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1.
Phase curves for the CO2 bands at 7883, 7820, and 8689 Å are presented. While the weaker bands at 7820 and 7883 Å show a definite “inverse phase effect,” the band at 8689 Å shows a more normal phase curve; it also exhibited much larger day-to-day variations in the CO2 abundance near superior conjunction in 1971. Because the variation of the phase curves with band strength is comparable to temporal variations on Venus, simultaneous observations of strong and weak bands are still needed to determine the dependence on band strength accurately. 相似文献
2.
Edwin S. Barker 《Icarus》1975,25(2):268-281
The Venus water vapor line at 8197.71 Å has been monitored at several positions on the disk of Venus and at phase angles between 21° and 162°. Variations in the abundance have been found with spatial location, phase angle and time. During the 1972–1974 period, the total two-way absorption has varied from less than 1 to 77 μm of water vapor. The dependence on phase angle indicates 20 to 50 μm over the disk between 30° and 110° and small, but detectable amounts present during the rest of the observations. The spatial distribution with respect to the intensity equator is uniform with no location on the disk having systematically a higher or lower abundance. Comparisons made between the water vapor abundandances and the CO2 abundances determined from near-simultaneous observations of CO2 bands at the same positions on the disk of Venus show no correlation for the majority of the samples. 相似文献
3.
Forty-seven well exposed photographic plates of Venus which show the spectrum of the carbon dioxide band at 7820Å were obtained at Table Mountain Observatory in September and October 1972. These spectra showed a semiregular four-day variation in the CO2 abundance over the disk of the planet (Young et al., 1974). We also find evidence for temporal variations in the rotational temperature of this band and temperature variations over the disk. The two quantities, CO2 abundance and temperature, do not show any obvious relationship; however, an increase in the temperature usually is accompanied by a decrease in the abundance of CO2. The average temperature, found from a curve-of-growth analysis assuming a constant CO2 line width, is 249±1.4K (one standard deviation). This temperature is noticeably higher than the rotational temperature of 242±2K found for this same band in 1967 (Schorn et al., 1969) and of 242±1.2K in 1968–1969 (Young et al., 1971). 相似文献
4.
The abundances of molecular oxygen in the atmospheres of Venus and Mars are sensitive to fundamental photochemical processes. A new upper limit is reported for the molecular oxygen mixing ratio (O2/CO2 < × 10?7) in the integrated column above the visible cloud tops of Venus, based on spectroscopic observations carried out in early spring, 1982. During the same observing period, an O2 column abundance of 8.5 cm-am for the atmosphere of Mars was measured, slightly below the O2 abundances measured a decade earlier. 相似文献
5.
We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO2 band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO2 band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H2O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO2 phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.). 相似文献
6.
An observational program to study variations of the vertical distribution of CO in the Venus atmosphere is presented. Measurements of the J = 0 → 1 absorption line at 2.6 mm wavelength are reported for two phase angles in 1977, one near eastern elongation (Feb.) and the other near inferior conjunction (Apr.). The two spectra are significantly different, with the April absorption line being narrower and deeper. The results of numerical inversion calculations show that the CO mixing ratio increases a factor of ～ 100 between 78 and 100 km and that the CO abundance above ～ 100 km is greatest on the night-side hemisphere. These conclusions are in qualitative agreement with theoretical models. In addition to the CO observations, a search for other molecules was made to provide further information on the composition of the Venus middle atmosphere. The J = 0 → 1 transition of 13CO was detected and upper limits were derived for nine other molecules. 相似文献
7.
