish mass-balance constraints regarding the bulk composition of the lunar crust, and to gauge the degree of regional heterogeneity in the composition of the lunar crust. The most ideally polymict type of sample is finely-mixed regolith (lunar soil), or its lithified equivalent, regolith breccia. Fortunately, lunar regolith breccias can occasionally be found at great distances from their points of origin — most of the known lunar meteorites are regolith breccias. We are searching for examples of exotic regolith samples among the Apollo regolith breccia collection. Most of the 21 Apollo regolith breccias analyzed for this study strongly resemble the local soils over which they were collected. Nine regolith breccias from Apollo 16 are surprisingly mature compared to previously-analyzed Apollo 16 regolith breccias, and six of the seven from Apollo 16 Station 5 have lower, more local-soil-like,mg ratios than previously analyzed regolith breccias from this station. Several of the Apollo 14 regolith breccias investigated show significantly highermg, and lower Al, than the local soils.The most interesting sample we have investigated is 14076,1, from a lithology that constitutes roughly half of a 2.0-g pebble. The presence of spherules indicates a regolith derivation for 14076,1, yet its highly aluminous (30 wt.% Al2O3) composition is clearly exotic to the 1.6-km traverse surface over which the Apollo 14 samples were collected. This sample resembles soils from the Descartes (Apollo 16) highlands far more than it does any other polymict sample from the Fra Mauro (Apollo 14) region. The I/sFeO maturity index is extremely low, but this may be a result of thermal annealing. A variety of siderophile elements occur in 14076,1 at typical regolith concentrations. The chemistry of the second most aluminous regolith sample from Apollo 14, 14315, can only be roughly approximated as a mixture of local regolith and 14076,1-like material. However, the low a priori statistical probability for long-distance horizontal transport by impact cratering, along with the relatively high contents of incompatible elements in 14076,1 (despite its high Al content), suggest that this regolith breccia probably originated within a few hundred kilometers of the Appollo 14 site. If so, its compositional resemblance to ferroan anorthosite tends to suggest that the regional crust is, or originally was, far richer in ferroan anorthosite than implied by the meager statistics for pristine rocks from this site. Thus, 14076,1 tends to strengthen the hypothesis that ferroan anorthosite originated as the flotation crust of a global magmasphere.  相似文献   

8.
The major element compositions of 93 low specific gravity (<2.60), high-silica (>60%) glass particles, from a sample of lunar fines (14259,20) were determined by electron microprobe analyses. The size, shape, abundance, mineralogy and major element composition of most (>60%) of the high-silica glasses is consistent with their being fragments of interstitial glass from mare basalts. However, one group of 30 glasses with between 72% and 78% SiO2 and an average of ～2.6% FeO can be distinguished from other high-silica glasses both chemically and petrographically. Glass particles with this composition do not contain crystalline inclusions and are fairly homogeneous not only within a single particle, but also from particle to particle. The chemistry and petrology of these glasses suggest that they are not fragments of interstitial glass or shock-melted particles from a “granitic” source rock. Rather, the homogeneity and lack of crystalline inclusions suggest that this group of high-silica glasses was the product of lunar acidic volcanism.  相似文献   

9.
Irregularly shaped, large and clear (LAC) glass inclusions are present in plagioclase phenocrysts in several andesitic lavas erupted from Tolimán volcano, Guatemala. Their morphology is different from densely spaced, fine-grained glass inclusions that form concentric zones in dusty or cellular textured plagioclase phenocrysts. The large size of LAC inclusions make them suitable for microprobe analysis and average bulk compositions are presented for glasses in 30 phenocrysts from eight lava samples. Their compositions are rhyolitic and in disequilibrium, or out-range (Anderson 1976) with respect to whole-rock and groundmass glass compositions. LAC inclusions typically occur in large, tabular plagioclase phenocrysts with relatively uniform, sodic compositions (An 40–54). Compositions of feldspar phenocrysts not containing LAC inclusions range from An 41 to An 81. Petrographic and chemical data support a primary origin for LAC glasses, suggest mixing of mafic and silicic magmas, and also constrain a mechanism for magma mixing. Rapid growth of plagioclase and entrapment of LAC glass occurs during mixing in a vapor-rich silicic liquid under low degrees of undercooling. These conditions are possibly produced in a high-level magma body such as that envisioned by Huppert et al. (1982), where replenishment and subsequent crystallization of a hydrous magma induces density instability and mixing with the resident magma.  相似文献   

10.
The Luna 16 regolith sample differs from Apollo 11, 12 and 14 regolith and basalt samples by having smaller negative Eu and Sr anomalies and nearly chondritic Eu/Sm and Eu/Sr ratios although the overall REE, Ba, Sr and U concentrations are 25 to 45 times chondrites. Major element data, in particular FeO vs. Al2O3, show that the Luna 16 regolith sample is composed of materials that follow a quantitatively different Fe/Al variation than do Apollo 11, 12, 14 and 15 samples. The small Eu and Sr anomalies and the displaced Fe/Al variation are two chemical features unique to the Luna 16 regolith sample. The Luna 16 regolith sample can contain little if any of the rock types abundant at Apollo sites, thus indicating that the unique chemical features are typical of local or nearby materials and indicate a separate petrogenetic province for major component rock types of the Luna 16 regolith.  相似文献   