Submillimeter line observations of CO in the Venus middle atmosphere (mesosphere) were observed with the James Clerk Maxwell Telescope (JCMT, Mauna Kea) about the May 2000, February 2002 superior and July 1999, March 2001 inferior conjunctions of Venus. Combined 12CO and 13CO isotope spectral line measurements at 345 and 330 gHz frequencies, respectively, provided enhanced sensitivity and vertical coverage for simultaneous retrievals of atmospheric temperatures and CO mixing ratios over the altitude region 75-105 km with vertical resolution 4-5 km. Supporting millimeter 12CO spectral line observations with the Kitt Peak 12-m telescope (Steward Observatories) provide enhanced temporal coverage and CO mixing sensitivity. Implementation of CO/temperature profile retrievals for the 2000, 2002 dayside (superior conjunction) and 1999, 2001 nightside (inferior conjunction) periods yields a first-time definition of the vertical structure and diurnal variation of a low-to-mid-latitude mesopause within the Venus atmosphere. At the times of these 1999-2002 observations, the Venus mesopause was located at a slightly lower level in the nightside (0.5 mbar, ∼87 km) versus the dayside (0.2 mbar, ∼91 km) atmosphere. Average diurnal variation of Venus mesospheric temperatures appears to be ≤ 5 K at and below the mesopause. Diurnal variation of Venus thermospheric temperatures increases abruptly just above the mesopause, reaching 50 K by the 0.01-mbar pressure level (∼102 km). Atmospheric temperatures above and below the Venus mesopause exhibited global-scale (≥4000 km horizontal) variations of large amplitude (7-15 K) on surprisingly short timescales (daily to monthly) during the 2001 nightside and 2002 dayside observing periods. Venus dayside mesospheric temperatures observed during the 2002 superior conjunction were also 10-15 K warmer than observed during the 2000 superior conjunction. A characteristic timescale for these global temperature variations is not defined, but their magnitude is comparable to previous determinations of secular variability in nightside mesospheric temperatures (Clancy and Muhleman, 1991). 相似文献
8.
Vladimir A. Krasnopolsky 《Icarus》2008,197(2):377-385
Venus was observed at 2.4 and 3.7 μm with a resolving power of 4×104 using the long-slit high-resolution spectrograph CSHELL at NASA IRTF. The observations were made along a chord that covered a latitude range of ± 60° at a local time near 8:00. The continuous reflectivity and limb brightening at 2.4 μm are fitted by the clouds with a single scattering albedo 1−a=0.01 and a pure absorbing layer with τ=0.09 above the clouds. The value of 1−a agrees with the refractive index of H2SO4 (85%) and the particle radius of 1 μm. The absorbing layer is similar to that observed by the UV spectrometer at the Pioneer Venus orbiter. However, its nature is puzzling. CO2 was measured using its R32 and R34 lines. The retrieved product of the CO2 abundance and airmass is constant at 1.9 km-atm along the instrument slit in the latitude range of ± 60°. The CO mixing ratio (measured using the P21 line) is rather constant at 70 ppm, and its variations of ∼10% may be caused by atmospheric dynamics. The observed value is higher than the 50 ppm retrieved previously from a spectrum of the full disk, possibly, because of some downward extension of the mesospheric morningside bulge of CO. The observations of the HF R3 line reveal a constant HF mixing ratio of 3.5±0.5 ppb within ± 60° of latitude, which is within the scatter in the previous measurements of HF. OCS has been detected for the first time at the cloud tops by summing 17 lines of the P-branch. The previous detections of OCS refer to the lower atmosphere at 30-35 km. The retrieved OCS mixing ratio varies with a scale height of 1 to 3 km. The mean OCS mixing ratio is ∼2 ppb at 70 km and ∼14 ppb at 64 km. Vertical motions in the atmosphere may change the OCS abundance. The detected OCS should significantly affect Venus' photochemistry. A sensitive search for H2S using its line at 2688.93 cm−1 results in a 3 sigma upper limit of 23 ppb, which is more restrictive than the previous limit of 100 ppb. 相似文献
9.
We present the first detections of the ground-state H216O (110-101) rotational transition (at 556.9 GHz) and the 13CO (5-4) rotational transition from the atmosphere of Venus, measured with the Submillimeter Wave Astronomy Satellite (SWAS). The observed spectral features of these submillimeter transitions originate primarily from the 70-100 km altitude range, within the Venus mesosphere. Observations were obtained in December 2002, and January, March, and July 2004, coarsely sampling one Venus diurnal period as seen from Earth. The measured water vapor absorption line depth shows large variability among the four observing periods, with strong detections of the line in December 2002 and July 2004, and no detections in January and March 2004. Retrieval of atmospheric parameters was performed using a multi-transition inversion algorithm, combining simultaneous retrievals of temperature, carbon monoxide, and water profiles under imposed constraints. Analysis of the SWAS spectra resulted in measurements or upper limits for the globally averaged mesospheric water vapor abundance for each of the four observation periods, finding variability over at least two orders of magnitude. The results are consistent with both temporal and diurnal variability, but with short-term fluctuations clearly dominating. These results are fully consistent with the long-term study of mesospheric water vapor from millimeter and submillimeter observations of HDO [Sandor, B.J., Clancy, R.T., 2005. Icarus 177, 129-143]. The December 2002 observations detected very rapid change in the mesospheric water abundance. Over five days, a deep water absorption feature consistent with a water vapor abundance of 4.5±1.5 parts per million suddenly gave way to a significantly shallower absorption, implying a decrease in the water vapor abundance by a factor of nearly 50 in less that 48 h. In 2004, similar changes in the water vapor abundance were measured between the March and July SWAS observing periods, but variability on time scales of less than a week was not detected. The mesospheric water vapor is expected to be in equilibrium with aerosol particles, primarily composed of concentrated sulfuric acid, in the upper haze layers of the Venus atmosphere. If true, moderate amplitude (10-15 K) variability in mesospheric temperature, previously noted in millimeter spectroscopy observations of Venus, can explain the rapid water vapor variability detected by SWAS. 相似文献
10.
To investigate further the Venus inverse phase effect, 12 plates of the 8689 Å CO2 band, taken in 1971, were analyzed for abundances and temperatures using the curve-of-growth method. We found an average rotational temperature of 230 ± 1°K for an average slope of the curve of growth of 0.56 ± 0.03. Day-to-day variations in the equivalent widths of the CO2 lines can be as large as 25%, and long-term changes in the cloud-top temperature are confirmed. On the other hand, the widely accepted “inverse” phase effect of CO2 line equivalent widths near superior conjunction receives no firm support from these results. 相似文献
11.
The equilibrium suggested as a buffer for CO2 in the Venus atmosphere, CaCO3 + SiO2 = CaSiO3 + CO2, cannot act as a buffer at the Venus surface/troposphere – the pressure–temperature slope of the equilibrium and that of the atmosphere (dry adiabat with significant greenhouse heating) do not provide buffering capacity (if indeed CaCO3 were present). Instead, perturbations to T or P(CO2) can produce catastrophic expansion or collapse of the atmosphere. This instability can be generalized to all devolatilization reactions that produce a radiatively active gas in a planetary atmosphere dominated by such gases, and gives a simple thermochemical criterion for whether a reaction could buffer such an atmosphere. Simple decarbonation reactions fail this criterion, suggesting that the abundance of CO2 in a CO2-dominated atmosphere cannot be buffered by chemical reactions with the surface; a similar conclusion holds for the abundance of H2O in an H2O-dominated (steam) atmosphere. Buffering of minor gases is more likely; a mineral buffer equilibrium for SO2 proposed for Venus, FeS2 + CO2 = Fe3O4 + SO2 + CO, passes the thermochemical criterion, as does a reaction involving Ca sulfate. These inferences can be generalized to atmospheres in ‘moist’ adiabatic equilibria, and to extrasolar Venus-like planets, and will help in interpreting the compositions of their atmospheres. 相似文献
12.
Vladimir A. Krasnopolsky 《Icarus》2006,182(1):80-91
High-resolution spectra of Venus and Mars at the NO fundamental band at 5.3 μm with resolving power ν/δν=76,000 were acquired using the TEXES spectrograph at NASA IRTF on Mauna Kea, Hawaii. The observed spectrum of Venus covered three NO lines of the P-branch. One of the lines is strongly contaminated, and the other two lines reveal NO in the lower atmosphere at a detection level of 9 sigma. A simple photochemical model for NO and N at 50-112 km was coupled with a radiative transfer code to simulate the observed equivalent widths of the NO and some CO2 lines. The derived NO mixing ratio is 5.5±1.5 ppb below 60 km and its flux is . Predissociation of NO at the (0-0) 191 nm and (1-0) 183 nm bands of the δ-system and the reaction with N are the only important loss processes for NO in the lower atmosphere of Venus. The photochemical impact of the measured NO abundance is significant and should be taken into account in photochemical modeling of the Venus atmosphere. Lightning is the only known source of NO in the lower atmosphere of Venus, and the detection of NO is a convincing and independent proof of lightning on Venus. The required flux of NO is corrected for the production of NO and N by the cosmic ray ionization and corresponds to the lightning energy deposition of . For a flash energy on Venus similar to that on the Earth (∼109 J), the global flashing rate is ∼90 s−1 and ∼6 km−2 y−1 which is in reasonable agreement with the existing optical observations. The observed spectrum of Mars covered three NO lines of the R-branch. Two of these lines are contaminated by CO2 lines, and the line at 1900.076 cm−1 is clean and shows some excess over the continuum. Some photochemical reactions may result in a significant excitation of NO (v=1) in the lowest 20 km on Mars. However, quenching of NO (v=1) by CO2 is very effective below 40 km. Excitation of NO (v=1) in the collisions with atomic oxygen is weak because of the low temperature in the martian atmosphere, and we do not see any explanation of a possible emission of NO at 5.3 μm. Therefore the data are treated as the lack of absorption with a 2 sigma upper limit of 1.7 ppb to the NO abundance in the lower atmosphere of Mars. This limit is above the predictions of photochemical models by a factor of 3. 相似文献
13.