11.
Luna 16 sample B-1 was the largest fragment (62 mg) obtained in the sample exchange with the USSR. Petrologic, mineralogic, and chemical investigations have been made on this fragment in conjunction with Rb-Sr and40Ar/39Ar investigations by our colleagues. Sample B-1 is a fine-grained ophitic basalt but is distinguished from the Apollo samples by containing a single pyroxene, predominantly pigeonitic, an ilmenite content (7%) intermediate to that of the Apollo 11 and 12 samples, and subequal amounts of pyroxene (50%) and plagioclase (40%). Chemically it is distinguished by a high Sr content (437 ppm) and a high K/U value (4700). The K-content (1396 ppm) is higher than that of Luna 16 soil sample A-2.  相似文献   

12.
Variations in major-element chemistry and modal compositions of the mantle xenolith-bearing calc-alkalic ejecta from Ichinomegata volcano are inferred to be due to mixing of three magmatic end members: Basalt I (SiO2 51 wt% , MgO 8.5 wt%), Basalt II (SiO2 54 wt%, MgO 5 wt%), and Dacite (SiO2 65 wt%, MgO2 wt%). Ultramafic xenoliths are found in mafic mixtures of Dacite-Basalt I and Dacite-Basalt II. The thermal histories of the xenoliths in both mixtures are compared with each other. Chemical compositions of olivine and orthopyroxene in xenoliths suggest that xenoliths in Basalt I were equilibrated at about 800 °C, while those in Basalt II were also equilibrated originally at about 800 °C but were subsequently annealed at about 1000 °C for more than 102–3 years prior to the eruption.The chemical composition of Basalt I indicates that it can coexist with upper mantle peridotite and it is an appropriate candidate for a carrier of ultramafic xenoliths from the upper mantle. On the other hand, Basalt II is fractionated and it cannot be directly derived from the upper mantle. Two pulses of xenolith-bearing basalt injection into a dacite magma chamber are inferred to have occurred. The first injection did not lead to eruption and subsequently formed a dacite/basalt stratified magma chamber. In the lower layer, the basalt was slightly differentiated to become Basalt II and ultramafic xenoliths carried by the first pulse were annealed at the bottom of the layer. The duration of the annealing of the xenoliths implies a minimum life-time of the Dacite-Basalt II stratification in the magma chamber beneath Ichinomegata of 102–3 years. The second injection of the xenolith-bearing basalt (Basalt I) was immediately followed by eruption, and all the magmas were effused with mixing in a conduit. Consequently, the ultramafic xenoliths carried by the second pulse are not annealed.  相似文献   

13.
The Amealco Tuff is a widespread (>2880 km2), trachyandesitic to rhyolitic pyroclastic deposit in the central Mexican Volcanic Belt that was erupted from the Amealco caldera at 4.7ǂ.1 Ma. It includes three major ignimbrites, each showing complex mingling of pumice fragments and matrix glass with andesitic to rhyolitic compositions. The different glasses are well mingled throughout each of the pyroclastic-flow deposits. Mingling of glasses may have occurred just before and during the explosive eruptions that produced the pyroclastic flows, as the distinct melts had insufficient time to homogenize. Mingling of glasses is evident in each of the three separate major ignimbrites of the Amealco Tuff; thus, the processes that caused it were repetitive. It is infered that the repetitive mingling of melts was due to repeated mafic magma inputs to an evolved magma chamber.  相似文献   

14.
 Glass fragments from three different hyaloclastites have been used to evaluate the range of cooling rates experienced by undersea volcanic deposits. We found that the glass fragments retain structures with a range of apparent quench rates from 25 to 0.15 K min–1. The most rapid cooling rates are interpreted to be those resulting from cooling of the lava near the water interface. Simple conductive cooling models produce a range of quench rates comparable to those of the more rapidly cooled samples. The very slow apparent quench rates are unlikely to result from simple linear cooling through the glass transition, because of the onset of crystallization; instead, they are indicators of a more complex thermal history that involves the annealing of glasses at temperatures within the glass transition interval for a dwell time sufficient to allow the relaxation of the glass to lower temperature structures. The thermal history recorded in these samples illustrates the complexity of eruptive processes and demonstrates that quench rates for natural glasses retain information relevant to more complex cooling models. Received: 10 February 1999 / Accepted: 9 September 1999  相似文献   

15.
Track densities in feldspar crystals from L16A14 and L16G14 (6–8 cm and 29-21 cm) range from 2.5 × 108/cm2 to > 2 × 109/cm2. No significant difference is found between the two positions. The track densities are similar to those observed in heavily irradiated samples of Apollo 11, 12 and 14 and indicate that these two positions are composed of well mixed materials from a number of sources. This is in contrast to a number of fines samples from Apollo 12 and 14 which are less irradiated and represent relatively recent additions to the lunar surface.  相似文献   