We review two models describing the Venus climate system: the carbonate and pyrite models. It has been argued carbonate and pyrite are potentially important minerals controlling the climate of Venus, though existence of either minerals has not been confirmed. Although it used to be proposed that carbonation reaction might explain the Venus’ atmospheric CO2 abundance, it is unlikely Venus’ surface is reactive enough to control the Venus’ massive CO2 atmosphere. Venus’ surface carbonate is also able to affect the climate through the reaction with atmospheric SO2 to form anhydrite. Under the carbonate model the climate state is not in equilibrium and would be unstable due to the reaction between carbonate and SO2. On the other hand, pyrite-magnetite reaction is proposed to explain the Venus’ atmospheric SO2 abundance. Under pyrite-magnetite reaction, however, the climate would be stabilized such that the existing climate state is maintained over a geological timescale, while some observational facts such as atmospheric abundance of SO2 and surface temperature could also be reasonably explained. 相似文献
14.
We present equivalent widths of Venus CO2 scans of the P branch (P8–P32) of the 5ν3 band at 8689 Å, the P16 line of the 5ν3 band, and the P14 line of the ν1 + 5ν3 band at 7820 Å covering phase angles between 5°.1 and 170°. The equivalent widths reach a minimum at 10°, in agreement with a phase function with a backward lobe at 160° which is caused by a single internal reflection within the cloud particles. This is evidence that Venus cloud particles are composed of liquid droplets. Maximum equivalent widths are observed at ～60°, a value which is closer to the maximum of single-layer Mie scattering models than to that of two-layer models. At high phase angles we observe equivalent widths greater than those computed from homogeneous scattering models, indicating that at high altitudes the mixing ratio of scattering particles to CO2 increases with depth. At all phase angles, particularly at large phase angles, the temporal and spatial variations in the observed equivalent widths confuse the phase variation. 相似文献
15.
The phase function for anisotropic scattering is applied to a homogeneous atmospheric model to ascertain the effects of anisotropy on the near-infrared spectrum of Venus. L. D. G. Young's equivalent widths for the 820 Å CO2 band are analyzed to derive allowed combinations of CO2 specific abundance, continuum albedo, pressure, and degree of anisotropy. From these combinations, values are derived for the photon mean-free path and total optical thickness of the clouds. The Venera 10 measurement of the transmitted flux at 7200 Å is then used in conjunction with spherical albedo requirements to reduce the range of possible solutions to the equivalent-width analysis. Through the application of approximate similarity relations, the “true” (i.e., anisotropic) atmospheric parameters are derived from the isotropic values. For an assumed Mie scatterer with an average anisotropy factor of 〈cos θ〉 = 0.7, the results indicate a total optical thickness of about 55 with a single-scattering albedo of 0.9992 to 0.9995. 相似文献
16.
Properties of acoustic-gravity waves in the upper atmosphere of Venus are studied using a two-fluid model which includes the effects of wave-induced diffusion in a diffusively separated atmosphere. In conjunction with neutral mass spectrometer data from the Pioneer Venus orbiter, the theory should provide information on the distribution of wave sources in the Venus upper atmosphere. Observed wave structure in species density measurements should generally have periods ?30–35 min, small N2, CO, and O amplitudes, and highly variable phase shifts relative to CO2. A near resonance may exist between downward phase-propagating internal gravity and diffusion waves near the 165-km level at periods near 29 min. As a result, if very large He wave amplitudes are observed near this level, it will indicate that the wave source is below the 150- to 175-km level and that the exospheric temperature is close to 350°K. Wave energy dissipation may be an important mechanism for heating of the nightside Venus thermosphere. Large-density oscillations in stratospheric cloud layer constituents are also possible and may be detectable by the Pioneer Venus large probe neutral mass spectrometer. 相似文献
17.
During the 1973 to 1974 opportunity, we obtained thermal maps of Venus on 16 days during a span of 43 days just before inferior conjunction. The spatial resolution was about 3 arcsec. The average limb darkening differs from that given by Ingersoll and Orton (1974). Real day-to-day changes in limb darkening were found. An indication of 4-day repetition of a thermal anomaly was found on one occasion. The lifetime of this disturbance probably lies between 4 and 8 days. Solar-related anomalies appear to repeat in most of the images. A southern hemisphere, solar-related disturbance showed significant changes in both position and intensity over 30 days, and we tentatively identify its lifetime as about equal to this period. 相似文献
18.
Edwin S. Barker 《Icarus》1976,28(2):247-268
The patrol of Martian water vapor carried out with the echelle-coudé scanner at McDonald Observatory during the 1972–1974 apparition has produced 469 individual photoelectric scans of Doppler-shifted Martian H2O lines. Almost an entire Martian year was covered during the 1972–1974 period (Ls = 118?269° and 301?80°). Three types of coverage have been obtained: (1) regular—the slit placed pole to pole on the central meridian; (2) latitudinal—the slit placed parallel to the Martian equator at various latitudes; (3) diurnal—the slit placed parallel to the terminator at several times during a Martian day measured from local noon.Both the seasonal and diurnal effects seem to be controlled by the insolation and not the local topography with respect to the 6.1 mb surface. A slight negative correlation with elevation was noted which improved during the seasons of greater H2O content. The previous seasonal behavior has been confirmed and amplified. The following are the primary conclusions: (1) The planetwide abundance is low (5?15 μm of ppt H2O) during both equinoctical periods. (2) The maximum abundance of about 40 μm occurs in each hemisphere after solstice at about 40° latitude in that hemisphere. (3) The latitude of the maximum amount in the N-S distribution precedes the latitude of maximum insolation by 10–20° of latitude. (4) During the “drier” seasons (5–20 μm) near the equinoxes on Mars, the atmospheric water vapor changes by a factor of 2–3x over a diurnal cycle with the maximum near local noon. (5) The effects of the 1973 dust storm during the southern summer reduced the amount of water vapor over the southern hemisphere regions to 3–8 μm. 相似文献
19.
Eleven high-dispersion spectra of Venus, taken with blue Doppler shifts have enabled us to unmask the 7323.88 Å forbidden line of Ca ii from terrestrial absorption. We obtain an equivalent width of 7.4±0.4 mÅ for this line in integrated sunlight. Our value of W λ is smaller than previous values and much more accurate. The HSRA solar model gives a solar calcium abundance of A Ca = 6.21. 相似文献
20.
Guido Sonnabend Peter Krötz Frank Schmülling Theodor Kostiuk Jeff Goldstein Manuela Sornig Dušan Stupar Timothy Livengood Tilak Hewagama Kelly Fast Arnaud Mahieux 《Icarus》2012,217(2):856-862
We report temperatures in Venus’ upper mesosphere/lower thermosphere, deduced from reanalyzing very high resolution infrared spectroscopy of CO2 emission lines acquired in 1990 and 1991. Kinetic temperatures at ～110 km altitude (0.15 Pa) are derived from the Doppler width of fully-resolved single line profiles measured near 10.4 μm wavelength using the NASA GSFC Infrared Heterodyne Spectrometer (IRHS) at the NASA IRTF on Mauna Kea, HI, close to Venus inferior conjunction and two Venus solstices. Measured temperatures range from ～200 to 240 K with uncertainty typically less than 10 K. Temperatures retrieved from similar measurement in 2009 using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the NOAO McMath Telescope at Kitt Peak, AZ are 10–20 K lower. Temperatures retrieved more recently from the SOIR instrument on Venus EXpress are consistent with these results when the geometry of observation is accounted for. It is difficult to compare ground-based sub-mm retrievals extrapolated to 110 km due to their much larger field of view, which includes the night side regions not accessible to infrared heterodyne observations. Temperature variability appears to be high on day-to-day as well as longer timescales. Observed short term and long term variability may be attributed to atmospheric dynamics, diurnal variability and changes over solar activity and seasons. The Venus International Reference Atmosphere (VIRA) model predicts cooler temperatures at the sampled altitudes in the lower thermosphere/upper mesosphere and is not consistent with these measurements. 相似文献