16.
The lunar crust at the Apollo 16 landing site contains substantial amounts of a “primitive component” in which the ferromagnesian group of elements is concentrated. The composition of this component can be retrieved via an analysis of mixing relationships displayed by lunar breccias. It is found to be a komatiite which is compositionally similar to terrestrial komatiites both in major and minor elements. The komatiite component of the lunar crust is believed to have formed by extensive degrees of melting of the lunar interior at depths greater than were involved in the formation of the lunar magma ocean which was parental to the crust. After formation of the anorthositic crust, it was invaded by extensive flows and intrusions of komatiite magma from these deeper source regions. The komatiites became intimately mixed with the anorthosite by intensive meteoroid impacts about 4.5 b.y. ago, thereby accounting for the observed mixing relationships displayed by the crust. The compositional similarity between lunar and terrestrial komatiites strongly implies a corresponding similarity between the compositions of their source regions in the lunar interior and the Earth's upper mantle. The composition of the lunar interior can be modelled more specifically by combining the komatiite composition with its liquidus olivine composition (as determined experimentally) in proportions chosen so as to produce a cosmochemically acceptable range of Mg/Si ratios for the bulk Moon. Except for higher FeO and lower Na2O, the range of compositions thereby obtained for the bulk moon is very similar to the composition of the Earth's upper mantle.The effects of meteoritic contamination on the abundances of cobalt and nickel in lunar highland breccias were subtracted on the assumption that the contaminating projectiles were chondritic. The cobalt and nickel residuals thereby obtained were found to correlate strongly with the (Mg + Fe) content of the breccias, demonstrating that the Co and Ni are associated with the ferromagnesian component of the breccias and are genuinely indigenous to the Moon. The lunar highland Co and Ni residuals also display striking Ni/Co versus Ni correlations which follow a similar trend to those displayed by terrestrial basalts, picrites and komatiites. The lunar trends provide further decisive evidence of the indigenous nature of the Co and Ni residuals and suggest the operation of extensive fractionation controlled by olivine-liquid equilibria in producing the primitive component of the lunar breccias. Indigenous nickel abundances at the Apollo 14, 15 and 17 sites are much lower than at the Apollo 16 site, although rocks from all sites follow the same Ni/Co versus Ni trends. It is suggested that the primitive component at the Apollo 14, 15 and 17 sites was generally of basaltic composition, in contrast to the komatiitic nature of the Apollo 16 primitive component.  相似文献   

17.
Two Luna 16 soils have been analyzed for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, Ge, In, Ur, Ni, Rb, Re, Sb, Se, Te, Tl, and Zn. A meteoritic component similar to that in Apollo 11 and 12 soils seems to be present, corresponding to ∼1.5 to 2% Cl chondrites or equivalent. It probably consists largely of micrometeorites. Three elements show strong enrichments compared to Apollo 11 and 12 soils: Cd (5× to 200×), Ag (5× to 10×), and Bi (3×). Presumably these elements were brought in by Cd-Ag-Bi rich material, similar to that in Unit VI of Apollo core 12028.  相似文献   

18.
The magnetic susceptibility of 11 glass spherules from the Apollo 15, 16, and 17 fines and two specimens of a relatively large glass spherical shell were studied as a function of temperature from room temperature to liquid helium temperatures. All but one specimen showed the presence of antiferromagnetic inclusions. Closely spaced temperature measurements of the magnetic susceptibility below 77 K on five of the specimens showed antiferromagnetic temperature transitions (Néel transitions). With the exception of ilmenite in one specimen, these transitions did not correspond to any transitions in known antiferromagnetic compounds.  相似文献   

19.
The Gd and Sm isotopic compositions have been measured in the Luna 16, G-2 soil. This sample has the largest low energy neutron fluence ψ = 5.9 × 1016n/cm2 (E < 0.18eV) yet observed in a lunar sample. The ratio of the number of neutrons captured per atom by149Sm to157Gd is 0.76 which is distinct from the value of 0.86 observed at the Apollo 11, 12 and 14 sites. This indicates a softer neutron energy spectrum at the Sea of Plenty.  相似文献   

20.
Volcanic glass shards from tephra layers in the Byrd Station ice core were chemically analyzed by electron microprobe. Tephra in seven layers have similar peralkaline trachyte compositions. The tephra are believed to originate from Mt. Takahe, on the basis of their chemical similarity to analyzed rocks from Mt. Takahe and because dated rock samples from the volcano are younger than 250,000 years old. Glass shards from 726 m deep in the Dome C ice core, which is 2400 km from Byrd Station, are composed of peralkaline trachyte and may have also been derived from Mt. Takahe. The tephra could have resulted from eruptions which were triggered by increased ice loading during the late Wisconsin glaciation. Preliminary grain size data suggest the eruptions were only minor and they were unlikely to have instantaneously altered global climate as have explosive eruptions in the tropics. Nevertheless, the effect of this localized volcanic activity upon the Antarctic energy budget warrants further investigation.  相似文献   

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